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1. 发明授权

US06232276B1 Trinuclear molybdenum multifunctional additive for lubricating oils 失效
标题翻译：用于润滑油的三核钼多功能添加剂
公开(公告)号：US06232276B1
公开(公告)日：2001-05-15
申请号：US08844019
申请日：1997-04-18
申请人： Edward Ira Stiefel , Jonathan M. McConnachie , Daniel Paul Leta , Manuel A. Francisco , Catherine Louise Coyle , Peter John Guzi , Charles F. Pictroski
发明人： Edward Ira Stiefel , Jonathan M. McConnachie , Daniel Paul Leta , Manuel A. Francisco , Catherine Louise Coyle , Peter John Guzi , Charles F. Pictroski
IPC分类号： C10M13900
CPC分类号： C07F11/005 , C10M135/18 , C10M137/10 , C10M159/18 , C10M2219/068 , C10M2223/045 , C10M2227/09 , C10N2210/06 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A lubricating oil composition is provided comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one trinuclear molybdenum compound. Preferably, the trinuclear molybdenum compound is selected from those compounds having the formula Mo3SkL4Qz and mixtures thereof in which L is a ligand having organo groups with a sufficient number of carbon atoms to render the compound soluble in the oil, k varies from 4 through 7, Q is selected from the group of compounds having lone pair electrons including water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5. In general, the organo groups of the mono-anionic ligands will be the same although they may be different, and they preferably are selected from alkyl, aryl, substituted aryl, and ether groups. For example, when L is a dialkyldithiocarbamate or a dialkyldithiophosphate, the alkyl groups will have from about 1 to 30 carbon atoms.
摘要翻译：提供润滑油组合物，其包含主要量的润滑粘度的油和少量的至少一种三核钼化合物。优选地，三核钼化合物选自具有式Mo 3 S k L 4 Q z的那些化合物及其混合物，其中L是具有足够数目碳原子的有机基团的配体，以使化合物可溶于油，k从4至7变化， Q选自具有包括水，胺，醇，膦和醚在内的单对电子的化合物的组，z的范围为0至5.通常，单阴离子配体的有机基团将是相同的，尽管它们可以不同，它们优选选自烷基，芳基，取代的芳基和醚基。例如，当L是二烷基二硫代氨基甲酸酯或二烷基二硫代磷酸酯时，烷基将具有约1至30个碳原子。

2. 发明申请

US20090240640A1 Apparatus and method for predicting engine test performance from bench test data 审中-公开
标题翻译：从台架试验数据预测发动机试验性能的装置和方法
公开(公告)号：US20090240640A1
公开(公告)日：2009-09-24
申请号：US12381803
申请日：2009-03-17
申请人： David Alan Blain , Liepao Oscar Farng , Manuel A. Francisco , Glenn A. Murgacz , Peter A. Gordon , Eugenio Sanchez
发明人： David Alan Blain , Liepao Oscar Farng , Manuel A. Francisco , Glenn A. Murgacz , Peter A. Gordon , Eugenio Sanchez
IPC分类号： G06F15/18 , B01J19/00 , G01N25/00 , G06F1/02
CPC分类号： G01N33/2888 , G01N17/043
摘要： An apparatus for evaluating deposit formation characteristics of lubricant samples. The apparatus includes a reactor chamber having a closed first end and a second end, said closed first end of said reactor chamber forming a lubricant sump and said second end open to the atmosphere, an electric heater for heating a test coupon positioned thereon, said electric heater positioned within said reactor chamber, above said lubricant sump, an air supply tube, said air supply tube having a first end in fluid communication with a source of air and a second end, said second end positioned adjacent the test coupon, said air supply tube having a sample orifice located between said first end and said second end of said air supply tube and a lubricant supply tube, said lubricant supply tube having a first end positioned within said lubricant sump and in fluid communication with a source of lubricant and a second end, said second end positioned within said sample orifice of said air supply tube. A method of predicting lubricant deposit formation in an end use engine test and a method for predicting whether a candidate lubricant sample will pass an End Use Test are also provided.
摘要翻译：用于评估润滑剂样品的沉积物形成特性的装置。该装置包括具有封闭的第一端和第二端的反应室，所述反应器室的所述封闭的第一端形成润滑油槽，而所述第二端敞开于大气;电加热器，用于加热位于其上的试样，所述电位于所述反应器室内的加热器，位于所述润滑油池上方，空气供应管，所述空气供应管具有与空气源流体连通的第一端和第二端，所述第二端邻近测试试样定位，所述空气供应管，其具有位于所述空气供应管的所述第一端和所述第二端之间的样品孔和润滑剂供应管，所述润滑剂供应管具有位于所述润滑油槽内并与润滑剂源流体连通的第一端和第二所述第二端位于所述空气供应管的所述样品孔内。还提供了在最终用途发动机试验中预测润滑剂沉积物形成的方法和预测候选润滑剂样品是否将通过最终用途试验的方法。

