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1. 发明授权

US4096194A High purity iso-butylene recovery 失效
标题翻译：高纯度异丁烯回收率
公开(公告)号：US4096194A
公开(公告)日：1978-06-20
申请号：US710982
申请日：1976-08-02
申请人： David Moy , Marvin S. Rakow
发明人： David Moy , Marvin S. Rakow
IPC分类号： C07C29/04
CPC分类号： C07C29/04
摘要： An improved process for hydrating with liquid water over a solid catalyst and with a liquid solvent a liquid iso-olefin selected from the group consisting of C.sub.4 iso-olefins and C.sub.5 iso-olefins to form a corresponding product alcohol in the liquid state. The improvement comprises maintaining the liquid iso-olefins, the solvent, and the water in a single liquid phase in order to increase the conversion percentage of the iso-olefin to the corresponding alcohol.
摘要翻译：用固体催化剂和液体溶剂与液态水进行水合的改进方法是选自C4异烯烃和C5异烯烃的液体异烯烃，以形成液态的相应的产物醇。改进之处在于将液体异烯烃，溶剂和水保持在单一液相中以提高异烯烃转化成相应醇的转化率。

2. 发明申请

US20100086472A1 Single-walled carbon nanotube catalysts and method for preparing same 有权
标题翻译：单壁碳纳米管催化剂及其制备方法
公开(公告)号：US20100086472A1
公开(公告)日：2010-04-08
申请号：US11602136
申请日：2006-11-20
申请人： Jun Ma , David Moy
发明人： Jun Ma , David Moy
IPC分类号： D01F9/12
CPC分类号： D01F9/127 , B01J21/005 , B01J23/002 , B01J23/005 , B01J23/78 , B01J37/0236 , B01J37/031 , B01J37/08 , B01J37/18 , B01J2523/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , B01J2523/22 , B01J2523/842 , B01J2523/845 , B01J2523/41 , B01J2523/31
摘要： An activated catalyst capable of selectively growing single-walled carbon nanotubes when reacted with carbonaceous gas is provided. The activated catalyst is formed by reducing a catalyst that comprises a complex oxide. The complex oxide may be of formula Ax-wFwBy-vGvOz wherein x/y≦2; z/y≦4; 0≦w≦0.3x; 0≦v≦0.3y; A is a Group VIII element; F is an element that is different from A but has, in said composition, the same valence state as A; B is an element different from A and F, and is an element whose simple oxide, in which B is at the same valence state as in the complex oxide, is not reducible in the presence of hydrogen gas at a temperature less than about 900° C.; G is an element different from A, B and F, and is an element whose simple oxide, in which G is at the same valence state as in the complex oxide, is not reducible in the presence of hydrogen gas at a temperature less than about 900° C.; and O is oxygen. The complex oxide is reduced at a temperature less that 950° C. Methods of making, uses for and carbon fibril-containing product made with these activated catalysts are also provided.
摘要翻译：提供能够与碳质气体反应时能够选择性地生长单壁碳纳米管的活化催化剂。通过还原包含复合氧化物的催化剂形成活化的催化剂。复合氧化物可以具有式Ax-wFwBy-vGvOz，其中x / y＆nlE; 2; z / y＆nlE; 4; 0＆nlE; w＆nlE; 0.3x; 0＆nlE; v＆nlE; 0.3y; A是VIII族元素; F是与A不同的元素，在所述组合物中具有与A相同的价态; B是与A和F不同的元素，并且是其中B与复合氧化物处于相同价态的简单氧化物在氢气存在下在小于约900°的温度下不可还原的元素 C。; G是不同于A，B和F的元素，并且是其中G与复合氧化物处于相同价态的简单氧化物的元素在氢气存在下在小于约 900°C。而O是氧。复合氧化物在低于950℃的温度下还原。还提供了用这些活化的催化剂制备，用于含有原纤维的产物的方法。

