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1. 发明授权

US6018074A Process for the preparation of polyalcohols 失效
标题翻译：制备多元醇的方法
公开(公告)号：US6018074A
公开(公告)日：2000-01-25
申请号：US68300
申请日：1998-10-05
申请人： Detlef Kratz , Achim Stammer , Tom Witzel , Martin Brudermuller
发明人： Detlef Kratz , Achim Stammer , Tom Witzel , Martin Brudermuller
IPC分类号： C07C27/02 , C07C29/09 , C07C29/128 , C07C29/38 , C07C31/22 , C07C35/08 , C07C67/02 , C07C67/08 , C07C67/44 , C07C69/06 , C07C45/00 , C07C31/18
CPC分类号： C07C29/38 , C07C29/1285 , C07C67/08 , C07C2101/14
摘要： A process for the preparation of polyalcohols comprises the stages:(a) Reaction of an alkanal or ketone with formaldehyde in aqueous solution in the presence of a tertiary amine, to form a formates containing polyalcohol product mixture,(b) removal of water, excess tertiary amine, excess formaldehyde(c) heating of remaining mixture from (b) with removal of further formaldehyde and tertiary amine with formation of the formates of the polyalcohol,(d) transfer of tertiary amine removed from stage (b) and/or from stage (c), to synthesis stage (a) and/or to the subsequent transesterification stage (e),(e) transesterification of the resulting formates of the polyalcohol from stage (c) with an alcohol of the formula ROH in the presence of a transesterification catalyst to give polyalcohols and formates of the formula ##STR1## where R is a hydrocarbon radical, preferably alkyl of 1-6, particularly preferably 1-2, carbon atoms, and(f) isolation of the polyalcohols.
摘要翻译： PCT No.PCT / EP96 / 04922 Sec。 371日期：1998年10月5日 102（e）日期1998年10月5日PCT 1996年11月11日PCT公布。公开号WO97 / 17313 日期1997年5月15日制备多元醇的方法包括以下阶段：（a）在叔胺存在下，在水溶液中使烷醛或酮与甲醛反应，形成含有多元醇产物混合物的甲酸盐，（b）的水，过量的叔胺，过量的甲醛（c）从（b）加热剩余的混合物，同时除去多元醇的甲酸盐形成的另外的甲醛和叔胺，（d）从阶段（b）中除去的叔胺的转移，和（或）从阶段（c）到合成阶段（a）和/或后续酯交换反应阶段（e），（e）所得到的多元醇的甲酸酯从阶段（c）与式ROH的醇进行酯交换反应在酯交换催化剂的存在下，得到下式的多元醇和甲酸盐，其中R是烃基，优选1-6的烷基，特别优选1-2的碳原子，和（f）多元醇的分离。

2. 发明授权

US06809224B2 Method for the separation of formaldehyde from a reaction mixture containing polyols by the addition of solvents before and/or during the distillation 失效
标题翻译：在蒸馏之前和/或期间通过加入溶剂从含有多元醇的反应混合物中分离甲醛的方法
公开(公告)号：US06809224B2
公开(公告)日：2004-10-26
申请号：US10168999
申请日：2002-06-26
申请人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Gerhard Schulz
发明人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Gerhard Schulz
IPC分类号： C07C4582
CPC分类号： C07C45/82 , C07C45/83 , C07C47/19
摘要： Formaldehyde is removed by distillation from reaction solutions containing a methlolated alkanal which was obtained from the reaction of formaldehyde with an alkanal which has at least one acidic hydrogen atom &agr; to the carbonyl function or from the reaction of a 2-alkylacrolein or acrolein with water and formaldehyde, by a process in which this reaction was carried out in the presence of catalytic amounts of organic amine. The process permits the improved removal of formaldehyde from the reaction mixture and furthermore facilitates the hydrogenation of the alkanals thus obtained to give polyols.
摘要翻译：从甲醛与具有至少一个羰基官能度的至少一个酸性氢原子的α-烷醛或由2-烷基丙烯醛或丙烯醛与水的反应的甲醛反应获得的含有甲基化的烷醛的反应溶液中蒸馏除去甲醛，甲醛，通过在催化量的有机胺存在下进行该反应的方法。该方法允许从反应混合物中改善甲醛的去除，并且进一步促进由此获得的链烷烃的氢化以产生多元醇。

3. 发明授权

US06586642B2 Color number improvement in polyhydric alcohols by hydrogenation 失效
公开(公告)号：US06586642B2
公开(公告)日：2003-07-01
申请号：US10168986
申请日：2002-06-26
申请人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Mathias Haake , Michael Koch , Gerhard Schulz
发明人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Mathias Haake , Michael Koch , Gerhard Schulz
IPC分类号： C07C2726
CPC分类号： C07C29/90 , C07C29/80 , Y02P20/582 , C07C31/20 , C07C31/22 , C07C31/245
摘要： A process for greatly improving the color index of polyhydric alcohols, especially trimethylolpropane, by hydrogenation comprises using, in the hydrogenation, an alcohol which has already been purified by distillation. The catalysts used are those conventionally employed in hydrogenations, preferably copper, nickel, palladium or ruthenium catalysts.