3. 发明授权

US5490946A Ashless benzotriazole-thiadiazol compounds as anti-oxidant, anti-wear and friction modifiers in lubricants and the lubricants containing such compounds 失效
标题翻译：无灰苯并三唑 - 噻二唑化合物作为润滑剂中的抗氧化剂，抗磨损和摩擦改性剂以及含有这些化合物的润滑剂
公开(公告)号：US5490946A
公开(公告)日：1996-02-13
申请号：US328206
申请日：1994-10-25
申请人： Morton Beltzer , Manuel A. Francisco , John W. Frankenfeld
发明人： Morton Beltzer , Manuel A. Francisco , John W. Frankenfeld
IPC分类号： C10M135/36 , C10M133/44
CPC分类号： C10M135/36 , C10M2207/123 , C10M2207/129 , C10M2207/22 , C10M2215/064 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10N2210/01 , C10N2240/02 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/14 , C10N2240/40
摘要： Adducts of benzotriazole or substituted benzotriazole with formaldehyde or with thiadiazole or substituted thiadiazole are useful as ashless anti-wear/anti-friction/anti-oxidant additives for lubricants. Formulated lubricants containing such adducts exhibit compound levels of anti-wear, anti-friction and oxidation stability performance.
摘要翻译：苯并三唑或取代的苯并三唑与甲醛或噻二唑或取代的噻二唑的加合物可用作润滑剂的无灰抗磨/抗摩擦/抗氧化添加剂。含有这种加合物的配方润滑剂具有抗磨损，抗摩擦和氧化稳定性能的复合水平。

4. 发明申请

US20070265178A1 Lubricating compositions containing ashless catalytic antioxidant additives 有权
标题翻译：含有无灰催化抗氧化添加剂的润滑组合物
公开(公告)号：US20070265178A1
公开(公告)日：2007-11-15
申请号：US11732326
申请日：2007-04-03
申请人： Abhimanyu O. Patil , Jacob J. Habeeb , Michael E. Landis , Manuel A. Francisco , Manika Varma-Nair
发明人： Abhimanyu O. Patil , Jacob J. Habeeb , Michael E. Landis , Manuel A. Francisco , Manika Varma-Nair
IPC分类号： C10M133/12 , C07C209/10
CPC分类号： C10M133/12 , C07C211/50 , C10M169/04 , C10M2215/066 , C10N2230/10 , C10N2240/08
摘要： The invention comprises lubricating compositions and hydraulic fluids containing N,N′-diaryl-o-phenylenediamine compounds that impart good levels of oxidation inhibition in the lubricants and hydraulic fluids. The invention further comprises a method of making N,N′-diaryl-o-phenylenediamine compounds.
摘要翻译：本发明包括含有N，N'-二芳基邻苯二胺化合物的润滑组合物和液压油，其在润滑剂和液压流体中赋予良好的氧化抑制水平。本发明还包括制备N，N'-二芳基邻苯二胺化合物的方法。

