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1. 发明授权

US5218041A Polyoxymethylene molding materials having improved thermal stability and reduced formaldehyde emission 失效
标题翻译：具有改善的热稳定性和降低甲醛释放的聚甲基乙烯模塑材料
公开(公告)号：US5218041A
公开(公告)日：1993-06-08
申请号：US772244
申请日：1991-10-07
申请人： Detlef Arnoldi , Edwin Nun
发明人： Detlef Arnoldi , Edwin Nun
IPC分类号： C08K3/04 , C08K5/13 , C08L25/08 , C08L25/14 , C08L33/06 , C08L33/10 , C08L59/00 , C08L61/28
CPC分类号： C08L59/00 , C08L25/08 , C08L25/14 , C08L33/06 , C08L33/10 , C08L61/28
摘要： Polyoxymethylene molding materials having improved thermal stability and reduced formaldehyde emission consisting essentially of a polyoxymethylene as the main component and containing in addition, relative in each instance to the weight of the polyoxymethylene, 0.1 to 10% by weight of an endocopolymerizate, 0.05 to 3% by weight of a phenolic antioxidant, 0 to 5% by weight carbon black and 0 to 3% by weight of further additives customary in polyoxymethylene molding materials.
摘要翻译：具有改进的热稳定性和甲醛释放降低的聚甲醛成型材料基本上以聚甲醛为主要成分，并且另外相对于聚甲醛的重量相对含量为0.1〜10重量％，内缀合物为0.05〜3重量％的酚类抗氧化剂，0-5重量％的炭黑和0-3重量％的聚氧亚甲基成型材料中通常的其它添加剂。

2. 发明授权

US5693709A Polyoxymethylene with improved acid stability, process for production and use thereof 失效
标题翻译：具有改善的酸稳定性的聚甲醛，其制备方法和用途
公开(公告)号：US5693709A
公开(公告)日：1997-12-02
申请号：US701800
申请日：1996-08-26
申请人： Edwin Nun , Stephanie Schauhoff , Detlef Arnoldi
发明人： Edwin Nun , Stephanie Schauhoff , Detlef Arnoldi
IPC分类号： C08L59/00 , C08L71/00 , C08L75/04 , C08K5/05
CPC分类号： C08L59/00 , C08L71/00 , C08L75/04
摘要： Polyoxymethylene with improved acid stability, process for production and use thereof. By adding 0.01 to 5 parts of an alkali metal salt of a polybasic acid, for example oxalic acid, citric acid and/or 0.01 to 5 parts of a polyalkylene glycol, for example polyethylene glycol and/or 0.1 to 100 parts of a thermoplastic polyurethane, each related to 100 parts of a polyoxymethylene, this polymer is stabilized against attack by acids, wherein in particular the combination of an alkali metal salt, in particular an oxalate, with small proportions of a thermoplastic polyurethane is advantageous. The proportion of thermoplastic polyurethane may be reduced when the thermoplastic polyurethane has a Shore A hardness of 70 to 96. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The products are useful when exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.
摘要翻译：具有改善的酸稳定性的聚甲醛，其制备方法和用途。通过加入0.01至5份多元酸的碱金属盐，例如草酸，柠檬酸和/或0.01至5份聚亚烷基二醇，例如聚乙二醇和/或0.1至100份热塑性聚氨酯各自与100份聚甲醛相关，该聚合物被抗酸侵蚀稳定，其中特别是碱金属盐，特别是草酸盐与小比例的热塑性聚氨酯的组合是有利的。当热塑性聚氨酯的肖氏A硬度为70至96时，热塑性聚氨酯的比例可能会降低。在酸作用下稳定的POM的重量损失可能小于不稳定的POM的重量损失的3％。当暴露于酸性剂如灌溉系统，洗碗机，卫生设备时，该产品是有用的。

