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1. 发明申请

WO2011031374A2 OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：烃的氧化
公开(公告)号：WO2011031374A2
公开(公告)日：2011-03-17
申请号：PCT/US2010/041801
申请日：2010-07-13
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , DAKKA, Jihad, M. , ZUSHMA, Stephen
发明人： WANG, Kun , DAKKA, Jihad, M. , ZUSHMA, Stephen
IPC分类号： C07C407/00
CPC分类号： C07C409/08 , C07C407/00 , C07C409/14 , C07C2601/14 , C07C409/10
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen- containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R 1 and R 2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO 3 H, NH 2 , OH and NO2, or from the atoms H, F, Cl, Br and I provided that R 1 and R 2 can be linked to one another via a covalent bond; each of Q 1 and Q 2 is independently selected from C, CH, N and CR 3 ; each of X and Z is independently selected from C, S, CH 2 , N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is O, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R 3 can be any of the entities listed for R 1 . The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with at least one solid sorbent chosen from alkali metal carbonates, alkali metal bicarbonates, alkali metal hydroxides, alkali metal hydroxide-carbonate complexes, alkaline earth metal carbonates, alkaline earth metal bicarbonates, alkaline earth metal hydroxides and alkaline earth metal hydroxide-carbonate complexes to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，在含有环状酰亚胺的催化剂存在下使烃与含氧气体接触（I）的基团：其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或来自基团 SO 3 H，NH 2，OH和NO 2，或者来自原子H，F，Cl，Br和I，条件是R 1和 R 2可以通过共价键相互连接; Q 1和Q 2中的每一个独立地选自C，CH，N和CR 3; X和Z中的每一个独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y是O或OH; k是0,1或2; 1是0,1或2; m是1至3，并且R 3可以是针对R 1所列出的任何实体。该接触产生包含氧化的烃产物和所述式（I）的未反应的酰亚胺催化剂的流出物，并且流出物用至少一种选自碱金属碳酸盐，碱金属碳酸氢盐，碱金属氢氧化物，碱金属氢氧化物 - 碳酸盐络合物，碱土金属碳酸盐，碱土金属碳酸氢盐，碱土金属氢氧化物和碱土金属氢氧化物 - 碳酸盐络合物以去除至少部分未反应的酰亚胺催化剂并产生包含所述氧化烃产物的经处理的流出物。然后可以回收有机相。

2. 发明申请

WO2010098916A2 PROCESS FOR PRODUCING PHENOL 审中-公开
标题翻译：生产苯酚的方法
公开(公告)号：WO2010098916A2
公开(公告)日：2010-09-02
申请号：PCT/US2010/021949
申请日：2010-01-25
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , WANG, Kun , BENITEZ, Francisco, M. , LATTNER, James, R. , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , ZUSHMA, Stephen
发明人： WANG, Kun , BENITEZ, Francisco, M. , LATTNER, James, R. , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , ZUSHMA, Stephen
IPC分类号： C07C37/08
CPC分类号： C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C409/10 , C07C409/14 , C07C2601/08 , C07C2601/14 , C07C49/403 , C07C49/10 , C07C49/395 , C07C49/08 , C07C39/04
摘要： Disclosed is a process for producing phenol or a substituted phenol and a co-product comprising the steps of (i) contacting a first stream comprising an alkylaromatic compound with a second stream comprising an oxygen-containing gas in the presence of a first catalyst comprising a cyclic imide under conditions to convert at least a portion of said alkylaromatic compound to an alkylaromatic hydroperoxide, (ii) producing an effluent stream comprising said cyclic imide, said alkylaromatic hydroperoxide, and said alkylaromatic compound wherein said effluent stream has an alkylaromatic hydroperoxide concentration of from 10 to 40 wt%; and (iii) contacting in a second reactor at least a portion of said effluent stream with a second catalyst to convert said alkylaromatic hydroperoxide to a product stream comprising phenol and said co-product.
摘要翻译：公开了生产苯酚或取代苯酚和副产物的方法，包括以下步骤：（i）使包含烷基芳族化合物的第一物流与包含含氧气体的第二物流在在将至少一部分所述烷基芳族化合物转化为烷基芳族氢过氧化物的条件下，存在包含环状酰亚胺的第一催化剂，（ii）产生包含所述环状酰亚胺，所述烷基芳族氢过氧化物和所述烷基芳族化合物的流出物流，其中所述流出物流具有10至40重量％的烷基芳族氢过氧化物浓度; 和（iii）在第二反应器中使至少一部分所述流出物流与第二催化剂接触以将所述烷基芳族氢过氧化物转化为包含苯酚和所述副产物的产物流。

