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1. 发明授权

US06677481B2 Cracking of neo-C9 and neo-C13 carboxylic acids to either pivalic acid or methyl pivalate 失效
公开(公告)号：US06677481B2
公开(公告)日：2004-01-13
申请号：US09901238
申请日：2001-07-09
申请人： Edmund J. Mozeleski , Richard H. Schlosberg , Dennis J. Davoren , Carl Robert Beck , Linda J. Broadbelt , Ned C. Haubein
发明人： Edmund J. Mozeleski , Richard H. Schlosberg , Dennis J. Davoren , Carl Robert Beck , Linda J. Broadbelt , Ned C. Haubein
IPC分类号： C07C5114
CPC分类号： C07C51/44 , C07C51/10 , C07C51/14 , C07C67/36 , C07C53/128 , C07C69/24
摘要： A method for production of pivalic acid comprising the steps of: (a) reacting isobutylene, carbon monoxide, and a first catalyst to produce a reaction mixture; (b) contacting the reaction mixture with water, thereby producing a crude acid product having pivalic acid and oligomeric neo-carboxylic acid; (c) then separating the pivalic acid and the oligomeric neo-carboxylic acid from the crude acid product; (d) then reacting the oligomeric neo-carboxylic acid with a source of carbon monoxide at a temperature of less than 200° C. in the presence of a second catalyst to produce a C5 carbocation product, wherein the first and second catalyst are either the same or different; and (e) reacting the C5 carbocation product with water; thereby producing pivalic acid having an overall yield of at least 80 wt. %.

2. 发明授权

US06919474B2 Cracking of neo-C9 and neo-C13 carboxylic acids to either pivalic acid or methyl pivalate 失效
标题翻译：将新C9和新-C13羧酸裂解成新戊酸或新戊酸甲酯
公开(公告)号：US06919474B2
公开(公告)日：2005-07-19
申请号：US10365132
申请日：2003-03-31
申请人： Edmund J. Mozeleski , Richard H. Schlosberg , Dennis J. Davoren , Carl Robert Beck , Linda J. Broadbelt , Ned C. Haubein
发明人： Edmund J. Mozeleski , Richard H. Schlosberg , Dennis J. Davoren , Carl Robert Beck , Linda J. Broadbelt , Ned C. Haubein
IPC分类号： C07C51/10 , C07C51/14 , C07C51/44 , C07C67/36 , C07C69/00 , C07C67/38
CPC分类号： C07C51/44 , C07C51/10 , C07C51/14 , C07C67/36 , C07C53/128 , C07C69/24
摘要： A method for production of pivalic acid comprising the steps of: (a) reacting isobutylene, carbon monoxide, and a first catalyst to produce a reaction mixture; (b) contacting the reaction mixture with water, thereby producing a crude acid product having pivalic acid and oligomeric neo-carboxylic acid; (c) separating the pivalic acid and the oligomeric neo-carboxylic acid from the crude acid product; (d) reacting the oligomeric neo-carboxylic acid with a source of carbon monoxide at a temperature of less than 200° C. in the presence of a second catalyst to produce a C5 carbocation product, wherein the first and second catalyst are either the same or different; and (e) reacting the C5 carbocation product with water; thereby producing pivalic acid having an overall yield of at least 80 wt. %.
摘要翻译：一种生产新戊酸的方法，包括以下步骤：（a）使异丁烯，一氧化碳和第一催化剂反应以产生反应混合物; （b）使反应混合物与水接触，从而产生具有新戊酸和低聚新羧酸的粗酸产物; （c）从粗酸产物中分离新戊酸和低聚新羧酸; （d）在低于200℃的温度下，在第二种催化剂的存在下使低聚新羧酸与一氧化碳源反应，生成C 5 -C 5碳阳离子产物，其中第一和第二催化剂可以相同或不同; 和（e）使C 5 -C 5碳阳离子产物与水反应; 从而产生总产率至少为80重量％的新戊酸。％。

