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1. 发明授权

US07339088B1 Alkylbenzene refining process and apparatus 失效
标题翻译：烷基苯精制工艺及装置
公开(公告)号：US07339088B1
公开(公告)日：2008-03-04
申请号：US10974271
申请日：2004-10-27
申请人： Dennis E. O'Brien , Douglas G. Stewart , Bipin V. Vora
发明人： Dennis E. O'Brien , Douglas G. Stewart , Bipin V. Vora
IPC分类号： C07C7/04 , B01D3/00
CPC分类号： B01D3/143 , C07C7/04 , C07C15/107
摘要： Improved processes and apparatus use a finishing column with a mid-cut that provides alkylbenzene products of high purity containing less than about 1 ppmw benzene and less than about 50 ppmw heavies while accommodating enhancements in the efficiencies and the capacities of the distillation train to recover alkylbenzene from alkylation reaction product and while enabling the use of catalytic treatments to reduce olefinic-component content.
摘要翻译：改进的方法和设备使用具有中间切割的精整塔，其提供含有小于约1ppmw苯和小于约50ppmw重的高纯度的烷基苯产物，同时适应提高蒸馏塔回收烷基苯的效率和容量同时能够使用催化处理来降低烯烃成分含量。

2. 发明授权

US4364821A Fluid contacting process 失效
标题翻译：流体接触过程
公开(公告)号：US4364821A
公开(公告)日：1982-12-21
申请号：US301241
申请日：1981-09-11
申请人： Dennis E. O'Brien
发明人： Dennis E. O'Brien
IPC分类号： B01D11/04 , B01J8/02 , C10G21/00 , C10G21/22 , C10G21/12
CPC分类号： C10G21/00 , B01D11/043 , B01D11/0488 , B01J8/0214
摘要： A process for contacting two immiscible fluids is disclosed. A liquid stream enters the top of an apparatus and travels downward within an annular bed of packing. A vapor stream or a less dense liquid stream enters the bottom of the apparatus and travels upward making many radial flow passes through succeedingly higher parts of the annular bed. The sigmoid flow of the rising stream is channeled by horizontal disks within the open central volume of the annular bed and by horizontal open-centered rings which surround the annular bed at staggered elevations.
摘要翻译：公开了一种接触两种不混溶流体的方法。液体流进入设备的顶部并在环形填料床内向下运动。蒸汽流或较不致密的液体流进入设备的底部并向上运动，使许多径向流通过环形床的后续更高的部分。上升流的乙状结构的流动由环形床的开放中心体积内的水平圆盘引导，并且以水平的开放中心的环绕环形床以交错的高度引导。

3. 发明授权

US06417420B1 Alkylaromatic process with removal of aromatic byproducts using efficient distillation 失效
标题翻译：使用有效蒸馏除去芳族副产物的烷基芳族化合物
公开(公告)号：US06417420B1
公开(公告)日：2002-07-09
申请号：US09793260
申请日：2001-02-26
申请人： Douglas G. Stewart , Dennis E. O'Brien
发明人： Douglas G. Stewart , Dennis E. O'Brien
IPC分类号： C07C264
CPC分类号： B01D3/141 , C07C15/00
摘要： A process for the production of alkylaromatic hydrocarbons by alkylating aromatic hydrocarbons with olefinic hydrocarbons is disclosed. The olefinic hydrocarbons are produced by dehydrogenating paraffinic hydrocarbons. Aromatic byproducts formed in dehydrogenation are removed using an aromatic byproducts removal zone and either a dividing wall distillation column or thermally coupled distillation columns. The process significantly decreases the cost of utilities in producing alkylaromatics, such as precursors for detergent manufacture.
摘要翻译：公开了通过用烯烃烷基化芳烃来生产烷基芳烃的方法。烯烃是通过使链烷烃烃脱氢生产的。使用芳族副产物去除区和分隔壁蒸馏塔或热偶联蒸馏塔除去在脱氢中形成的芳族副产物。该方法显着降低了生产烷基芳族化合物（例如洗涤剂制造前体）的公用事业的成本。

