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1. 发明授权

US08962746B2 Methods of making blocked-mercapto alkoxy-modified silsesquioxane compounds 有权
标题翻译：制备封端巯基烷氧基改性倍半硅氧烷化合物的方法
公开(公告)号：US08962746B2
公开(公告)日：2015-02-24
申请号：US12344804
申请日：2008-12-29
申请人： William L. Hergenrother , Chenchy Jeffrey Lin , James H. Pawlow , Terrence E. Hogan
发明人： William L. Hergenrother , Chenchy Jeffrey Lin , James H. Pawlow , Terrence E. Hogan
IPC分类号： C08L83/06 , C08G77/06 , C08G77/392 , C08G77/04 , C08G77/28 , C08K5/548 , C08L9/06 , C08K5/56 , C08L9/00
CPC分类号： C08G77/06 , C08G77/04 , C08G77/08 , C08G77/28 , C08G77/392 , C08K5/548 , C08K5/56 , C08L9/00 , C08L9/06 , C08L2205/02 , C08L2205/03 , C08L21/00 , C08L2666/08
摘要： Methods of forming blocked-mercapto alkoxy-modified silsesquioxanes are provided. The blocked-mercapto alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber as alcohol (a volatile organic compound (VOC)), during compounding and further processing. The blocked-mercapto alkoxy-modified silsesquioxane compounds also contain a blocked mercapto group which, when de-blocked, allows the mercapto group to interact with the polymer(s) in a rubber composition. Further described are rubber compounds containing the blocked-mercapto alkoxy-modified silsesquioxanes.
摘要翻译：提供了形成封端巯基烷氧基改性倍半硅氧烷的方法。封端巯基烷氧基改性倍半硅氧烷化合物含有在橡胶中作为二氧化硅分散剂参与烷氧基硅烷 - 二氧化硅反应的烷氧基硅烷基，其中作为醇（挥发性有机化合物）释放0至约0.1重量％的橡胶（VOC）），在复合和进一步加工过程中。封端巯基烷氧基改性的倍半硅氧烷化合物还含有封端的巯基，当脱封时，巯基与橡胶组合物中的聚合物相互作用。进一步描述含有封端巯基烷氧基改性倍半硅氧烷的橡胶化合物。

2. 发明授权

US07915368B2 Method for making alkoxy-modified silsesquioxanes 有权
标题翻译：制备烷氧基改性倍半硅氧烷的方法
公开(公告)号：US07915368B2
公开(公告)日：2011-03-29
申请号：US11752715
申请日：2007-05-23
申请人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： C08G77/08
CPC分类号： C08G77/08 , B60C1/00 , C08G77/18 , C08G77/28 , C08K3/013 , C08L9/00 , C08L21/00 , C08L83/06 , C08L83/08 , Y02P20/584 , C08L83/00
摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.
摘要翻译：提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。

3. 发明申请

US20100029850A1 Adducts Of Metathesis Polymers And Preparation Thereof 有权
标题翻译：复分解聚合物的加合物及其制备方法
公开(公告)号：US20100029850A1
公开(公告)日：2010-02-04
申请号：US12535449
申请日：2009-08-04
申请人： James H. Pawlow , William L. Hergenrother , Mark N. Dedecker , Daniel F. Graves
发明人： James H. Pawlow , William L. Hergenrother , Mark N. Dedecker , Daniel F. Graves
IPC分类号： C08L67/02
CPC分类号： C08G61/08 , C08F8/46 , C08F283/14 , C08G2261/1426 , C08G2261/3322 , C08G2261/418 , F03B17/02 , Y02E10/20 , C08F222/06 , C08F110/14 , C08F132/06
摘要： Adducts of an unsaturated metathesis polymer or interpolymer and an unsaturated diacid anhydride. A process for producing adducts of an unsaturated metathesis polymer or interpolymer and unsaturated diacid anhydride.
摘要翻译：不饱和分解聚合物或互聚物和不饱和二酸酐的加合物。一种制备不饱和分解聚合物或互聚物和不饱和二酸酐的加合物的方法。

