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1. 发明授权

US06235819B1 Process to scavenge amines in polymeric compounds by treatment with triazine derivatives and compositions therefrom 失效
标题翻译：通过用三嗪衍生物及其组合物处理来清除高分子化合物中的胺的方法
公开(公告)号：US06235819B1
公开(公告)日：2001-05-22
申请号：US09002056
申请日：1997-12-31
申请人： David F. Lawson , Ashley S. Hilton , John R. Schreffler , Roderic P. Quirk
发明人： David F. Lawson , Ashley S. Hilton , John R. Schreffler , Roderic P. Quirk
IPC分类号： C08K534
CPC分类号： C08K5/3492
摘要： A method for scavenging amines within polymeric compositions of matter comprising the step of adding to a polymeric composition of matter at least one triazine compound, wherein said triazine compound is defined according to the formula: where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.
摘要翻译：一种用于清除物质的聚合物组合物中的胺的方法，其包括向物质的聚合物组合物中加入至少一种三嗪化合物的步骤，其中所述三嗪化合物根据下式定义：其中X选自氢，卤化物，具有1至约20个碳原子的胺和有机基团，Y选自卤化物，烷氧基衍生物，胺衍生物，芳氧基衍生物和脲衍生物，条件是取代基Y可通过反应置换与仲胺，Z选自烷氧基衍生物，氨基衍生物，芳氧基衍生物和脲衍生物，条件是取代基Z可通过与仲胺的反应置换。

2. 发明授权

US6063873A Process to scavenge amines in polymeric compounds by treatment with triazine derivatives, and compositions therefrom 失效
标题翻译：通过用三嗪衍生物处理在高分子化合物中清除胺及其组合物的方法
公开(公告)号：US6063873A
公开(公告)日：2000-05-16
申请号：US2054
申请日：1997-12-31
申请人： David F. Lawson , Ashley S. Hilton , John R. Schreffler , Roderic P. Quirk
发明人： David F. Lawson , Ashley S. Hilton , John R. Schreffler , Roderic P. Quirk
IPC分类号： B60C1/00 , C07D251/34 , C07D251/50 , C08K5/29 , C08K5/3492 , C08L21/00 , C08C19/22
CPC分类号： C08K5/34922 , Y10T152/10495
摘要： A rubber tread stock comprising a vulcanizable composition of matter, and a triazine, wherein said triazine is defined by the formula ##STR1## where X is selected from the group consisting of hydrogen, halides, amines, and organic groups having from 1 to about 20 carbon atoms, Y is selected from the group consisting of halides, alkoxy derivatives, amine derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Y is displacable by a reaction with a secondary amine, and Z is selected from the group consisting of alkoxy derivatives, amino derivatives, aryloxy derivatives, and urea derivatives, with the proviso that the substituent Z is displacable by a reaction with a secondary amine.
摘要翻译：一种橡胶胎面料，其包含可硫化的物质组合物和三嗪，其中所述三嗪由下式定义：其中X选自氢，卤化物，胺和具有1至约20个碳原子的有机基团， Y选自卤化物，烷氧基衍生物，胺衍生物，芳氧基衍生物和脲衍生物，条件是取代基Y可以通过与仲胺的反应置换，并且Z选自烷氧基衍生物，氨基衍生物，芳氧基衍生物和脲衍生物，条件是取代基Z可通过与仲胺的反应置换。

