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1. 发明授权

US07053250B1 Method of preparing a polyether polyol 失效
标题翻译：制备聚醚多元醇的方法
公开(公告)号：US07053250B1
公开(公告)日：2006-05-30
申请号：US11110286
申请日：2005-04-20
申请人： Edward M. Dexheimer , Jacob Wildeson , Werner Hinz
发明人： Edward M. Dexheimer , Jacob Wildeson , Werner Hinz
IPC分类号： C07C43/18 , C08G59/02
CPC分类号： C08G65/2663 , B01J27/26 , B01J35/023 , B01J37/009 , B01J37/343
摘要： An improved method for synthesizing a double metal cyanide (DMC) catalyst combines and sonicates aqueous and non-aqueous solutions of a first metal salt, such as Zn(OAc)2, of a second metal salt, such as CoCl2, and of an alkali metal cyanide, such as NaCN, to synthesize the DMC catalyst, Zn3[Co(CN)6]2. An improved method of producing a polyether polyol uses the DMC catalyst to produce the polyol.
摘要翻译：合成双金属氰化物（DMC）催化剂的改进方法将第二金属盐的第一金属盐（例如Zn（OAc）2 N）的水溶液和非水溶液合并并超声处理，作为CoCl 2 N，以及碱金属氰化物如NaCN，合成DMC催化剂，Zn 3 [Co（CN）6 N' 2 。制备聚醚多元醇的改进方法使用DMC催化剂制备多元醇。

2. 发明授权

US07671228B2 Method of forming a polyethercarbonate polyol using a CO2-philic compound or substituent 失效
标题翻译：使用CO 2亲本化合物或取代基形成聚醚碳酸酯多元醇的方法
公开(公告)号：US07671228B2
公开(公告)日：2010-03-02
申请号：US11092107
申请日：2005-03-29
申请人： Werner Hinz , Jacob Wildeson , Edward M. Dexheimer
发明人： Werner Hinz , Jacob Wildeson , Edward M. Dexheimer
IPC分类号： C07C69/96
CPC分类号： C08G64/34 , C08G64/183
摘要： A method of forming a polyethercarbonate polyol enhances incorporation of CO2 into the polyethercarbonate polyol. The method provides a catalyst including a multimetal cyanide compound. An H-functional initiator, an alkylene oxide, and CO2 are reacted in the presence of the multimetal cyanide compound in a reactor. The method further provides a CO2-philic compound or a CO2-philic substituent. The CO2-philic compound and substituent enhance incorporation of the CO2 into the polyethercarbonate polyol and reduce formation of cyclic alkylene carbonates, such as cyclic propylene carbonate, which are undesirable byproducts.
摘要翻译：形成聚醚碳酸酯多元醇的方法增强了将CO 2引入到聚醚碳酸酯多元醇中。该方法提供了包含多金属氰化合物的催化剂。在多元氰化物化合物的存在下，在反应器中使H官能引发剂，烯化氧和CO 2反应。该方法还提供了一种二氧化碳亲和化合物或二氧化碳亲油取代基。二氧化碳亲和化合物和取代基增强了CO 2在聚醚碳酸酯多元醇中的引入，并且减少了环状碳酸亚烷基酯的形成，例如环丙烯碳酸酯，这是不期望的副产物。

3. 发明授权

US07268204B2 Complex of a multimetal cyanide compound and methods of forming polyethercarbonate polyols 失效
标题翻译：多金属氰化合物的复合物和形成聚醚碳酸酯多元醇的方法
公开(公告)号：US07268204B2
公开(公告)日：2007-09-11
申请号：US11091981
申请日：2005-03-29
申请人： Werner Hinz , Jacob Wildeson , Edward M. Dexheimer
发明人： Werner Hinz , Jacob Wildeson , Edward M. Dexheimer
IPC分类号： C08G64/00
CPC分类号： B01J27/26 , B01J31/04 , B01J31/1691 , B01J31/1805 , B01J31/2239 , B01J35/0006 , B01J35/023 , B01J2531/0205 , B01J2531/16 , B01J2531/26 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08G64/34
摘要： A method of forming a polyethercarbonate polyol enhances incorporation of CO2 into the polyethercarbonate polyol. The method provides a catalyst including a multimetal cyanide compound. The multimetal cyanide compound has an ordered structure defined by a cationic catalytic center and an anionic backbone with the anionic backbone spatially arranged about the cationic catalytic center. The anionic backbone is modified with a supplemental anionic spacer to affect the spatial arrangement and catalytic activity of the cationic catalytic center. The supplemental anionic spacer is incorporated into the multimetal cyanide compound to establish the general formula, M1a[M2b(CN)cMd3Xe]f, wherein M1, M2, and M3 are various metal ions and X is the supplemental anionic spacer. An H-functional initiator, an alkylene oxide, and CO2 are reacted in the presence of the modified multimetal cyanide compound to form the polyethercarbonate polyol.
摘要翻译：形成聚醚碳酸酯多元醇的方法增强了CO 2 CO 2向聚醚碳酸酯多元醇中的引入。该方法提供了包含多金属氰化合物的催化剂。多金属氰化合物具有由阳离子催化中心和阴离子主链定义的有序结构，阴离子主链在阳离子催化中心周围空间布置。阴离子主链用补充阴离子间隔物修饰以影响阳离子催化中心的空间排列和催化活性。将补充的阴离子间隔物掺入多金属氰化物化合物中以建立通式，其中M 1，（CN）其中C 1，C 2，C 3，...， M 1，M 2和M 3是各种金属离子，X是补充阴离子间隔物。在改性的多金属氰化物化合物的存在下，使H官能引发剂，烯化氧和CO 2 2反应形成聚醚碳酸酯多元醇。