4. 发明授权

US06586641B2 Method for the decomposition of high boiling by-products produced in the synthesis of polyhydric alcohols 失效
标题翻译：分解合成多元醇产生的高沸点副产物的方法
公开(公告)号：US06586641B2
公开(公告)日：2003-07-01
申请号：US10169001
申请日：2002-06-26
申请人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Gerhard Schulz
发明人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Gerhard Schulz
IPC分类号： C07C3118
CPC分类号： C07C29/80 , C07C31/20 , C07C31/22 , C07C31/205 , C07C31/245
摘要： A process is provided for increasing the yield in the preparation of polyhydric alcohols obtained from methylolated alkanals by hydrogenation, wherein derivatives of these alcohols are decomposed by adding 5 ppm to 1% by weight, preferably 100 to 1000 ppm, of a suitable acid to an anhydrous mixture containing these derivatives, heating the mixture to temperatures of 100 to 300° C. and then separating off the polyhydric alcohol by distillation. This process makes it possible simply and efficiently to decompose compounds which boil above the polyhydric alcohol and are unwanted by-products of its synthesis.
摘要翻译：提供了一种通过氢化提高由羟甲基化的链烷醇制备的多元醇的产率的方法，其中这些醇的衍生物通过将5ppm至1wt％，优选100-1000ppm的合适的酸加成到含有这些衍生物的无水混合物，将混合物加热至100-300℃，然后蒸馏除去多元醇。该方法使得可以简单有效地分解沸腾在多元醇上的化合物并且是其合成的不希望的副产物。

5. 发明授权

US06692616B2 Method for purifying trimethylolpropane, which is produced by hydrogenation, by means of continuous distillation 失效
标题翻译：通过连续蒸馏通过氢化制备三羟甲基丙烷的方法
公开(公告)号：US06692616B2
公开(公告)日：2004-02-17
申请号：US10168980
申请日：2002-06-26
申请人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Harald Rust , Gerhard Schulz
发明人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Harald Rust , Gerhard Schulz
IPC分类号： B01D314
CPC分类号： C07C29/80 , C07C31/225 , C07C31/12 , C07C31/245 , C07C31/04
摘要： A process is disclosed for the purification, by distillation, of trimethylolpropane originating from the hydrogenation of 2,2-dimethylolbutanal, said process including the following steps: (a) reaction of n-butyraldehyde with formaldehyde in the presence of catalytic amounts of a tertiary amine, and hydrogenation of the resulting mixture to give a mixture containing trimethylolpropane; (b) separation of water, methanol, trialkylamine and/or trialkylammonium formate by distillation; (c) heating of the residue obtained in (b) under reduced pressure to a temperature at which TMP is volatile and compounds boiling above TMP are cleaved, in order to separate off, by distillation, TMP and compounds more volatile than TMP; (d) distillation of the distillate obtained in (c) in order to separate off the more volatile compounds and recover pure TMP; and (e) optional distillation of the TMP obtained in (d) in order to recover TMP with a low APHA color index. A process is also disclosed in which trialkylammonium formate is distilled under mild conditions from crude mixtures of polyhydric alcohols, predominantly trimethylolpropane.
摘要翻译：公开了一种通过蒸馏纯化来自2,2-二羟甲基丁烷的氢化的三羟甲基丙烷的方法，所述方法包括以下步骤：（a）在催化量的叔碳酸存在下，正丁醛与甲醛的反应胺，并氢化得到的混合物，得到含有三羟甲基丙烷的混合物;（b）通过蒸馏分离水，甲醇，三烷基胺和/或三烷基铵甲酸盐;（c）将（b）中得到的残余物在减压下加热至 TMP挥发的温度和TMP沸点高的化合物被切割，以便通过蒸馏分离TMP和比TMP更易挥发的化合物;（d）蒸馏（c）中获得的馏出物，以分离出更多的挥发性化合物，回收纯TMP; 为了回收具有低APHA颜色指数的TMP，还可以任选地蒸馏（d）中获得的TMP。还公开了一种方法，其中在温和条件下从多元醇，主要是三羟甲基丙烷的粗混合物中蒸馏出三烷基铵甲酸盐。

