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1. 发明授权

US4024144A Polycyclic dyestuffs 失效
标题翻译：多环染料
公开(公告)号：US4024144A
公开(公告)日：1977-05-17
申请号：US578770
申请日：1975-05-19
申请人： Manfred Groll , Volker Hederich , Hans-Samuel Bien
发明人： Manfred Groll , Volker Hederich , Hans-Samuel Bien
IPC分类号： C07D471/06 , C07D487/04 , C09B57/12 , C09B57/00 , C07D487/06
CPC分类号： C07D471/06 , C07D487/04 , C09B57/12
摘要： Polycyclic dyestuffs free from sulphonic acid groups of the formula ##STR1## in which A denotes an arylene radical andB--so.sub.2 --or denotes an arylene radical substituted by an aryloxysulphonyl group,Are suitable for dyeing organic materials, especially for dyeing and printing hydrophobic fibre materials and for bulk-dyeing synthetic materials.
摘要翻译：不含磺酸基团的多环染料，其中A表示亚芳基，B-SO2-OR表示被芳基磺酰基取代的亚芳基，适用于染色有机材料，特别用于染色和印刷疏水性纤维材料与大理石合成材料。

2. 发明授权

US3932419A Quinophthalone dyestuffs 失效
标题翻译：喹酞酮染料
公开(公告)号：US3932419A
公开(公告)日：1976-01-13
申请号：US363990
申请日：1973-05-25
申请人： Manfred Groll , Volker Hederich , Hans-Samuel Bien
发明人： Manfred Groll , Volker Hederich , Hans-Samuel Bien
IPC分类号： C08K5/00 , C08K5/3432 , C08L23/00 , C08L33/00 , C08L33/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09B25/00 , D06P1/16
CPC分类号： C09B25/00
摘要： Quinophthalone dyestuffs of the formula ##SPC1##In which Ac denotes an acyl radical, X denotes a non-ionic substituent, Y denotes hydrogen or halogen and n denotes a number from 0 to 3 as well as their production and their use for dyeing and printing organic materials.
摘要翻译：喹喔啉酮染料，其中Ac表示酰基，X表示非离子取代基，Y表示氢或卤素，n表示0至3的数，以及它们的生产及其用于染色和印刷有机材料的用途。

3. 发明授权

US4101551A Quinophthalone dyestuffs 失效
标题翻译：喹酞酮染料
公开(公告)号：US4101551A
公开(公告)日：1978-07-18
申请号：US702045
申请日：1976-07-02
申请人： Manfred Groll , Hans-Samuel Bien, deceased
发明人： Manfred Groll , Hans-Samuel Bien, deceased
IPC分类号： C09B25/00 , C09B62/523 , C07D215/22
CPC分类号： C09B62/523 , C09B25/00 , Y10S8/922 , Y10S8/924
摘要： The invention relates to water-insoluble quinophthalone dyestuffs of the formula ##STR1## in which T represents W--Ar or ##STR2## and Ar denotes aryl,W denotes oxygen, sulphur or N--R,R denotes hydrogen or alkyl,A denotes alkylene, O R.sub.1 denotes alkyl or aryl,R.sub.2 denotes hydrogen or alkyl,X denotes halogen, alkyl, alkoxy, nitro or acylamino,Y denotes hydrogen or halogen,Z denotes hydrogen, alkyl or halogen andn denotes a number from 0 to 3The new dyestuffs and their mixtures are distinguished by good affinity to polyester fibres and good general fastness properties.
摘要翻译：本发明涉及式“IMAGE”的水不溶性喹酞酮染料，其中T代表W-Ar或者“IMA”，Ar表示芳基，W表示氧，硫或NR，R表示氢或烷基，A表示亚烷基，O R1表示烷基或芳基，R2表示氢或烷基，X表示卤素，烷基，烷氧基，硝基或酰氨基，Y表示氢或卤素，Z表示氢，烷基或卤素，N表示0至3的数字新染料和它们的混合物通过对聚酯纤维的亲和力和良好的通用牢度性质来区分。