5. 发明授权

US4950386A Acidic promotion of transition metal sulfide catalysts for selective hydrogenation 失效
标题翻译：酸性促进过渡金属硫化物催化剂用于选择性氢化
公开(公告)号：US4950386A
公开(公告)日：1990-08-21
申请号：US231939
申请日：1988-08-15
申请人： Manuel A. Francisco
发明人： Manuel A. Francisco
IPC分类号： C10G45/46
CPC分类号： C10G45/46
摘要： It has now been discovered that hydrocarbon feeds containing a polycyclic aromatic compound or mixtures thereof can be selectively hydrogenated by contacting the feed with a transition metal catalyst and hydrogen in the presence of an acid to provide a hydrocarbon mixture in which the aromatic content consists substantially of mono- and di-aromatic compounds. Useful acids include Lewis acids and acids having a pKa in the range of 0 to about -10.
摘要翻译：现在已经发现，含有多环芳族化合物或其混合物的烃进料可以通过在酸存在下使进料与过渡金属催化剂和氢接触来选择性氢化，以提供烃混合物，其中芳烃含量基本上由单和二芳族化合物。有用的酸包括路易斯酸和pKa在0至约-10范围内的酸。

6. 发明授权

US10035959B2 Slurry hydroconversion using enhanced slurry catalysts 有权
公开(公告)号：US10035959B2
公开(公告)日：2018-07-31
申请号：US14308905
申请日：2014-06-19
申请人： Ramanathan Sundararaman , Thomas Francis Degnan, Jr. , Rustom Merwan Billimoria , Natalie Ann Fassbender , Manuel A. Francisco , Anjaneya Sarma Kovvali , Randolph J. Smiley , John Peter Greeley , William Ernest Lewis , Roby Bearden, Jr.
发明人： Ramanathan Sundararaman , Thomas Francis Degnan, Jr. , Rustom Merwan Billimoria , Natalie Ann Fassbender , Manuel A. Francisco , Anjaneya Sarma Kovvali , Randolph J. Smiley , John Peter Greeley , William Ernest Lewis , Roby Bearden, Jr.
IPC分类号： C10G47/26 , C10G49/06 , C10G49/12 , C10G69/14 , C10G49/04 , C10G69/06 , C10G9/00
CPC分类号： C10G49/12 , C10G9/005 , C10G49/04 , C10G49/06 , C10G69/06 , C10G69/14
摘要： Systems and methods are provided for slurry hydroconversion of a heavy oil feed, such as an atmospheric or vacuum resid. The systems and methods allow for slurry hydroconversion using catalysts with enhanced activity and/or catalysts that can be recycled as a side product from a complementary refinery process.

7. 发明授权

US5422023A Corrosion inhibitor for aviation turbine oils (PNE-628) 失效
标题翻译：航空涡轮机油防腐剂（PNE-628）
公开(公告)号：US5422023A
公开(公告)日：1995-06-06
申请号：US135212
申请日：1993-10-12
申请人： Manuel A. Francisco
发明人： Manuel A. Francisco
IPC分类号： C10M161/00 , C10M169/04 , C10M133/58
CPC分类号： C10M169/044 , C10M161/00 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/2835 , C10M2207/286 , C10M2209/086 , C10M2219/10 , C10M2219/102 , C10M2219/104 , C10M2219/106 , C10M2219/108 , C10N2230/08 , C10N2230/12 , C10N2240/00 , C10N2240/02 , C10N2240/10 , C10N2240/101 , C10N2240/102 , C10N2240/103 , C10N2240/104 , C10N2240/105 , C10N2240/106 , C10N2240/12 , C10N2240/121 , C10N2240/14 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： A lubricating oil composition for jet engines which comprises: (a) an aviation turbine oil; (b) from about 0.025 to about 5.0 wt %, based on lubricating oil composition, of a dimercaptothiadiazole of the formula: ##STR1## where R and R.sup.1 are each independently hydrogen or hydrocarbyl radical having from 1 to 20 carbon atoms; and (c) from about 1.0 to about 30.0 wt %, based on lubricating oil composition, of an alphaolefin/maleic ester copolymer of the formula ##STR2## where R.sup.3 and R.sup.4 are each independently C.sub.1 to C.sub.18 alkyl, and n is an integer such that the average molecular weight of the copolymer is from 500 to 20,000.
摘要翻译：一种用于喷气发动机的润滑油组合物，包括：（a）航空涡轮机油; （b）基于润滑油组合物的约0.025至约5.0重量％的下式的二巯基噻二唑其中R和R 1各自独立地为氢或具有1至20个碳原子的烃基; 和（c）基于润滑油组合物的约1.0至约30.0重量％的式（Ia）的α-烯烃/马来酸酯共聚物，其中R 3和R 4各自独立地为C 1至C 18烷基，n为是共聚物的平均分子量为500〜20,000的整数。