4. 发明授权

US06407303B1 Isomerization process with adsorptive separation and integrated fractional distillation 失效
$Isomerization process with adsorptive separation and integrated fractional distillation$
标题翻译：异构化过程与吸附分离和一体化分馏
公开(公告)号：US06407303B1
公开(公告)日：2002-06-18
申请号：US09710627
申请日：2000-11-10
申请人： Dennis E. O'Brien , Lynn H. Rice
发明人： Dennis E. O'Brien , Lynn H. Rice
IPC分类号： C07C513
CPC分类号： B01D3/141 , C07C7/12 , C07C9/16 , C07C13/10 , C07C13/18 , C07C2601/08 , C07C2601/14
摘要： Construction and operational costs of simulated moving bed adsorptive separation process units are reduced by recovering desorbent from both the extract and raffinate streams of the process in a single integrated fraction column. Both streams are fractionated to recover desorbent, which is removed at one end of a dividing wall column, while separate extract and raffinate products are removed from the other end of the column. A specific embodiment includes the use of the integrated fractionation column in an isomerization application.
摘要翻译：模拟移动床吸附分离工艺单元的结构和运行成本通过在单个集成分馏塔中回收来自萃取液和萃余液流的脱附剂而减少。将两个流分馏以回收解吸剂，其在分隔壁塔的一端被除去，而从塔的另一端除去单独的提取物和萃余液产物。具体实施方案包括在异构化应用中使用集成分馏塔。

5. 发明授权

US5983476A Conversion of an HF alkylation unit 失效
公开(公告)号：US5983476A
公开(公告)日：1999-11-16
申请号：US94415
申请日：1998-06-09
申请人： Steven F. Eshelman , Dennis E. O'Brien
发明人： Steven F. Eshelman , Dennis E. O'Brien
IPC分类号： C07C2/70 , B23P11/00
CPC分类号： C07C2/70 , C07C2527/1206 , Y10T29/49716
摘要： A method of converting an HF alkylation process into a solid catalyst alkylation process is disclosed. In this method, an HF alkylation unit having an HF stripper downstream of the HF alkylation reactor is modified to a benzene rectifier. By modifying the HF stripper, this invention not only makes use of the existing HF stripper but also allows the entire downstream product recovery section, which comprises four fractionation columns, to be used in the modified process with only relatively minor modifications. Thus this invention maximizes the use of existing equipment and minimizes the investment necessary to eliminate the use of HF in detergent alkylation.

6. 发明授权

US4361658A Process for polymeric gelation 失效
标题翻译：聚合胶凝方法
公开(公告)号：US4361658A
公开(公告)日：1982-11-30
申请号：US223482
申请日：1981-01-08
申请人： Robert D. Lundberg , Dennis E. O'Brien , Henry S. Makowski, deceased , Robert R. Klein
发明人： Robert D. Lundberg , Dennis E. O'Brien , Henry S. Makowski, deceased , Robert R. Klein
IPC分类号： B01J19/06 , C08J3/11 , C08F8/36
CPC分类号： C08J3/11 , B01J19/06 , C08J2323/32 , Y10S524/916
摘要： The present invention relates to a process for forming a polymeric solution or gel having a viscosity of at least about 50,000 cps which includes the steps forming a solvent system of an organic liquid and a polar cosolvent, the polar cosolvent being less than about 15 wt. % of the solvent system, a viscosity of the solvent system being less than about 1000 cps; dissolving to form a solution, a concentration of the neutralized sulfonated polymer in the solution being about 0.1 to about 20 wt. %, a viscosity of the solution being less than about 20,000 cps; and admixing or contacting said solution with about 5 to about 500 vol. % water, the water being immiscible with the solution and the polar cosolvent transferring from the solution phase to the water phase thereby causing the viscosity of said solution to increase rapidly from less to 20,000 cps to greater than 50,000 cps.
摘要翻译：本发明涉及形成具有至少约50,000cps的粘度的聚合物溶液或凝胶的方法，其包括形成有机液体和极性助溶剂的溶剂体系的步骤，极性助溶剂小于约15wt。％的溶剂体系，溶剂系统的粘度小于约1000cps; 溶解形成溶液时，中和的磺化聚合物在溶液中的浓度为约0.1至约20wt。％，溶液的粘度小于约20,000cps; 并将所述溶液混合或接触约5至约500vol。％的水，水与溶液不混溶，极性助溶剂从溶液相转移到水相，从而导致所述溶液的粘度从少于20,000cps快速增加到大于50,000cps。