3. 发明申请

US20090286679A1 SINGLE-WALLED CARBON NANOTUBE CATALYST 审中-公开
标题翻译：单壁碳纳米管催化剂
公开(公告)号：US20090286679A1
公开(公告)日：2009-11-19
申请号：US11841505
申请日：2007-08-20
申请人： Jun Ma , David Moy
发明人： Jun Ma , David Moy
IPC分类号： B01J23/00
CPC分类号： D01F9/127 , B01J21/005 , B01J23/002 , B01J23/005 , B01J23/78 , B01J37/0236 , B01J37/031 , B01J37/08 , B01J37/18 , B01J2523/00 , B82Y30/00 , B82Y40/00 , C01B32/162 , C01B2202/02 , B01J2523/22 , B01J2523/842 , B01J2523/845 , B01J2523/41 , B01J2523/31
摘要： An activated catalyst capable of selectively growing single-walled carbon nanotubes when reacted with carbonaceous gas is provided. The activated catalyst is formed by reducing a catalyst that comprises a complex oxide. The complex oxide may be of formula AxByOz, wherein x/y≦2 and z/y≦4, A being a Group VIII element and B being an element such that an oxide of element B is not reducible in the presence of hydrogen at a temperature less than or equal to about 900° C. Methods of making, uses for and carbon fibril-containing product made with these activated catalysts are also provided.
摘要翻译：提供能够与碳质气体反应时能够选择性地生长单壁碳纳米管的活化催化剂。通过还原包含复合氧化物的催化剂形成活化的催化剂。复合氧化物可以具有式AxByOz，其中x / y <= 2且z / y <= 4，A是VIII族元素，B是使元素B的氧化物在氢气存在下不可还原的元素在低于或等于约900℃的温度下，还提供了用这些活化的催化剂制备，使用和含碳原子纤维的产品的方法。

4. 发明申请

US20080175782A1 CARBIDE NANOFIBRILS AND METHOD OF MAKING SAME 失效
标题翻译：碳化硅纳米纤维及其制备方法
公开(公告)号：US20080175782A1
公开(公告)日：2008-07-24
申请号：US11841493
申请日：2007-08-20
申请人： David Moy , Chun-Ming Niu
发明人： David Moy , Chun-Ming Niu
IPC分类号： C01B31/30 , C01B31/34 , C01B31/36
CPC分类号： C04B35/62277 , B82Y30/00 , C01B32/90 , C01B32/956 , C04B35/62281 , C04B2235/3418 , C04B2235/428 , C04B2235/5264 , C04B2235/5288 , C04B2235/5296 , C04B2235/5481 , C04B2235/767 , C04B2235/81 , C04B2235/9661 , C30B25/005 , C30B29/36 , D01F9/08 , Y10S977/734
摘要： A plurality of carbide, such as silicon carbide, tungsten carbide, etc., nanofibrils predominantly having diameters substantially less than about 100 nm and a method for making such carbide nanofibrils. The method includes the steps of: heating a plurality of carbon nanotubes or nanofibrils predominantly having diameters less than about 50 nm in a reaction chamber in the presence of a gas of the form QnAm, where Q is a metal capable of forming a carbide, A is an element or radical and n and m are integers necessary to satisfy valences, such as, for example silicon monoxide, and an inert gas in a reaction vessel to a temperature substantially less than 1700 C but sufficently high to cause substantial reaction of the metal in the gas with the carbon of said carbon nanotubes or nanofibrils to form, in situ, solid carbide nanofibrils, the temperature being sufficiently low to prevent substantial fusing together of individidual ones of said carbide nanofibrils, removing at least a portion of A-based gas from said reaction chamber as said reaction progresses, and maintaining said temperature until substantially all the carbon of said nanotubes or nanofibrils has been converted into Q-based carbide.
摘要翻译：多个碳化物，例如碳化硅，碳化钨等，主要具有基本上小于约100nm的直径的纳米原纤维和制造这种碳化物纳米原纤维的方法。该方法包括以下步骤：在反应室中，在存在下列形式的气体的情况下，加热主要具有小于约50nm直径的碳纳米管或纳米原纤维其中Q是能够形成碳化物的金属，A是元素或基团，n和m是满足价态所必需的整数，例如一氧化硅，以及反应容器中的惰性气体，温度基本上小于1700℃，但足够高，导致气体中的金属与所述碳纳米管或纳米原纤维的碳的实质反应，原位形成整体碳化物纳米原纤维，其温度足够低以防止大量熔融在一起所述碳化物纳米原纤维的单独的，当所述反应进行时，从所述反应室中除去至少一部分A基气体，并保持所述温度，直到所述纳米管或纳米原纤维的基本上全部为碳转为Q型碳化物。