4. 发明授权

US06921737B1 Method of synthesizing a double metal cyanide catalyst 失效
标题翻译：合成双金属氰化物催化剂的方法
公开(公告)号：US06921737B1
公开(公告)日：2005-07-26
申请号：US10853814
申请日：2004-05-26
申请人： Edward M. Dexheimer , Jacob Wildeson , Werner Hinz
发明人： Edward M. Dexheimer , Jacob Wildeson , Werner Hinz
IPC分类号： B01J27/26 , B01J35/02 , B01J37/00 , B01J37/34 , C08G64/34 , C08G65/26
CPC分类号： C08G65/2663 , B01J27/26 , B01J35/023 , B01J37/009 , B01J37/343
摘要： An improved method for synthesizing a double metal cyanide (DMC) catalyst combines and sonicates aqueous and non-aqueous solutions of a first metal salt, such as Zn(OAc)2, of a second metal salt, such as CoCl2, and of an alkali metal cyanide, such as NaCN, to synthesize the DMC catalyst, Zn3[Co(CN)6]2. An improved method of producing a polyether polyol uses the DMC catalyst to produce the polyol.
摘要翻译：合成双金属氰化物（DMC）催化剂的改进方法将第二金属盐的第一金属盐（例如Zn（OAc）2 N）的水溶液和非水溶液合并并超声处理，作为CoCl 2 N，以及碱金属氰化物如NaCN，合成DMC催化剂，Zn 3 [Co（CN）6 N' 2 。制备聚醚多元醇的改进方法使用DMC催化剂制备多元醇。

5. 发明申请

US20060223972A1 Complex of a multimetal cyanide compound and methods of forming polyethercarbonate polyols 失效
标题翻译：多金属氰化合物的复合物和形成聚醚碳酸酯多元醇的方法
公开(公告)号：US20060223972A1
公开(公告)日：2006-10-05
申请号：US11091981
申请日：2005-03-29
申请人： Werner Hinz , Jacob Wildeson , Edward Dexheimer
发明人： Werner Hinz , Jacob Wildeson , Edward Dexheimer
IPC分类号： C08G64/00
CPC分类号： B01J27/26 , B01J31/04 , B01J31/1691 , B01J31/1805 , B01J31/2239 , B01J35/0006 , B01J35/023 , B01J2531/0205 , B01J2531/16 , B01J2531/26 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C08G64/34
摘要： A method of forming a polyethercarbonate polyol enhances incorporation of CO2 into the polyethercarbonate polyol. The method provides a catalyst including a multimetal cyanide compound. The multimetal cyanide compound has an ordered structure defined by a cationic catalytic center and an anionic backbone with the anionic backbone spatially arranged about the cationic catalytic center. The anionic backbone is modified with a supplemental anionic spacer to affect the spatial arrangement and catalytic activity of the cationic catalytic center. The supplemental anionic spacer is incorporated into the multimetal cyanide compound to establish the general formula, M1a[M2b(CN)cMd3Xe]f, wherein M1, M2, and M3 are various metal ions and X is the supplemental anionic spacer. An H-functional initiator, an alkylene oxide, and CO2 are reacted in the presence of the modified multimetal cyanide compound to form the polyethercarbonate polyol.
摘要翻译：形成聚醚碳酸酯多元醇的方法增强了CO 2 CO 2向聚醚碳酸酯多元醇中的引入。该方法提供了包含多金属氰化合物的催化剂。多金属氰化合物具有由阳离子催化中心和阴离子主链定义的有序结构，阴离子主链在阳离子催化中心周围空间布置。阴离子主链用补充阴离子间隔物修饰以影响阳离子催化中心的空间排列和催化活性。将补充的阴离子间隔物掺入多金属氰化物化合物中以建立通式M 1，（CN）其中C 1，C 2，C 3，...， M 1，M 2和M 3是各种金属离子，X是补充阴离子间隔物。在改性的多金属氰化物化合物的存在下，使H官能引发剂，烯化氧和CO 2 2反应形成聚醚碳酸酯多元醇。