3. 发明授权

US08501895B2 Method for making alkoxy-modified silsesquioxanes and amino alkoxy-modified silsesquioxanes 有权
标题翻译：制备烷氧基改性倍半硅氧烷和氨基烷氧基改性倍半硅氧烷的方法
公开(公告)号：US08501895B2
公开(公告)日：2013-08-06
申请号：US12347047
申请日：2008-12-31
申请人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： C08G77/26
CPC分类号： C08G77/28 , C08G77/26 , Y02P20/584
摘要： A method is presented for making an amino alkoxy-modified silsesquioxane (amino AMS) comprising one or more compounds selected from the group consisting of an amino-AMS, an amino/mercaptan co-AMS, an amino/blocked mercaptan co-AMS, and mixtures of these. The use of solid strong cationic catalysts in this reaction system is advantageous because the catalyst remains as a solid throughout the reaction, allowing simplified separation of the solid catalyst from the soluble amino AMS or amino co-AMS products, resulting in total or near total recovery of the amino AMS or amino co-AMS products, as well as virtual total recovery of the catalyst for recycling. The use of the solid strong cationic catalysts is advantageous because it results in amino AMS products that are free of, or substantially free of, residual acid catalyst.
摘要翻译：提出了一种制备氨基烷氧基改性倍半硅氧烷（氨基AMS）的方法，其包含一种或多种选自氨基AMS，氨基/硫醇共-AMS，氨基/封端的硫醇共-AMS的化合物和这些的混合物。在该反应体系中使用固体强阳离子催化剂是有利的，因为催化剂在整个反应中保持固体，使固体催化剂与可溶性氨基AMS或氨基共聚AMS产物的分离更简单，导致总的或接近总的回收的氨基AMS或氨基共AMS产物，以及用于再循环的催化剂的虚拟总回收率。使用固体强阳离子催化剂是有利的，因为其导致氨基AMS产物不含或基本上不含残留的酸催化剂。

4. 发明授权

US06790889B2 Processability of silica-filled rubber stocks 失效
标题翻译：二氧化硅填充橡胶原料的加工性能
公开(公告)号：US06790889B2
公开(公告)日：2004-09-14
申请号：US10095604
申请日：2002-03-11
申请人： William L. Hergenrother , Ashley S. Hilton , William M. Cole , James Oziomek
发明人： William L. Hergenrother , Ashley S. Hilton , William M. Cole , James Oziomek
IPC分类号： C08C524
CPC分类号： C08K5/5419 , B60C1/0016 , C08K3/36 , C08K5/0008 , C08K5/103 , C08K5/151 , C08K5/1535 , C08K9/12 , Y10T152/10855 , C08L21/00
摘要： The present invention provides silica-filled, vulcanized elastomeric compounds comprising an elastomer mixed with at least a silica filler, a processing aid, and a curing agent, and processes for the preparation of the same. Generally, the present invention provides processing aids which effectively reduce or replace the amount (i.e., about 10 percent by weight based upon the silica filler) of the processing aid bis[3-triethyoxysilyl)propyl]tetrasulfide (“Si69”) used in the production of silica-filled rubber stocks. These new processing aids include alkyl alkoxysilanes, fatty acid esters of hydrogenated and non-hydrogenated sugars and the polyoxyethylene derivatives thereof, and combinations thereof, with or without various non-reinforcing fillers such as mineral fillers. The processing aids do not hinder the physical properties of the compounds and have been found to be excellent substitutes for Si69. The processing aids may be supported on the silica filler or any of the other fillers employed in the composition for improved handling, safety and performance. Processes for the preparation of the silica filled vulcanizable elastomers are provided as well as pneumatic tires employing tread stock comprising the novel vulcanizable elastomers.
摘要翻译：本发明提供二氧化硅填充的硫化弹性体化合物，其包含与至少二氧化硅填料混合的弹性体，加工助剂和固化剂，及其制备方法。通常，本发明提供加工助剂，其有效地减少或替代加工助剂双[3-三乙氧基甲硅烷基]丙基]四硫化物（“Si69”）的量（即，基于二氧化硅填料的约10重量％）生产二氧化硅填充橡胶原料。这些新的加工助剂包括烷基烷氧基硅烷，氢化和非氢化的糖的脂肪酸酯及其聚氧乙烯衍生物，以及它们的组合，与或不同的各种非增强填料如矿物填料。加工助剂不妨碍化合物的物理性能，并且已被发现是Si69的优良替代物。加工助剂可以负载在二氧化硅填料或用于组合物中的任何其它填料以提高处理，安全性和性能。提供用于制备二氧化硅填充的可硫化弹性体的方法以及使用包含新型可硫化弹性体的胎面胶料的充气轮胎。

