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1. 发明申请

US20090149584A1 USE OF HEXAHYDROPHTHALIMIDE COMBINATIONS AS SOFTENER 审中-公开
标题翻译：使用十六氢化合物作为SOFTENER
公开(公告)号：US20090149584A1
公开(公告)日：2009-06-11
申请号：US12297839
申请日：2007-04-20
申请人： Klemens Massonne , Boris Breitscheidel , Jurgen Holzmann , Axel Salden , Klaus Rossato , Martina Egen , Detlef Kratz , Lucien Thil , Jan-Dirk Arndt
发明人： Klemens Massonne , Boris Breitscheidel , Jurgen Holzmann , Axel Salden , Klaus Rossato , Martina Egen , Detlef Kratz , Lucien Thil , Jan-Dirk Arndt
IPC分类号： C08K5/3417
CPC分类号： C07D209/48 , C08K5/3417 , C08L27/06
摘要： The use of hexahydrophthalimide compounds of the formula (I) is described as plasticizers for molding compositions, in particular polyvinyl chloride, in which R is alkyl, cycloalkyl, or cycloalkylalkyl, where the two last named moieties can be unsubstituted or alkyl-substituted, and the moiety R has at least 6 carbon atoms.
摘要翻译：将式（I）的六氢邻苯二甲酰亚胺化合物用作模塑组合物，特别是聚氯乙烯的增塑剂，其中R是烷基，环烷基或环烷基烷基，其中两个最后命名的部分可以是未取代的或烷基取代的，以及部分R具有至少6个碳原子。

2. 发明授权

US06380443B1 Preparation of 1,3-diols 失效
标题翻译： 1,3-二醇的制备
公开(公告)号：US06380443B1
公开(公告)日：2002-04-30
申请号：US09677862
申请日：2000-10-03
申请人： Detlef Kratz , Harald Rust , Roland Krokoszinski , Volker Helf
发明人： Detlef Kratz , Harald Rust , Roland Krokoszinski , Volker Helf
IPC分类号： C07C2704
CPC分类号： C07C45/72 , C07C29/141 , C07C45/50 , C07C47/02 , C07C31/20 , C07C31/125
摘要： A process for preparing 1,3-diols having 6 or more carbon atoms comprises a) provision of at least one alkanal having at least three carbon atoms; b) thermal treatment of the alkanal in the absence of a basic catalyst; c) hydrogenation of the aldol addition product formed in step b); and d) isolation of the 1,3-diol obtained. The process of the present invention makes it possible to prepare 1,3-diols simply and inexpensively.
摘要翻译：制备具有6个或更多个碳原子的1,3-二醇的方法包括：a）提供至少一种具有至少三个碳原子的链烷烃; b）在没有碱性催化剂的情况下热处理链烷烃; c）步骤b）中形成的醛醇加成产物的氢化; 和d）所获得的1,3-二醇的分离。本发明的方法使得可以简单且廉价地制备1,3-二醇。

3. 发明授权

US06201160B1 Preparation of alcohols 失效
标题翻译：醇的制备
公开(公告)号：US06201160B1
公开(公告)日：2001-03-13
申请号：US08737736
申请日：1996-11-19
申请人： Martin Brudermüller , Matthias Irgang , Martin Schmidt-Radde , Franz Merger , Tom Witzel , Detlef Kratz , Eckehard Danz , Arnold Wittwer , Michael Hesse , Manfred Sauerwald , Cristina Freire Erdbrügger
发明人： Martin Brudermüller , Matthias Irgang , Martin Schmidt-Radde , Franz Merger , Tom Witzel , Detlef Kratz , Eckehard Danz , Arnold Wittwer , Michael Hesse , Manfred Sauerwald , Cristina Freire Erdbrügger
IPC分类号： C07C2704
CPC分类号： C07C29/145 , B01J21/08 , B01J23/72 , B01J23/868 , C07C29/141 , C07C29/175 , C07C2601/08 , C07C2603/68 , C07C31/205 , C07C31/20 , C07C31/12 , C07C31/125 , C07C31/278 , C07C31/274
摘要： Alcohols are prepared by the catalytic hydrogenation of the corresponding carbonyl compounds at elevated temperatures and at superatmospheric pressure in the liquid phase by a process in which the catalyst used contains copper on an SiO2-containing carrier in the presence or absence of one or more of the elements magnesium, barium, zinc and chromium.
摘要翻译：醇通过在液相中在升高的温度和超大气压下的催化氢化制备，其中使用的催化剂在含有SiO 2的载体上含有铜，在存在或不存在一种或多种元素镁，钡，锌和铬。