3. 发明授权

US5541284A Method for processing crude polyoxymethylene 失效
标题翻译：粗聚甲醛加工方法
公开(公告)号：US5541284A
公开(公告)日：1996-07-30
申请号：US406141
申请日：1995-03-20
申请人： Detlef Arnoldi , Udo Gropp , Edwin Nun
发明人： Detlef Arnoldi , Udo Gropp , Edwin Nun
IPC分类号： C08G2/28 , C08G2/10
CPC分类号： C08G2/28
摘要： The subject invention relates to method for processing crude polyoxymethylene in which the isolation of unstable components from crude polyoxymethylene, such as residual monomers which are at least partly in the form of cyclic formaldehyde derivatives, is effected by treatment of the crude polyoxymethylene with an inert gaseous medium. The method of the invention is characterized in that the gaseous medium contains at least 10 volume % of water vapor, and less than 0.1 volume % of a volatile base, and/or less than 1 volume % of a volatile solvent. In an alternative variant method, the gaseous medium contains at least 10 volume % of water vapor and the treatment occurs at a temperature between 114.degree. C and the softening temperature of the crude polyoxymethylene and at a pressure of less 1.2 .multidot.10.sup.5 Pa.
摘要翻译：本发明涉及用于处理粗聚甲醛的方法，其中从粗聚甲醛分离不稳定组分，例如至少部分为环状甲醛衍生物形式的残留单体，其通过用惰性气体处理粗聚甲醛来实现中。本发明的方法的特征在于，气态介质含有至少10体积％的水蒸气和少于0.1体积％的挥发性碱，和/或少于1体积％的挥发性溶剂。在另一变体方法中，气体介质含有至少10体积％的水蒸气，并且处理在114℃和粗聚甲醛的软化温度之间并且在1.2×10 5 Pa以下的压力下进行。

4. 发明授权

US5393813A Polyoxymethylene having improved acid stability 失效
标题翻译：具有改善的酸稳定性的聚甲醛
公开(公告)号：US5393813A
公开(公告)日：1995-02-28
申请号：US140357
申请日：1993-10-22
申请人： Stephanie Schauhoff , Edwin Nun , Detlef Arnoldi
发明人： Stephanie Schauhoff , Edwin Nun , Detlef Arnoldi
IPC分类号： C08K5/09 , C08K5/3477 , C08K5/3492 , C08L59/00 , C08L61/28 , C08L71/02 , C08L75/04 , C08J5/10 , C08K5/34 , C08L59/02
CPC分类号： C08K5/34924 , C08L59/00 , C08L61/28 , C08L71/02 , C08L75/04
摘要： By adding melamine cyanurate, polyoxymethylene is stabilized against acid attack, wherein in particular as little as under 3 parts of MCA per 100 parts of POM are effective. The weight loss of a stabilized POM under the action of acid may be less than 3% of that of an unstabilized POM. The product is useful in products which are exposed to acidic agents such as irrigation systems, dishwashers, sanitary installations.
摘要翻译：通过加入三聚氰胺氰尿酸酯，聚甲醛稳定，防止酸侵蚀，其中特别是每100份POM少于3份MCA的有效性。在酸作用下稳定的POM的重量损失可能小于不稳定的POM的失重量的3％。该产品适用于暴露于酸性剂（如灌溉系统，洗碗机，卫生设备）的产品中。

