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1. 发明申请

US20070119520A1 METHOD FOR TREATING OR PRE-TREATING COMPONENTS COMPRISING ALUMINUM SURFACES 审中-公开
标题翻译：用于处理或预处理包含铝表面的组件的方法
公开(公告)号：US20070119520A1
公开(公告)日：2007-05-31
申请号：US11483111
申请日：2006-07-07
申请人： Edgar Busch , Jorg Hieke , Thomas Kolberg , Peter Schubach , Harald Jaschke , Christoph Klocke , Alfred Rutka
发明人： Edgar Busch , Jorg Hieke , Thomas Kolberg , Peter Schubach , Harald Jaschke , Christoph Klocke , Alfred Rutka
IPC分类号： C23C22/20
CPC分类号： C23C22/73 , C23C22/36 , C23C22/365
摘要： A method for treating or pre-treating parts, profiles, strips, or wires comprising surfaces of aluminum, or other metal surfaces with an acidic, aqueous solution containing fluoride and phosphate.
摘要翻译：用含有氟化物和磷酸盐的酸性水溶液处理或预处理包含铝或其它金属表面的部件，型材，条带或电线的方法。

2. 发明授权

US08784991B2 Process for coating metallic surfaces with an aqueous composition, and this composition 有权
标题翻译：用水性组合物涂覆金属表面的方法，以及该组合物
公开(公告)号：US08784991B2
公开(公告)日：2014-07-22
申请号：US13080940
申请日：2011-04-06
申请人： Thomas Kolberg , Manfred Walter , Peter Schubach
发明人： Thomas Kolberg , Manfred Walter , Peter Schubach
IPC分类号： B05D3/10 , C08K3/16 , C08L63/00
CPC分类号： C23C26/00 , B05D3/007 , B05D3/0413 , B05D7/52 , C09D1/00 , C09D5/08 , C23C18/122 , C23C18/1241 , C23C18/14 , C23C22/34 , C23C22/364 , C23C22/365 , C23C22/367 , C23C22/368 , C23C2222/20 , Y02T50/67 , Y10T428/273 , Y10T428/31529 , Y10T428/31663
摘要： A composition and a method for coating metallic surfaces with a silane/silanol/siloxane/polysiloxane-containing composition, whereby the composition contains a) at least one compound selected from the silanes, silanols, siloxanes and polysiloxanes, b) at least two compounds selected from titanium-, hafnium-, zirconium-, aluminum- or boron-containing compounds, optionally c) at least one type of cation selected from cations of metals of the 1st to 3rd and 5th to 8th sub-groups including the lanthanides and the 2nd main group of the periodic table of the elements or at least one corresponding compound, d) at least one organic compound selected from monomers, oligomers, polymers, copolymers and block copolymers or e) at least one substance affecting the pH value, water and optionally at least one organic solvent.
摘要翻译：一种用硅烷/硅烷醇/硅氧烷/聚硅氧烷的组合物涂覆金属表面的组合物和方法，其中组合物含有a）至少一种选自硅烷，硅烷醇，硅氧烷和聚硅氧烷的化合物，b）选择至少两种化合物从钛，铪，锆，铝或硼的化合物任选地，c）至少一种选自第1至第3和第5至第8族金属的阳离子的阳离子，包括镧系元素和第2族元素周期表的主要组分或至少一种相应的化合物，d）至少一种选自单体，低聚物，聚合物，共聚物和嵌段共聚物的有机化合物，或e）至少一种影响pH值的物质，水和任选地至少一种有机溶剂。