6. 发明申请

US20060224010A1 Method of forming a polyether-carbonate polyol using a CO2-philic compound or substituent 失效
标题翻译：使用CO 2亲本化合物或取代基形成聚醚 - 碳酸酯多元醇的方法
公开(公告)号：US20060224010A1
公开(公告)日：2006-10-05
申请号：US11092107
申请日：2005-03-29
申请人： Werner Hinz , Jacob Wildeson , Edward Dexheimer
发明人： Werner Hinz , Jacob Wildeson , Edward Dexheimer
IPC分类号： C07C69/96
CPC分类号： C08G64/34 , C08G64/183
摘要： A method of forming a polyethercarbonate polyol enhances incorporation of CO2 into the polyethercarbonate polyol. The method provides a catalyst including a multimetal cyanide compound. An H-functional initiator, an alkylene oxide, and CO2 are reacted in the presence of the multimetal cyanide compound in a reactor. The method further provides a CO2-philic compound or a CO2-philic substituent. The CO2-philic compound and substituent enhance incorporation of the CO2 into the polyethercarbonate polyol and reduce formation of cyclic alkylene carbonates, such as cyclic propylene carbonate, which are undesirable byproducts.
摘要翻译：形成聚醚碳酸酯多元醇的方法增强了CO 2 CO 2向聚醚碳酸酯多元醇中的引入。该方法提供了包含多金属氰化合物的催化剂。在多元氰化物化合物的存在下，在反应器中使H官能引发剂，烯化氧和CO 2 2反应。该方法还提供了一种CO 2 - 2亲核化合物或一种CO 2 - 二取代基。 CO 2 - 2亲核化合物和取代基增强了CO 2 CO 2在聚醚碳酸酯多元醇中的引入，并且减少环状碳酸亚烷基酯的形成，例如环状碳酸亚丙酯，这是不期望的副产物。

7. 发明授权

US06713599B1 Formation of polymer polyols with a narrow polydispersity using double metal cyanide (DMC) catalysts 失效
标题翻译：使用双金属氰化物（DMC）催化剂形成具有窄多分散性的聚合物多元醇
公开(公告)号：US06713599B1
公开(公告)日：2004-03-30
申请号：US10403197
申请日：2003-03-31
申请人： Werner Hinz , Jacob Wildeson , Edward Michael Dexheimer , Raymond Neff
发明人： Werner Hinz , Jacob Wildeson , Edward Michael Dexheimer , Raymond Neff
IPC分类号： C08G6510
CPC分类号： C08G18/4866 , C08G64/183 , C08G65/2663 , C08G65/2696
摘要： A method of forming a polyol includes the steps of reacting an initiator with an alkylene oxide, and optionally carbon dioxide, in the presence of a double metal cyanide catalyst and a sterically hindered chain transfer agent capable of protonating the growing polyol polymer. The presence of the chain transfer agent reduces the polydispersity of the resultant polyol.
摘要翻译：形成多元醇的方法包括在双金属氰化物催化剂和能够使生长的多元醇聚合物质子化的空间位阻链转移剂的存在下使引发剂与烯化氧和任选的二氧化碳反应的步骤。链转移剂的存在降低所得多元醇的多分散性。

