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    • 6. 发明授权
    • Vapor detection with high speed gas chromatography
    • 用高速气相色谱法进行气相检测
    • US5108705A
    • 1992-04-28
    • US594267
    • 1990-10-03
    • David P. RounbehlerDavid P. LiebEugene K. AchterDavid B. GernesAbdul Tafreshi
    • David P. RounbehlerDavid P. LiebEugene K. AchterDavid B. GernesAbdul Tafreshi
    • G01N1/22G01N21/76G01N30/46G01N30/62G01N30/74G01N30/84
    • G01N30/62G01N30/84G01N2030/623G01N2030/8405G01N21/76G01N30/461G01N30/74
    • Disclosed are a method and apparatus for high speed, selective detection of vapors of specific compounds, particularly nitrogen-containing compounds, utilizing, a bypass branch and high speed gas chromatography for improved selectively and sensitivity of detection. A system with two gas chromatographs (GC's) alternating in series with two pyrolyzers provides two time intervals of detection in a downstream detector, with the second time interval containing signals delayed and further separated relative to signals from the first time interval. The bypass branch, in diverting a portion of the flow of gas samples from passage through the second gas chromatograph and second pyrolyzer, avoids interferences in the first time interval of detection from non-GC-retained compounds decomposed in the second pyrolyzer. Also disclosed is an arrangement for rapid, precise heating of vapor concentrator tubes in which vapors are rapidly focussed and then injected into a GC, and for rapid, precise heating of the GC's.
    • 公开了一种用于高速,选择性地检测特定化合物,特别是含氮化合物的蒸气的方法和装置,利用旁路分支和高速气相色谱法提高选择性和灵敏度。 具有与两个热解器串联交替的两个气相色谱仪(GC)的系统在下游检测器中提供两个检测时间间隔,其中第二时间间隔包含相对于来自第一时间间隔的信号延迟和进一步分离的信号。 旁路分支在将一部分气体样品从通过第二气相色谱仪和第二热解器的过程中转移时,避免了在第二次热解器中分解的非GC保留化合物的第一时间间隔内的干扰。 还公开了一种用于快速精确加热蒸汽浓缩管的装置,其中蒸气快速聚焦,然后注入GC,并快速,精确地加热GC。