4. 发明授权

US06692616B2 Method for purifying trimethylolpropane, which is produced by hydrogenation, by means of continuous distillation 失效
标题翻译：通过连续蒸馏通过氢化制备三羟甲基丙烷的方法
公开(公告)号：US06692616B2
公开(公告)日：2004-02-17
申请号：US10168980
申请日：2002-06-26
申请人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Harald Rust , Gerhard Schulz
发明人： Matthias Dernbach , Detlef Kratz , Achim Stammer , Harald Rust , Gerhard Schulz
IPC分类号： B01D314
CPC分类号： C07C29/80 , C07C31/225 , C07C31/12 , C07C31/245 , C07C31/04
摘要： A process is disclosed for the purification, by distillation, of trimethylolpropane originating from the hydrogenation of 2,2-dimethylolbutanal, said process including the following steps: (a) reaction of n-butyraldehyde with formaldehyde in the presence of catalytic amounts of a tertiary amine, and hydrogenation of the resulting mixture to give a mixture containing trimethylolpropane; (b) separation of water, methanol, trialkylamine and/or trialkylammonium formate by distillation; (c) heating of the residue obtained in (b) under reduced pressure to a temperature at which TMP is volatile and compounds boiling above TMP are cleaved, in order to separate off, by distillation, TMP and compounds more volatile than TMP; (d) distillation of the distillate obtained in (c) in order to separate off the more volatile compounds and recover pure TMP; and (e) optional distillation of the TMP obtained in (d) in order to recover TMP with a low APHA color index. A process is also disclosed in which trialkylammonium formate is distilled under mild conditions from crude mixtures of polyhydric alcohols, predominantly trimethylolpropane.
摘要翻译：公开了一种通过蒸馏纯化来自2,2-二羟甲基丁烷的氢化的三羟甲基丙烷的方法，所述方法包括以下步骤：（a）在催化量的叔碳酸存在下，正丁醛与甲醛的反应胺，并氢化得到的混合物，得到含有三羟甲基丙烷的混合物;（b）通过蒸馏分离水，甲醇，三烷基胺和/或三烷基铵甲酸盐;（c）将（b）中得到的残余物在减压下加热至 TMP挥发的温度和TMP沸点高的化合物被切割，以便通过蒸馏分离TMP和比TMP更易挥发的化合物;（d）蒸馏（c）中获得的馏出物，以分离出更多的挥发性化合物，回收纯TMP; 为了回收具有低APHA颜色指数的TMP，还可以任选地蒸馏（d）中获得的TMP。还公开了一种方法，其中在温和条件下从多元醇，主要是三羟甲基丙烷的粗混合物中蒸馏出三烷基铵甲酸盐。

5. 发明授权

US06207865B1 Method for the hydrogenation of carbonyl compounds 有权
标题翻译：羰基化合物氢化方法
公开(公告)号：US06207865B1
公开(公告)日：2001-03-27
申请号：US09462628
申请日：2000-01-11
申请人： Boris Breitscheidel , Marc Walter , Detlef Kratz , Gerhard Schulz , Manfred Sauerwald
发明人： Boris Breitscheidel , Marc Walter , Detlef Kratz , Gerhard Schulz , Manfred Sauerwald
IPC分类号： C07C29136
CPC分类号： C07B31/00 , B01J25/00 , C07C29/141 , C07C31/20 , C07C31/22
摘要： A carbonyl compound or a mixture of two or more carbonyl compounds is catalytically hydrogenated in the presence of a Raney copper catalyst in the form of nuggets.
摘要翻译：羰基化合物或两种或多种羰基化合物的混合物在掘金形式的阮内铜催化剂存在下进行催化氢化。