4. 发明授权

US4537721A Cu-Pc dyestuffs 失效
标题翻译： Cu-Pc染料
公开(公告)号：US4537721A
公开(公告)日：1985-08-27
申请号：US561609
申请日：1983-12-14
申请人： Manfred Groll , Dieter Ockelmann
发明人： Manfred Groll , Dieter Ockelmann
IPC分类号： C09B47/26 , C09B47/32
CPC分类号： C09B47/32
摘要： Basic copper phthalocyanine dyestuffs of the general formula ##STR1## in which Cu-Pc denotes the radical of an m+n-valent copper phthalocyanine radical,A denotes alkyleneB denotes a radical of the formula ##STR2## R.sub.1 denotes hydrogen or alkyl, R.sub.2, R.sub.3 and R.sub.4, independently of one another, denote alkyl which can be substituted by hydroxyl or alkoxy groups,R.sub.5 denotes hydrogen, alkyl or aminoalkyl,R.sub.6 and R.sub.7, independently of each other, denote hydrogen or alkyl which can be substituted by hydroxyl, alkoxy or amino groups, andR.sub.8 denotes hydrogen or alkyl, orR.sub.1 can form a closed ring with R.sub.2,R.sub.2 can form a closed ring with R.sub.3,R.sub.5 can form a closed ring with R.sub.6 and/orR.sub.6 can form a closed ring with R.sub.7,m denotes a number from 1.0 to 2.5,n denotes a number from 0 to 1.4,wherem+n is 1.8 to 2.5,p denotes 0, 1, 2 or 3 andX.sup.(-) denotes an anion,are used for dyeing paper.
摘要翻译：基本铜酞菁染料，其中Cu-Pc表示m + n价铜酞菁基团的基团，A表示亚烷基B表示下式的基团铜酞菁染料，其中，R表示氢或烷基，R2，R3和R4彼此独立地表示可以被羟基或烷氧基取代的烷基，R5表示氢，烷基或氨基烷基，R6和R7彼此独立地表示氢或可被取代的烷基由羟基，烷氧基或氨基组成，R8表示氢或烷基，或R1可以与R2形成闭环，R2可以与R3形成闭环，R5可与R6和/或R6形成闭环，可形成封闭用R7表示环，m表示1.0〜2.5的数，n表示0〜1.4的数，m + n为1.8〜2.5，p表示0,1,2或3，X（ - ）表示阴离子用于染色纸。

5. 发明授权

US3989692A Reactive dyestuffs 失效
标题翻译：活性染料
公开(公告)号：US3989692A
公开(公告)日：1976-11-02
申请号：US490008
申请日：1974-07-19
申请人： Horst Jager , Manfred Groll
发明人： Horst Jager , Manfred Groll
IPC分类号： C09B62/016 , C07D203/12 , C09B47/04
CPC分类号： C09B62/016
摘要： Phthalocyanine reactive dyestuffs of the formula ##SPC1##Wherein Pc, R.sub.1, R.sub.2, R.sub.3 -R.sub.5, a, b and c and Z have the meaning given in the description. They are outstandingly suitable for dyeing and printing materials containing cellulose, such as natural and regenerated cellulose, in accordance with the techniques known for the purpose. The new dyestuffs are also suitable for dyeing materials containing amide groups, such as wool, silk and synthetic polyamides. Dyeings obtained on textile cellulose, in particular, distinguish themselves by very good fastness properties, especially fastness to light and to wet processing.
摘要翻译：式+ q，10，其中Pc，R1，R2，R3-R5，a，b和c和Z的酞菁活性染料具有说明书中给出的含义。根据目的已知的技术，它们非常适合于含有纤维素的染色和印刷材料，例如天然和再生纤维素。新的染料也适用于含有酰胺基团的染色材料，如羊毛，丝绸和合成聚酰胺。特别是通过纺织纤维素获得的染色，通过非常好的牢度性质，特别是耐光牢度和湿法加工来区别。

