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    • 4. 发明授权
    • Water soluble crosslinked ethyleneimine grafted polyamidoamine
    • 水溶性交联乙烯亚胺接枝聚酰胺胺
    • US4371674A
    • 1983-02-01
    • US173479
    • 1980-07-30
    • Otto HertelEmil ScharfJaroslav MelzerRolf Fikentscher
    • Otto HertelEmil ScharfJaroslav MelzerRolf Fikentscher
    • C08G81/00C08G69/48D21H17/55D21H17/56
    • C08G69/48
    • Process for the production of water-soluble auxiliaries for the papermaking industry by reacting(a) 1 part by weight of a polyamidoamine obtained by condensing 1 mole of a dicarboxylic acid having from 4 to 10 carbon atoms with from 0.8 to 1.4 moles of a polyalkylene polyamine having from 3 to 10 alkyleneamine units and containing up to 8 ethyleneimine units per basic nitrogen atom with (b) 0.1 to 4 parts by weight of an .alpha.,.omega.-dichloro polyalkylene oxide obtained by reacting a polyalkylene oxide having from 8 to 100 alkylene oxide units with a compound selected from the group consisting of a thionyl chloride and phosgene and then cleaving the reaction products by heating them to a temperature of from 70.degree. to 150.degree. C. in the presence of a tertiary amine as catalyst,as crosslinking agent, at a temperature above 20.degree. C. in aqueous solution or in a water-soluble organic solvent, the reaction being carried out to a point at which the viscosity of an aqueous solution containing 20% by weight of auxiliary is from 300 to 2,500 mPas.
    • 通过使(a)通过将1重量份通过将1摩尔具有4至10个碳原子的二羧酸缩合得到的聚酰胺胺与0.8至1.4摩尔聚亚烷基二醇来制备用于造纸工业的水溶性助剂的方法 多胺具有3至10个亚烷基胺单元并且每个碱性氮原子含有至多8个亚乙基亚胺单元,和(b)0.1至4重量份通过使具有8至100个亚烷基的聚环氧烷反应获得的α,ω-二氯聚环氧烷 氧化物单元与选自亚硫酰氯和光气的化合物反应,然后在作为催化剂的叔胺的存在下将反应产物加热至70℃至150℃的温度,作为交联剂 在水溶液或水溶性有机溶剂中在20℃以上的温度下进行反应,直至水溶液的粘度为 20重量%的助剂为300至2,500mPas。