5. 发明授权

US06342552B1 Processability of silica-filled rubber stocks 有权
标题翻译：二氧化硅填充橡胶原料的加工性能
公开(公告)号：US06342552B1
公开(公告)日：2002-01-29
申请号：US09723674
申请日：2000-11-28
申请人： William L. Hergenrother , Ashley S. Hilton , William M. Cole , James Oziomek
发明人： William L. Hergenrother , Ashley S. Hilton , William M. Cole , James Oziomek
IPC分类号： C08K524
CPC分类号： C08K5/5419 , B60C1/0016 , C08K3/36 , C08K5/0008 , C08K5/103 , C08K5/151 , C08K5/1535 , C08K9/12 , Y10T152/10855 , C08L21/00
摘要： The present invention provides silica-filled, vulcanized elastomeric compounds comprising an elastomer mixed with at least a silica filler, a processing aid, and a curing agent, and processes for the preparation of the same. Generally, the present invention provides processing aids which effectively reduce or replace the amount (i.e., about 10 percent by weight based upon the silica filler) of the processing aid bis[3-triethyoxysilyl)propyl]tetrasulfide (“Si69”) used in the production of silica-filled rubber stocks. These new processing aids include alkyl alkoxysilanes, fatty acid esters of hydrogenated and non-hydrogenated sugars and the polyoxyethylene derivatives thereof, and combinations thereof, with or without various non-reinforcing fillers such as mineral fillers. The processing aids do not hinder the physical properties of the compounds and have been found to be excellent substitutes for Si69. The processing aids may be supported on the silica filler or any of the other fillers employed in the composition for improved handling, safety and performance. Processes for the preparation of the silica filled vulcanizable elastomers are provided as well as pneumatic tires employing tread stock comprising the novel vulcanizable elastomers.
摘要翻译：本发明提供二氧化硅填充的硫化弹性体化合物，其包含与至少二氧化硅填料混合的弹性体，加工助剂和固化剂，及其制备方法。通常，本发明提供加工助剂，其有效地减少或替代加工助剂双[3-三乙氧基甲硅烷基]丙基]四硫化物（“Si69”）的量（即，基于二氧化硅填料的约10重量％）生产二氧化硅填充橡胶原料。这些新的加工助剂包括烷基烷氧基硅烷，氢化和非氢化的糖的脂肪酸酯及其聚氧乙烯衍生物，以及它们的组合，与或不同的各种非增强填料如矿物填料。加工助剂不妨碍化合物的物理性能，并且已被发现是Si69的优良替代物。加工助剂可以负载在二氧化硅填料或用于组合物中的任何其它填料以提高处理，安全性和性能。提供用于制备二氧化硅填充的可硫化弹性体的方法以及使用包含新型可硫化弹性体的胎面胶料的充气轮胎。

6. 发明授权

US08822620B2 Method for making alkoxy-modified silsesquioxanes 有权
标题翻译：制备烷氧基改性倍半硅氧烷的方法
公开(公告)号：US08822620B2
公开(公告)日：2014-09-02
申请号：US13030611
申请日：2011-02-18
申请人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： C08G77/08
CPC分类号： C08G77/08 , B60C1/00 , C08G77/18 , C08G77/28 , C08K3/013 , C08L9/00 , C08L21/00 , C08L83/06 , C08L83/08 , Y02P20/584 , C08L83/00
摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.
摘要翻译：提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。

7. 发明申请

US20080293858A1 METHOD FOR MAKING ALKOXY-MODIFIED SILSESQUIOXANES 有权
标题翻译：制备改性硅烷氧基硅烷的方法
公开(公告)号：US20080293858A1
公开(公告)日：2008-11-27
申请号：US11752715
申请日：2007-05-23
申请人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： B60C1/00 , C07F7/00
CPC分类号： C08G77/08 , B60C1/00 , C08G77/18 , C08G77/28 , C08K3/013 , C08L9/00 , C08L21/00 , C08L83/06 , C08L83/08 , Y02P20/584 , C08L83/00
摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.
摘要翻译：提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。