5. 发明授权

US07393514B2 Carbide nanofibrils and method of making same 失效
标题翻译：硬质合金纳米纤丝及其制造方法
公开(公告)号：US07393514B2
公开(公告)日：2008-07-01
申请号：US11265804
申请日：2005-11-02
申请人： David Moy , Chun-Ming Niu
发明人： David Moy , Chun-Ming Niu
IPC分类号： C01B31/36
CPC分类号： C04B35/62277 , B82Y30/00 , C01B32/90 , C01B32/956 , C04B35/62281 , C04B2235/3418 , C04B2235/428 , C04B2235/5264 , C04B2235/5288 , C04B2235/5296 , C04B2235/5481 , C04B2235/767 , C04B2235/81 , C04B2235/9661 , C30B25/005 , C30B29/36 , D01F9/08 , Y10S977/734
摘要： A plurality of carbide, such as silicon carbide, tungsten carbide, etc., nanofibrils predominantly having diameters substantially less than about 100 nm and a method for making such carbide nanofibrils. The method includes the steps of: heating a plurality of carbon nanotubes or nanofibrils predominantly having diameters less than about 50 nm in a reaction chamber in the presence of a gas of the form QnAm, where Q is a metal capable of forming a carbide, A is an element or radical and n and m are integers necessary to satisfy valences, such as, for example silicon monoxide, and an inert gas in a reaction vessel to a temperature substantially less than 1700 C but sufficently high to cause substantial reaction of the metal in the gas with the carbon of said carbon nanotubes or nanofibrils to form, in situ, solid carbide nanofibrils, the temperature being sufficiently low to prevent substantial fusing together of individidual ones of said carbide nanofibrils, removing at least a portion of A-based gas from said reaction chamber as said reaction progresses, and maintaining said temperature until substantially all the carbon of said nanotubes or nanofibrils has been converted into Q-based carbide.
摘要翻译：多个碳化物，例如碳化硅，碳化钨等，主要具有基本上小于约100nm的直径的纳米原纤维和制造这种碳化物纳米原纤维的方法。该方法包括以下步骤：在反应室中，在存在下列形式的气体的情况下，加热主要具有小于约50nm直径的碳纳米管或纳米原纤维其中Q是能够形成碳化物的金属，A是元素或基团，n和m是满足价态所必需的整数，例如一氧化硅，以及反应容器中的惰性气体，温度基本上小于1700℃，但足够高，导致气体中的金属与所述碳纳米管或纳米原纤维的碳的实质反应，原位形成整体碳化物纳米原纤维，其温度足够低以防止大量熔融在一起所述碳化物纳米原纤维的单独的，当所述反应进行时，从所述反应室中除去至少一部分A基气体，并保持所述温度，直到所述纳米管或纳米原纤维的基本上全部为碳转为Q型碳化物。

6. 发明授权

US07074379B2 Process for producing single wall nanotubes using unsupported metal catalysts and single wall nanotubes produced according to this method 失效
标题翻译：使用未负载的金属催化剂和根据该方法生产的单壁纳米管制备单壁纳米管的方法
公开(公告)号：US07074379B2
公开(公告)日：2006-07-11
申请号：US09839932
申请日：2001-04-20
申请人： David Moy , Asif Chishti
发明人： David Moy , Asif Chishti
IPC分类号： D01F9/12
CPC分类号： B82Y30/00 , B01J3/04 , B01J3/042 , B01J19/121 , B01J19/26 , B01J2219/0875 , B82Y40/00 , C01B32/162 , C01B2202/02 , D01F9/127 , D01F9/1278 , Y10S977/742 , Y10S977/75 , Y10S977/842 , Y10S977/843 , Y10S977/896
摘要： A process for producing hollow, single-walled carbon nanotubes by catalytic decomposition of one or more gaseous carbon compounds by first forming a gas phase mixture carbon feed stock gas comprising one or more gaseous carbon compounds, each having one to six carbon atoms and only H, O, N, S or el as hetero atoms, optionally admixed with hydrogen, and a gas phase metal containing compound which is unstable under reaction conditions for said decomposition, and which forms a metal containing catalyst which acts as a decomposition catalyst under reaction conditions; and then conducting said decomposition reaction under decomposition reaction conditions, thereby producing said nanotubes.
摘要翻译：一种通过一种或多种气态碳化合物的催化分解来制备中空单壁碳纳米管的方法，首先形成一种气相混合物碳原料气体，其包含一种或多种具有1-6个碳原子的气态碳化合物，并且仅H ，O，N，S或el作为任选与氢混合的杂原子，以及在所述分解的反应条件下不稳定的含气相金属的化合物，并且在反应条件下形成用作分解催化剂的含金属催化剂 ; 然后在分解反应条件下进行所述分解反应，从而制备所述纳米管。