8. 发明授权

US09816039B2 Upgrading heavy oils by selective oxidation 有权
公开(公告)号：US09816039B2
公开(公告)日：2017-11-14
申请号：US14810130
申请日：2015-07-27
申请人： Manuel A. Francisco , Thomas Francis Degnan, Jr. , Colin L. Beswick , Ramanathan Sundararaman
发明人： Manuel A. Francisco , Thomas Francis Degnan, Jr. , Colin L. Beswick , Ramanathan Sundararaman
IPC分类号： C10G67/12 , C10G55/06 , C10G55/04 , C10G27/04 , C10G27/12
CPC分类号： C10G67/12 , C10G27/04 , C10G27/12 , C10G55/04 , C10G55/06 , C10G2300/1033 , C10G2300/1077 , C10G2300/1096
摘要： A heavy petroleum oil feed is upgraded by having its amenability to cracking improved by subjecting the oil to selective partial oxidation with a catalytic oxidation system to partially oxidize aromatic ring systems in the heavy oil. The partially oxidized oil can then be cracked in the conventional manner but at lower severities to lower molecular weight cracking products. The cracking following the partial oxidation step may be thermal in nature as by thermal cracking, delayed, contact or fluid coking or fluid catalytic cracking or hydrogenative as in hydrocracking.

9. 发明申请

US20160060550A1 UPGRADING HEAVY OILS BY SELECTIVE OXIDATION 有权
标题翻译：通过选择性氧化提升重油
公开(公告)号：US20160060550A1
公开(公告)日：2016-03-03
申请号：US14810130
申请日：2015-07-27
申请人： Manuel A. Francisco , Thomas Francis DEGNAN, JR. , Colin L. BESWICK , Ramanathan SUNDARARAMAN
发明人： Manuel A. Francisco , Thomas Francis DEGNAN, JR. , Colin L. BESWICK , Ramanathan SUNDARARAMAN
IPC分类号： C10G67/12 , C10G55/04 , C10G55/06
CPC分类号： C10G67/12 , C10G27/04 , C10G27/12 , C10G55/04 , C10G55/06 , C10G2300/1033 , C10G2300/1077 , C10G2300/1096
摘要： A heavy petroleum oil feed is upgraded by having its amenability to cracking improved by subjecting the oil to selective partial oxidation with a catalytic oxidation system to partially oxidize aromatic ring systems in the heavy oil. The partially oxidized oil can then be cracked in the conventional manner but at lower severities to lower molecular weight cracking products. The cracking following the partial oxidation step may be thermal in nature as by thermal cracking, delayed, contact or fluid coking or fluid catalytic cracking or hydrogenative as in hydrocracking.
摘要翻译：重油石油进料通过使其通过用催化氧化体系进行选择性部分氧化以部分氧化重油中的芳香环体系来改善其改性的改性。然后部分氧化的油可以以常规方式裂解，但是在较低的严重程度下破坏较低分子量的裂化产物。在部分氧化步骤之后的裂化本质上可以是热裂解，延迟的，接触的或流体的焦化或流化催化裂化或加氢裂化中的氢化。

10. 发明授权

US08734639B2 Upgrading of petroleum resid, bitumen or heavy oils by the separation of asphaltenes and/or resins therefrom using ionic liquids 有权
标题翻译：通过使用离子液体分离沥青质和/或树脂来升级石油渣，沥青或重油
公开(公告)号：US08734639B2
公开(公告)日：2014-05-27
申请号：US12080179
申请日：2008-04-01
申请人： Michael Siskin , Manuel A. Francisco , Rustom M. Billimoria
发明人： Michael Siskin , Manuel A. Francisco , Rustom M. Billimoria
IPC分类号： C10G29/20
CPC分类号： C10G21/003 , C10G21/06
摘要： Petroleum resid, bitumen and/or heavy oil is upgraded by the separation of asphaltenes and/or resins from such resids, bitumen and/or heavy oils by contacting them with an ionic liquid with which the asphaltenes and/or resins interact.
摘要翻译：沥青和/或重油通过将沥青质和/或树脂与沥青质和/或重质油与沥青质和/或树脂相互作用的离子液体接触而从这些沥青，沥青和/或重油中分离得到提高。

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