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    • 3. 发明申请
    • POLARIMETRIC RAMAN SYSTEM AND METHOD FOR ANALYSING A SAMPLE
    • 极化拉曼系统和分析样品的方法
    • WO2007082937A1
    • 2007-07-26
    • PCT/EP2007/050547
    • 2007-01-19
    • ECOLE POLYTECHNIQUECENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUEOSSIKOVSKI, RazvigorDE MARTINO, AntonelloDREVILLON, Bernard
    • OSSIKOVSKI, RazvigorDE MARTINO, AntonelloDREVILLON, Bernard
    • G01N21/65G01N21/21G01J3/44
    • G01J3/44G01J3/02G01J3/0224G01N21/21G01N21/65G01N21/658G01N2021/4792
    • The present invention concerns a Raman method and system for analysing a sample (4) comprising an excitation source (1) emitting an incident light beam (2), a sample holder (3), on which the sample (4) can be mounted, means for focusing the incident light beam (2) onto the sample surface (16) to generate a Raman scattered light having an intensity, means for collecting the Raman scattered light to form a Raman scattered light beam (5), a detection system (6) measuring intensity of the Raman scattered light beam (5) as a function of time. According to the invention, it comprises at least a polarization state generator (PSG) (7) able to generate four independent polarization states or a polarization state analyser (PSA) (8) able to analyse four independent polarization states in order to detect the intensity of the Raman scattered light beam (5) making it possible to calculate a partial or complete Mueller- Stokes matrix of the sample (4), the incident light beam (2) passing through said PSG (7) before being scattered by the sample (4) and the Raman scattered light beam (5) passing through said PSA (8) after being scattered by the sample (4).
    • 本发明涉及一种用于分析样品(4)的拉曼方法和系统,该样品(4)包括发射入射光束(2)的激发源(1),可以安装样品(4)的样品保持器(3) 用于将入射光束(2)聚焦到样品表面(16)上以产生具有强度的拉曼散射光的装置,用于收集拉曼散射光以形成拉曼散射光束(5)的装置,检测系统(6) )测量拉曼散射光束(5)的强度作为时间的函数。 根据本发明,它包括至少能够产生四个独立极化状态的偏振状态发生器(PSG)(7)或能够分析四个独立极化状态的偏振状态分析器(PSA)(8),以便检测强度 的拉曼散射光束(5),使得可以计算样品(4)的部分或完整的米勒 - 斯托克斯矩阵,入射光束(2)在被样品散射之前穿过所述PSG(7) 4)和被样品(4)散射之后穿过所述PSA(8)的拉曼散射光束(5)。