7. 发明授权

US06699454B1 Catalysts for the manufacture of carbon fibrils and methods of use thereof 失效
标题翻译：用于制造碳原纤维的催化剂及其使用方法
公开(公告)号：US06699454B1
公开(公告)日：2004-03-02
申请号：US08477576
申请日：1995-06-07
申请人： David Moy , Asif Chishti
发明人： David Moy , Asif Chishti
IPC分类号： D01F912
CPC分类号： B82Y30/00 , B01J23/76 , B01J37/031 , D01F9/127
摘要： A method for the manufacture of a catalyst for the production of carbon fibrils comprising contacting a fibril-forming catalyst or precursors of a fibril-forming catalyst with an effective amount of a surfactant and/or polyol. A catalyst for the production of carbon fibrils formed by contacting a fibril-forming catalyst or precursors of a fibril-forming catalyst with an effective amount of a surfactant and/or polyol. Improved carbon fibrils or carbon fibril aggregates free of a continuous carbon thermal overcoat, with graphitic layers substantially parallel to the fibril axis, having a substantially constant diameter from about 1.0 to about 100 nanometers, and possessing enhanced dispersion into other materials and enhanced electrical conductivity in those materials.
摘要翻译：一种制备用于生产碳原纤维的催化剂的方法，包括使原纤维形成催化剂或原纤维形成催化剂的前体与有效量的表面活性剂和/或多元醇接触。一种用于生产形成碳原子的催化剂通过使原纤维形成催化剂或原纤维形成催化剂的前体与有效量的表面活性剂和/或多元醇接触。改进的碳原纤维或不含连续碳热外涂层的碳原纤聚集体，石墨层基本上平行于原纤维轴，具有约1.0至约100纳米的基本恒定的直径，并且在这些材料中具有增强的其它材料的分散性和增强的导电性。

8. 发明授权

US06203814B1 Method of making functionalized nanotubes 失效
标题翻译：制备功能化纳米管的方法
公开(公告)号：US06203814B1
公开(公告)日：2001-03-20
申请号：US08352400
申请日：1994-12-08
申请人： Alan Fisher , Robert Hoch , David Moy , Chunming Niu , Naoya Ogata , Howard Tennent , Thomas McCarthy
发明人： Alan Fisher , Robert Hoch , David Moy , Chunming Niu , Naoya Ogata , Howard Tennent , Thomas McCarthy
IPC分类号： A61K970
CPC分类号： H01M4/60 , A61K33/44 , A61K48/00 , B82Y30/00 , B82Y40/00 , C01B32/152 , C01B32/174 , C01B2202/34 , C01B2202/36 , C07H21/02 , C07K17/06 , D01F9/12 , D01F11/14 , G01N33/5438 , G01N33/582 , G01N2030/8863 , G11C13/025 , Y10S530/811 , Y10S977/742 , Y10S977/746 , Y10S977/847 , Y10T428/249921 , Y10T428/25 , Y10T428/2927
摘要： Graphitic nanotubes, which includes tubular fullerenes (commonly called “buckytubes”) and fibrils, which are functionalized by chemical substitution or by adsorption of functional moieties. More specifically the invention relates to graphitic nanotubes which are uniformly or non-uniformly substituted with chemical moieties or upon which certain cyclic compounds are adsorbed and to complex structures comprised of such functionalized fibrils linked to one another. The invention also relates to methods of introducing functional groups onto the surface of such fibrils.
摘要翻译：石墨纳米管，其包括管状富勒烯（通常称为“巴氏管”）和原纤维，其通过化学取代或功能部分的吸附官能化。更具体地，本发明涉及由化学部分均匀或不均匀取代或其上吸附某些环状化合物的石墨纳米管和由彼此连接的这种官能化原纤维组成的复合结构。本发明还涉及在这种原纤维的表面上引入官能团的方法。

