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1. 发明授权

US3932473A Process for the manufacture of 1-nitro-anthraquinone 失效
标题翻译：制备1-硝基 - 蒽醌的方法
公开(公告)号：US3932473A
公开(公告)日：1976-01-13
申请号：US353001
申请日：1973-04-20
申请人： Erich Klauke , Reinhold Schmitz , Hans-Samuel Bien
发明人： Erich Klauke , Reinhold Schmitz , Hans-Samuel Bien
IPC分类号： C07C205/47 , C07C20060101 , C07C67/00 , C07C201/00 , C09B1/00 , C07C79/37
CPC分类号： C07C205/47
摘要： Pure 1-nitro-anthraquinone is produced by nitrating anthraquinone in aqueous hydrogen fluoride containing about 5 - 30 weight percent of water with nitric acid as nitrating agent at about 0.degree. - 150.degree.C preferably 20.degree. - 70.degree.C.
摘要翻译：通过在约0-150℃，优选20-70℃下，用硝酸作为硝化剂，将含有约5-30重量％水的氟化氢水溶液中的蒽醌硝化作为硝基化蒽醌。

2. 发明授权

US4007164A Azo dyestuffs containing 6-fluoro-pyrimidinyl 4-reactive group 失效
标题翻译：含有6-氟 - 嘧啶基-4-反应性基团的偶氮染料
公开(公告)号：US4007164A
公开(公告)日：1977-02-08
申请号：US129598
申请日：1971-03-30
申请人： Hans-Samuel Bien , Erich Klauke
发明人： Hans-Samuel Bien , Erich Klauke
IPC分类号： C09B62/20 , C09B62/22 , C09B62/24 , D06P1/38 , D06P3/66
CPC分类号： C09B62/20
摘要： Reactive dyestuffs of the formula ##STR1## in which D is the radical of an organic dyestuff, e.g. an azo dyestuff; R is hydrogen or lower alkyl; O is a bridge member, e.g. --SO.sub.2 --; n is the number 0 or 1; R.sub.1 is hydrogen or a substituent; R.sub.2 is hydrogen, optionaly substituted alkyl, alkenyl, aralkyl or aryl; and F is fluoro; are disclosed. These dyestuffs are suitable for dyeing textile materials containing hydroxyl groups or nitrogen, e.g. cellulose and wool. The dyeings have excellent fastness properties especially wet processing fastness.
摘要翻译：其中D是有机染料的基团的式（IMAGE）的反应性染料，例如，偶氮染料 R是氢或低级烷基; O是桥梁，例如 -SO2-; n是数字0或1; R1是氢或取代基; R2是氢，任选取代的烷基，烯基，芳烷基或芳基; F为氟; 被披露。这些染料适用于染色含有羟基或氮的纺织品，例如染色。纤维素和羊毛。染色具有优异的坚牢度特性，特别是湿加工牢度。

3. 发明授权

US4115378A Water soluble reactive axodyestuffs containing a fluorotriazinyl group attached via a nitrogen bridge to the dyestuff molecule 失效
标题翻译：含有通过氮桥连接到染料分子上的含氟三嗪基的水溶性反应性轴质药物
公开(公告)号：US4115378A
公开(公告)日：1978-09-19
申请号：US151149
申请日：1971-06-08
申请人： Hans-Samuel Bien , Erich Klauke , Klaus Wunderlich
发明人： Hans-Samuel Bien , Erich Klauke , Klaus Wunderlich
IPC分类号： C09B62/04 , C09B62/06 , C09B62/08 , C09B62/10
CPC分类号： C09B62/04
摘要： Reactive dyestuffs are disclosed having the formula ##STR1## in which D is the radical of an organic nonanthraquinoid dyestuff; R is hydrogen or a lower alkyl; R.sub.1 is amino or substrated amino with substituents attached by a single bond, optionally etherified hydroxy, optionally etherified mercapto or an optionally substituted hydrocarbon radical; Q is an alkylene, aralkylene, arylene, --CO-- or --SO-- which is directly linked to a carbon atom of the ring of the dyestuff D; n is the number 0 or 1 and F is a fluoro substituent. The group --N(R) is directly linked to a carbon atom of the triazine ring and on the other side, the group --N(R) is linked to a carbon atom of the ring of the dyestuff D either directly (if n = 0) or (if n = 1) via one of the bridge members mentioned above. These dyestuffs are primarily suitable for dyeing of textile materials containing hydroxyl or nitrogen such as natural and regenerated cellulose, wood silk, polyamide and polyurethane. The fastness properties, particularly wet fastness, are excellent.
摘要翻译：公开了具有式“IMAGE”的反应性染料，其中D是有机非蒽醌染料的基团; R是氢或低级烷基; R1是具有通过单键连接的取代基的氨基或亚基氨基，任选醚化的羟基，任选醚化的巯基或任选取代的烃基; Q是与染料D的环的碳原子直接连接的亚烷基，亚芳基，亚芳基，-CO-或-SO-; n为0或1，F为氟取代基。基团-N（R）直接连接到三嗪环的碳原子上，另一方面，基团-N（R）直接连接到染料D的环的碳原子上（如果n = 0）或（如果n = 1）。这些染料主要适用于染色含有羟基或氮的纺织材料，如天然纤维素和再生纤维素，木丝，聚酰胺和聚氨酯。坚牢度，特别是耐湿牢度优异。

