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1. 发明申请

WO2011031374A2 OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：烃的氧化
公开(公告)号：WO2011031374A2
公开(公告)日：2011-03-17
申请号：PCT/US2010/041801
申请日：2010-07-13
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , DAKKA, Jihad, M. , ZUSHMA, Stephen
发明人： WANG, Kun , DAKKA, Jihad, M. , ZUSHMA, Stephen
IPC分类号： C07C407/00
CPC分类号： C07C409/08 , C07C407/00 , C07C409/14 , C07C2601/14 , C07C409/10
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen- containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R 1 and R 2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO 3 H, NH 2 , OH and NO2, or from the atoms H, F, Cl, Br and I provided that R 1 and R 2 can be linked to one another via a covalent bond; each of Q 1 and Q 2 is independently selected from C, CH, N and CR 3 ; each of X and Z is independently selected from C, S, CH 2 , N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is O, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R 3 can be any of the entities listed for R 1 . The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with at least one solid sorbent chosen from alkali metal carbonates, alkali metal bicarbonates, alkali metal hydroxides, alkali metal hydroxide-carbonate complexes, alkaline earth metal carbonates, alkaline earth metal bicarbonates, alkaline earth metal hydroxides and alkaline earth metal hydroxide-carbonate complexes to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，在含有环状酰亚胺的催化剂存在下使烃与含氧气体接触（I）的基团：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或来自基团 SO 3 H，NH 2，OH和NO 2，或者来自原子H，F，Cl，Br和I，条件是R 1和 R 2可以通过共价键相互连接; Q 1和Q 2中的每一个独立地选自C，CH，N和CR 3; X和Z中的每一个独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y是O或OH; k是0,1或2; 1是0,1或2; m是1至3，并且R 3可以是针对R 1所列出的任何实体。该接触产生包含氧化的烃产物和所述式（I）的未反应的酰亚胺催化剂的流出物，并且流出物用至少一种选自碱金属碳酸盐，碱金属碳酸氢盐，碱金属氢氧化物，碱金属氢氧化物 - 碳酸盐络合物，碱土金属碳酸盐，碱土金属碳酸氢盐，碱土金属氢氧化物和碱土金属氢氧化物 - 碳酸盐络合物以去除至少部分未反应的酰亚胺催化剂并产生包含所述氧化烃产物的经处理的流出物。然后可以回收有机相。

2. 发明申请

WO2010098916A2 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2010098916A2
公开(公告)日：2010-09-02
申请号：PCT/US2010/021949
申请日：2010-01-25
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , BENITEZ, Francisco, M. , LATTNER, James, R. , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , ZUSHMA, Stephen
发明人： WANG, Kun , BENITEZ, Francisco, M. , LATTNER, James, R. , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , ZUSHMA, Stephen
IPC分类号： C07C37/08
CPC分类号： C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C409/10 , C07C409/14 , C07C2601/08 , C07C2601/14 , C07C49/403 , C07C49/10 , C07C49/395 , C07C49/08 , C07C39/04
摘要： Disclosed is a process for producing phenol or a substituted phenol and a co-product comprising the steps of (i) contacting a first stream comprising an alkylaromatic compound with a second stream comprising an oxygen-containing gas in the presence of a first catalyst comprising a cyclic imide under conditions to convert at least a portion of said alkylaromatic compound to an alkylaromatic hydroperoxide, (ii) producing an effluent stream comprising said cyclic imide, said alkylaromatic hydroperoxide, and said alkylaromatic compound wherein said effluent stream has an alkylaromatic hydroperoxide concentration of from 10 to 40 wt%; and (iii) contacting in a second reactor at least a portion of said effluent stream with a second catalyst to convert said alkylaromatic hydroperoxide to a product stream comprising phenol and said co-product.
摘要翻译：公开了生产苯酚或取代苯酚和副产物的方法，包括以下步骤：（i）使包含烷基芳族化合物的第一物流与包含含氧气体的第二物流在在将至少一部分所述烷基芳族化合物转化为烷基芳族氢过氧化物的条件下，存在包含环状酰亚胺的第一催化剂，（ii）产生包含所述环状酰亚胺，所述烷基芳族氢过氧化物和所述烷基芳族化合物的流出物流，其中所述流出物流具有10至40重量％的烷基芳族氢过氧化物浓度; 和（iii）在第二反应器中使至少一部分所述流出物流与第二催化剂接触以将所述烷基芳族氢过氧化物转化为包含苯酚和所述副产物的产物流。