6. 发明授权

US06187971B1 Method for producing polyalcohols 失效
标题翻译：生产多元醇的方法
公开(公告)号：US06187971B1
公开(公告)日：2001-02-13
申请号：US09331370
申请日：1999-06-21
申请人： Detlef Kratz , Achim Stammer , Gerhard Schulz , Guido Voit
发明人： Detlef Kratz , Achim Stammer , Gerhard Schulz , Guido Voit
IPC分类号： C07C3118
CPC分类号： C07C45/75 , C07C29/141 , Y02P20/582 , C07C31/04 , C07C31/12 , C07C31/125 , C07C31/20 , C07C31/22
摘要： Methylolalkanal of the formula II (R=CH2OH, C1-C22-alkyl, aryl or C6-C22-aralkyl) is prepared spe-wise by a) reacting a C2-C24-aldehyde with formaldehyde in the presence of a tertiary amine, b) separating the reaction mixture i) into a bottom fraction comprising the compound of formula II and an incompletely methylolated compound of the formula III and a distillate stream comprising unconverted or partially converted starting materials, or ii) into an aqueous phase and an organic phase, and recycling the distillate stream or the organic phase to a), and c) subjecting the bottom fraction or the aqueous phase i) to a catalytic or thermal reaction to convert the compound of formula III to the compound of formula II and to a corresponding methylene compound of formula IV (R′=H or R) and ii) separating the reaction product into an overhead stream comprising the compound of formula IV and unconverted formaldehyde which is recycled to a), and a bottom fraction comprising the compound of formula II.
摘要翻译：在叔胺存在下，通过使C2-C24-醛与甲醛反应制备式II的（C 1 -C 22 - 烷基，芳基或C 6 -C 22 - 芳烷基）的羟甲基烷醛，b）将反应混合物分离）至包含式II化合物的底部馏分和式III的不完全羟甲基化的化合物和包含未转化的或部分转化的起始物质的馏出物流，或ii）进入水相和有机相，并将馏出物流或有机相至a），和c）使底部馏分或水相）进行催化或热反应以将式III化合物转化为式II化合物和相应的式IV的亚甲基化合物（R '= H或R）和ii）将反应产物分离成包含式IV化合物和未转化甲醛的塔顶物流，将其再循环至a），以及包含式II化合物的塔底馏分。

7. 发明授权

US5756839A Process for preparing D,L-aspartic acid from ammonium salts of the maleic acid 失效
标题翻译：从马来酸的铵盐制备D，L-天冬氨酸的方法
公开(公告)号：US5756839A
公开(公告)日：1998-05-26
申请号：US809141
申请日：1997-03-24
申请人： Detlef Kratz , Tom Witzel , Rudolf Bazner , Matthias Kroner , Uwe Pressler
发明人： Detlef Kratz , Tom Witzel , Rudolf Bazner , Matthias Kroner , Uwe Pressler
IPC分类号： C07C227/06 , C07C229/24 , C07C227/00 , C07C229/00
CPC分类号： C07C227/06 , C07C229/24
摘要： A process is disclosed for preparing D,L-aspartic acid by beating aqueous solutions of ammonium salts of the maleic acid. The molar ratio of maleic acid to ammonia ranges from 1:1 to 1:50. The process is carried out at temperatures from 60.degree. to 250.degree. C. and pressures of at least 1 bar. The pressure applied during the reaction is adjusted to ensure that the reaction mixture is almost completely present in liquid phase. Excess ammonia is removed and the reaction solution is acidified so as to release D,L-aspartic acid, which is then isolated.
摘要翻译： PCT No.PCT / EP95 / 03600 Sec。 371日期1997年3月24日 102（e）1997年3月24日PCT PCT 1995年9月13日PCT公布。出版物WO96 / 09277 日期：1996年3月28日公开了通过马来酸的铵盐的打浆水溶液制备D，L-天冬氨酸的方法。马来酸与氨的摩尔比为1:1至1:50。该方法在60℃至250℃的温度和至少1巴的压力下进行。调节反应期间施加的压力以确保反应混合物几乎完全存在于液相中。除去过量的氨，并将反应溶液酸化，以释放分离的D，L-天冬氨酸。