4. 发明申请

US20090171014A1 METHODS OF MAKING BLOCKED-MERCAPTO ALKOXY-MODIFIED SILSESQUIOXANE COMPOUNDS 有权
标题翻译：制备嵌段 - 羧酸改性硅烷氧基化合物的方法
公开(公告)号：US20090171014A1
公开(公告)日：2009-07-02
申请号：US12344804
申请日：2008-12-29
申请人： William L. Hergenrother , Chenchy Jeffrey Lin , James H. Pawlow , Terrence E. Hogan
发明人： William L. Hergenrother , Chenchy Jeffrey Lin , James H. Pawlow , Terrence E. Hogan
IPC分类号： C08L83/06 , C08G77/06 , C08G77/08 , C08G77/18
CPC分类号： C08G77/06 , C08G77/04 , C08G77/08 , C08G77/28 , C08G77/392 , C08K5/548 , C08K5/56 , C08L9/00 , C08L9/06 , C08L2205/02 , C08L2205/03 , C08L21/00 , C08L2666/08
摘要： Methods of forming blocked-mercapto alkoxy-modified silsesquioxanes are provided. The blocked-mercapto alkoxy-modified silsesquioxane compounds contain an alkoxysilane group that participates in an alkoxysilane-silica reaction as a silica dispersing agent in rubber, with the release of zero to about 0.1% by weight of the rubber as alcohol (a volatile organic compound (VOC)), during compounding and further processing. The blocked-mercapto alkoxy-modified silsesquioxane compounds also contain a blocked mercapto group which, when de-blocked, allows the mercapto group to interact with the polymer(s) in a rubber composition. Further described are rubber compounds containing the blocked-mercapto alkoxy-modified silsesquioxanes.
摘要翻译：提供了形成封端巯基烷氧基改性倍半硅氧烷的方法。封端巯基烷氧基改性倍半硅氧烷化合物含有在橡胶中作为二氧化硅分散剂参与烷氧基硅烷 - 二氧化硅反应的烷氧基硅烷基，其中作为醇（挥发性有机化合物）释放0至约0.1重量％的橡胶（VOC）），在复合和进一步加工过程中。封端巯基烷氧基改性的倍半硅氧烷化合物还含有封端的巯基，当脱封时，巯基与橡胶组合物中的聚合物相互作用。进一步描述含有封端巯基烷氧基改性倍半硅氧烷的橡胶化合物。

5. 发明申请

US20090165913A1 AMINO ALKOXY-MODIFIED SILSESQUIOXANE ADHESIVES FOR IMPROVED METAL ADHESION AND METAL ADHESION RETENTION TO CURED RUBBER 有权
标题翻译：用于改进金属粘合剂和金属粘合剂固化橡胶的AMINO ALKOXY改性SILSESQUIOXANE粘合剂
公开(公告)号：US20090165913A1
公开(公告)日：2009-07-02
申请号：US12347086
申请日：2008-12-31
申请人： William L. Hergenrother , Walter Tomaszewski , Ashley Hilton , Michael Hayes , James H. Pawlow , Terrence E. Hogan
发明人： William L. Hergenrother , Walter Tomaszewski , Ashley Hilton , Michael Hayes , James H. Pawlow , Terrence E. Hogan
IPC分类号： B60C9/00 , C08G77/26 , B32B15/02 , B32B15/085
CPC分类号： C08K7/06 , B29C66/71 , B29C66/74283 , B29D30/38 , B29D2030/383 , B29D2030/483 , B60C1/00 , B60C2009/0014 , B60C2009/0021 , C08G77/26 , C08G77/28 , C08L21/00 , C09D183/08 , C09J183/08 , D07B1/0666 , Y02P20/582 , Y10T428/31663 , B29K2021/00
摘要： Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water.
摘要翻译：还包含巯基硅烷或封端巯基硅烷的氨基烷氧基改性倍半硅氧烷（氨基AMS）和/或氨基共-MSMS化合物是用于涂覆电镀或未镀覆金属丝的优良粘合剂，用于将线粘附到橡胶原料上。氨基AMS和/或氨基/硫醇共-AMS粘合剂可以与所有类型的橡胶一起使用，并且不需要对橡胶硫化橡胶使用特殊的粘合剂添加剂，例如但不限于钴，树脂和高硫含量。特别地，使用氨基AMS和/或氨基/硫醇共-AMS化合物作为用于将线接合到橡胶上的粘合剂也提高了增强材料的粘附性能，以获得足够的粘合，其耐受在时间上的劣化，特别是电阻热老化和/或热氧化老化，特别是在水存在下的腐蚀。