3. 发明申请

WO2012134549A1 PRODUCTION OF CYCLOHEXYLBENZENE HYDROPEROXIDE 审中-公开
标题翻译：环丙基苯甲醛氢过氧化物的生产
公开(公告)号：WO2012134549A1
公开(公告)日：2012-10-04
申请号：PCT/US2011/062200
申请日：2011-11-28
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , MOZELESKI, Edmund, J. , DAKKA, Jihad, M.
发明人： WANG, Kun , MOZELESKI, Edmund, J. , DAKKA, Jihad, M.
IPC分类号： C07C407/00 , C07C409/14 , C07C37/08 , C07C39/04 , C07C45/53 , C07C49/403
CPC分类号： C07C37/08 , C07C45/53 , C07C407/00 , C07C407/003 , C07C2601/14 , C07C409/14 , C07C39/04 , C07C49/403
摘要： In a process for producing cyclohexylbenzene hydroperoxide, cyclohexylbenzene is contacted with oxygen to produce a reaction product comprising cyclohexylbenzene hydroperoxide and unreacted cyclohexylbenzene. The reaction product is then maintained under conditions such that crystals of cyclohexylbenzene hydroperoxide form and separate from the reaction product. The cyclohexylbenzene hydroperoxide crystals are then recovered from the reaction product.
摘要翻译：在生产环己基苯氢过氧化物的方法中，使环己基苯与氧接触以产生包含环己基苯氢过氧化物和未反应的环己基苯的反应产物。然后将反应产物保持在使得环己基苯氢过氧化物的晶体形成并与反应产物分离的条件下。然后从反应产物中回收环己基苯氢过氧化物晶体。

4. 发明申请

WO2012145030A1 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2012145030A1
公开(公告)日：2012-10-26
申请号：PCT/US2011/065059
申请日：2011-12-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , GARCIA, Roberto , DAKKA, Jihad, M. , KISS, Gabor
发明人： WANG, Kun , GARCIA, Roberto , DAKKA, Jihad, M. , KISS, Gabor
IPC分类号： B01J29/08 , B01J29/90 , C07C2/66 , C07C2/74 , C07C13/28 , C07C15/04 , C07C37/08 , C07C45/53 , C07C9/16 , C07C49/403 , C07C39/04
CPC分类号： C07C37/08 , B01J23/42 , B01J23/44 , B01J29/06 , B01J29/08 , B01J29/18 , B01J29/70 , B01J29/7007 , B01J29/7476 , B01J29/90 , B01J31/0247 , B01J35/0006 , B01J2229/186 , B01J2229/42 , B01J2231/70 , C07C2/66 , C07C4/06 , C07C5/11 , C07C5/367 , C07C6/126 , C07C7/1485 , C07C45/53 , C07C407/00 , C07C2521/04 , C07C2521/06 , C07C2521/12 , C07C2521/16 , C07C2523/06 , C07C2523/14 , C07C2523/30 , C07C2523/44 , C07C2523/46 , C07C2523/75 , C07C2523/755 , C07C2527/053 , C07C2527/173 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2529/84 , C07C2529/85 , C07C2529/89 , C07C2601/14 , C07C2601/16 , Y02P20/52 , Y02P20/584 , C07C409/08 , C07C39/04 , C07C49/10 , C07C409/14 , C07C49/403 , C07C13/28 , C07C13/20 , C07C15/04
摘要： In a process for producing phenol, a composition comprising an alkylaromatic compound is contacted with an oxygen-containing stream in the presence of an oxidation catalyst comprising a cyclic imide under oxidation conditions effective to oxidize 15 wt% or less of the alkylaromatic compound based upon the total weight of the composition and produce an oxidation product comprising unreacted alkylaromatic compound and alkylaromatic hydroperoxide in a molar ratio of 6:1 to 100:1. Thereafter, at least a portion of the oxidation product is contacted with an acidic molecular sieve catalyst under cleavage conditions effective to convert at least a portion of the alkylaromatic hydroperoxide into phenol and cyclohexanone.
摘要翻译：在生产苯酚的方法中，包含烷基芳族化合物的组合物在含有环氧酰亚胺的氧化催化剂存在下在含氧物流的存在下，在氧化条件下，在有效氧化15重量％或更少的烷基芳族化合物的条件下，基于组合物的总重量，并产生摩尔比为6:1至100:1的未反应的烷基芳族化合物和烷基芳香族氢过氧化物的氧化产物。此后，在有效将至少一部分烷基芳香族氢过氧化物转化为苯酚和环己酮的切割条件下，氧化产物的至少一部分与酸性分子筛催化剂接触。