4. 发明授权

US4206306A Reactive phthalocyanine dyestuffs containing a fluorotriazinyl group attached via a nitrogen bridge to the dyestuff molecule 失效
标题翻译：含有通过氮桥连接到染料分子上的氟三嗪基的反应性酞菁染料
公开(公告)号：US4206306A
公开(公告)日：1980-06-03
申请号：US871494
申请日：1978-01-23
申请人： Hans-Samuel Bien , Erich Klauke , Klaus Wunderlich
发明人： Hans-Samuel Bien , Erich Klauke , Klaus Wunderlich
IPC分类号： C09B62/04 , C09B47/04 , C09B62/10 , D06P1/382 , D06P3/66
CPC分类号： C09B62/04
摘要： Reactive dyestuffs are disclosed having the formula ##STR1## in which D is the radical of an organic nonanthraquinoid dyestuff; R is hydrogen or lower alkyl; R.sub.1 is amino or substituted amino with substituents attached by a single bond, optionally etherified hydroxy, optionally etherified mercapto or an optionally substituted hydrocarbon radical; Q is an alkylene, aralkylene, arylene, --CO-- or --SO-- which is directly linked to a carbon atom of the ring of the dyestuff D; n is the number 0 or 1 and F is a fluoro substituent. The group --N(R) is directly linked to a carbon atom of the triazine ring and on the other side, the group --N(R) is linked to a carbon atom of the ring of the dyestuff D either directly (if n=0) or (if n=1) via one of the bridge members mentioned above. These dyestuffs are primarily suitable for dyeing of textile materials containing hydroxyl or nitrogen such as natural and regenerated cellulose, wood, silk, polyamide and polyurethane. The fastness properties, particularly wet fastness, are excellent.
摘要翻译：公开了具有式“IMAGE”的反应性染料，其中D是有机非蒽醌染料的基团; R是氢或低级烷基; R1是具有通过单键连接的取代基的氨基或取代的氨基，任选醚化的羟基，任选醚化的巯基或任选取代的烃基; Q是与染料D的环的碳原子直接连接的亚烷基，亚芳基，亚芳基，-CO-或-SO-; n为0或1，F为氟取代基。基团-N（R）直接连接到三嗪环的碳原子上，另一方面，基团-N（R）直接连接到染料D的环的碳原子上（如果n = 0）或（如果n = 1）。这些染料主要适用于染色含有羟基或氮的纺织材料，如天然和再生纤维素，木材，丝绸，聚酰胺和聚氨酯。坚牢度，特别是耐湿牢度优异。