3. 发明授权

US06717010B2 Cracking of neo-C9 and neo-C13 carboxylic acids to either pivalic acid or methyl pivalate 失效
标题翻译：将新C9和新-C13羧酸裂解成新戊酸或新戊酸甲酯
公开(公告)号：US06717010B2
公开(公告)日：2004-04-06
申请号：US10434915
申请日：2003-05-09
申请人： Edmund J. Mozeleski , Richard H. Schlosberg , Dennis J. Davoren , Carl Robert Beck , Linda J. Broadbelt , Ned C. Haubein
发明人： Edmund J. Mozeleski , Richard H. Schlosberg , Dennis J. Davoren , Carl Robert Beck , Linda J. Broadbelt , Ned C. Haubein
IPC分类号： C07C5114
CPC分类号： C07C51/44 , C07C51/10 , C07C51/14 , C07C67/36 , C07C53/128 , C07C69/24
摘要： A method for production of pivalic acid comprising the steps of: (a) reacting isobutylene, carbon monoxide, and a first catalyst to produce a reaction mixture; (b) contacting the reaction mixture with water, thereby producing a crude acid product having pivalic acid and oligomeric neo-carboxylic acid; (c) then separating the pivalic acid and the oligomeric neo-carboxylic acid from the crude acid product; (d) then reacting the oligomeric neo-carboxylic acid with a source of carbon monoxide at a temperature of less than 200° C. in the presence of a second catalyst to produce a C5 carbocation product, wherein the first and second catalyst are either the same or different; and (e) reacting the C5 carbocation product with water; thereby producing pivalic acid having an overall yield of at least 80 wt. %.
摘要翻译：一种生产新戊酸的方法，包括以下步骤：（a）使异丁烯，一氧化碳和第一催化剂反应以产生反应混合物; （b）使反应混合物与水接触，从而产生具有新戊酸和低聚新羧酸的粗酸产物; （c）然后从所述粗酸产物中分离出所述新戊酸和所述低聚新羧酸; （d）然后使所述低聚新羧酸与一氧化碳源在小于200℃的温度下在第二催化剂存在下反应，以产生C5碳阳离子产物，其中所述第一和第二催化剂是相同或不同; 和（e）使C5碳阳离子产物与水反应; 从而产生总产率至少为80重量％的新戊酸。％。

4. 发明授权

US07005537B2 Production of esters 有权
标题翻译：生产酯
公开(公告)号：US07005537B2
公开(公告)日：2006-02-28
申请号：US09750567
申请日：2000-12-26
申请人： Edmund J. Mozeleski , Carl R. Beck , Kirk C. Nadler , Richard H. Schlosberg
发明人： Edmund J. Mozeleski , Carl R. Beck , Kirk C. Nadler , Richard H. Schlosberg
IPC分类号： C07C67/36 , C07C67/38 , C07C67/24
CPC分类号： C07C67/38 , C07C67/37 , C07C69/24
摘要： Disclosed is a process for the production of esters. In particular, the process includes contacting an olefin or an ether with carbon monoxide and an acid composition comprising BF3.2CH3OH to from a product composition, adding an alcohol to the product composition, and separating the BF3.2CH3OH from the ester. The separated BF3.2CH3OH may then be recycled to the reaction unit.
摘要翻译：公开了一种生产酯的方法。特别地，该方法包括使烯烃或醚与一氧化碳和包含BF 3/2CH 3 OH的酸组合物从产物组合物接触，向醇中加入醇产物组合物，并从该酯中分离出BF 3/3CH 3 OH。然后将分离的BF 3/2CH 3 OH再循环到反应单元中。

5. 发明授权

US07456319B2 Para-alkylation of aromatic primary amines 失效
标题翻译：芳族伯胺的对烷基化
公开(公告)号：US07456319B2
公开(公告)日：2008-11-25
申请号：US11296997
申请日：2005-12-08
申请人： George A Knudsen , Richard H. Schlosberg
发明人： George A Knudsen , Richard H. Schlosberg
IPC分类号： C07C209/68
CPC分类号： C07C209/68 , C07C211/45
摘要： A method is provided for producing primarily para alkyl aromatic amines by alkylating a primary aromatic amine with an olefin in the presence of an acid activated clay.
摘要翻译：提供了一种通过在酸活化粘土存在下用烯烃烷基化伯芳族胺来主要制备对位烷基芳族胺的方法。

6. 发明授权

US06994799B2 Ester-containing fluid compositions 失效
公开(公告)号：US06994799B2
公开(公告)日：2006-02-07
申请号：US09747146
申请日：2000-12-22
申请人： Eddy Van Driessche , Georges Mathys , Richard H. Schlosberg , Christian Francois , Chris De Roover
发明人： Eddy Van Driessche , Georges Mathys , Richard H. Schlosberg , Christian Francois , Chris De Roover
IPC分类号： C09K5/00
CPC分类号： C09D11/033 , C07C69/24 , C09D7/20 , C10M105/34 , C10M2207/2815 , C10N2270/00
摘要： Disclosed are ester-containing fluid compositions, methods of making such compositions, and methods of using such compositions. The fluid compositions comprise a mix of branched and linear ester compounds, and the fluid compositions are characterized by certain performance limitations. The preferred method of making the fluid compositions enables the ester mix to be made in a one step process with little finishing required to obtain desirable performance characteristics.

