会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 1. 发明授权
    • Preparation of hexafluoropropylene from the pyrolysis of trifluoromethane and tetrafluoroethylene
    • 从三氟甲烷和四氟乙烯的热解制备六氟丙烯
    • US06403848B1
    • 2002-06-11
    • US09820631
    • 2001-03-30
    • Dong Ju MoonHong Gon KimByoung Sung AhnMoon Jo ChungYoung Soo Kwon
    • Dong Ju MoonHong Gon KimByoung Sung AhnMoon Jo ChungYoung Soo Kwon
    • C07C1702
    • C07C17/269C07C21/18
    • The present invention relates to a process for preparing hexafluoropropylene(CF3CF═CF2, HFP) from the pyrolysis of trifluoromethane(CHF3, R23) and tetrafluoroethylene(C2F4, TFE) and more particularly, to the process for preparing hexafluoropropylene from the pyrolysis of an admixture of R23 and TFE mixed in an appropriate molar ratio at below 900 which is lower than the conventional reaction temperature and longer residence time, after investigating the pyrolysis reaction of R23 and TFE by the computer simulation. The process for preparing HFP is performed by carefully controlling reaction temperature with heat balance resulted from an endothermic pyrolysis of R23 and an exothermic dimerization of TFE to prevent from carbon formation, recycling unreacted R23 and TFE in the product separated and purified from distillation column, adding fresh R23 additionally to keep an appropriate molar ratio of R23 and TFE, to improve a total yield of HFP and to minimize heat supply from outside.
    • 本发明涉及从三氟甲烷(CHF 3,R 23)和四氟乙烯(C 2 F 4,TFE)的热解制备六氟丙烯(CF 3 CF = CF 2,HFP)的方法,更具体地说,涉及从混合物的热解制备六氟丙烯的方法 通过计算机模拟研究R23和TFE的热解反应后,R23和TFE以适合的摩尔比混合在900以下,低于常规反应温度和较长的停留时间。 制备HFP的过程是通过仔细控制反应温度和由R23的吸热热解产生的热平衡和TFE的放热二聚反应来防止形成碳,循环未反应的R23和TFE,从蒸馏塔中分离和纯化,加入 新鲜的R23另外保持适当的R23和TFE的摩尔比,以提高HFP的总产率并最小化从外部的供热。
    • 3. 发明授权
    • Process for manufacturing 1,1,1,2-tetrafluoroethane
    • 制备1,1,1,2-四氟乙烷的方法
    • US5841007A
    • 1998-11-24
    • US630678
    • 1996-04-12
    • Byoung Sung AhnYoung Soo KwonKun You ParkMoon Jo Chung
    • Byoung Sung AhnYoung Soo KwonKun You ParkMoon Jo Chung
    • C07C17/20C07C17/21C07C19/08C07C17/00
    • C07C19/08C07C17/206C07C17/21
    • The present invention relates to a process for manufacturing 1,1,1,2-tetrafluoroethane (HFC-134a) from trichloroethylene (TCE) and hydrogen fluoride (HF) by reacting the HCFC-133a with the HF to produce the HFC-134a and reacting the TCE with the HF to produce 1-choro-2,2,2-trifluoroethane (HCFC-133a), characterized by that a part of said HF is mixed with the mixture containing the HFC-134a and the remaining portion of said HF is fed with said TCE in portions to at least two sections of a reactor for producing said HCFC-133a. According the present process, the temperature change in the reactor for producing HCFC-133a is maintained within a narrow range over the whole reaction procedures, and the catalytic activity is well maintained. Further, the formation of by-products is considerably prevented and thus the productivity is remarkably enhanced.
    • 本发明涉及通过使HCFC-133a与HF反应生成HFC-134a,从三氯乙烯(TCE)和氟化氢(HF)制备1,1,1,2-四氟乙烷(HFC-134a) 使TCE与HF反应以产生1-氯-2,2,2-三氟乙烷(HCFC-133a),其特征在于,将所述HF的一部分与含有HFC-134a和所述HF的剩余部分的混合物混合 与所述TCE一起供给至用于生产所述HCFC-133a的反应器的至少两个部分。 根据本方法,生产HCFC-133a的反应器中的温度变化在整个反应过程中保持在窄范围内,并且催化活性得到很好的维持。 此外,可以显着地防止副产物的形成,从而显着提高生产率。