5. 发明申请

WO2012145029A2 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2012145029A2
公开(公告)日：2012-10-26
申请号：PCT/US2011/065058
申请日：2011-12-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , DAKKA, Jihad, M.
发明人： WANG, Kun , DAKKA, Jihad, M.
IPC分类号： B01J29/08
CPC分类号： C07C37/50 , B01J29/08 , B01J29/90 , B01J31/0244 , C07C37/08 , C07C45/53 , C07C51/31 , C07C407/00 , C07C2601/14 , Y02P20/52 , Y02P20/584 , C07C39/04 , C07C49/403 , C07C55/14 , C07C409/14
摘要： In a process for producing phenol, cyclohexylbenzene is contacted with oxygen in the presence of an oxidation catalyst comprising a cyclic imide under oxidation conditions effective to produce a product comprising cyclohexylbenzene hydroperoxide and unreacted cyclic imide catalyst. At least a portion of the product is contacted with a cleavage catalyst under conditions effective to convert at least a portion of the cyclohexylbenzene hydroperoxide into a second product comprising further unreacted cyclic imide catalyst, phenol, and cyclohexanone. A portion of the further unreacted cyclic imide catalyst may then be removed from the second product and optionally recycled back to the oxidation step.
摘要翻译：在生产苯酚的方法中，在有效产生包含环己基苯氢过氧化物和未反应的环状酰亚胺催化剂的产物的氧化条件下，环己基苯在含有环状酰亚胺的氧化催化剂存在下与氧接触。在有效地将至少一部分环己基苯氢过氧化物转化成包含另外未反应的环状酰亚胺催化剂，苯酚和环己酮的第二产物的条件下，将产物的至少一部分与裂解催化剂接触。然后可以从第二产物中除去部分未反应的环状酰亚胺催化剂，并任选地再循环回氧化步骤。

6. 发明申请

WO2012145028A2 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2012145028A2
公开(公告)日：2012-10-26
申请号：PCT/US2011/065056
申请日：2011-12-15
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , GARCIA, Roberto , DAKKA, Jihad, M. , MOZELESKI, Edmund, J.
发明人： WANG, Kun , GARCIA, Roberto , DAKKA, Jihad, M. , MOZELESKI, Edmund, J.
IPC分类号： B01J29/08
CPC分类号： C07C37/08 , B01J29/06 , B01J29/08 , B01J29/90 , C07C2/74 , C07C45/53 , C07C51/31 , C07C249/08 , C07C407/00 , C07C2601/14 , Y02P20/52 , Y02P20/584 , C07C39/04 , C07C49/403 , C07C55/14 , C07C409/14 , C07C251/44 , C07C13/28
摘要： In a process for producing phenol, cyclohexylbenzene is contacted with an oxygen- containing compound in the presence of an oxidation catalyst comprising a cyclic imide under oxidation conditions effective to produce a product comprising cyclohexylbenzene hydroperoxide and unreacted cyclic imide catalyst. Without removing all the unreacted cyclic imide catalyst, at least a portion of the product is contacted with an acidic molecular sieve under conditions effective to adsorb at least a portion of the unreacted cyclic imide and to convert at least part of the cyclohexylbenzene hydroperoxide in the product portion into phenol and cyclohexanone.
摘要翻译：在生产苯酚的方法中，在有效产生包含环己基苯氢过氧化物和未反应的环状酰亚胺催化剂的产物的氧化条件下，环己基苯在含有环状酰亚胺的氧化催化剂存在下与含氧化合物接触。在不除去所有未反应的环状酰亚胺催化剂的情况下，至少一部分产物在有效吸附至少一部分未反应的环状酰亚胺的条件下与酸性分子筛接触，并将至少部分环己基苯氢过氧化物转化成产物部分成苯酚和环己酮。