6. 发明授权

US08642691B2 Amino alkoxy-modified silsesquioxane adhesives for improved metal adhesion and metal adhesion retention to cured rubber 有权
标题翻译：氨基烷氧基改性的倍半硅氧烷粘合剂，用于改善金属粘附和金属粘附保持固化橡胶
公开(公告)号：US08642691B2
公开(公告)日：2014-02-04
申请号：US13174129
申请日：2011-06-30
申请人： William L. Hergenrother , Walter Tomaszewski , Ashley Hilton , Michael Hayes , James H. Pawlow , Terrence E. Hogan , Zhong-Ren Chen
发明人： William L. Hergenrother , Walter Tomaszewski , Ashley Hilton , Michael Hayes , James H. Pawlow , Terrence E. Hogan , Zhong-Ren Chen
IPC分类号： C08K3/08 , B60C1/00
CPC分类号： C08K3/08 , C08G77/26 , C08K5/544 , C09J183/08 , C08L21/00
摘要： Amino alkoxy-modified silsesquioxanes (amino AMS), and/or amino co-AMS compounds that also comprise a mercaptosilane or a blocked mercaptosilane, are excellent adhesives for coating plated or unplated metal wire for adherence of the wire to a rubber stock. The amino AMS and/or the amino/mercaptan co-AMS adhesives can be used with all types of rubber and there is no requirement for the use of special adhesive additives to the rubber vulcanizates, such as, but not limited to, cobalt, resins and high sulfur levels. In particular, the use of amino AMS and/or amino/mercaptan co-AMS compounds as adhesives for bonding wire to rubber also improves the adherence performance of the reinforcements to obtain sufficient bonding that is resistant to degradation over the course of time, especially resistance to thermal aging and/or thermo-oxidizing aging, in particular corrosion in the presence of water. Vulcanized rubber compositions that contain an amino AMS and/or amino/mercaptan co-AMS compound also have improved adhesion to embedded uncoated steel after humidity aging compared with vulcanized rubber compositions not containing the amino alkoxy-modified silsesquioxane.
摘要翻译：还包含巯基硅烷或封端巯基硅烷的氨基烷氧基改性倍半硅氧烷（氨基AMS）和/或氨基辅AMS化合物是用于涂覆电镀或未镀覆金属丝的优良粘合剂，用于将线粘附到橡胶原料上。氨基AMS和/或氨基/硫醇共-AMS粘合剂可以与所有类型的橡胶一起使用，并且不需要对橡胶硫化橡胶使用特殊的粘合剂添加剂，例如但不限于钴，树脂和高硫含量。特别地，使用氨基AMS和/或氨基/硫醇共-AMS化合物作为用于将线接合到橡胶上的粘合剂也提高了增强材料的粘附性能，以获得足够的粘合，其耐受在时间上的劣化，特别是电阻热老化和/或热氧化老化，特别是在水存在下的腐蚀。与不含氨基烷氧基改性的倍半硅氧烷的硫化橡胶组合物相比，含有氨基AMS和/或氨基/硫醇共-AMS化合物的硫化橡胶组合物在湿度老化后也具有改善的对包埋未涂层钢的粘附性。