5. 发明授权

US4045457A Anthraquinone dyestuffs 失效
标题翻译：蒽醌染料
公开(公告)号：US4045457A
公开(公告)日：1977-08-30
申请号：US624292
申请日：1975-10-20
申请人： Gunter Gehrke , Reinold Schmitz , Hans-Samuel Bien , Helmut Herzog
发明人： Gunter Gehrke , Reinold Schmitz , Hans-Samuel Bien , Helmut Herzog
IPC分类号： C09B1/503 , C09B1/515 , C09B1/10
CPC分类号： C09B1/503 , C09B1/515
摘要： The invention relates to a process for the preparation of water-insoluble chlorine-containing diaminodihydroxyanthraquinone dyestuffs. The process consists in that 2,8-dichloro-1,5-dinitroanthraquinone and/or 2,5-dichloro-1,8-dinitroanthraquinone is warmed with sulphur in concentrated sulphuric acid having a maximum SO.sub.3 content of 20% - possibly in the presence of boric acid - the resulting compounds are, if appropriate, post-halogenated and/or alkylated, preferably in the same reaction batch.The main advantage of this process is that it starts from 1,6- and/or 1,7-dichloroanthraquinone, for which there was hitherto no industrial use, but which unavoidably also arise during the synthesis 1,5- and 1,8-dichloroanthraquinones.
摘要翻译：本发明涉及一种制备水不溶性含氯二氨基二羟基蒽醌染料的方法。该方法是将2,8-二氯-1,5-二硝基蒽醌和/或2,5-二氯-1,8-二硝基蒽醌与SO 2含量最高为20％的浓硫酸硫化 - 可能在硼酸的存在 - 如果合适的话，所得化合物是后卤化和/或烷基化的，优选在相同的反应批料中。

6. 发明授权

US4000167A Nitroanthraquinones 失效
标题翻译： NITROANTHRAQUINONES
公开(公告)号：US4000167A
公开(公告)日：1976-12-28
申请号：US431713
申请日：1974-01-08
申请人： Walter Hohmann , Helmut Herzog , Hans-Samuel Bien
发明人： Walter Hohmann , Helmut Herzog , Hans-Samuel Bien
IPC分类号： C07C67/00 , C07C201/00 , C07C205/47 , C09B1/28 , C09B1/515 , C09B1/16
CPC分类号： C09B1/28 , Y10S8/921 , Y10S8/922 , Y10S8/929 , Y10S8/933
摘要： Compounds of the formula ##SPC1##In which R represents an alkyl, alkenyl, cycloalkyl or aralkyl radical, one X represents a nitro group and the other X represents hydrogen and their mixtures. They are very suitable for the dyeing of synthetic fibres, such as fibres of polyesters.

7. 发明授权

US3989450A Nitroanthraquinones 失效
标题翻译：硝基蒽醌
公开(公告)号：US3989450A
公开(公告)日：1976-11-02
申请号：US431710
申请日：1974-01-08
申请人： Walter Hohmann , Helmut Herzog , Hans-Samuel Bien
发明人： Walter Hohmann , Helmut Herzog , Hans-Samuel Bien
IPC分类号： C09B1/32 , D06P1/20 , D06P1/90 , C09B1/00
CPC分类号： D06P1/908 , C09B1/32 , Y10S8/921 , Y10S8/922
摘要： Process for dyeing and printing synthetic fiber materials using compounds of the formula ##SPC1##In whichR represents an optionally substituted phenyl radical, as well as special new dyestuffs within the above formula.
摘要翻译：使用式IN的化合物对合成纤维材料进行染色和印刷的方法，其中R表示任选取代的苯基，以及上述式中的特殊新型染料。

8. 发明授权

US4065446A Reactive dyestuffs containing urea alkylene linkage between chromophore and reactive radical 失效
标题翻译：活性染料在发色团和反应性基团之间含有脲亚烷基键
公开(公告)号：US4065446A
公开(公告)日：1977-12-27
申请号：US237920
申请日：1972-03-24
申请人： Hans-Samuel Bien , Wolfgang Harms
发明人： Hans-Samuel Bien , Wolfgang Harms
IPC分类号： C09B62/00 , C09B62/20 , C09B62/22 , C09B62/24 , C09B62/26
CPC分类号： C09B62/00
摘要： Dyestuffs are disclosed having the formula ##STR1## in which W is a reactive radical;D is the radical of an organic dyestuff;X.sub.1 is hydrogen or alkyl;X.sub.2 and X.sub.3 are hydrogen, alkyl, cycloalkyl, aralkyl or aryl; or X.sub.2 and X.sub.3 together are alkylene;Alkylene is C.sub.1 -C.sub.6 -alkylene or cycloalkylene; and n is 0 or 1.The dyestuffs are used in the dyeing of textile materials containing hydroxyl groups and nitrogen, especially natural and regenerated cellulose, wool, silk, synthetic polyamide fibers and synthetic polyurethane. The dyeings obtained are, in general, distinguished by good to very good fastness properties, especially by excellent wet fastness.
摘要翻译：公开了具有其中W是反应性基团的式“IMAGE”的染料; D是有机染料的基团; X1是氢或烷基; X 2和X 3是氢，烷基，环烷基，芳烷基或芳基; 或X2和X3一起是亚烷基; 亚烷基是C1-C6-亚烷基或亚环烷基; n为0或1。