3. 发明申请

WO2012036824A1 OXIDATION OF ALKYLBENZENES AND CYCLOALKYLBENZENES 审中-公开
标题翻译：氧化亚苄基和环丙基苯乙烯
公开(公告)号：WO2012036824A1
公开(公告)日：2012-03-22
申请号：PCT/US2011/047840
申请日：2011-08-16
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , SMITH, Charles, M. , BECKER, Christopher, L. , ZUSHMA, Stephen
发明人： DAKKA, Jihad, M. , MOZELESKI, Edmund, J. , SMITH, Charles, M. , BECKER, Christopher, L. , ZUSHMA, Stephen
IPC分类号： C07C409/14 , C07C2/74 , C07C13/28 , C07C37/08 , C07C39/04 , C07C45/53 , C07C49/403
CPC分类号： C07C407/00 , C07C2/74 , C07C37/08 , C07C37/11 , C07C45/53 , C07C51/16 , C07C249/08 , C07C2601/14 , C07D223/10 , Y02P20/52 , C07C409/10 , C07C409/14 , C07C409/06 , C07C251/44 , C07C13/28 , C07C39/04 , C07C49/403
摘要： A process for oxidizing a composition comprising contacting an alkylbenzene general formula (I): where R 1 and R 2 each independently represents hydrogen or an alkyl group having from 1 to 4 carbon atoms, wherein R 1 and R 2 may be joined to form a cyclic group having from 4 to 10 carbon atoms, the cyclic group being optionally substituted, and R 3 represents hydrogen, one or more alkyl groups having from 1 to 4 carbon atoms or a cyclohexyl group; and (ii) about 0.05 wt% to about 5 wt% of phenol, with oxygen in the presence of a catalyst containing a cyclic imide having the general formula (II): wherein X represents an oxygen atom, a hydroxyl group, or an acyloxy group under conditions effective to convert at least a portion of the alkylbenzene to a hydroperoxide.
摘要翻译：一种用于氧化组合物的方法，包括使通式（I）的烷基苯：其中R 1和R 2各自独立地表示氢或具有1至4个碳原子的烷基，其中R 1和R 2可以连接形成具有 4至10个碳原子，环状基团任选被取代，R 3表示氢，一个或多个具有1至4个碳原子的烷基或环己基; 和（ii）约0.05重量％至约5重量％的苯酚，在含有具有通式（II）的环状酰亚胺的催化剂存在下，使用氧：其中X表示氧原子，羟基或酰氧基在有效将至少一部分烷基苯转化为氢过氧化物的条件下进行。

4. 发明申请

WO2009058527A1 OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：氢氧化物
公开(公告)号：WO2009058527A1
公开(公告)日：2009-05-07
申请号：PCT/US2008/079150
申请日：2008-10-08
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , VARTULI, James, C. , ZUSHMA, Stephen
发明人： DAKKA, Jihad, M. , VARTULI, James, C. , ZUSHMA, Stephen
IPC分类号： C07C407/00 , C07C409/08 , C07C409/02 , C07C409/14 , C07C55/14 , C07C39/16
CPC分类号： C07C409/04 , B01D15/00 , B01J31/0235 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/33 , C07C45/53 , C07C407/00 , C07C407/003 , C07C409/08 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/06 , C07C409/10
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen- containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I); wherein each of R 1 and R 2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO 3 H, NH 2 , OH and NO2, or from the atoms H, F, Cl, Br and I provided that R 1 and R 2 can be linked to one another via a covalent bond; each of Q 1 and Q 2 is independently selected from C, CH, N and CR 3 ; each of X and Z is independently selected from C, S, CH 2 , N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is O, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R 3 can be any of the entities listed for R 1 . The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of said formula (I) and the effluent is treated with a solid sorbent to remove at least part of the unreacted imide catalyst and produce a treated effluent comprising said oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，在包含通式（I）的环状酰亚胺的催化剂的存在下，使烃与含氧气体接触; 其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或者来自SO 3 H，NH 2，OH和NO 2基团，或者从原子H，F，Cl，Br和I 并且R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k是O，1或2; 1是0,1或2; m为1至3，R3可为R1列出的任何实体。接触产生包含氧化烃产物和所述式（I）的未反应酰亚胺催化剂的流出物，并且用固体吸附剂处理流出物以除去至少部分未反应的酰亚胺催化剂并产生包含所述氧化烃产物的经处理的流出物。然后可以回收有机相。