9. 发明授权

US6099965A Rigid porous carbon structures, methods of making, methods of using and products containing same 失效
公开(公告)号：US6099965A
公开(公告)日：2000-08-08
申请号：US857383
申请日：1997-05-15
申请人： Howard Tennent , David Moy , Chun-Ming Niu
发明人： Howard Tennent , David Moy , Chun-Ming Niu
IPC分类号： B32B9/00 , B01J21/18 , C01B31/02 , C04B14/38 , C04B20/00 , C04B30/02 , C04B38/00 , D01F9/12 , D01F11/14 , D04H1/42 , D04H1/58 , C01B11/04
CPC分类号： B01J20/205 , B01J20/20 , B01J20/28007 , B01J20/28011 , B01J20/28014 , B01J20/28047 , B01J20/28057 , B01J21/18 , B01J21/185 , B01J23/28 , B01J23/44 , B01J35/06 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B82Y30/00 , B82Y40/00 , C01B31/02 , C01B31/0253 , C04B14/386 , C04B20/006 , C04B30/02 , C04B35/63432 , C04B35/63456 , C04B35/63476 , C04B35/806 , C04B35/83 , C04B38/00 , C04B38/0051 , D01F11/14 , D01F9/12 , D04H1/4242 , D04H1/4382 , D04H1/58 , C04B2111/00129 , C04B2235/386 , C04B2235/48 , C04B2235/524 , C04B2235/5288 , C04B2235/6021 , C04B2235/77 , Y10S977/748 , Y10S977/752 , Y10S977/753 , Y10S977/767 , Y10T428/249962 , Y10T428/249967 , Y10T428/25 , Y10T428/2918 , Y10T428/2938 , Y10T428/30 , Y10T442/614 , Y10T442/624 , Y10T442/63 , Y10T442/699
摘要： This invention relates to rigid porous carbon structures and to methods of making same. The rigid porous structures have a high surface area which are substantially free of micropores. Methods for improving the rigidity of the carbon structures include causing the nanofibers to form bonds or become glued with other nanofibers at the fiber intersections. The bonding can be induced by chemical modification of the surface of the nanofibers to promote bonding, by adding "gluing" agents and/or by pyrolyzing the nanofibers to cause fusion or bonding at the interconnect points.

10. 发明授权

US5861454A Rubber composition containing carbon fibrils and a pneumatic tire 失效
标题翻译：含有碳原子纤维和充气轮胎的橡胶组合物
公开(公告)号：US5861454A
公开(公告)日：1999-01-19
申请号：US612924
申请日：1996-08-24
申请人： Hiroharu Ikeda , Naoya Ogata , Robert Hausslein , David Moy , Chun Ming Niu
发明人： Hiroharu Ikeda , Naoya Ogata , Robert Hausslein , David Moy , Chun Ming Niu
IPC分类号： B60C1/00 , C08K3/00
CPC分类号： B60C1/00 , B60C1/0016
摘要： A rubber composition containing carbon fibrils in which 0.5 to 60 parts by weight of carbon fibril material comprised primarily of an aggregate of fibrils having an average particle diameter of 0.05 to 50 microns in which fine, filiform carbon fibrils of 3.5 to 75 nm in diameter are intertwined with each other is mixed with 99.5 to 40 parts by weight of synthetic rubber and/or natural rubber and a pneumatic tire in which the surface layer is provided with this rubber composition.
摘要翻译： PCT No.PCT / US94 / 10168 Sec。 371日期：1996年8月24日 102（e）日期1996年8月24日PCT 1994年9月9日PCT公布。第WO95 / 07316号公报日期1995年3月16日含有碳原纤维的橡胶组合物，其中0.5至60重量份的碳原纤材料主要由平均粒径为0.05至50微米的原纤维聚集体组成，其中细的丝状碳原纤维为3.5〜与75.5-40重量份合成橡胶和/或天然橡胶以及表面层设置有该橡胶组合物的充气轮胎混合直径为75纳米。

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