3. 发明申请

US20110189488A1 PROCESS FOR COATING METALLIC SURFACES WITH AN AQUEOUS COMPOSITION, AND THIS COMPOSITION 有权
标题翻译：用金属组合物涂覆金属表面的方法，以及该组合物
公开(公告)号：US20110189488A1
公开(公告)日：2011-08-04
申请号：US13080940
申请日：2011-04-06
申请人： Thomas Kolberg , Manfred Walter , Peter Schubach
发明人： Thomas Kolberg , Manfred Walter , Peter Schubach
IPC分类号： B32B15/08 , B05D3/10 , C08K3/16 , C08L63/00
CPC分类号： C23C26/00 , B05D3/007 , B05D3/0413 , B05D7/52 , C09D1/00 , C09D5/08 , C23C18/122 , C23C18/1241 , C23C18/14 , C23C22/34 , C23C22/364 , C23C22/365 , C23C22/367 , C23C22/368 , C23C2222/20 , Y02T50/67 , Y10T428/273 , Y10T428/31529 , Y10T428/31663
摘要： A compositon and a method for coating metallic surfaces with a silane/silanol/siloxane/polysiloxane-containing composition, whereby the composition contains a) at least one compound selected from the silanes, silanols, siloxanes and polysiloxanes, b) at least two compounds selected from titanium-, hafnium-, zirconium-, aluminum- or boron-containing compounds, optionally c) at least one type of cation selected from cations of metals of the 1st to 3rd and 5th to 8th sub-groups including the lanthanides and the 2nd main group of the periodic table of the elements or at least one corresponding compound, d) at least one organic compound selected from monomers, oligomers, polymers, copolymers and block copolymers or e) at least one substance affecting the pH value, water and optionally at least one organic solvent.
摘要翻译：一种用硅烷/硅烷醇/硅氧烷/聚硅氧烷的组合物涂覆金属表面的组合物和方法，其中组合物含有a）至少一种选自硅烷，硅烷醇，硅氧烷和聚硅氧烷的化合物，b）选择至少两种化合物从钛，铪，锆，铝或硼的化合物任选地，c）至少一种选自第1至第3和第5至第8族金属的阳离子的阳离子，包括镧系元素和第2族元素周期表的主要组分或至少一种相应的化合物，d）至少一种选自单体，低聚物，聚合物，共聚物和嵌段共聚物的有机化合物，或e）至少一种影响pH值的物质，水和任选地至少一种有机溶剂。

4. 发明申请

US20080127859A1 Method for Coating Metallic Surfaces with an Aqueous Multi-Component Composition 审中-公开
标题翻译：用多金属组合物涂覆金属表面的方法
公开(公告)号：US20080127859A1
公开(公告)日：2008-06-05
申请号：US11667879
申请日：2005-11-09
申请人： Thomas Kolberg , Manfred Walter , Peter Schubach
发明人： Thomas Kolberg , Manfred Walter , Peter Schubach
IPC分类号： C09D5/08 , B05D3/06 , B05D3/02
摘要： The invention relates to a process for coating metallic surfaces with a composition containing silane/silanol/siloxane/polysiloxane, wherein, in addition to a) at least one compound selected from silanes, silanols, siloxanes and polysiloxanes, b) at least one compound containing titanium, hafnium, zirconium, aluminium and/or boron, and c) at least one type of cation selected from cations of metals of subgroups 1 to 3 and 5 to 8, including lanthanides, and of main group 2 of the periodic table of the elements, and/or at least one corresponding compound, the composition contains at least one substance d) selected from: d1) silicon-free compounds having at least one amino, urea and/or ureido group in each case, d2) anions of nitrite and/or compounds having at least one nitro group, d3) compounds based on peroxide, and d4) phosphorus-containing compounds, anions of at least one phosphate and/or anions of at least one phosphonate, as well as e) water, and f) optionally also at least one organic solvent. The invention further relates to corresponding aqueous compositions.
摘要翻译：本发明涉及一种用含有硅烷/硅烷醇/硅氧烷/聚硅氧烷的组合物涂覆金属表面的方法，其中除了a）至少一种选自硅烷，硅烷醇，硅氧烷和聚硅氧烷的化合物之外，b）至少一种含钛，铪，锆，铝和/或硼，以及c）至少一种阳离子，其选自亚族1至3和5至8族的金属的阳离子，包括镧系元素，以及元素周期表的主族2的阳离子元素和/或至少一种相应的化合物，所述组合物含有至少一种选自以下的物质：d 1）具有至少一个氨基，脲和/或脲基的无硅化合物在每种情况下，基于过氧化物的亚硝酸盐和/或具有至少一个硝基的化合物，d 3 N 3）化合物，d 4，含磷化合物，至少一种磷酸盐的阴离子和/或至少一种膦酸盐的阴离子，以及e）wa 和f）任选地还有至少一种有机溶剂。本发明还涉及相应的含水组合物。