5. 发明申请

WO2011066037A1 OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：氢氧化物
公开(公告)号：WO2011066037A1
公开(公告)日：2011-06-03
申请号：PCT/US2010/050970
申请日：2010-09-30
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , ZUSHMA, Stephen , COUTE, Nicolas, P. , BENITEZ, Francisco, M. , MOZELESKI, Edmund, J.
发明人： DAKKA, Jihad, M. , ZUSHMA, Stephen , COUTE, Nicolas, P. , BENITEZ, Francisco, M. , MOZELESKI, Edmund, J.
IPC分类号： C07C407/00 , C07C29/50 , C07C409/00
CPC分类号： C07C29/50 , C07C407/00 , C07C2601/14 , C07C35/08 , C07C409/14 , C07C409/04
摘要： In a process for oxidizing a hydrocarbon, the hydrocarbon is contacted with oxygen in the presence of an N-substituted cyclic imide and under conditions to oxidize the hydrocarbon to produce an oxidized hydrocarbon product and at least one decomposition product of the N-substituted cyclic imide. At least a portion of the at least one decomposition product is contacted with hydroxylamine or a salt thereof under conditions to convert the at least one decomposition product back to said imide.
摘要翻译：在氧化烃的方法中，在N-取代的环状酰亚胺的存在下，在氧化烃的条件下，使烃与氧接触以产生氧化的烃产物和至少一种N-取代的环状酰亚胺的分解产物。将至少一种分解产物的至少一部分与羟胺或其盐在将至少一种分解产物转化回所述酰亚胺的条件下接触。

6. 发明申请

WO2010074779A1 OXIDATION OF ALKYLAROMATIC COMPOUNDS 审中-公开
标题翻译：烷基化合物的氧化
公开(公告)号：WO2010074779A1
公开(公告)日：2010-07-01
申请号：PCT/US2009/057239
申请日：2009-09-17
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , ZUSHMA, Stephen , STANAT, Jon, E.
发明人： DAKKA, Jihad, M. , ZUSHMA, Stephen , STANAT, Jon, E.
IPC分类号： C07C407/00 , C07C409/02 , B01J31/02 , C07D209/48
CPC分类号： C07C407/00 , B01J31/006 , B01J31/0247 , B01J2231/70 , C07C37/08 , C07C45/53 , C07C409/08 , C07C409/10 , C07C409/14 , C07C2601/14 , C07D209/48 , Y02P20/52 , C07C39/04 , C07C49/08
摘要： In a process for oxidizing an alkylaromatic compound to the corresponding hydroperoxide, a feed comprising an alkylaromatic compound is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide. The contacting is conducted at a temperature of about 90°C to about 150°C, with the cyclic imide being present in an amount between about 0.05 wt% and about 5 wt% of the alkylarom in the feed and the catalyst being substantially free of alkali metal compounds. The contacting oxidizes at least part of the alkylaromatic compound in said feed to the corresponding hydroperoxide.
摘要翻译：在将烷基芳族化合物氧化成相应的氢过氧化物的方法中，包含烷基芳族化合物的进料在含有环状酰亚胺的催化剂存在下与含氧气体接触。接触在约90℃至约150℃的温度下进行，环状酰亚胺的存在量为进料中烷基溴的约0.05重量％至约5重量％，催化剂基本上不含碱金属化合物。接触将至少部分所述进料中的烷基芳族化合物氧化成相应的氢过氧化物。

