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1. 发明授权

US06569820B2 Manufacture of lubricant additives 有权
标题翻译：制造润滑油添加剂
公开(公告)号：US06569820B2
公开(公告)日：2003-05-27
申请号：US09816053
申请日：2001-03-23
申请人： Jonathan M. McConnachie , Ian A. W. Bell , Edward I. Stiefel , Stanley J. Brois , Ernestine W. Hill , Alisdair J. Brown
发明人： Jonathan M. McConnachie , Ian A. W. Bell , Edward I. Stiefel , Stanley J. Brois , Ernestine W. Hill , Alisdair J. Brown
IPC分类号： C10M13900
CPC分类号： C10M159/18 , C07F11/005 , C10M135/18 , C10M2219/068 , C10M2227/09 , C10N2210/06 , C10N2240/08 , C10N2270/02
摘要： Oil-soluble or oil-dispersible trinuclear molybdenum-sulfur compounds are made by reacting, in a polar medium, a reactant molybdenum compound containing an anion that possesses a trinuclear molybdenum core, and a dithiocarbamate that is produced in situ.
摘要翻译：通过在极性介质中使含有具有三核钼核的阴离子的反应物钼化合物和原位产生的二硫代氨基甲酸酯反应制备油溶性或油分散性三核钼硫化合物。

2. 发明授权

US06358894B1 Molybdenum-antioxidant lube oil compositions 失效
标题翻译：钼抗氧化润滑油组合物
公开(公告)号：US06358894B1
公开(公告)日：2002-03-19
申请号：US08969277
申请日：1997-11-13
申请人： Daniel Paul Leta , Jonathan M. McConnachie , Edward Ira Stiefel , Charles Frederick Pictroski , Kathleen Marie Creegan
发明人： Daniel Paul Leta , Jonathan M. McConnachie , Edward Ira Stiefel , Charles Frederick Pictroski , Kathleen Marie Creegan
IPC分类号： C10M13900
CPC分类号： C10M135/18 , C07F11/005 , C10M137/10 , C10M159/18 , C10M2219/068 , C10M2223/045 , C10M2227/09 , C10N2210/06 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： The invention relates to lubricating oil compositions of a major amount of an oil of lubricating viscosity in admixture with an effective minor amount of an oil soluble or dispersible trinuclear molybdenum containing complex and of an antioxidant, preferably, copper containing antioxidants and diphenyl amines and effective diphenylamine derivatives to enhance the lubricating properties of the oil. Also included are additive concentrates containing these compositions. The invention further includes the method of making these compositions.
摘要翻译：本发明涉及主要量的具有润滑粘度的油的润滑油组合物与有效少量的油溶性或可分散的含有三核钼的络合物和抗氧化剂，优选含有铜的抗氧化剂和二苯胺和有效的二苯胺衍生物以增强油的润滑性能。还包括含有这些组合物的添加剂浓缩物。本发明还包括制备这些组合物的方法。

3. 发明授权

US5837657A Method for reducing viscosity increase in sooted diesel oils 失效
标题翻译：减少柴油柴油粘度增加的方法
公开(公告)号：US5837657A
公开(公告)日：1998-11-17
申请号：US982681
申请日：1997-12-02
申请人： Howard L. Fang , Jonathan M. McConnachie , Edward Ira Stiefel
发明人： Howard L. Fang , Jonathan M. McConnachie , Edward Ira Stiefel
IPC分类号： C10M135/18 , C10M137/10 , C10M159/18 , C10M135/00 , C10M139/00
CPC分类号： C10M159/18 , C10M135/18 , C10M137/10 , C10M2219/068 , C10M2223/045 , C10M2227/09 , C10N2210/06 , C10N2240/102 , C10N2240/103
摘要： The present invention is directed to a method for improving the performance of a sooted diesel oil and controlling soot induced viscosity increase by adding to a major amount of a diesel oil a minor amount of a composition comprising at least one compound having the formula Mo.sub.3 S.sub.k L.sub.n Q.sub.z and mixtures thereof wherein the L are independently selected ligands having organo groups with a sufficient number of carbon atoms to render the compound soluble or dispersible in the oil, n is from 1 to 4, k varies from 4 through 10, Q is selected from the group of neutral electron donating compounds such as water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5 and includes nonstoichiometric values.
摘要翻译：本发明涉及一种通过向主要量的柴油中加入少量含有至少一种具有式Mo3SkLnQz的化合物的组合物和混合物的混合物来提高烟灰柴油的性能并控制烟灰诱导的粘度增加的方法其中L是具有足够数目的碳原子的具有有机基团的独立选择的配体，以使化合物在油中可溶或可分散，n为1至4，k从4至10变化，Q选自中性给电子化合物如水，胺，醇，膦和醚，z范围为0至5，并包括非化学计量值。