5. 发明授权

US09879349B2 Method for coating metallic surfaces with an aqueous composition 有权
公开(公告)号：US09879349B2
公开(公告)日：2018-01-30
申请号：US13326633
申请日：2011-12-15
申请人： Thomas Kolberg , Manfred Walter , Peter Schubach
发明人： Thomas Kolberg , Manfred Walter , Peter Schubach
IPC分类号： B05D3/00 , B05D7/00 , C09D1/00 , C23C26/00 , C09D5/08 , C23C18/12 , C23C18/14 , C23C22/34 , C23C22/36 , B05D3/04
CPC分类号： C23C26/00 , B05D3/007 , B05D3/0413 , B05D7/52 , C09D1/00 , C09D5/08 , C23C18/122 , C23C18/1241 , C23C18/14 , C23C22/34 , C23C22/364 , C23C22/365 , C23C22/367 , C23C22/368 , C23C2222/20 , Y02T50/67 , Y10T428/273 , Y10T428/31529 , Y10T428/31663
摘要： The invention relates to a process for coating metallic surfaces with a composition containing at least one of a silane, silanol, siloxane or polysiloxane that is capable of condensation, water and optionally an organic solvent. The composition also contains compound containing Ti, Hf, Zr, Al or B; and at least one type of cation or an organic compound d) selected from monomers, oligomers, polymers, copolymers and block copolymers. The coating freshly applied with this composition is rinsed with a fluid and is not dried thoroughly before this rinsing step so that the compound capable of condensation does not condense substantially before the rinsing step.

6. 发明授权

US08101014B2 Process for coating metallic surfaces with a multicomponent aqueous composition 有权
标题翻译：用多组分含水组合物涂覆金属表面的方法
公开(公告)号：US08101014B2
公开(公告)日：2012-01-24
申请号：US12696696
申请日：2010-01-29
申请人： Thomas Kolberg , Manfred Walter , Peter Schubach
发明人： Thomas Kolberg , Manfred Walter , Peter Schubach
IPC分类号： C09D1/00 , C08K5/22 , C08K3/10 , C08K5/53 , C08K5/09
CPC分类号： C09D5/084 , C08K3/10 , C08K5/0008 , C09D7/61 , C23C2222/20 , Y02T50/67 , Y10T428/31663
摘要： The invention relates to a process for coating metallic surfaces with a composition containing silane/silanol/siloxane/polysiloxane, wherein, in addition to a) at least one compound selected from silanes, silanols, siloxanes and polysiloxanes, b) at least one compound containing titanium, hafnium, zirconium, aluminum and/or boron, and c) at least one type of cation selected from cations of metals of subgroups 1 to 3 and 5 to 8, including lanthanides, and of main group 2 of the periodic table of the elements, and/or at least one corresponding compound, the composition contains at least one substance d) selected from: d1) silicon-free compounds having at least one amino, urea and/or ureido group in each case, d2) anions of nitrite and/or compounds having at least one nitro group, d3) compounds based on peroxide, and d4) phosphorus-containing compounds, anions of at least one phosphate and/or anions of at least one phosphonate, as well as e) water, and f) optionally also at least one organic solvent. The invention further relates to corresponding aqueous compositions.
摘要翻译：本发明涉及一种用含有硅烷/硅烷醇/硅氧烷/聚硅氧烷的组合物涂覆金属表面的方法，其中除了a）至少一种选自硅烷，硅烷醇，硅氧烷和聚硅氧烷的化合物之外，b）至少一种含钛，铪，锆，铝和/或硼，以及c）至少一种阳离子，其选自亚族1至3和5至8族的金属的阳离子，包括镧系元素，以及元素周期表的主族2的阳离子元素和/或至少一种相应的化合物，所述组合物含有至少一种选自以下的物质d）：d1）在每种情况下具有至少一个氨基，脲和/或脲基的无硅化合物，d2）亚硝酸根阴离子和/或具有至少一个硝基的化合物，d3）基于过氧化物的化合物和d4）含磷化合物，至少一种磷酸盐和/或至少一种膦酸盐的阴离子的阴离子，以及e）水，和 f）任选地还至少一个orga nic溶剂。本发明还涉及相应的含水组合物。