6. 发明授权

US5163971A Dyestuff mixtures of metal phthalocyanine and pyridone azo reactive dyes 失效
标题翻译：金属酞菁和吡咯烷酮偶氮染料的混合物
公开(公告)号：US5163971A
公开(公告)日：1992-11-17
申请号：US701249
申请日：1991-05-16
申请人： Josef-Walter Stawitz , Frank-Michael Stohr , Manfred Groll , Karl-Josef Herd , Karl-Heinz Schundehutte, deceased
发明人： Josef-Walter Stawitz , Frank-Michael Stohr , Manfred Groll , Karl-Josef Herd , Karl-Heinz Schundehutte, deceased
IPC分类号： C09B67/22 , D06P1/38 , D06P3/04 , D06P3/60
CPC分类号： C09B67/0041 , C09B67/0042 , Y10S8/917 , Y10S8/918 , Y10S8/924
摘要： Dyestuff mixtures containing one or more dyestuffs of the formula ##STR1## and one or more dyestuffs of the formula ##STR2## in which the substituents have the meanings given in the description are highly suitable for producing green cotton dyeings.
摘要翻译：含有一种或多种式（I）的染料和一种或多种式（II）的染料的染料混合物其中取代基具有本说明书中给出的含义非常适合于生产绿色棉花染色。

7. 发明授权

US5051501A Reactive phthalocyanine dyestuffs containing a fluorochloropyrimidinyl group 失效
标题翻译：含有氟氯嘧啶基的反应性酞菁染料
公开(公告)号：US5051501A
公开(公告)日：1991-09-24
申请号：US431969
申请日：1989-11-06
申请人： Karl H. Schundehutte , Manfred Groll , Josef W. Stawitz
发明人： Karl H. Schundehutte , Manfred Groll , Josef W. Stawitz
IPC分类号： C09B62/26
CPC分类号： C09B62/26
摘要： Novel reactive dyestuffs of the formula ##STR1## wherein Pc=radical of a Cu- or Ni-phthalocyanine,R.sub.1, R.sub.2 =H, C.sub.1 -C.sub.4 -alkyl optionally substituted with --OH, --COOH, --OSO.sub.3 H or --SO.sub.3 H, or together C.sub.2 -alkylene,B=C.sub.2 -C.sub.6 -alkylene or phenylene optionally substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, halogen, nitro, cyano, COOH, SO.sub.3 H, carboxanide, sulphonamide, C.sub.1 -C.sub.4 -alkylcarbonylamino or --NHCONH.sub.2,R.sub.3, R.sub.4 =H, C.sub.1 -C.sub.4 -alkyl optionally substituted with OH, --COOH, --OSO.sub.3 H or --SO.sub.3 H, or optionally sulphur- or carboxyl-substituted phenyl, or together C.sub.2 -alkylene,a=1.0 to 2.7,b=0.8 to 1.2, andc=0.5 to 1.5, where a+b+c=3 to 4.
摘要翻译：式（1）的新型活性染料其中Pc = Cu-或Ni-酞菁的基团，R1，R2 = H，任选被-OH，-COOH，-OSO3H或-SO3H取代的C1-C4-烷基或C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，卤素，硝基，氰基，COOH，SO 3 H，甲酰胺，磺酰胺，C 1 -C 4 - 烷基羰基氨基或-NHCONH 2，R 3，R 4 = H，任选被OH，-COOH，-OSO 3 H或-SO 3 H取代的C 1 -C 4 - 烷基，或任选的硫或羧基取代的苯基，或一起为C 2-亚烷基，a = 1.0至2.7 ，b = 0.8〜1.2，c = 0.5〜1.5，其中a + b + c = 3〜4。

8. 发明授权

US4286962A Phthalocyanine reactive dyestuffs, their preparation and their use for dyeing materials containing hydroxyl groups or amide groups 失效
标题翻译：酞菁活性染料，它们的制备及其用于含有羟基或酰胺基团的染料的用途
公开(公告)号：US4286962A
公开(公告)日：1981-09-01
申请号：US108312
申请日：1979-12-31
申请人： Volker Ehrig , Manfred Groll , Klaus Wunderlich
发明人： Volker Ehrig , Manfred Groll , Klaus Wunderlich
IPC分类号： C09B62/10
CPC分类号： C09B62/10 , Y10S8/917 , Y10S8/918 , Y10S8/919
摘要： Dyestuffs of the formula ##STR1## wherein the substituents have the meaning indicated in the description,and their use for dyeing and printing materials containing hydroxyl groups or amide groups, such as textile fibres, filaments and fabrics of wool, silk or synthetic polyamide or polyurethane fibres and for dyeing and printing natural or regenerated cellulose with dyeings and prints which are fast to washing.The dyeings obtained with the dyestuffs are distinguished by good to very good fastness properties, in particular by outstanding fastness to wet processing.
摘要翻译：具有式（IMAGE）的染料，其中取代基具有说明书中指出的含义，以及它们用于染色和印刷含有羟基或酰胺基的材料，例如纺织纤维，长丝和羊毛，丝绸或合成聚酰胺或聚氨酯的织物纤维和用于染色和印刷具有快速洗涤的染色和印花的天然或再生纤维素。用染料获得的染色的特征在于良好至非常好的坚牢度性质，特别是通过优异的湿润处理牢度。