8. 发明授权

US5470497A Refrigeration working fluid compositions containing trifluoroethane and neopentyl glycol or trimethylolpropane esters of C.sub.7 and C.sub.9 acids 失效
标题翻译：含有C 3和C 9酸的三氟乙烷和新戊二醇或三羟甲基丙烷酯的制冷工作流体组合物
公开(公告)号：US5470497A
公开(公告)日：1995-11-28
申请号：US365187
申请日：1994-12-28
申请人： Richard H. Schlosberg , Carolyn B. Duncan , Martin A. Krevalis, Jr.
发明人： Richard H. Schlosberg , Carolyn B. Duncan , Martin A. Krevalis, Jr.
IPC分类号： C09K5/04 , C10M105/38 , C10M171/00 , C10N20/00 , C10N30/00 , C10N40/30
CPC分类号： C09K5/045 , C10M105/38 , C10M171/008 , C09K2205/24 , C10M2207/281 , C10M2207/282 , C10M2207/283 , C10M2207/286 , C10M2211/022 , C10M2211/06 , C10N2240/00 , C10N2240/22 , C10N2240/30 , C10N2240/50 , C10N2240/52 , C10N2240/54 , C10N2240/56 , C10N2240/58 , C10N2240/60 , C10N2240/66
摘要： There are disclosed refrigeration working fluid compositions comprising 1,1,1-trifluoroethane refrigerant and either a neopentylglycol ester of 3,5,5-trimethylhexanoic acid or a trimethylolpropane ester of a mixture of 65 wt. % 3,5,5-trimethylhexanoic acid, 22.2 wt. % n-heptanoic acid and 12.8 wt. % methylhexanoic acid. The esters exhibit suitable viscosity ranges and miscibility with the refrigerant over a broad compositional range.
摘要翻译：公开了包含1,1,1-三氟乙烷制冷剂和3,5,5-三甲基己酸的新戊二醇酯或65重量％混合物的混合物的三羟甲基丙烷酯的制冷工作流体组合物。％3,5,5-三甲基己酸，22.2重量％％正庚酸和12.8重量％％甲基己酸。该酯在宽的组成范围内表现出合适的粘度范围和与制冷剂的混溶性。

9. 发明授权

US5453561A Reactive separation process 失效
标题翻译：反应分离过程
公开(公告)号：US5453561A
公开(公告)日：1995-09-26
申请号：US187673
申请日：1994-01-27
申请人： Ramzi Y. Saleh , Michael Siskin , Glen B. Brons , Stephen N. Vaughn , Richard H. Schlosberg
发明人： Ramzi Y. Saleh , Michael Siskin , Glen B. Brons , Stephen N. Vaughn , Richard H. Schlosberg
IPC分类号： B01D17/025 , C07C7/148 , C07C11/02 , C07C29/10 , C10G50/00 , C07C7/00
CPC分类号： C07C29/10 , C07C7/148
摘要： The invention concerns a method for reactive separation of mixtures containing hydrocarbons and oxygenated hydrocarbons, by contacting a mixture of hydrocarbons such as C.sub.2 to C.sub.26 hydrocarbons and mixtures thereof and oxygenated hydrocarbons, such as C.sub.2 to C.sub.40 oxygenated hydrocarbons and mixtures thereof to form a mixture of hydrocarbons and lower molecular weight oxygenated hydrocarbons and heating the mixture in water at temperature typically from about and pressure sufficient to cleave the oxygenated hydrocarbons to lower molecular weight products to form a liquid layer containing water soluble reaction products and an organic layer containing primarily hydrocarbons.
摘要翻译：本发明涉及通过使烃类混合物例如C 2至C 26烃及其混合物和含氧烃如C2至C40含氧烃及其混合物的混合物与烃和氧化烃的混合物进行反应分离的方法，以形成混合物碳氢化合物和较低分子量的氧化烃，并将混合物在水中加热，其温度通常为足以将氧化烃切割成较低分子量产物的温度，形成含有水溶性反应产物和主要含有烃的有机层的液体层。

10. 发明授权

US4385981A Liquefaction of carbonous materials with vapor phase hydrogen donor solvents 失效
标题翻译：碳质材料与气相氢供体溶剂的液化
公开(公告)号：US4385981A
公开(公告)日：1983-05-31
申请号：US255569
申请日：1981-04-20
申请人： Daniel R. Neskora , Richard H. Schlosberg
发明人： Daniel R. Neskora , Richard H. Schlosberg
IPC分类号： C10G1/04 , C10G1/00
CPC分类号： C10G1/042
摘要： Disclosed is a method for enhancing the conversion of carbonous materials, such as coal and oil shale. The method comprises converting the carbonous material in the presence of a vapor phase hydrogen donor material containing 1 or more hydrogen donor solvents wherein each donor material is characterized by: (a) a heterocyclic ring in which the heteroatom is nitrogen, (b) having at least one donatable hydrogen located on the heterocyclic ring, and (c) becoming more unsaturated and/or aromatic upon the loss of the donatable hydrogen(s). The conversion is performed at substantially atmospheric pressure, at an effective vapor residence time and at a temperature from about the boiling point of the hydrogen donor material to about 550.degree. C.
摘要翻译：公开了一种提高碳质材料如煤和油页岩的转化率的方法。该方法包括在含有1个或更多个氢供体溶剂的气相氢供体材料的存在下转化碳质材料，其中每个供体材料的特征在于：（a）其中杂原子是氮的杂环，（b）具有位于杂环上的至少一个可供氢的氢，和（c）在可用氢的丧失时变得更不饱和和/或芳族。转化在基本上大气压下，在有效的蒸气停留时间和约从氢供体材料的沸点至约550℃的温度下进行。

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