7. 发明授权

US06497771B1 Aqueous solution and method for phosphatizing metallic surfaces 失效
标题翻译：水溶液和金属表面磷化的方法
公开(公告)号：US06497771B1
公开(公告)日：2002-12-24
申请号：US09622975
申请日：2001-01-09
申请人： Peter Schubach , Joachim Heitbaum , Thomas Kolberg , Margit Fleischhacker-Jeworrek , Peter Jorns , Michael Deemer , Ralf Stickler , Jurgen Specht , Michael Lenhard
发明人： Peter Schubach , Joachim Heitbaum , Thomas Kolberg , Margit Fleischhacker-Jeworrek , Peter Jorns , Michael Deemer , Ralf Stickler , Jurgen Specht , Michael Lenhard
IPC分类号： C23C2207
CPC分类号： C23C22/182 , C23C22/12 , C23C22/13 , C23C22/365
摘要： An aqueous solution contains phosphate for producing layers of phosphate on metal surfaces selected from the group consisting of iron, steel, zinc, zinc alloys, aluminum and aluminum alloys. The solution contains 0.3 to 5 g Zn2+/1, 0.1 to 2 g nitroguanidine/1 and 0.05 to 0.5 g hydroxylamine/l, with an S-value amounting to 0.03 to 0.3 and the ratio of the weight of Zn2+ to P2O5=1:5 to 1.30.
摘要翻译：水溶液含有磷酸盐，用于在选自铁，钢，锌，锌合金，铝和铝合金的金属表面上生产磷酸盐层。该溶液含有0.3-5g Zn2 + / l，0.1-2g硝基胍/ 1和0.05-0.5g羟胺/ l，S值为0.03-0.3，Zn2 +与P2O5的重量比= 1： 5至1.30。

8. 发明授权

US11142655B2 Process for coating metallic surfaces with a multicomponent aqueous composition 有权
公开(公告)号：US11142655B2
公开(公告)日：2021-10-12
申请号：US13006970
申请日：2011-01-14
申请人： Thomas Kolberg , Manfred Walter , Peter Schubach
发明人： Thomas Kolberg , Manfred Walter , Peter Schubach
IPC分类号： C23C22/48 , C09D5/08 , C09D7/61 , C08K3/10 , C08K5/00
摘要： The invention relates to a process for coating metallic surfaces with a composition containing silane/silanol/siloxane/polysiloxane, wherein, in addition to a) at least one compound selected from silanes, silanols, siloxanes and polysiloxanes, b) at least one compound containing titanium, hafnium, zirconium, aluminium and/or boron, and c) at least one type of cation selected from cations of metals of subgroups 1 to 3 and 5 to 8, including lanthanides, and of main group 2 of the periodic table of the elements, and/or at least one corresponding compound, the composition contains at least one substance d) selected from: d1) silicon-free compounds having at least one amino, urea and/or ureido group in each case, d2) anions of nitrite and/or compounds having at least one nitro group, d3) compounds based on peroxide, and d4) phosphorus-containing compounds, anions of at least one phosphate and/or anions of at least one phosphonate, as well as e) water, and f) optionally also at least one organic solvent. The invention further relates to corresponding aqueous compositions.