5. 发明授权

US5767231A Method of producing non-vitrified processing aid low in residual monomers for thermoplastic polymers 失效
标题翻译：生产用于热塑性聚合物的残留单体低的非玻璃化加工助剂的方法
公开(公告)号：US5767231A
公开(公告)日：1998-06-16
申请号：US504853
申请日：1995-07-20
申请人： Volker Schull , Detlef Arnoldi
发明人： Volker Schull , Detlef Arnoldi
IPC分类号： C08F6/14 , C08F6/00 , C08F6/06 , C08L27/06 , C08L33/12 , C08F6/16
CPC分类号： C08F6/001 , C08F6/006 , C08L27/06 , C08L33/12
摘要： A method for lowering the residual monomer content of non-vitrified processing aids for thermoplastic polymers involves subjecting an emulsion polymerizate containing methylmethacrylate and, optionally, up to 50% by weight of a comonomer to a post-catalysis step to reduce the residual monomer content followed by a spray-drying step where the residual monomer content is further reduced. The spray-drying step is performed at an exit temperature which is either above the boiling point of methylmethacrylate or if an optional comonomer is present which has a higher boiling point than methacrylate, at a temperature above the boiling point of the comonomer. The resulting product which is suitable for use as a non-vitrified processing aid has a residual monomer content of 100 ppm or less. The processing aid can be used with thermoplastics to form containers, e.g., beverage bottles of PVC, which would not adversely affect odor or taste of the contained food product.
摘要翻译：降低热塑性聚合物的非玻璃化加工助剂的残留单体含量的方法包括将含有甲基丙烯酸甲酯和任选的至多50重量％的共聚单体的乳液聚合物经历催化后步骤以减少残余单体含量，随后通过喷雾干燥步骤进一步降低剩余单体含量。喷雾干燥步骤在高于甲基丙烯酸甲酯的沸点的出口温度下进行，或者在高于共聚单体沸点的温度下，如果存在沸点高于甲基丙烯酸酯的任选共聚单体。得到的适用于非玻璃化加工助剂的产品的残留单体含量为100ppm以下。加工助剂可以与热塑性塑料一起使用以形成容器，例如PVC的饮料瓶，其不会不利地影响所含食品的气味或味道。

6. 发明授权

US06960699B2 Method for the hydroformylation of olefins 有权
公开(公告)号：US06960699B2
公开(公告)日：2005-11-01
申请号：US10506603
申请日：2003-03-08
申请人： Walter Tötsch , Detlef Arnoldi , Alfred Kaizik , Martin Trocha
发明人： Walter Tötsch , Detlef Arnoldi , Alfred Kaizik , Martin Trocha
IPC分类号： C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C45/75 , C07C45/80 , C07C45/82 , C07C29/14
CPC分类号： C07C29/141 , C07C29/16 , C07C45/50 , C07C31/125 , C07C47/02
摘要： The invention relates to a process for preparing alcohols by hydroformylation of olefins or olefin mixtures, separation from the catalyst and subsequent hydrogenation, with an extraction being carried out after removal of the catalyst and before the hydrogenation of the aldehydes.

7. 发明授权

US4222956A Process for the production of cyanocarboxylic acids 失效
标题翻译：制备氰基羧酸的方法
公开(公告)号：US4222956A
公开(公告)日：1980-09-16
申请号：US12133
申请日：1979-02-14
申请人： Axel Kleemann , Peter Schalke , Detlef Arnoldi
发明人： Axel Kleemann , Peter Schalke , Detlef Arnoldi
IPC分类号： C07C255/19 , C07C20060101 , C07C67/00 , C07C253/00 , C07C120/00 , C07C121/407
CPC分类号： C07C255/00
摘要： Cyanocarboxylic acids are prepared by reacting halocarboxylic acids with cyanohydrins, preferably at a pH of 9 to 11.
摘要翻译：氰基羧酸通过卤代羧酸与氰醇反应制备，优选在9至11的pH下进行。

8. 发明申请

US20050171389A1 Method for the hydroformylation of olefins 有权
标题翻译：烯烃加氢甲酰化的方法
公开(公告)号：US20050171389A1
公开(公告)日：2005-08-04
申请号：US10506603
申请日：2003-03-08
申请人： Walter Totsch , Detlef Arnoldi , Alfred Kaizik , Martin Trocha
发明人： Walter Totsch , Detlef Arnoldi , Alfred Kaizik , Martin Trocha
IPC分类号： C07B61/00 , C07C29/141 , C07C29/16 , C07C31/125 , C07C45/50 , C07C45/75 , C07C45/80 , C07C45/82 , C07C27/22 , C07C29/15
CPC分类号： C07C29/141 , C07C29/16 , C07C45/50 , C07C31/125 , C07C47/02
摘要： The invention relates to a process for preparing alcohols by hydroformylation of olefins or olefin mixtures, separation from the catalyst and subsequent hydrogenation, with an extraction being carried out after removal of the catalyst and before the hydrogenation of the aldehydes.
摘要翻译：本发明涉及通过烯烃或烯烃混合物的加氢甲酰化，从催化剂分离和随后的氢化制备醇的方法，在除去催化剂之后和醛的氢化之前进行萃取。