6. 发明授权

US06187971B1 Method for producing polyalcohols 失效
标题翻译：生产多元醇的方法
公开(公告)号：US06187971B1
公开(公告)日：2001-02-13
申请号：US09331370
申请日：1999-06-21
申请人： Detlef Kratz , Achim Stammer , Gerhard Schulz , Guido Voit
发明人： Detlef Kratz , Achim Stammer , Gerhard Schulz , Guido Voit
IPC分类号： C07C3118
CPC分类号： C07C45/75 , C07C29/141 , Y02P20/582 , C07C31/04 , C07C31/12 , C07C31/125 , C07C31/20 , C07C31/22
摘要： Methylolalkanal of the formula II (R=CH2OH, C1-C22-alkyl, aryl or C6-C22-aralkyl) is prepared spe-wise by a) reacting a C2-C24-aldehyde with formaldehyde in the presence of a tertiary amine, b) separating the reaction mixture i) into a bottom fraction comprising the compound of formula II and an incompletely methylolated compound of the formula III and a distillate stream comprising unconverted or partially converted starting materials, or ii) into an aqueous phase and an organic phase, and recycling the distillate stream or the organic phase to a), and c) subjecting the bottom fraction or the aqueous phase i) to a catalytic or thermal reaction to convert the compound of formula III to the compound of formula II and to a corresponding methylene compound of formula IV (R′=H or R) and ii) separating the reaction product into an overhead stream comprising the compound of formula IV and unconverted formaldehyde which is recycled to a), and a bottom fraction comprising the compound of formula II.
摘要翻译：在叔胺存在下，通过使C2-C24-醛与甲醛反应制备式II的（C 1 -C 22 - 烷基，芳基或C 6 -C 22 - 芳烷基）的羟甲基烷醛，b）将反应混合物分离）至包含式II化合物的底部馏分和式III的不完全羟甲基化的化合物和包含未转化的或部分转化的起始物质的馏出物流，或ii）进入水相和有机相，并将馏出物流或有机相至a），和c）使底部馏分或水相）进行催化或热反应以将式III化合物转化为式II化合物和相应的式IV的亚甲基化合物（R '= H或R）和ii）将反应产物分离成包含式IV化合物和未转化甲醛的塔顶物流，将其再循环至a），以及包含式II化合物的塔底馏分。

7. 发明授权

US06187957B1 Preparation of amines 失效
标题翻译：胺的制备
公开(公告)号：US06187957B1
公开(公告)日：2001-02-13
申请号：US09459856
申请日：1999-12-14
申请人： Gerald Meyer , Frank Funke , Gerhard Schulz , Detlef Kratz , Marc Walter , Michael Hesse
发明人： Gerald Meyer , Frank Funke , Gerhard Schulz , Detlef Kratz , Marc Walter , Michael Hesse
IPC分类号： C07C20900
CPC分类号： C07C213/02 , B01J23/72 , B01J35/10 , B01J37/0009 , C07C209/16 , C07C209/60 , C07C211/03 , C07C217/08
摘要： Amines are prepared by reacting primary or secondary alcohols, aldehydes or ketones with nitrogen compounds selected from the group consisting of ammonia and primary and secondary amines at elevated temperatures and superatmospheric pressures in the presence of hydrogen and of a catalyst containing copper and oxygen-containing compounds of titanium by a process in which the catalyst is used in the form of moldings which have been prepared with the addition of metallic copper powder.
摘要翻译：通过在氢气和含铜和含氧化合物的催化剂的高温和超大气压下，使伯醇或仲醇，醛或酮与选自氨和伯胺和仲胺的氮化合物反应制备胺的钛，其中催化剂以通过添加金属铜粉制备的模制品的形式使用。

8. 发明授权

US5955620A Dehydrogenation of 1,4-butanediol to .gamma.-butyrolactone 失效
标题翻译：将1,4-丁二醇脱氢成γ-丁内酯
公开(公告)号：US5955620A
公开(公告)日：1999-09-21
申请号：US923553
申请日：1997-09-04
申请人： Hans Jochen Mercker , Frank-Friedrich Pape , Joachim Simon , Andreas Henne , Michael Hesse , Ulrich Kohler , Roman Dostalek , Cristina Freire Erdbrugger , Detlef Kratz
发明人： Hans Jochen Mercker , Frank-Friedrich Pape , Joachim Simon , Andreas Henne , Michael Hesse , Ulrich Kohler , Roman Dostalek , Cristina Freire Erdbrugger , Detlef Kratz
IPC分类号： C07D307/33 , B01J23/72 , B01J23/78 , C07B61/00 , C07D315/00 , C07D307/32
CPC分类号： C07D315/00 , B01J23/78 , B01J23/72 , B01J35/0053 , B01J35/0066
摘要： A process for dehydrogenating 1,4-butanediol to .gamma.-butyrolactone in the gas phase in the presence of a copper-containing catalyst, wherein the catalyst contains 4-40% by weight of copper and 0-5% by weight of Na.sub.2 O, based on the total weight of the catalyst, on a carrier consisting of 80-100% by weight of SiO.sub.2 and 0-20% by weight of CaO.
摘要翻译：在含铜催化剂存在下，在气相中将1,4-丁二醇脱氢为γ-丁内酯的方法，其中催化剂含有4-40重量％的铜和0-5重量％的Na 2 O，基于在由80-100重量％的SiO 2和0-20重量％的CaO组成的载体上的催化剂的总重量。