9. 发明授权

US5294266A Process for a passivating postrinsing of conversion layers 失效
标题翻译：转化层的钝化方法
公开(公告)号：US5294266A
公开(公告)日：1994-03-15
申请号：US978193
申请日：1992-11-18
申请人： Dieter Hauffe , Thomas Kolberg , Gerhard Muller , Horst Gehmecker , Werner Rausch , Peter Schubach , Thomas Wendel
发明人： Dieter Hauffe , Thomas Kolberg , Gerhard Muller , Horst Gehmecker , Werner Rausch , Peter Schubach , Thomas Wendel
IPC分类号： C23C22/34 , C23C22/36 , C23C22/60 , C23C22/83
CPC分类号： C23C22/73 , C23C22/34 , C23C22/361 , C23C22/60 , C23C22/83
摘要： The invention is in a composition and process for the chromium free passivating postrinsing of conversion layers on metals before the application of a paint or adhesive. The conversion layers can be on the bases of phosphate layers, at least two polyvalent metal ions with complex formers, titanium, zirconium and/or hafnium. The postrinsing agent is an aqueous solution which has been adjusted to a pH value of up to 5 and which contains an aluminum fluorozirconate having an Al:Zr:F mole ratio of (0.15 to 8.0):1:(5 to 52), and in which solutions the total concentration of Al+Zr+F is 0.1 to 8.0 g/l. The postrinsing solutions may additionally contain at least one of the anions benzoate, caprylate, ethyl hexoate, salicylate in a total concentration of 0.05 to 0.5 g/1 and may preferably be adjusted to the required pH value with cations of volatile bases, such as ammonium, ethanolammonium and di- and triethanolammonium. The paint is subsequently applied suitably by cathodic electrocoating or powder coating or from a low-solvent high-solids paint.The rinsing treatment is over a period of 1 to 120 seconds at temperatures of 20.degree. to 80.degree. C. The invention is used as a pretreatment to the application of a paint coating, film coating or adhesive coating.
摘要翻译：本发明是用于在施加涂料或粘合剂之前的金属上的转化层的无铬钝化的组合物和方法。转化层可以在磷酸盐层，至少两种具有复合成型剂的多价金属离子，钛，锆和/或铪的基础上。 postrinsing剂是一种水溶液，其pH值调至5以下，并含有Al：Zr：F摩尔比为（0.15〜8.0）：1：（5〜52）的氟锆酸铝，其中Al + Zr + F的总浓度为0.1〜8.0g / l。 postrinsing溶液还可以含有至少一种阴离子苯甲酸酯，辛酸酯，己酸乙酯，水杨酸酯，总浓度为0.05至0.5g / l，并且可优选用挥发性碱如铵的阳离子调节至所需的pH值，乙醇铵和二乙醇胺和三乙醇铵。随后通过阴极电涂或粉末涂料或低溶剂高固体涂料适当地施涂涂料。在20〜80℃的温度下，漂洗处理时间为1〜120秒。本发明用作涂料涂料，薄膜包衣或粘合剂涂料的预处理。

10. 发明申请

US20120177826A1 METHOD FOR COATING METALLIC SURFACES WITH AN AQUEOUS COMPOSITION 有权
标题翻译：用金属组合物涂覆金属表面的方法
公开(公告)号：US20120177826A1
公开(公告)日：2012-07-12
申请号：US13326633
申请日：2011-12-15
申请人： Thomas KOLBERG , Manfred Walter , Peter Schubach
发明人： Thomas KOLBERG , Manfred Walter , Peter Schubach
IPC分类号： B05D7/14 , B05D1/38 , B05D3/10
CPC分类号： C23C26/00 , B05D3/007 , B05D3/0413 , B05D7/52 , C09D1/00 , C09D5/08 , C23C18/122 , C23C18/1241 , C23C18/14 , C23C22/34 , C23C22/364 , C23C22/365 , C23C22/367 , C23C22/368 , C23C2222/20 , Y02T50/67 , Y10T428/273 , Y10T428/31529 , Y10T428/31663
摘要： The invention relates to a process for coating metallic surfaces with a composition containing at least one of a silane, silanol, siloxane or polysiloxane that is capable of condensation, water and optionally an organic solvent. The composition also contains compound containing Ti, Hf, Zr, Al or B; and at least one type of cation or an organic compound d) selected from monomers, oligomers, polymers, copolymers and block copolymers. The coating freshly applied with this composition is rinsed with a fluid and is not dried thoroughly before this rinsing step so that the compound capable of condensation does not condense substantially before the rinsing step.
摘要翻译：本发明涉及用含有能够缩合的硅烷，硅烷醇，硅氧烷或聚硅氧烷，水和任选的有机溶剂中的至少一种的组合物涂覆金属表面的方法。该组合物还含有含有Ti，Hf，Zr，Al或B的化合物; 和至少一种选自单体，低聚物，聚合物，共聚物和嵌段共聚物的阳离子或有机化合物d）。用该组合物新鲜施用的涂层用流体冲洗，并且在该漂洗步骤之前不彻底干燥，使得能够冷凝的化合物在漂洗步骤之前基本上不会冷凝。

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