9. 发明授权

US4024144A Polycyclic dyestuffs 失效
标题翻译：多环染料
公开(公告)号：US4024144A
公开(公告)日：1977-05-17
申请号：US578770
申请日：1975-05-19
申请人： Manfred Groll , Volker Hederich , Hans-Samuel Bien
发明人： Manfred Groll , Volker Hederich , Hans-Samuel Bien
IPC分类号： C07D471/06 , C07D487/04 , C09B57/12 , C09B57/00 , C07D487/06
CPC分类号： C07D471/06 , C07D487/04 , C09B57/12
摘要： Polycyclic dyestuffs free from sulphonic acid groups of the formula ##STR1## in which A denotes an arylene radical andB--so.sub.2 --or denotes an arylene radical substituted by an aryloxysulphonyl group,Are suitable for dyeing organic materials, especially for dyeing and printing hydrophobic fibre materials and for bulk-dyeing synthetic materials.
摘要翻译：不含磺酸基团的多环染料，其中A表示亚芳基，B-SO2-OR表示被芳基磺酰基取代的亚芳基，适用于染色有机材料，特别用于染色和印刷疏水性纤维材料与大理石合成材料。

10. 发明授权

US4162946A Process for concentrating halogenoanthraquinones 失效
标题翻译：浓缩卤代蒽醌的方法
公开(公告)号：US4162946A
公开(公告)日：1979-07-31
申请号：US829848
申请日：1977-09-01
申请人： Bernd Thelen , Norbert Majer , Reinold Schmitz , Hans-Samuel Bien
发明人： Bernd Thelen , Norbert Majer , Reinold Schmitz , Hans-Samuel Bien
IPC分类号： B01D3/10 , B01D3/14 , B01D3/28 , C07C49/68
CPC分类号： B01D3/10 , B01D3/146 , B01D3/148
摘要： A process for concentrating at least one of (a) individual halogenoanthraquinones (b) binary mixtures of di-halogenoanthraquinones and (c) binary mixtures of trihalogenoanthraquinones, from a mixture containing at least two halogenoanthraquinones, comprising subjecting said mixture containing at least two halogenoanthraquinones to fractional vacuum distillation in a heated rectification column having an efficiency corresponding to about 20 to 50 theoretical stages with an absolute pressure at the top of about 0.5 to 50 mm Hg and a reflux to take-off ratio of about 5/1 to 50/1. Advantageously, distillation is carried out continuously in a cascade of columns, the products withdrawn from the top of the first column being 2-chloroanthraquinone in the first stage, 1-chloroanthraquinone in the second stage, 1,6- and 1,7-dichloroanthraquinone in the third stage and 1,5- and 1,8-dichloroanthraquinone in the fourth stage, 1,4,5- and 1,4,6-trichloroanthraquinone being obtained in the sump of the 4th stage and being separated therefrom by film evaporation. The mixture of halogenoanthraquinones is advantageously a mixture of chloroanthraquinones such as is obtained by the action of chlorine, chloric acid or a chlorate on various industrial mixtures of nitro- or sulfo-anthraquinones.
摘要翻译：从（a）各个卤代蒽醌（b）二卤代蒽醌的二元混合物和（c）三卤代蒽醌的二元混合物中的至少一种，从含有至少两种卤代蒽醌的混合物中浓缩至少一种方法，包括将含有至少两种卤代蒽醌的所述混合物在加热精馏塔中的分馏真空蒸馏，其具有对应于约20至50个理论级的效率，顶部的绝对压力为约0.5至50mm Hg，回流与起飞比为约5/1至50/1 。有利地，在级联塔中连续进行蒸馏，在第一阶段从第一塔顶部取出的2-氯蒽醌，第二阶段的1-氯蒽醌，1,6-和1,5-二氯蒽醌在第四阶段和第四阶段的1,5-和1,8-二氯蒽醌中，在第4阶段的贮槽中获得1,4,5-和1,4,6-三氯蒽醌，并通过薄膜蒸发与其分离。卤代蒽醌的混合物有利地是氯蒽醌的混合物，例如通过氯，氯酸或氯酸盐在硝基或磺基 - 蒽醌的各种工业混合物上的作用获得的。

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