7. 发明授权

US06479720B1 Alkylaromatic process using efficient prefractionation 失效
$Alkylaromatic process using efficient prefractionation$
标题翻译：使用有效的初步分选的烷基芳族工艺
公开(公告)号：US06479720B1
公开(公告)日：2002-11-12
申请号：US09474973
申请日：1999-12-29
申请人： Dennis E. O'Brien , Dennis H. Bielinski , Zhanping Xu
发明人： Dennis E. O'Brien , Dennis H. Bielinski , Zhanping Xu
IPC分类号： C07C15067
CPC分类号： C07C15/00
摘要： A process for the production of alkylaromatic hydrocarbons by alkylating aromatic hydrocarbons with linear olefinic hydrocarbons is disclosed. The linear olefinic hydrocarbons are produced by dehydrogenating linear paraffinic hydrocarbons which are extracted from a heartcut that is distilled from a kerosene boiling range fraction in either a dividing wall fractionation column or in two fully thermally coupled fractionation columns. The process significantly decreases the cost of utilities in producing alkylaromatic precursors for detergent manufacture.
摘要翻译：公开了通过用直链烯烃烷基化芳烃来生产烷基芳烃的方法。线性烯烃是通过从线性链烷烃脱氢制备的，所述线性链烷烃是从分裂壁分馏塔中的煤油沸程馏分或两个完全热耦合的分馏塔中蒸馏的心切出提取的。该方法显着降低了生产用于洗涤剂制造的烷基芳族前体的公用事业的成本。

8. 发明授权

US6137021A Conversion of an HF alkylation unit 失效
标题翻译： HF烷基化单元的转化
公开(公告)号：US6137021A
公开(公告)日：2000-10-24
申请号：US372116
申请日：1999-08-20
申请人： Steven F. Eshelman , Dennis E. O'Brien
发明人： Steven F. Eshelman , Dennis E. O'Brien
IPC分类号： C07C2/70 , C07C15/067 , C07C2/56 , C07C2/58 , C07C2/64 , C07C2/68
CPC分类号： C07C2/70 , C07C2527/1206 , Y10T29/49716
摘要： A method of converting an HF alkylation process into a solid catalyst alkylation process is disclosed. In this method, an HF alkylation unit having an HF stripper downstream of the HF alkylation reactor is modified to a benzene rectifier. By modifying the HF stripper, this invention not only makes use of the existing HF stripper but also allows the entire downstream product recovery section, which comprises four fractionation columns, to be used in the modified process with only relatively minor modifications. Thus this invention maximizes the use of existing equipment and minimizes the investment necessary to eliminate the use of HF in detergent alkylation.
摘要翻译：公开了将HF烷基化方法转化为固体催化剂烷基化方法。在该方法中，在HF烷基化反应器下游具有HF剥离剂的HF烷基化单元被改性为苯整流体。通过改造HF汽提器，本发明不仅利用了现有的HF汽提器，而且还允许包括四个分馏塔的整个下游产品回收部分在修改过程中被使用，只有较小的修改。因此，本发明使现有设备的使用最大化，并最大限度地减少消除在洗涤剂烷基化中使用HF所需的投资。