7. 发明申请

WO2009025939A2 OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：烃的氧化
公开(公告)号：WO2009025939A2
公开(公告)日：2009-02-26
申请号：PCT/US2008/069779
申请日：2008-07-11
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , VARTULI, James, C. , ZUSHMA, Stephen
发明人： DAKKA, Jihad, M. , VARTULI, James, C. , ZUSHMA, Stephen
IPC分类号： C07C407/00 , C07C409/08
CPC分类号： C07C409/08 , C07C29/50 , C07C37/08 , C07C37/20 , C07C45/53 , C07C51/313 , C07C407/00 , C07C407/003 , C07C409/04 , C07C409/10 , C07C2601/14 , Y02P20/52 , C07C55/14 , C07C35/08 , C07C39/04 , C07C39/16 , C07C409/14
摘要： In a process for oxidizing a hydrocarbon to a corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, the hydrocarbon is contacted with an oxygen- containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I), wherein each of R 1 and R 2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO 3 H, NH 2 , OH and NO2, or from the atoms H, F, Cl, Br and I provided that R 1 and R 2 can be linked to one another via a covalent bond; each of Q 1 and Q 2 is independently selected from C, CH, N and CR 3 ; each of X and Z is independently selected from C, S, CH 2 , N, P and an element of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3, and R 3 can be any of the entities listed for R 1 . The contacting produces an effluent comprising an oxidized hydrocarbon product and unreacted imide catalyst of formula (I) and the effluent is treated with an aqueous solution of a base to produce an aqueous phase comprising at least part of the unreacted imide catalyst of formula (I) and an organic phase comprising oxidized hydrocarbon product. The organic phase can then be recovered.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，在含有环状酰亚胺的催化剂存在下使烃与含氧气体接触其中R 1和R 2各自独立地选自具有1至20个碳原子的烃基和取代的烃基，或来自基团 SO 3 H，NH 2，OH和NO 2，或者来自原子H，F，Cl，Br和I，条件是R 1和 R 2可以通过共价键相互连接; Q 1和Q 2中的每一个独立地选自C，CH，N和CR 3; X和Z中的每一个独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y是O或OH; k是0,1或2; 1是0,1或2; m是1至3，并且R 3可以是针对R 1所列出的任何实体。该接触产生包含氧化的烃产物和式（I）的未反应的酰亚胺催化剂的流出物，并将该流出物用碱的水溶液处理以产生包含至少部分式（I）的未反应的酰亚胺催化剂的水相，和包含氧化烃产物的有机相。然后可以回收有机相。

8. 发明申请

WO2008101617A1 OXIDATION OF SEC-BUTYLBENZENE AND PRODUCTON OF PHENOL AND METHYL ETHYL KETONE 审中-公开
标题翻译：苯乙烯和甲基乙基酮的甲苯磺酸氧化
公开(公告)号：WO2008101617A1
公开(公告)日：2008-08-28
申请号：PCT/EP2008/001044
申请日：2008-02-07
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , EXXONMOBIL CHEMICAL LIMITED , DAKKA, Jihad, M. , ZUSHMA, Stephen , STANAT, Jon, E.
发明人： DAKKA, Jihad, M. , ZUSHMA, Stephen , STANAT, Jon, E.
IPC分类号： C07C2/66 , C07C37/08 , C07C39/04 , C07C45/53 , C07C409/08 , C07C49/10
CPC分类号： C07C409/08 , C07C2/66 , C07C37/08 , C07C45/53 , C07C407/00 , C07C2529/70 , C07C15/02 , C07C49/10 , C07C39/04
摘要： In a process for oxidizing sec-butylbenzene to the corresponding hydroperoxide, a feed containing sec-butylbenzene is contacted with an oxygen- containing gas in a reactor comprising a gas inlet and a gas outlet for said oxygen- containing gas. The contacting is conducted at a temperature, T, in degrees Centigrade, between about 90°C and about 140°C and an oxygen partial pressure at the gas outlet of the reactor, Opp, in kPa determined by the formula (I) (1527.33 - 10.83T) > O pp > (1320.48 - 10.83T) (I), provided that Opp is always greater than zero. The resulting hydroperoxide can be cleaved, optionally in the presence of a catalyst, to co-produce phenol and methyl ethyl ketone.
摘要翻译：在将仲丁基苯氧化成相应的氢过氧化物的过程中，含有仲丁基苯的进料在含有气体入口的反应器和含氧气体的气体出口的反应器中与含氧气体接触。接触在T，以摄氏度，约90℃至约140℃之间的温度和反应器气体出口处的氧分压Opp（以公式（I）确定的kPa）（1527.33） - 1083T）>（1320.48-10.83T）（I），条件是Opp总是大于零。所得氢过氧化物可以任选在催化剂存在下裂解，共同生产苯酚和甲基乙基酮。

