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    • 1. 发明授权
    • Method of forming a semiconductor thin film on a plastic substrate
    • 在塑料基板上形成半导体薄膜的方法
    • US06376290B1
    • 2002-04-23
    • US09116119
    • 1998-07-16
    • Dharam Pal GosainJonathan WestwaterMiyako NakagoeSetsuo UsuiKazumasa Nomoto
    • Dharam Pal GosainJonathan WestwaterMiyako NakagoeSetsuo UsuiKazumasa Nomoto
    • H01L2100
    • H01L29/66765H01L29/78603
    • A method is provided for forming a semiconductor thin film which is free from damage to the film with radiation of a pulse laser beam with the optimum energy value for perfect polycrystallization. For forming an amorphous silicon thin film, a surface of a plastic substrate as a base and insulating layers are each radiated with a pulse laser beam for removing volatile contaminants like a resist as a pretreatment. Damage to the film caused by a gas emitted from the base substrate and the insulating layers resulting from volatile contaminants is thus prevented. A protective layer including a gas barrier layer and a refractory buffer layer is formed on the substrate. Gas penetration from the substrate to the amorphous silicon film is thereby prevented. Conduction of heat produced by energy beam radiation to the substrate is prevented as well. It is possible to increase energy intensity of energy beam radiated for polycrystallization of the amorphous silicon film to the optimal value for perfect polycrystallization.
    • 提供了一种用于形成半导体薄膜的方法,该半导体薄膜不会损坏具有用于完美多晶化的最佳能量值的脉冲激光束的辐射。 为了形成非晶硅薄膜,以用作去除挥发性污染物如抗蚀剂的脉冲激光束作为基底和绝缘层的塑料基板的表面各自辐射,作为预处理。 因此防止了由基底衬底发出的气体和由挥发性污染物引起的绝缘层引起的膜损伤。 在基板上形成包括阻气层和难熔缓冲层的保护层。 从而防止了从基板到非晶硅膜的气体渗透。 也可以防止能量束辐射产生的热量传导到基板上。 可以将非晶硅膜的多晶化辐射的能量束的能量强度提高到完美多晶化的最佳值。
    • 5. 发明授权
    • Memory device, manufacturing method thereof and integrated circuit thereof
    • 存储器件及其制造方法及其集成电路
    • US06461917B2
    • 2002-10-08
    • US09888862
    • 2001-06-25
    • Kazumasa NomotoDharam Pal GosainSetsuo UsuiTakashi Noguchi
    • Kazumasa NomotoDharam Pal GosainSetsuo UsuiTakashi Noguchi
    • H01L218247
    • H01L27/1203B82Y10/00H01L21/84H01L27/115H01L29/7883
    • A memory device, a manufacturing method thereof, and an integrated circuit thereof are provided for storing information over a long period of time even if the memory device is manufactured at low temperatures. On a substrate made of glass, etc., a memory transistor and a selection transistor are formed, with a silicon nitride film and a silicon dioxide film in between. The memory transistor and the selection transistor are connected in series at a second impurity region. The conduction region for memory of the memory transistor is made of non-single crystal silicon and a storage region comprises a plurality of dispersed particulates made of non-single crystal silicon. Therefore, electrical charges can be stored partially if a tunnel insulating film has any defects. The tunnel insulating film is formed by exposing the surface of the conduction region for memory to the ionized gas containing oxygen atoms.
    • 提供了一种存储器件,其制造方法及其集成电路,用于长时间存储信息,即使存储器件在低温下制造。 在由玻璃等制成的基板上,形成存储晶体管和选择晶体管,其间具有氮化硅膜和二氧化硅膜。 存储晶体管和选择晶体管在第二杂质区域串联连接。 用于存储晶体管的存储器的导电区域由非单晶硅制成,并且存储区域包括由非单晶硅制成的多个分散的微粒。 因此,如果隧道绝缘膜有任何缺陷,则可以部分地存储电荷。 隧道绝缘膜通过将用于记忆的导电区域的表面暴露于含有氧原子的电离气体而形成。
    • 6. 发明授权
    • Memory device having a storage region is constructed with a plurality of dispersed particulates
    • 具有存储区域的存储器件由多个分散的颗粒构成
    • US06274903B1
    • 2001-08-14
    • US09404479
    • 1999-09-24
    • Kazumasa NomotoDharam Pal GosainSetsuo UsuiTakashi Noguchi
    • Kazumasa NomotoDharam Pal GosainSetsuo UsuiTakashi Noguchi
    • H01L29788
    • H01L27/1203B82Y10/00H01L21/84H01L27/115H01L29/7883
    • A memory device, a manufacturing method thereof, and an integrated circuit thereof are provided for storing information over a long period of time even if the memory device is manufactured at low temperatures. On a substrate made of glass, etc., a memory transistor and a selection transistor are formed, with a silicon nitride film and a silicon dioxide film in between. The memory transistor and the selection transistor are connected in series at a second impurity region. The conduction region for memory of the memory transistor is made of non-single crystal silicon and a storage region comprises a plurality of dispersed particulates made of non-single crystal silicon. Therefore, electrical charges can be stored partially if a tunnel insulating film has any defects. The tunnel insulating film is formed by exposing the surface of the conduction region for memory to the ionized gas containing oxygen atoms.