7. 发明申请

US20110213066A1 Hairy Polymeric Nanoparticles With First And Second Shell Block Polymer Arms 有权
标题翻译：具有第一和第二壳块聚合物臂的多毛聚合物纳米颗粒
公开(公告)号：US20110213066A1
公开(公告)日：2011-09-01
申请号：US12754367
申请日：2010-04-05
申请人： Xiaorong Wang , Hideki Kitano , James H. Pawlow , Christopher G. Robertson , Yaohong Chen , Yuan-Yong Yan
发明人： Xiaorong Wang , Hideki Kitano , James H. Pawlow , Christopher G. Robertson , Yaohong Chen , Yuan-Yong Yan
IPC分类号： C08F271/02 , C08F279/02 , C08L53/02 , B82B1/00
CPC分类号： C08F279/02 , C08F297/046 , C08L9/06 , C08L21/00 , C08L2205/03 , C08L2207/53 , C08L7/00 , C08L9/00 , C08L53/00 , C08L53/02
摘要： Compositions and methods are included for preparing a hairy polymeric nanoparticle including first and second shell block polymer arms are at least partially phase-separated and surround a polymeric core. One type of polymeric arm can have a greater polarity than the other type(s) of polymeric arms. A rubber composition including the hairy nanoparticles is also provided.
摘要翻译：包括用于制备毛发聚合物纳米颗粒的组合物和方法，包括第一和第二壳嵌段聚合物臂至少部分地相分离并且围绕聚合物芯。一种类型的聚合物臂可以具有比其它类型的聚合物臂更大的极性。还提供了包含毛状纳米颗粒的橡胶组合物。

8. 发明申请

US20110144235A1 Method For Making Alkoxy-Modified Silsesquioxanes 有权
标题翻译：制备烷氧基改性倍半硅氧烷的方法
公开(公告)号：US20110144235A1
公开(公告)日：2011-06-16
申请号：US13030611
申请日：2011-02-18
申请人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： C08K5/5419 , B60C1/00 , C08L19/00
CPC分类号： C08G77/08 , B60C1/00 , C08G77/18 , C08G77/28 , C08K3/013 , C08L9/00 , C08L21/00 , C08L83/06 , C08L83/08 , Y02P20/584 , C08L83/00
摘要： A method is presented for making alkoxy-modified silsesquioxanes (AMS) or co-alkoxy-modified silsesquioxanes (co-AMS,) comprising the steps of (a) combining as a reaction mixture (i) water, (ii) an acid-stable solvent for the water, (iii) a solid strong cationic hydrolysis and condensation catalyst, and (iv) a trialkoxysilane compound, (b) allowing the reaction mixture to react for about 0.5 hours to about 200 hours to form the alkoxy-modified silsesquioxanes; and (c) recovering the alkoxy-modified silsesquioxanes from the reaction mixture. The use of solid strong cationic catalysts in this reaction system is advantageous because they remain as solids throughout the reaction, allowing simplified separation of the solid catalyst from the soluble AMS or co-AMS products, resulting in total or near total recovery of the AMS or co-AMS products, the products being free of, or substantially free of residual acid catalyst, as well as virtual total recovery of the catalyst for recycling. The improved AMS and co-AMS compounds, vulcanizable rubber compounds containing them, and a pneumatic tire having a component made from the vulcanized rubber compounds are also presented.
摘要翻译：提出了制备烷氧基改性倍半硅氧烷（AMS）或共 - 烷氧基改性倍半硅氧烷（co-AMS）的方法，该方法包括以下步骤：（a）将反应混合物（i）和（ii）酸稳定溶剂，（iii）固体强阳离子水解和缩合催化剂，和（iv）三烷氧基硅烷化合物，（b）使反应混合物反应约0.5小时至约200小时以形成烷氧基改性倍半硅氧烷; 和（c）从反应混合物中回收烷氧基改性的倍半硅氧烷。在该反应系统中使用固体强阳离子催化剂是有利的，因为它们在整个反应中保持固体，允许固体催化剂与可溶性AMS或共AMS产物的简单分离，导致AMS或共AMS产品，产品没有或基本上没有残留的酸催化剂，以及用于再循环的催化剂的虚拟总回收。还提出了改进的AMS和共AMS化合物，含有它们的可硫化橡胶化合物和具有由硫化橡胶化合物制成的组分的充气轮胎。