9. 发明申请

WO2010042273A1 OXIDATION OF HYDROCARBONS 审中-公开
标题翻译：氢氧化物
公开(公告)号：WO2010042273A1
公开(公告)日：2010-04-15
申请号：PCT/US2009/054000
申请日：2009-08-17
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , LATTNER, James, R. , HAGEMEISTER, Mark, P. , STANAT, Jon, E. , BUCHANAN, J., Scott , DAKKA, Jihad, M. , ZUSHMA, Stephen
发明人： LATTNER, James, R. , HAGEMEISTER, Mark, P. , STANAT, Jon, E. , BUCHANAN, J., Scott , DAKKA, Jihad, M. , ZUSHMA, Stephen
IPC分类号： C07C37/08 , C07C39/04 , C07C45/53 , B01J31/02
CPC分类号： C07C409/08 , C07C37/07 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/10 , C07C409/14 , C07C2601/14 , Y02P20/52 , C07C49/403 , C07C39/04
摘要： In a process for oxidizing a hydrocarbon to the corresponding hydroperoxide, alcohol, ketone, carboxylic acid or dicarboxylic acid, a reaction medium comprising a hydrocarbon is contacted with an oxygen-containing gas in a reaction zone and in the presence of a catalyst comprising a cyclic imide. During the oxidation process, a portion of the reaction medium is continuously or intermittently removed from the reaction zone, is stripped of water and organic acid impurities and then returned to the reaction zone.
摘要翻译：在将烃氧化成相应的氢过氧化物，醇，酮，羧酸或二羧酸的方法中，将包含烃的反应介质在反应区中与含氧气体接触，并且在包含环状酰亚胺。在氧化过程中，反应介质的一部分从反应区连续或间断地除去，汽提水和有机酸杂质，然后返回到反应区。

10. 发明申请

WO2010027562A1 PROCESS FOR PRODUCING ALKYLBENZENE HYDROPEROXIDES 审中-公开
标题翻译：生产烷基苯乙烯氢过氧化物的方法
公开(公告)号：WO2010027562A1
公开(公告)日：2010-03-11
申请号：PCT/US2009/050481
申请日：2009-07-14
申请人： EXXONMOBIL CHEMICAL PATENTS INC. , DAKKA, Jihad, M. , ZUSHMA, Stephen
发明人： DAKKA, Jihad, M. , ZUSHMA, Stephen
IPC分类号： C07C37/00 , C07C45/51 , C07C407/00
CPC分类号： C07C409/10 , C07C37/08 , C07C45/53 , C07C407/00 , C07C409/08 , C07C49/08 , C07C39/04
摘要： In a process for producing alkylbenzene hydroperoxides, a feed comprising (i) secbutylbenzene, (ii) cumene in an amount greater than 10 wt% of the total feed and (iii) at least one of iso-butylbenzene and tert-butylbenzene in an amount up to 20 wt% of the total feed is contacted with an oxygen-containing gas in the presence of a catalyst comprising a cyclic imide of the general formula (I): wherein each of R 1 and R 2 is independently selected from hydrocarbyl and substituted hydrocarbyl radicals having 1 to 20 carbon atoms, or from the groups SO 3 H, NH 2 , OH, and NO 2 or from the atoms H, F, Cl, Br, and I, provided that R 1 and R 2 can be linked to one another via a covalent bond; each of Q 1 and Q 2 is independently selected from C, CH, N and CR 3 ; each of X and Z is independently selected from C, S, CH 2 , N, P and elements of Group 4 of the Periodic Table; Y is O or OH; k is 0, 1, or 2; 1 is 0, 1, or 2; m is 1 to 3; and R 3 can be any of the entities listed for R 1 . The contacting is conducted under conditions to convert the sec- butylbenzene and cumene to their associated hydroperoxides.
摘要翻译：在制备烷基苯氢过氧化物的方法中，所述进料包含（i）仲丁基苯，（ii）大于总进料的10重量％的异丙基苯，和（iii）至少一种量的异丁基苯和叔丁基苯在包含通式（I）的环状酰亚胺的催化剂的存在下，将至多20重量％的总进料与含氧气体接触：其中R 1和R 2各自独立地选自烃基和取代的烃基具有1至20个碳原子，或由SO 3 H，NH 2，OH和NO 3基团或源自H，F，Cl，Br和I原子，条件是R 1和R 2可以通过共价键彼此连接; Q1和Q2中的每一个独立地选自C，CH，N和CR 3; X和Z各自独立地选自C，S，CH 2，N，P和元素周期表第4族的元素; Y为O或OH; k为0,1或2; 1是0,1或2; m为1〜3; 而R3可以是为R1列出的任何实体。在将仲丁基苯和异丙基苯转化为相关联的氢过氧化物的条件下进行接触。

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