9. 发明授权

US5952438A Polymeric polyamines from alternating polyketones 失效
标题翻译：交替聚酮的聚合多胺
公开(公告)号：US5952438A
公开(公告)日：1999-09-14
申请号：US992530
申请日：1997-12-17
申请人： Detlef Kratz , Ferdinand Lippert , Peter Schwab , Dieter Boeckh , Johannes Perner
发明人： Detlef Kratz , Ferdinand Lippert , Peter Schwab , Dieter Boeckh , Johannes Perner
IPC分类号： A61K8/84 , A61Q5/00 , A61Q19/00 , B01F17/00 , B01F17/52 , C08G59/50 , C08G67/02 , C08G73/02 , C08G73/06 , C08L63/00 , C09J179/02 , C09K3/00 , C09K15/30 , C10L1/22 , C10L1/238 , C10L1/2383 , C10L1/28 , C10L10/18 , C10M149/02 , C10M149/14 , C11D3/37 , D06P1/52 , D06P5/08
CPC分类号： D06P5/08 , A61K8/84 , A61Q19/00 , A61Q5/00 , B01F17/005 , C08G67/02 , C08G73/0611 , C08G73/0672 , C08L63/00 , C09K15/30 , C10L1/238 , C10L1/285 , C10M149/14 , C11D3/0021 , C11D3/3723 , D06P1/5278
摘要： Polymeric polyamines obtainable by reacting linear, alternating carbon monoxide/1-alkene copolymers with ammonia or amines of the formula (I)R--NH.sub.2 (I)where R is --NH.sub.2, --OH, C.sub.1 -C.sub.10 -alkyl, C.sub.6 -C.sub.20 -aryl, C.sub.7 -C.sub.20 -arylalkyl, C.sub.7 -C.sub.20 -alkylaryl or an organosilicon radical having 3 to 30 carbon atoms,or with a reagent which releases ammonia or the amine (I), and subsequent hydrogenation.
摘要翻译：通过使线性交替一氧化碳/ 1-烯烃共聚物与式（I）R-NH 2（I）的胺反应获得的聚合多胺，其中R是-NH 2，-OH，C 1 -C 10 - 烷基，C 6 -C 20 - 芳基，C7-C20芳基烷基，C7-C20烷基芳基或具有3-30个碳原子的有机硅基团，或与释放氨或胺（I）的试剂反应，然后进行氢化。

10. 发明授权

US5847131A Preparation of N-substituted cyclic amines 失效
标题翻译： N-取代的环胺的制备
公开(公告)号：US5847131A
公开(公告)日：1998-12-08
申请号：US876329
申请日：1997-06-16
申请人： Joachim Simon , Roman Dostalek , Heinz Lingk , Rainer Becker , Andreas Henne , Rolf Lebkucher , Cristina Freire Erdbrugger , Michael Hesse , Detlef Kratz
发明人： Joachim Simon , Roman Dostalek , Heinz Lingk , Rainer Becker , Andreas Henne , Rolf Lebkucher , Cristina Freire Erdbrugger , Michael Hesse , Detlef Kratz
IPC分类号： C07D295/02 , B01J23/72 , B01J37/02 , C07B61/00 , C07D295/03 , C07D295/023
CPC分类号： C07D295/03 , B01J23/72 , B01J37/0203
摘要： N-Substituted cyclic amines are prepared by reacting diols with primary amines over a copper-containing catalyst which is obtainable by impregnation of an inert support with an aqueous solution of an ammine complex of a readily thermally decomposable copper compound and subsequent drying and calcination and contains from 5 to 50% by weight of copper, calculated as CuO.
摘要翻译： N-取代的环胺通过二元醇与伯胺在含铜催化剂上反应制备，所述催化剂可通过用容易热分解的铜化合物的氨络合物的水溶液浸渍惰性载体而得到，随后进行干燥和煅烧， 5至50重量％的铜，以CuO计。

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