9. 发明申请

US20100093920A1 NICKEL CATALYST SYSTEM FOR THE PREPARATION OF HIGH CIS POLYBUTADIENE 有权
标题翻译：用于制备高分子量聚丁二烯的镍系催化剂体系
公开(公告)号：US20100093920A1
公开(公告)日：2010-04-15
申请号：US12571889
申请日：2009-10-01
申请人： James H. PAWLOW , Terrence E. HOGAN
发明人： James H. PAWLOW , Terrence E. HOGAN
IPC分类号： B60C1/00 , B01J31/02 , B01J27/24 , B01J31/14 , B01J27/14 , C08F4/26 , C08F4/48
CPC分类号： B60C1/0016 , B60C1/00 , B60C1/0025 , C08F136/06 , C08F2410/03 , C08F4/705 , C08F4/7006 , C08F4/7027 , C08F4/7052 , C08F4/709
摘要： Embodiments relate to a novel catalyst composition comprising a transition metal-containing compound, a PNP compound, an alkylating agent and a fluorine containing compound. Other embodiments relate to a method of polymerizing a diene monomer in the presence of the novel composition to form a diene-containing polymer having greater than 90% cis content.
摘要翻译：实施方案涉及包含含过渡金属的化合物，PNP化合物，烷化剂和含氟化合物的新型催化剂组合物。其它实施方案涉及在新组合物存在下聚合二烯单体以形成具有大于90％顺式含量的含二烯烃聚合物的方法。

10. 发明申请

US20090326255A1 METHOD FOR MAKING ALKOXY-MODIFIED SILSESQUIOXANES AND AMINO ALKOXY-MODIFIED SILSESQUIOXANES 有权
标题翻译：制备改性硅烷氧基硅烷和氨基烷氧基改性硅氧烷的方法
公开(公告)号：US20090326255A1
公开(公告)日：2009-12-31
申请号：US12347047
申请日：2008-12-31
申请人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
发明人： William L. Hergenrother , James H. Pawlow , Terrence E. Hogan , Ashley S. Hilton
IPC分类号： C07F7/02
CPC分类号： C08G77/28 , C08G77/26 , Y02P20/584
摘要： A method is presented for making an amino alkoxy-modified silsesquioxane (amino AMS) comprising one or more compounds selected from the group consisting of an amino-AMS, an amino/mercaptan co-AMS, an amino/blocked mercaptan co-AMS, and mixtures of these. The use of solid strong cationic catalysts in this reaction system is advantageous because the catalyst remains as a solid throughout the reaction, allowing simplified separation of the solid catalyst from the soluble amino AMS or amino co-AMS products, resulting in total or near total recovery of the amino AMS or amino co-AMS products, as well as virtual total recovery of the catalyst for recycling. The use of the solid strong cationic catalysts is advantageous because it results in amino AMS products that are free of, or substantially free of, residual acid catalyst.
摘要翻译：提出了一种制备氨基烷氧基改性倍半硅氧烷（氨基AMS）的方法，其包含一种或多种选自氨基AMS，氨基/硫醇共-AMS，氨基/封端的硫醇共-AMS的化合物和这些的混合物。在该反应体系中使用固体强阳离子催化剂是有利的，因为催化剂在整个反应中保持固体，使固体催化剂与可溶性氨基AMS或氨基共聚AMS产物的分离更简单，导致总的或接近总的回收的氨基AMS或氨基共AMS产物，以及用于再循环的催化剂的虚拟总回收率。使用固体强阳离子催化剂是有利的，因为其导致氨基AMS产物不含或基本上不含残留的酸催化剂。

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