4. 发明授权

US5372798A Fullerene compositions and preparation 失效
标题翻译：富勒烯组成和制备
公开(公告)号：US5372798A
公开(公告)日：1994-12-13
申请号：US207645
申请日：1994-03-08
申请人： Jonathan M. McConnachie , Edward I. Stiefel
发明人： Jonathan M. McConnachie , Edward I. Stiefel
IPC分类号： C01B19/00 , C01B31/02 , C01B31/00 , C01B7/00 , C01B17/00
CPC分类号： B82Y30/00 , B82Y40/00 , C01B19/002 , C01B31/0206 , C01B31/0213 , C01P2002/76 , C01P2002/77 , C01P2006/10 , Y10S423/39 , Y10S977/737
摘要： The invention relates to a composition that is the reaction of a fullerene containing at least one corrannulene ring structure and Y.sub.2 X.sub.2, wherein Y is Se or S, and X is Cl or Br. Generally, these compounds may be represented by the formula C.sup.f.sub.n X.sub.6 Y.sub.2 or more particularly C.sup.f.sub.n X.sub.5 (YYX). In the formula C.sup.f.sub.n more specifically, is a fullerene having at least one corrannulene ring structure. The compositions may be made by reacting fullerenes with Se.sub.2 X.sub.2 or S.sub.2 X.sub.2 wherein X is Cl or Br, preferably in liquid form and preferably heated for a time sufficient to produce the novel compositions. The compositions may be isolated in crystalline form by precipitation with a solvent such as hexane. In crystalline form the compositions may be represented by the generic formula C.sup.f.sub.n X.sub.8 Y.sub.4, or more particularly, C.sup.f.sub.n X.sub.5 (YYX).mY.sub.2 X.sub.2 because in crystalline form the compositions are typically associated with .mY.sub.2 X.sub.2 molecules wherein m is an integer at least equal to 1. The compositions have utility as crosslinking agents and lubricating oil and polymer additives, particularly as vulcanizing agents.
摘要翻译：本发明涉及一种组合物，其是含有至少一个corrannulene环结构的富勒烯与Y2X2的反应，其中Y为Se或S，X为Cl或Br。通常，这些化合物可以由式CfnX6Y2或更特别是CfnX5（YYX）表示。在式Cfn中更具体地，是具有至少一个corrannulene环结构的富勒烯。组合物可以通过使富勒烯与Se2X2或S2X2反应制备，其中X是Cl或Br，优选液体形式，优选加热足以产生新组合物的时间。组合物可以通过用溶剂如己烷沉淀而以结晶形式分离。在结晶形式中，组合物可以由通式CfnX8Y4，或更具体地，CfnX5（YYX）.YYX2X2表示，因为在结晶形式中，组合物通常与.mY2X2分子缔合，其中m是至少等于1的整数。组合物可用作交联剂和润滑油和聚合物添加剂，特别是作为硫化剂。

5. 发明授权

US08216958B2 Selective catalysts having silica supports for naphtha hydrodesulfurization 有权
标题翻译：具有用于石脑油加氢脱硫的二氧化硅载体的选择性催化剂
公开(公告)号：US08216958B2
公开(公告)日：2012-07-10
申请号：US12087978
申请日：2007-01-12
申请人： Jason Wu , Chuansheng Bai , Thomas R. Halbert , Stuart L. Soled , Sabato Miseo , Jonathan M. McConnachie , Valery Sokolovskii , David M. Lowe , Anthony F. Volpe, Jr. , Jun Han
发明人： Jason Wu , Chuansheng Bai , Thomas R. Halbert , Stuart L. Soled , Sabato Miseo , Jonathan M. McConnachie , Valery Sokolovskii , David M. Lowe , Anthony F. Volpe, Jr. , Jun Han
IPC分类号： B01J31/34 , B01J21/08 , C10G45/08
CPC分类号： C10G45/08 , B01J21/08 , B01J23/882 , B01J31/04 , B01J31/1805 , B01J31/181 , B01J31/183 , B01J31/2208 , B01J35/10 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J35/1066 , B01J37/0009 , B01J37/0203 , B01J37/20 , C10G2300/1044 , C10G2300/202 , C10G2300/207 , C10G2300/4018 , C10G2300/80 , C10G2400/02
摘要： A method for hydrodesulfurizing FCC naphtha is described. More particularly, a Co/Mo metal hydrogenation component is loaded on a silica or modified silica support in the presence of organic ligand and sulfided to produce a catalyst which is then used for hydrodesulfurizing FCC naphtha. The silica support has a defined pore size distribution which minimizes olefin saturation.
摘要翻译：描述了FCC石脑油加氢脱硫方法。更具体地说，在有机配体存在下将Co / Mo金属氢化组分负载在二氧化硅或改性二氧化硅载体上并硫化以产生催化剂，然后将其用于加氢脱硫FCC石脑油。二氧化硅载体具有确定的最小化烯烃饱和度的孔径分布。