8. 发明授权

US4137330A Metal salt catalyzed polymerization of (NPCl.sub.2) oligomers 失效
标题翻译：（NPCl {hd 2 {b）低聚物的金属盐催化聚合
公开(公告)号：US4137330A
公开(公告)日：1979-01-30
申请号：US876385
申请日：1978-02-09
申请人： Mark S. Prichard , Ashley S. Hilton , Mark L. Stayer, Jr. , Thomas A. Antkowiak
发明人： Mark S. Prichard , Ashley S. Hilton , Mark L. Stayer, Jr. , Thomas A. Antkowiak
IPC分类号： C01B21/097 , C01B21/098 , C01B25/10
CPC分类号： C01B21/0986 , C01B21/097
摘要： A process for producing benzene-soluble substantially linear dichlorophosphazene polymer having the formula (NPCl.sub.2).sub.x, in which x is greater than 20 and may be as high as 50,000 or higher, from a cyclic oligomer having the formula (NPCl.sub.2).sub.n, in which n is from 3 to 9, particularly the trimer (NPCl.sub.2).sub.3 or tetramer (NPCl.sub.2).sub.4, in the presence of a small but significant amount of an inorganic salt, preferably a halide of a metal such as Cr, Ni, Co, Cu, Fe, Mn or Mg which affords control of the molecular weight and avoids the formation of large amounts of gel.
摘要翻译：从具有式（NPCl2）n的环状低聚物生产具有式（NPCl2）x的苯可溶性基本线性二氯膦腈聚合物的方法，其中x大于20并可高达50,000或更高，其中 n为3至9，特别是三聚物（NPCl2）3或四聚体（NPCl2）4，在少量但显着量的无机盐存在下，优选金属如Cr，Ni，Co，Cu的卤化物，Fe，Mn或Mg，可以控制分子量，避免形成大量的凝胶。

9. 发明申请

US20110180195A1 COMPOUNDING SILICA-REINFORCED RUBBER WITH LOW VOLATILE ORGANIC COMPOUND (VOC) EMISSION 有权
标题翻译：具有低挥发性有机化合物（VOC）排放物的二氧化硅增强橡胶
公开(公告)号：US20110180195A1
公开(公告)日：2011-07-28
申请号：US12883778
申请日：2010-09-16
申请人： William L. Hergenrother , Chenchy J. Lin , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , Chenchy J. Lin , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： B60C13/00 , C07F7/08 , C07F7/10 , C08L7/00 , B60C15/00 , B60C15/06
CPC分类号： C07F7/21 , B60C1/00 , B60C1/0016 , C08G77/28 , C08K3/04 , C08K3/36 , C08K5/5406 , C08K5/5419 , C08K5/548 , C08K5/549 , C08K13/02 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L83/04 , C08L2205/02 , Y10T152/10 , Y10T152/10846 , Y10T428/2991 , Y10T428/2995 , C08L2666/02 , C08L83/00
摘要： Alkoxy-modified silsesquioxane compounds are described. The alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber of volatile organic compounds (VOC), especially alcohol, during compounding and further processing. Further described are methods for making alkoxy-modified silsesquioxanes, methods for making vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, vulcanizable rubber compounds containing alkoxy-modified silsesquioxanes, and pneumatic tires comprising a component that contains alkoxy-modified silsesquioxanes.
摘要翻译：描述了烷氧基改性的倍半硅氧烷化合物。烷氧基改性的倍半硅氧烷化合物含有作为二氧化硅分散剂参与烷氧基硅烷 - 二氧化硅反应的橡胶中的烷氧基硅烷基，释放出约0.1重量％的挥发性有机化合物（VOC）的橡胶，特别是醇，在复合和进一步加工过程中。还描述了制备烷氧基改性倍半硅氧烷的方法，制备含有烷氧基改性倍半硅氧烷的可硫化橡胶化合物的方法，含有烷氧基改性倍半硅氧烷的可硫化橡胶化合物，以及含有烷氧基改性倍半硅氧烷的组分的充气轮胎。

10. 发明授权

US07915368B2 Method for making alkoxy-modified silsesquioxanes 有权
标题翻译：制备烷氧基改性倍半硅氧烷的方法
公开(公告)号：US07915368B2
公开(公告)日：2011-03-29
申请号：US11752715
申请日：2007-05-23
申请人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： C08G77/08
CPC分类号： C08G77/08 , B60C1/00 , C08G77/18 , C08G77/28 , C08K3/013 , C08L9/00 , C08L21/00 , C08L83/06 , C08L83/08 , Y02P20/584 , C08L83/00
摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.
摘要翻译：提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。

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