7. 发明申请

WO2012018969A3 METHOD OF MAKING 6-HYDROXYHEXANOPHENONE AND 5-BENZOYLPENTANOIC ACID AND MONO OR DIESTERS THEREOF 审中-公开
公开(公告)号：WO2012018969A3
公开(公告)日：2012-02-09
申请号：PCT/US2011/046526
申请日：2011-08-04
申请人： EXXONMOBIL RESEARCH AND ENGINEERING COMPANY , WANG, Kun , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , BENITEZ, Francisco, M. , BAUGH, Lisa, S. , GODWIN, Allen, D. , SMIRNOVA, Diana , ZUSHMA, Stephen
发明人： WANG, Kun , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , BENITEZ, Francisco, M. , BAUGH, Lisa, S. , GODWIN, Allen, D. , SMIRNOVA, Diana , ZUSHMA, Stephen
IPC分类号： C08K5/10
摘要： Mono- or diester plasticizers of the formula (I): wherein A is either -OC(0)R' or =0, and X is either -COC(0)R or -C(0)OR, and R and R' are C 3 to C 13 alkyl, which are the same or different, formed from cyclohexylbenzene and processes of making them.

8. 发明申请

WO2010042261A1 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2010042261A1
公开(公告)日：2010-04-15
申请号：PCT/US2009/050489
申请日：2009-07-14
申请人： EXXONMOBIL CHEMICAL COMPANY , DAKKA, Jihad, M. , WANG, Kun , MOZELESKI, Edmund, J. , ZUSHMA, Stephen
发明人： DAKKA, Jihad, M. , WANG, Kun , MOZELESKI, Edmund, J. , ZUSHMA, Stephen
IPC分类号： C07C37/08 , C07C45/53 , C07C409/08 , C07C409/14
CPC分类号： B01J23/002 , B01J21/066 , B01J23/28 , B01J23/30 , B01J23/888 , B01J31/0247 , B01J31/38 , B01J37/031 , B01J37/10 , B01J2523/00 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C409/14 , C07C2601/08 , C07C2601/14 , C07C2601/18 , Y02P20/52 , C07C39/04 , C07C49/10 , C07C49/403 , B01J2523/17 , B01J2523/48 , B01J2523/69 , B01J2523/842 , B01J2523/68
摘要： In a process for producing phenol or a substituted phenol, an alkylaromatic hydroperoxide having a general formula (I): R1 / (I) I2C R2 in which R1 and R2 each independently represents an alkyl group having from 1 to 4 carbon atoms, provided that R1 and R2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, said cyclic group being optionally substituted, and R3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group, is contacted with a catalyst comprising an oxide of at least one metal from Groups 3 to 5 and Groups 7 to 14 of the Periodic Table of the Elements and an oxide of at least one metal from Group 6 of the Periodic Table of the Elements.
摘要翻译：在制备苯酚或取代苯酚的方法中，具有通式（I）的烷基芳基氢过氧化物：其中R 1和R 2各自独立地表示具有1至4个碳原子的烷基的R1 /（I） R1和R2可以连接形成具有4至10个碳原子的环状基团，所述环状基团任选被取代，并且R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基的烷基被接触使用包含元素周期表第3至5族和第7至14族的至少一种金属的氧化物的催化剂和至少一种元素周期表第6族金属的氧化物。