8. 发明授权

US06201160B1 Preparation of alcohols 失效
标题翻译：醇的制备
公开(公告)号：US06201160B1
公开(公告)日：2001-03-13
申请号：US08737736
申请日：1996-11-19
申请人： Martin Brudermüller , Matthias Irgang , Martin Schmidt-Radde , Franz Merger , Tom Witzel , Detlef Kratz , Eckehard Danz , Arnold Wittwer , Michael Hesse , Manfred Sauerwald , Cristina Freire Erdbrügger
发明人： Martin Brudermüller , Matthias Irgang , Martin Schmidt-Radde , Franz Merger , Tom Witzel , Detlef Kratz , Eckehard Danz , Arnold Wittwer , Michael Hesse , Manfred Sauerwald , Cristina Freire Erdbrügger
IPC分类号： C07C2704
CPC分类号： C07C29/145 , B01J21/08 , B01J23/72 , B01J23/868 , C07C29/141 , C07C29/175 , C07C2601/08 , C07C2603/68 , C07C31/205 , C07C31/20 , C07C31/12 , C07C31/125 , C07C31/278 , C07C31/274
摘要： Alcohols are prepared by the catalytic hydrogenation of the corresponding carbonyl compounds at elevated temperatures and at superatmospheric pressure in the liquid phase by a process in which the catalyst used contains copper on an SiO2-containing carrier in the presence or absence of one or more of the elements magnesium, barium, zinc and chromium.
摘要翻译：醇通过在液相中在升高的温度和超大气压下的催化氢化制备，其中使用的催化剂在含有SiO 2的载体上含有铜，在存在或不存在一种或多种元素镁，钡，锌和铬。

9. 发明授权

US07943047B2 Process for the treatment of wastewater from aldolization processes 有权
标题翻译：用于处理醛醇醛化工艺废水的工艺
公开(公告)号：US07943047B2
公开(公告)日：2011-05-17
申请号：US12088777
申请日：2006-09-25
申请人： Siegmar Maassen , Roland Krokoszinski , Detlef Kratz
发明人： Siegmar Maassen , Roland Krokoszinski , Detlef Kratz
IPC分类号： B01D11/04 , C07C45/80
CPC分类号： C07C45/74 , B01D3/143 , C02F1/04 , C02F1/20 , C02F1/26 , C02F1/66 , C02F9/00 , C02F2103/36 , C02F2209/06 , C07C45/80 , Y10S210/908 , C07C47/21
摘要： Process for the treatment of wastewater from an aldolization process which is contaminated with water-soluble and/or dispersed organic impurities by means of single-stage or multistage extraction with an organic liquid of the aldolization process wastewater which has been set to a pH of from 0 to 6, in which an organic liquid obtained by stripping of the acidified aldolization process wastewater or of the acidified and extracted aldolization process wastewater, condensation of the stripped compounds and phase separation of the condensate is used as extractant for the extraction of organic impurities from the acidified aldolization process wastewater and wastewater having a lower content of organic impurities than the aldolization process wastewater fed to the extraction is taken off from the stripping apparatus.
摘要翻译：用于通过单级或多级萃取与水溶性和/或分散的有机杂质污染的醛醇醛化方法处理废水的方法，该方法已经设定为pH为 0至6，其中通过汽提酸化的醛化工艺废水或酸化和提取的醛醇化工艺废水获得的有机液体，汽提化合物的冷凝和冷凝物的相分离用作萃取剂，用于萃取有机杂质酸化的醛醇化工艺废水和有机杂质含量低于进料到萃取的醛化工艺废水中的废水从汽提装置中取出。

10. 发明申请

US20090149584A1 USE OF HEXAHYDROPHTHALIMIDE COMBINATIONS AS SOFTENER 审中-公开
标题翻译：使用十六氢化合物作为SOFTENER
公开(公告)号：US20090149584A1
公开(公告)日：2009-06-11
申请号：US12297839
申请日：2007-04-20
申请人： Klemens Massonne , Boris Breitscheidel , Jurgen Holzmann , Axel Salden , Klaus Rossato , Martina Egen , Detlef Kratz , Lucien Thil , Jan-Dirk Arndt
发明人： Klemens Massonne , Boris Breitscheidel , Jurgen Holzmann , Axel Salden , Klaus Rossato , Martina Egen , Detlef Kratz , Lucien Thil , Jan-Dirk Arndt
IPC分类号： C08K5/3417
CPC分类号： C07D209/48 , C08K5/3417 , C08L27/06
摘要： The use of hexahydrophthalimide compounds of the formula (I) is described as plasticizers for molding compositions, in particular polyvinyl chloride, in which R is alkyl, cycloalkyl, or cycloalkylalkyl, where the two last named moieties can be unsubstituted or alkyl-substituted, and the moiety R has at least 6 carbon atoms.
摘要翻译：将式（I）的六氢邻苯二甲酰亚胺化合物用作模塑组合物，特别是聚氯乙烯的增塑剂，其中R是烷基，环烷基或环烷基烷基，其中两个最后命名的部分可以是未取代的或烷基取代的，以及部分R具有至少6个碳原子。

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