8. 发明授权

US5420170A Preparation of flexible, soft polyurethane foams having viscoelastic, structure-borne soundproofing properties, and polyoxyalkylene-polyol mixtures which can be used for this purpose 失效
标题翻译：制备具有粘弹性，结构隔音性能的柔性，软质聚氨酯泡沫，以及可用于此目的的聚氧化烯 - 多元醇混合物
公开(公告)号：US5420170A
公开(公告)日：1995-05-30
申请号：US619265
申请日：1990-11-28
申请人： Heinz-Dieter Lutter , Reinhard Leppkes , Peter Horn , Walter Decker , Volker Haase , Werner Hinz
发明人： Heinz-Dieter Lutter , Reinhard Leppkes , Peter Horn , Walter Decker , Volker Haase , Werner Hinz
IPC分类号： C08G18/48 , C08G18/66
CPC分类号： C08G18/4804 , C08G18/4841 , C08G18/6674 , C08G2101/0008 , C08G2101/0058 , C08G2101/0083 , C08G2350/00 , Y10S521/914
摘要： The present invention relates to a process for the preparation of flexible, soft polyurethane foams having viscoelastic, structure-borne soundproofing properties in a temperature range of from -20.degree. C. to +80.degree. C. by reactinga) a polyoxyalkylene-polyol mixture containingai) block polyoxypropylene-polyoxyethylene-polyol mixture having a hydroxyl number of from 14 to 65 and containing from 2 to 9% by weight of terminal ethylene oxide units, based on the weight of the polyoxypropylene units, prepared by anionic polymerization, at elevated temperatures, of 1,2-propyleneoxide onto an initiator molecule mixture having a mean functionality of from 2.3 to 2.8, comprising water and glycerol and/or trimethylolpropane, and polymerization of acylene oxide onto the resultant polyoxypropylene adduct, andaii) one or more difunctional and/or trifunctional polyoxypropylene-polyoxyethylene-polyol containing from 60 to 85% by weight of oxyethylene units, based on the total weight of polymerized alkylene oxide units, and having a hydroxyl number of from 20 to 80, andb) if desired low-molecular-weight chain extenders withc) organic and/or modified organic polyisocyanates in the presence ofd) catalysts,e) blowing agents, preferably water, and, if desired,f) auxiliaries and/or additives,and to the polyoxyalkylene-polyol mixtures (a) which can be used for this purpose.
摘要翻译：本发明涉及一种制备柔软的软质聚氨酯泡沫的方法，该泡沫在-20℃至+ 80℃的温度范围内具有粘弹性结构的隔音性能，通过使a）聚氧化烯 - 多元醇混合物含有ai）嵌段聚氧丙烯 - 聚氧乙烯 - 多元醇混合物，羟基数为14至65，并含有2至9重量％的末端环氧乙烷单元，基于通过阴离子聚合制备的聚氧丙烯单元的重量，在升高的温度，1,2-环氧丙烷至平均官能度为2.3至2.8的引发剂分子混合物，包含水和甘油和/或三羟甲基丙烷，以及将芳族氧化物聚合到所得聚氧丙烯加合物上，以及aii）一种或多种双官能和/或含有60至85重量％的氧化乙烯单元的三官能聚氧丙烯 - 聚氧乙烯 - 多元醇，基于聚合的Al的总重量环氧乙烷单元，羟值为20至80，和b）如果需要，在d）催化剂存在下，c）有机和/或改性有机多异氰酸酯的低分子增链剂，e）发泡剂，如果需要，f）助剂和/或添加剂，以及可用于该目的的聚氧化烯 - 多元醇混合物（a）。

9. 发明授权

US5340916A Polyoxypropylene-polyols and polyoxypropylene-polyoxyethylene-polyols containing hydroxyl groups 失效
标题翻译：含有羟基的聚氧丙烯 - 多元醇和聚氧丙烯 - 聚氧乙烯 - 多元醇
公开(公告)号：US5340916A
公开(公告)日：1994-08-23
申请号：US966228
申请日：1992-10-26
申请人： Rolf Henn , Werner Hinz , Ludwig Schuster , Klaus Vorspohl
发明人： Rolf Henn , Werner Hinz , Ludwig Schuster , Klaus Vorspohl
IPC分类号： C08G18/48 , C08G65/26 , C08G65/28 , C07C43/10 , C08G65/08
CPC分类号： C08G18/4816 , C08G18/4829 , C08G65/2606 , C08G2101/0025 , C08G2101/005 , C08G2105/02 , Y10S521/902
摘要： The present invention relates to a process for the preparation of a hard foam containing urethane groups or urethane and isocyanurate groups by the polyisocyanate polyaddition process, by reactinga) a polyoxypropylene- or polyoxyethylene-polyoxypropylene-polyol containing secondary hydroxyl groups, having a functionality of from 3.5 to 4.3, a hydroxyl number of from 350 to 650 and a viscosity of from 500 to 2,500 mPa.multidot.s at 23.degree. C. and prepared by anionic polymerization of 1,2-propylene oxide or ethylene oxide and 1,2-propylene oxide onto an initiator molecule mixture containing, based on the total weight,a1) from 40 to 80% by weight of a hexanetetrol,a2) from 1 to 30% by weight of a hexanetriol,a3) from 0 to 35% by weight of glycerol anda4) from 0 to 15% by weight of sorbitol or mannitol, or a mixture thereof,b) optionally, a low-molecular-weight chain extender and/or crosslinking agent withc) an organic, modified or unmodified polyisocyanate; in the presence ofd) a blowing agent,e) a catalyst and, optionally,f) assistants and/or additives, and novel polyoxypropylene-polyols and polyoxyethylene-polyoxypropylene-polyols which can be used for this purpose.
摘要翻译：本发明涉及通过使a）具有仲羟基的聚氧丙烯或聚氧乙烯 - 聚氧丙烯 - 多元醇，具有官能度的官能度的方法，通过多异氰酸酯加聚方法制备含有氨基甲酸酯基团或聚氨酯和异氰脲酸酯基团的硬质泡沫的方法， 3.5至4.3，羟值为350至650，在23℃下的粘度为500至2500mPax，并通过将1,2-环氧丙烷或环氧乙烷和1,2-环氧丙烷阴离子聚合制备到包含基于总重量的起始分子混合物，a1）为40至80重量％的己烷四醇，a2）1至30重量％的己烷三醇，a3）0至35重量％的甘油和 a4）0至15重量％的山梨糖醇或甘露醇或其混合物，b）任选的低分子量增链剂和/或交联剂，c）有机，改性或未改性的多异氰酸酯; 在d）发泡剂的存在下，e）可以用于此目的的催化剂和任选的f）助剂和/或添加剂，以及新的聚氧丙烯 - 多元醇和聚氧乙烯 - 聚氧丙烯 - 多元醇。