9. 发明授权

US4568392A Well treating fluid 失效
标题翻译：处理流体好
公开(公告)号：US4568392A
公开(公告)日：1986-02-04
申请号：US483394
申请日：1983-04-08
申请人： Charles R. Dawson , Norman N. Li , Dennis E. O'Brien
发明人： Charles R. Dawson , Norman N. Li , Dennis E. O'Brien
IPC分类号： C09K8/50 , E21B21/00 , C09K3/00 , C09K7/00
CPC分类号： C09K8/50 , E21B21/003
摘要： The instant invention is directed to shear thickening fluids which comprise a water-swellable material (clay), present in a sufficient concentration so as to be capable of forming a stiff paste upon interaction with the water used, and water wherein the clay and water are kept separated by an intervening hydrocarbon-surfactant composition. The intervening oil phase prevents the interaction between the water and the clay phases and results in a stable, nonreacting, pumpable composite until such time as the oil envelope is ruptured by application of a sufficiently high shear force. Upon such rupture, the materials interact rapidly forming a semi-rigid stiff paste.Various well-control problems, such as oil and gas with blowouts, can be controlled by use of the above-described composite. The composite is pumped down the well pipe. Exiting the orifices of the drill bit or a nozzle supplies the shear force needed to rupture the oil envelope thereby permitting the interaction between the clay and the water resulting in the formation of a stiff paste which can stop or prevent unwanted flow in or near the wellbore.
摘要翻译：本发明涉及剪切增稠流体，其包含水溶胀性材料（粘土），其以足够的浓度存在，以便能够在与所用的水相互作用时形成刚性糊料，以及其中粘土和水是通过中间的烃 - 表面活性剂组合物保持分离。中间油相防止水和粘土相之间的相互作用，并导致稳定的，不反应的可泵送复合材料，直到通过施加足够高的剪切力使油封破裂的时间为止。在这种破裂的情况下，材料相互作用迅速地形成半刚性刚性浆料。可以通过使用上述复合材料来控制各种井控问题，例如具有井喷的油和气。将复合材料从井管中抽出。排出钻头或喷嘴的孔口提供破裂油包壳所需的剪切力，从而允许粘土和水之间的相互作用，导致形成刚性浆料，从而可以阻止或防止在井筒内或附近不必要的流动。

10. 发明授权

US4333817A Separation of normally gaseous hydrocarbons from a catalytic reforming effluent and recovery of purified hydrogen 失效
标题翻译：将正常气态烃与催化重整流出物分离并回收纯化氢
公开(公告)号：US4333817A
公开(公告)日：1982-06-08
申请号：US228517
申请日：1981-01-26
申请人： Dennis E. O'Brien
发明人： Dennis E. O'Brien
IPC分类号： C01B3/50 , C10G35/04 , C10G61/06 , C10G47/00 , C10G49/22
CPC分类号： C10G61/06 , C01B3/50 , C10G35/04 , C01B2203/048
摘要： A process for the catalytic reforming of a hydrocarbonaceous feedstock, preferably to produce high quality gasoline boiling range products, is disclosed. Relatively impure hydrogen is separated from the reforming zone effluent, compressed, and recontacted with at least a portion of the liquid reformate product to provide relatively pure hydrogen, a portion of which is recycled to the reforming zone. The balance is further compressed and recontacted with at least a portion of the liquid reformate product in a plural stage absorption zone to provide an improved recovery of normally gaseous hydrocarbons as well as an improved recovery of purified hydrogen at a pressure suitable, for example, the relatively high pressure hydrotreating of sulfur-containing feedstocks.
摘要翻译：公开了一种烃原料的催化重整方法，优选生产优质汽油沸点产物。相对不纯的氢气与重整区流出物分离，压缩并与至少一部分液体重整产物重新混合以提供相对纯的氢，其一部分被再循环到重整区。将平衡物进一步压缩并与多级吸收区中的至少一部分液体重整产物重新配制，以提供常规气态烃的改进回收，以及在适合于例如含硫原料的相对高压加氢处理。

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