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    • 7. 发明授权
    • Catalyzation of thermoset resin adhesives for wood composites using computerized in-line metering and mixing equipment
    • 使用计算机化的在线计量和混合设备催化用于木材复合材料的热固性树脂粘合剂
    • US06607619B1
    • 2003-08-19
    • US09528509
    • 2000-03-17
    • Millard E. FouchtRobert A. Breyer
    • Millard E. FouchtRobert A. Breyer
    • B27N306
    • B27D1/04B27N3/06
    • The present invention provides a process and system for the manufacture of wood-based composites that implement feedback adjusted in-line addition of a curing accelerator/catalyst to a thermosetting resin adhesive based on at least one of: present moisture content of the wood substrate being bonded and the temperature of the wood substrate being bonded. The method includes: measuring the flow rate of a flowing stream of resin adhesive; measuring the flow rate of a flowing stream of accelerator/catalyst; mixing the flowing stream of accelerator/catalyst and the flowing stream of resin adhesive to form a mixed catalyzed resin adhesive in a proportion of resin adhesive and accelerator/catalyst determined by said flow rates; applying the mixed catalyzed resin adhesive to the wood substrate in an application area; measuring a present moisture content and a present temperature of the wood substrate prior to applying the mixed catalyzed resin adhesive thereto; varying on a continuous basis, the proportion of the accelerator/catalyst and resin adhesive in the mixed catalyzed resin adhesive in accordance with at least one of the present moisture content and the present temperature and bonding together said wood substrate to form said wood-based composite.
    • 本发明提供一种用于制造基于木质基复合材料的方法和系统,其基于以下至少一种实现固化促进剂/催化剂在线加成固化促进剂/催化剂的反应:木质底物的含水量 粘合和粘合的木质基材的温度。 该方法包括:测量树脂粘合剂流动流的流速; 测量加速器/催化剂流动流的流量; 将流动的加速剂/催化剂流与树脂粘合剂的流动流混合,以由所述流速确定的树脂粘合剂和促进剂/催化剂的比例形成混合催化树脂粘合剂; 将混合催化的树脂粘合剂施加到应用区域中的木质基材上; 在将混合催化的树脂粘合剂施加到其之前测量木质基材的当前水分含量和当前温度; 根据本发明的水分含量和当前温度中的至少一种,连续地改变加速剂/催化剂和树脂粘合剂在混合催化树脂粘合剂中的比例,并将所述木质基材粘合在一起以形成所述木质基复合材料 。
    • 10. 发明授权
    • Co-catalyst system for preparing polyurethane based plywood-patch
compositions
    • 用于制备聚氨酯基胶合板 - 贴剂组合物的助催化剂体系
    • US5011902A
    • 1991-04-30
    • US430048
    • 1989-11-01
    • Millard E. Foucht
    • Millard E. Foucht
    • C08G18/22
    • C08G18/22C08G18/227
    • A plywood-patching composition is provided based on a non-cellular polyurethane elastomer prepared by reacting a polyether or polyester polyol with a polyisocyanate in the presence of a catalytic amount of a co-catalyst system comprising an organo-bismuth compound, preferably a bismuth salt of a carboxylic acid, and at least one organo-metallic compound, preferably a metal salt of a carboxylic acid, wherein the metal is selected from the group consisting of zinc, antimony and lithium and wherein the bismuth and metal are present in an effective mole ratio; and process for preparing same. The catalysts utilized are relatively non-toxic, yet they promote rapid polymerization with essentially no foaming for a wide variety of non-cellular polyurethane elastomeric applications, particularly in plywood-patch applications where even small amounts of foaming are deleterious to the properties thereof.
    • 提供了一种基于非聚氨酯弹性体制备的非聚氨酯弹性体组合物,其通过使聚醚或聚酯多元醇与多异氰酸酯在催化量的助催化剂体系存在下反应制备,所述助催化剂体系包含有机铋化合物,优选铋盐 的羧酸和至少一种有机金属化合物,优选羧酸的金属盐,其中金属选自锌,锑和锂,其中铋和金属存在于有效的摩尔中 比; 及其制备方法。 所使用的催化剂是相对无毒的,但它们促进快速聚合,对于多种非细胞聚氨酯弹性体应用基本上不起泡,特别是在其中甚至少量发泡对其性质有害的胶合板贴片应用中。