9. 发明授权

US4282000A Dyestuff solutions, their preparation and their use for dyeing paper 失效
标题翻译：染料溶液，其制备及其用于染色纸的用途
公开(公告)号：US4282000A
公开(公告)日：1981-08-04
申请号：US115529
申请日：1980-01-25
申请人： Manfred Groll , Friedhelm Muller
发明人： Manfred Groll , Friedhelm Muller
IPC分类号： C09B69/00 , C09B47/26 , C09B67/26 , C09B69/04 , D21H21/28 , C09B47/08
CPC分类号： C09B69/04 , C09B47/26 , C09B67/0073 , D21H21/28 , Y10S8/919
摘要： Aqueous solutions of copper phthalocyanine-sulphonic acid salts of the formula ##STR1## in which Cu--Pc a copper phthalocyanine radical,m a number from 1.8 to 3.0,q a number from 1.0 to 2.0, with the proviso that the sum m+q is a number from 2.8 to 4.0, andM.sup..sym. a mixture of A.sub.n.sup..sym. and an ammonium ion of the formula ##STR2## wherein A.sup..sym. represents an alkali metal ion or NH.sub.4 ion,n represents a number from 0.8 to 2.0,m has the meaning indicated above,R.sub.1 and R.sub.2 designate hydrogen, C.sub.1 --C.sub.4 --alkyl or a radical --(CH.sub.2 --CH.sub.2 --O).sub.p --H andR.sub.3 designates the radical --(CH.sub.2 --CH.sub.2 --O).sub.p --H,whereinp is 1, 2, 3, 4, 5 or 6,process for the preparation of these solutions and their use for dyeing paper.
摘要翻译：铜酞菁磺酸盐的水溶液，其结构式为“IMAGE”，其中Cu-Pc为铜酞菁基，m为1.8至3。

10. 发明授权

US4277245A Process for dyeing and printing cellulose fibres 失效
标题翻译：染色和印花纤维素纤维的方法
公开(公告)号：US4277245A
公开(公告)日：1981-07-07
申请号：US123866
申请日：1980-02-22
申请人： Manfred Groll , Werner Kuhnel , Robert Kuth
发明人： Manfred Groll , Werner Kuhnel , Robert Kuth
IPC分类号： C09B47/24 , D06P1/14 , D06P3/60 , D06P3/82
CPC分类号： D06P3/8228 , C09B47/24 , D06P1/14 , D06P3/6041 , Y10S8/918
摘要： In order to dye and print cellulose fibres swollen with water-miscible swelling agents or fibre blends containing these fibres, the fibres are treated with a dyestuff of the general formula ##STR1## wherein Pc denotes the radical of a Cu phthalocyanine,Ni phthalocyanine or Co phthalocyanine molecule,Ar denotes aryl,Z.sup.(+) denotes a hydrogen ion, an alkali metal ion or an ammonium ion,Hal denotes chlorine or bromine,x denotes a number from 2 to 4,y denotes 0 or 1 andx+y.ltoreq.4, andz denotes a number from 0 to 4,and the dyestuff is fixed by heat treatment.
摘要翻译：为了染色和印刷与水混溶性溶胀剂或含有这些纤维的纤维混合物溶胀的纤维素纤维，纤维用通式为“IMAGE”的染料处理，其中Pc表示Cu酞菁，Ni酞菁或Co的基团酞菁分子，Ar表示芳基，Z（+）表示氢离子，碱金属离子或铵离子，Hal表示氯或溴，x表示2至4的数，y表示0或1，x + y < / = 4，z表示0〜4的数，通过热处理固定染料。

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