6. 发明申请

US20110147273A1 DESULFURIZATION PROCESS USING ALKALI METAL REAGENT 有权
标题翻译：使用碱金属试剂进行脱硫工艺
公开(公告)号：US20110147273A1
公开(公告)日：2011-06-23
申请号：US12967425
申请日：2010-12-14
申请人： Jorge L. Soto , Michael Raterman , Daniel P. Leta , Walter D. Vann , Lu Han , Jonathan M. McConnachie , James R. Bielenberg , William C. Baird, JR. , Roby Bearden, JR.
发明人： Jorge L. Soto , Michael Raterman , Daniel P. Leta , Walter D. Vann , Lu Han , Jonathan M. McConnachie , James R. Bielenberg , William C. Baird, JR. , Roby Bearden, JR.
IPC分类号： C10G19/02
CPC分类号： C10G29/06 , C10G19/02
摘要： Hydrocarbon feedstreams are desulfurized using an alkali metal reagent, optionally in the presence of hydrogen. Improved control over reaction conditions can be achieved in part by controlling the particle size of the alkali metal salt and by using multiple desulfurization reactors. After separation of the spent alkali metal reagent, the resulting product can have suitable characteristics for pipeline transport and/or further refinery processing.
摘要翻译：碳氢化合物原料流可以使用碱金属试剂任选在氢的存在下进行脱硫。可以通过控制碱金属盐的粒度和使用多个脱硫反应器来部分改善对反应条件的控制。在分离废碱金属试剂后，所得产物可具有用于管道运输和/或进一步精炼加工的合适特性。

7. 发明申请

US20100084316A1 Desulfurization of heavy hydrocarbons and conversion of resulting hydrosulfides utilizing a transition metal oxide 有权
标题翻译：使用过渡金属氧化物对重质烃进行脱硫和转化所得氢硫化物
公开(公告)号：US20100084316A1
公开(公告)日：2010-04-08
申请号：US12586824
申请日：2009-09-29
申请人： James R. Bielenberg , Jonathan M. McConnachie , Daniel P. Leta , Chris A. Wright , Leo D. Brown
发明人： James R. Bielenberg , Jonathan M. McConnachie , Daniel P. Leta , Chris A. Wright , Leo D. Brown
IPC分类号： C10G45/04 , C10G19/08
CPC分类号： C10G19/08
摘要： The present invention is a process for desulfurizing hydrocarbon feedstreams with alkali metal compounds and regenerating the alkali metal compounds via the use of a transition metal oxide. The present invention employs the use of a transition metal oxide, preferably copper oxide, in order to convert spent alkali metal hydrosulfides in the regeneration of the alkali hydroxide compounds for reutilization in the desulfurization process for the hydrocarbon feedstreams. Additionally, in preferred embodiments of the processes disclosed herein, carbonates which may be detrimental to the overall desulfurization process and related equipment are removed from the regenerated alkali metal stream.
摘要翻译：本发明是一种用碱金属化合物对烃类进料流进行脱硫和通过使用过渡金属氧化物再生碱金属化合物的方法。本发明使用过渡金属氧化物，优选氧化铜，以便在碱性氢氧化物化合物的再生中转化废碱金属氢硫化物，以便在烃进料流的脱硫过程中再利用。另外，在本文公开的方法的优选实施方案中，可从再生的碱金属流中除去可能对整个脱硫过程和相关设备有害的碳酸盐。