9. 发明申请

WO2012082232A1 PROCESS FOR PRODUCING CYCLOALKYLAROMATIC COMPOUNDS 审中-公开
标题翻译：生产环烷基脂肪族化合物的方法
公开(公告)号：WO2012082232A1
公开(公告)日：2012-06-21
申请号：PCT/US2011/057598
申请日：2011-10-25
申请人： EXXONMOBIL CHEMICAL PATENST INC. , WANG, Kun , DAKKA, Jihad, M. , ZUSHMA, Stephen , LATTNER, James, R. , BECKER, Christopher, L. , CHEN, Tan-jen
发明人： WANG, Kun , DAKKA, Jihad, M. , ZUSHMA, Stephen , LATTNER, James, R. , BECKER, Christopher, L. , CHEN, Tan-jen
IPC分类号： C07C37/08 , C07C45/53 , C07C2/74 , C07C6/12 , C07C409/14 , C07C13/28 , C07C39/04
CPC分类号： C07C2/74 , C07C37/08 , C07C45/53 , C07C2529/08 , C07C2529/18 , C07C2529/70 , C07C2601/14 , C07C39/04 , C07C49/403 , C07C13/28
摘要： In a process for producing a cycloalkylaromatic compound, an aromatic compound and a cyclic olefin are contacted with a first catalyst under conditions effective to produce a reaction product comprising the cycloalkylaromatic compound and at least one non-fused bicyclic by-product. The at least one non-fused bicyclic by-product is then contacted with a second catalyst under conditions effective to convert at least a portion of the at least one non- fused bicyclic by-product to a converted by-product.
摘要翻译：在生产环烷基芳族化合物的方法中，使芳族化合物和环烯烃与第一催化剂在有效生成包含环烷基芳族化合物和至少一个非稠合双环的反应产物的条件下接触副产品。然后在有效将至少一种非稠合双环副产物的至少一部分转化为转化副产物的条件下，使至少一种非稠合双环副产物与第二催化剂接触。

10. 发明申请

WO2013052217A2 MIXED METAL OXIDE CATALYSTS AND USE THEREOF 审中-公开
标题翻译：混合金属氧化物催化剂及其用途
公开(公告)号：WO2013052217A2
公开(公告)日：2013-04-11
申请号：PCT/US2012/052878
申请日：2012-08-29
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , GARCIA, Roberto , SMITH, Charles, M. , LEVIN, Doron , VARTULI, James, C.
发明人： WANG, Kun , GARCIA, Roberto , SMITH, Charles, M. , LEVIN, Doron , VARTULI, James, C.
IPC分类号： B01J23/30
CPC分类号： C07C37/08 , B01J21/066 , B01J23/002 , B01J23/10 , B01J23/30 , B01J37/009 , B01J37/036 , B01J37/06 , C07C2/66 , C07C45/53 , C07C407/00 , C07C2529/70 , Y02P20/52 , C07C39/04 , C07C49/403
摘要： Disclosed herein are catalyst compositions useful in selective decomposition of organic oxygenates. A feed comprising an organic oxygenate may be contacted with a catalyst comprising (a) at least 0.1 wt% of an oxide of an element selected from Group 3 of the Periodic Table of Elements, wherein Group 3 includes the Lanthanide series; (b) at least 0.1 wt% of an oxide of an element selected from Group 6 of the Periodic Table of Elements; and (c) at least 0.1 wt.% of an oxide of at least one element selected from Group 4 of the Periodic Table of Elements, wherein the wt%s are based upon the total combined weight of the oxides in (a) through (c) and excludes any other components.
摘要翻译：本文公开了可用于选择性分解有机含氧化合物的催化剂组合物。包含有机含氧化合物的进料可以与催化剂接触，所述催化剂包含（a）至少0.1重量％的选自元素周期表第3族元素的氧化物，其中第3族包括镧系; （b）至少0.1重量％的选自元素周期表第6族的元素的氧化物; 和（c）至少0.1重量％的选自元素周期表第4族中的至少一种元素的氧化物，其中wt％基于（a）至（a）中的氧化物的总重量， c）并排除任何其他组成部分。

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