9. 发明授权

US5476902A Processing agent having a C.sub.8 -C.sub.22 component 失效
标题翻译：具有C8-C22组分的加工剂
公开(公告)号：US5476902A
公开(公告)日：1995-12-19
申请号：US420902
申请日：1995-04-11
申请人： Volker H. Schull , Detlef Arnoldi
发明人： Volker H. Schull , Detlef Arnoldi
IPC分类号： C08L33/06 , C08L57/06 , C08L101/00 , C08L27/06 , C08L33/10
CPC分类号： C08L33/06 , C08L101/00 , C08L57/06
摘要： A processing agent for polyvinyl chloride and other thermoplastic polymers. The processing agent is a copolymer which contains a monomer whose homopolymer has a T.sub.g .gtoreq.65 C. and contains 3 to less than 75% by weight of a comonomer which has a C.sub.8 -C.sub.22 alkyl component. The alkyl component should be apportioned in such a fashion that the transmission of the copolymer in ethyl acetate is at least 90% in the case of a 10% solution.
摘要翻译：用于聚氯乙烯和其它热塑性聚合物的加工剂。加工剂是含有均聚物Tg> / = 65℃并且含有3至小于75重量％的具有C 8 -C 22烷基组分的共聚单体的共聚物。烷基组分应以如下方式分配：在10％溶液的情况下，共聚物在乙酸乙酯中的透过率至少为90％。

10. 发明授权

US5494488A Detergent composition and method of use with surfactant, silicate, and polycarboxylate 失效
标题翻译：洗涤剂组合物和使用表面活性剂，硅酸盐和聚羧酸盐的方法
公开(公告)号：US5494488A
公开(公告)日：1996-02-27
申请号：US191506
申请日：1994-02-04
申请人： Detlef Arnoldi , Wolfgang Leonhardt , Beata-Maria Lortz , Maurizio Ragnetti
发明人： Detlef Arnoldi , Wolfgang Leonhardt , Beata-Maria Lortz , Maurizio Ragnetti
IPC分类号： C11D3/12 , C11D3/37 , D06M15/263 , C11D3/08 , D06M11/79
CPC分类号： C11D3/3761 , C11D3/128
摘要： A detergent composition with improved dirt-suspending power, method for its production and use of a suitable polycarboxylate for this purpose. The novel detergent contains, in addition to the customary components such as surfactant, calcium-binding silicate, etc., at least 1% by weight of a polycarboxylate with the schematic structure (X, Y, Z) in which X stands for ##STR1## Y for ##STR2## and Z for--(F).sub.q --.These carboxylates can be produced from acrolein and optionally one or several comonomers by means of oxidizing radical donors without saponifying conditions and/or without subsequent Cannizzaro reaction. The novel detergents exhibits improvements over traditionally used co-builders in all essential detergent qualities. The carboxylates may be used in detergents, fine-fabric detergents, color detergents, liquid detergents and compact detergents.
摘要翻译：具有改善的污垢悬浮能力的洗涤剂组合物，用于其生产和使用合适的聚羧酸盐的方法。新型洗涤剂除了常规的组分如表面活性剂，钙结合硅酸盐等外还含有至少1重量％的具有示意性结构（X，Y，Z）的多羧酸盐，其中X代表 Y为，Z为 - （F）q-。这些羧酸盐可以由丙烯醛和任选的一种或多种共聚单体通过氧化自由基供体而不进行皂化条件和/或不经随后的Cannizzaro反应制备。新型洗涤剂在所有必需的洗涤剂质量方面表现出优于传统使用的共助洗剂的改进。羧酸盐可用于洗涤剂，细织洗涤剂，彩色洗涤剂，液体洗涤剂和紧凑型洗涤剂中。

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