8. 发明申请

US20090159500A1 Electrodesulfurization of heavy oils 有权
标题翻译：重油的电脱硫
公开(公告)号：US20090159500A1
公开(公告)日：2009-06-25
申请号：US12288564
申请日：2008-10-21
申请人： Mark A. Greaney , Chris A. Wright , Jonathan M. McConnachie , Howard Freund , Kun Wang
发明人： Mark A. Greaney , Chris A. Wright , Jonathan M. McConnachie , Howard Freund , Kun Wang
IPC分类号： C10G45/00
CPC分类号： C10G32/02
摘要： The electrodesulfurization of heavy oils wherein a feedstream comprised of bitumen or heavy oil is conducted, along with an effective amount of hydrogen, to an electrochemical cell. A current is applied to the cell wherein sulfur from the feedstream combines with hydrogen to form hydrogen sulfide which is removed.
摘要翻译：其中将由沥青或重油组成的原料流连同有效量的氢气一起进行到电化学电池的重油的硫化。将电流施加到电池，其中来自进料流的硫与氢结合以形成除去的硫化氢。

9. 发明授权

US06232276B1 Trinuclear molybdenum multifunctional additive for lubricating oils 失效
标题翻译：用于润滑油的三核钼多功能添加剂
公开(公告)号：US06232276B1
公开(公告)日：2001-05-15
申请号：US08844019
申请日：1997-04-18
申请人： Edward Ira Stiefel , Jonathan M. McConnachie , Daniel Paul Leta , Manuel A. Francisco , Catherine Louise Coyle , Peter John Guzi , Charles F. Pictroski
发明人： Edward Ira Stiefel , Jonathan M. McConnachie , Daniel Paul Leta , Manuel A. Francisco , Catherine Louise Coyle , Peter John Guzi , Charles F. Pictroski
IPC分类号： C10M13900
CPC分类号： C07F11/005 , C10M135/18 , C10M137/10 , C10M159/18 , C10M2219/068 , C10M2223/045 , C10M2227/09 , C10N2210/06 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A lubricating oil composition is provided comprising a major amount of an oil of lubricating viscosity and a minor amount of at least one trinuclear molybdenum compound. Preferably, the trinuclear molybdenum compound is selected from those compounds having the formula Mo3SkL4Qz and mixtures thereof in which L is a ligand having organo groups with a sufficient number of carbon atoms to render the compound soluble in the oil, k varies from 4 through 7, Q is selected from the group of compounds having lone pair electrons including water, amines, alcohols, phosphines, and ethers, and z ranges from 0 to 5. In general, the organo groups of the mono-anionic ligands will be the same although they may be different, and they preferably are selected from alkyl, aryl, substituted aryl, and ether groups. For example, when L is a dialkyldithiocarbamate or a dialkyldithiophosphate, the alkyl groups will have from about 1 to 30 carbon atoms.
摘要翻译：提供润滑油组合物，其包含主要量的润滑粘度的油和少量的至少一种三核钼化合物。优选地，三核钼化合物选自具有式Mo 3 S k L 4 Q z的那些化合物及其混合物，其中L是具有足够数目碳原子的有机基团的配体，以使化合物可溶于油，k从4至7变化， Q选自具有包括水，胺，醇，膦和醚在内的单对电子的化合物的组，z的范围为0至5.通常，单阴离子配体的有机基团将是相同的，尽管它们可以不同，它们优选选自烷基，芳基，取代的芳基和醚基。例如，当L是二烷基二硫代氨基甲酸酯或二烷基二硫代磷酸酯时，烷基将具有约1至30个碳原子。

10. 发明授权

US06211123B1 Lubricating oil compositions 失效
标题翻译：润滑油组成
公开(公告)号：US06211123B1
公开(公告)日：2001-04-03
申请号：US09335328
申请日：1999-06-17
申请人： Alisdair J. Brown , Ian A. W. Bell , John A. Cleverley , Jose M. G. Gomes , Edward I. Stiefel , Jonathan M. McConnachie
发明人： Alisdair J. Brown , Ian A. W. Bell , John A. Cleverley , Jose M. G. Gomes , Edward I. Stiefel , Jonathan M. McConnachie
IPC分类号： C10M13518
CPC分类号： C10M159/18 , C07F11/005 , C10M135/18 , C10M2219/068 , C10M2227/09 , C10N2210/06 , C10N2240/10 , C10N2240/101 , C10N2240/104 , C10N2240/106
摘要： A lubricating oil composition is provided comprising a major amount of an oil of lubricating viscosity and a minor amount of, as an additive, at least one compound comprising a trinuclear tungsten core and bonded thereto a ligand or ligands capable of rendering the compound oil-soluble or oil-dispersible.
摘要翻译：提供了一种润滑油组合物，其包含主要量的润滑粘度的油和少量的作为添加剂的少量至少一种包含三核钨芯的化合物，并且与其结合使能赋予化合物油溶性的配体或配体或油分散性。

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