10. 发明授权

US5059633A Preparation of flexible polyurethane foams having low compressive strength and block polyoxypropylenepolyoxyethylenepolyol mixtures which can be used for this purpose 失效
标题翻译：具有低抗压强度的柔性聚氨酯泡沫的制备和可用于该目的的嵌段聚氧丙烯聚氧乙烯多元醇混合物
公开(公告)号：US5059633A
公开(公告)日：1991-10-22
申请号：US619380
申请日：1990-11-28
申请人： Heinz-Dieter Lutter , Werner Hinz , Walter Decker , Reinhard Leppkes , Erhard Reich , Reinhard Peters , Volker Haase , Michael Lugmayr
发明人： Heinz-Dieter Lutter , Werner Hinz , Walter Decker , Reinhard Leppkes , Erhard Reich , Reinhard Peters , Volker Haase , Michael Lugmayr
IPC分类号： C08G18/48 , C08G18/72 , C08G65/26 , C08G65/28 , C08G101/00 , C08J9/00
CPC分类号： C08G18/4841 , C08G18/4837 , C08G65/2624 , C08G2101/0008 , C08G2101/0083 , Y10S521/914
摘要： Flexible polyurethane foams having low compressive strength and relatively good tensile strength are prepared by reactinga) a block polyoxypropylenepolyoxyethylenepolyol mixture which has a hydroxyl number of from 14 to 65, contains from 2 to 9% by weight, based on the weight of the polyoxypropylene units, of ethylene oxide units bonded in the terminal position and is prepared by anionic polymerization of the alkylene oxides with an initiator mixture having an average functionality of from 2.3 to 2.8 and consisting of water and glycerol and/or trimethylolpropane, or a mixture of these block polyoxypropylenepolyoxyethylenepolyol mixtures with bi- and/or trifunctional polyoxypropylenepolyoxyethylenepolyols having a hydroxyl number of from 20 to 70, andb) if required, low molecular weight chain extenders withc) organic and/or modified organic polyisocyanates in the presence ofd) catalysts,e) blowing agents, preferably water, and if required,f) assistants and/or additives.
摘要翻译：具有低抗压强度和相对良好拉伸强度的柔性聚氨酯泡沫通过使基于聚氧丙烯单元的重量的羟基数为14至65的嵌段聚氧丙烯聚氧乙烯多元醇混合物反应而制备，所述混合物含有2至9重量％的环氧乙烷单元，其结合在末端位置，并且通过环氧烷烃与平均官能度为2.3至2.8的引发剂混合物的阴离子聚合制备，并由水和甘油和/或三羟甲基丙烷组成，或这些嵌段具有羟基数为20至70的双官能和/或三官能聚氧丙烯聚氧乙烯多元醇的聚氧丙烯聚氧乙烯多元醇混合物，以及b）如果需要，在d）催化剂存在下，c）有机和/或改性有机多异氰酸酯的低分子量增链剂，e ）发泡剂，优选水，如果需要，f）助剂和/或添加剂。

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