    • 提供了一种存储器件,其制造方法及其集成电路,用于长时间存储信息,即使存储器件在低温下制造。 在由玻璃等制成的基板上,形成存储晶体管和选择晶体管,其间具有氮化硅膜和二氧化硅膜。 存储晶体管和选择晶体管在第二杂质区域串联连接。 用于存储晶体管的存储器的导电区域由非单晶硅制成,并且存储区域包括由非单晶硅制成的多个分散的微粒。 因此,如果隧道绝缘膜有任何缺陷,则可以部分地存储电荷。 隧道绝缘膜通过将用于记忆的导电区域的表面暴露于含有氧原子的电离气体而形成。
    • 7. 发明授权
    • Optical energy conversion apparatus
    • 光能转换装置
    • US07199303B2
    • 2007-04-03
    • US10221719
    • 2001-03-13
    • Akio MachidaSetsuo UsuiKazumasa Nomoto
    • Akio MachidaSetsuo UsuiKazumasa Nomoto
    • H01N6/00
    • H01L31/03682Y02E10/546
    • An optical energy conversion apparatus 10 includes a first impurity doped semiconductor layer 5, formed on a substrate, and which is of a semiconductor material admixed with a first impurity, an optically active layer 6, formed on the first impurity doped semiconductor layer 5, and which is of a hydrogen-containing amorphous semiconductor material, and a second impurity doped semiconductor layer 7, admixed with a second impurity and formed on the optically active semiconductor layer 6. The second impurity doped semiconductor layer is of a polycrystallized semiconductor material lower in hydrogen concentration than the material of the optically active semiconductor layer 6. The average crystal grain size in the depth-wise direction in an interfacing structure between the optically active semiconductor layer 6 and the second impurity doped semiconductor layer 7 is decreased stepwise in a direction proceeding from the surface of the second impurity doped semiconductor layer towards the substrate 1. By controlling the hydrogen concentration of the second impurity doped semiconductor layer 7, the number of dangling bonds in the second impurity doped semiconductor layer 7 is significantly decreased to exhibit superior crystallinity to improve the conversion efficiency of the apparatus 10.
    • 光能转换装置10包括形成在基板上的第一杂质掺杂半导体层5,其是与第一杂质混合的半导体材料,形成在第一杂质掺杂半导体层5上的光学活性层6,以及 其是含氢非晶半导体材料,和第二杂质掺杂半导体层7,与第二杂质混合并形成在光学活性半导体层6上。 第二杂质掺杂半导体层是多晶半导体材料,其氢浓度低于光学活性半导体层6的材料。 在光学活性半导体层6和第二杂质掺杂半导体层7之间的界面结构中的深度方向上的平均晶粒尺寸在从第二杂质掺杂半导体层的表面朝向衬底的方向上逐步降低 1。 通过控制第二杂质掺杂半导体层7的氢浓度,第二杂质掺杂半导体层7中的悬挂键数量显着降低,以显示出优异的结晶度,从而提高了装置10的转换效率。
    • 8. 发明申请
    • Optical energy conversion apparatus
    • 光能转换装置
    • US20050092358A1
    • 2005-05-05
    • US10999049
    • 2004-11-29
    • Akio MachidaSetsuo UsuiKazumasa Nomoto
    • Akio MachidaSetsuo UsuiKazumasa Nomoto
    • H01L31/00H01L31/0368
    • H01L31/03682Y02E10/546
    • An optical energy conversion apparatus 10 includes a first impurity doped semiconductor layer 5, formed on a substrate, and which is of a semiconductor material admixed with a first impurity, an optically active layer 6, formed on the first impurity doped semiconductor layer 5, and which is of a hydrogen-containing amorphous semiconductor material, and a second impurity doped semiconductor layer 7, admixed with a second impurity and formed on the optically active semiconductor layer 6. The second impurity doped semiconductor layer is of a polycrystallized semiconductor material lower in hydrogen concentration than the material of the optically active semiconductor layer 6. The average crystal grain size in the depth-wise direction in an interfacing structure between the optically active semiconductor layer 6 and the second impurity doped semiconductor layer 7 is decreased stepwise in a direction proceeding from the surface of the second impurity doped semiconductor layer towards the substrate 1. By controlling the hydrogen concentration of the second impurity doped semiconductor layer 7, the number of dangling bonds in the second impurity doped semiconductor layer 7 is significantly decreased to exhibit superior crystallinity to improve the conversion efficiency of the apparatus 10.
    • 光能转换装置10包括形成在基板上的第一杂质掺杂半导体层5,其是与第一杂质混合的半导体材料,形成在第一杂质掺杂半导体层5上的光学活性层6,以及 其是含氢非晶半导体材料,和第二杂质掺杂半导体层7,与第二杂质混合并形成在光学活性半导体层6上。 第二杂质掺杂半导体层是多晶半导体材料,其氢浓度低于光学活性半导体层6的材料。 在光学活性半导体层6和第二杂质掺杂半导体层7之间的界面结构中的深度方向上的平均晶粒尺寸在从第二杂质掺杂半导体层的表面朝向衬底的方向上逐步降低 1。 通过控制第二杂质掺杂半导体层7的氢浓度,第二杂质掺杂半导体层7中的悬挂键数量显着降低,以显示出优异的结晶度,从而提高了装置10的转换效率。