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    • 2. 发明授权
    • Process for the production of sodium carbonate crystals
    • 生产碳酸钠晶体的方法
    • US06228335B1
    • 2001-05-08
    • US08987978
    • 1997-12-10
    • William C. CopenhaferDavid E. Smith
    • William C. CopenhaferDavid E. Smith
    • C01D700
    • C01D7/12C01D7/126C22B3/44C22B26/10Y02P10/234
    • A process for the production of soda ash by withdrawing an aqueous mining solution containing dissolved sodium carbonate and at least about 1 wt % sodium bicarbonate from an underground alkali source; stripping CO2 gas from the withdrawn aqueous mining solution, to convert sodium bicarbonate dissolved therein to sodium carbonate; co-crystallizing sodium carbonate monohydrate and sodium sesquicarbonate by evaporation of water from the CO2-stripped aqueous mining solution, without co-crystallization of anhydrous sodium carbonate, to form a slurry of crystalline solids in an aqueous liquor; recovering crystalline solids from the slurry; and calcining the recovered crystalline solids to produce soda ash.
    • 一种通过从地下碱源中取出含有溶解的碳酸钠和至少约1重量%的碳酸氢钠的含水采矿溶液来生产苏打灰的方法; 从取出的含水开采溶液中汽提二氧化碳气体,将其中溶解的碳酸氢钠转化为碳酸钠; 通过从二氧化碳剥离的水性开采溶液中蒸发水而不使无水碳酸钠共同结晶,从而在含水液体中形成结晶固体的浆液,从而将碳酸钠一水合物和倍半碳酸钠共同结晶。 从浆料中回收结晶固体; 并煅烧回收的结晶固体以产生苏打灰。
    • 4. 发明授权
    • Process for producing sodium salts from brines of sodium ores
    • 从钠矿石盐水中生产钠盐的方法
    • US5283054A
    • 1994-02-01
    • US40059
    • 1993-03-30
    • William C. CopenhaferDavid E. SmithGerald F. Niedringhaus
    • William C. CopenhaferDavid E. SmithGerald F. Niedringhaus
    • C01D7/12C01D7/35C22B26/10
    • C01D7/126C01D7/35C22B26/10
    • A process for producing valuable sodium-based chemicals from a brine containing sodium carbonate and sodium bicarbonate, such as those containing from about 8% to about 20% total alkali obtained by contacting water with an underground trona formation by heating the brine at about 100.degree. C. to about 140.degree. C. to evaporate water, convert sodium bicarbonate to sodium carbonate and to drive off resulting carbon dioxide, reacting the brine with reduced sodium bicarbonate with an aqueous sodium hydroxide solution in amounts to convert essentially all of the remaining sodium bicarbonate in the brine to sodium carbonate, cooling to about 5.degree. C. to about 25.degree. C. to precipitate sodium carbonate decahydrate crystals, separating the crystals from their mother liquor, melting the separate crystals to form a sodium carbonate solution, heating the solution to from above about 60.degree. C. to below 110.degree. C. to evaporate water, precipitating sodium carbonate monohydrate crystals, separating the sodium carbonate monohydrate crystals from their mother liquor and calcining them to soda ash which is recovered as a product. The sodium hydroxide used in the above process is formed preferably by causticizing sodium carbonate values with calcium oxide or calcium hydroxide in a separate but parallel operating causticizing circuit.
    • 一种由含有碳酸钠和碳酸氢钠的盐水生产有价值的钠基化学品的方法,例如含有约8%至约20%的总碱的碱,其通过将水与地下天然碱形成物接触而获得,所述盐碱通过将盐水加热至约100度 在约140℃下蒸发水,将碳酸氢钠转化为碳酸钠并驱除所得的二氧化碳,将盐水与还原的碳酸氢钠与氢氧化钠水溶液反应,其量基本上将所有剩余的碳酸氢钠 在盐水中加入碳酸钠,冷却至约5摄氏度至约25摄氏度,以沉淀碳酸钠十水合物晶体,将晶体与母液分离,熔化分离的晶体,形成碳酸钠溶液,将溶液加热至 从高于约60摄氏度到低于110摄氏度,蒸发水,沉淀出碳酸钠一水合物 从其母液中分离碳酸钠一水合物晶体并将其煅烧成作为产物回收的苏打灰。 在上述方法中使用的氢氧化钠优选通过在单独的但平行的操作苛化电路中用氧化钙或氢氧化钙对苛性钠碳酸钠进行苛化。
    • 9. 发明授权
    • Return line mounted pump for riserless mud return system
    • 回流管式泵,用于立管泥浆返回系统
    • US07913764B2
    • 2011-03-29
    • US11833010
    • 2007-08-02
    • David E. SmithNils Lennart RollandHarald HufthammerRoger Stave
    • David E. SmithNils Lennart RollandHarald HufthammerRoger Stave
    • E21B7/12
    • E21B21/001E21B21/08E21B21/10
    • Systems and methods for drilling a well bore in a subsea formation from an offshore structure positioned on a water surface with a drill string that is suspended from the structure and includes a bottom hole assembly adapted to form a top hole portion of the well bore. A drilling fluid source on the offshore structure supplies drilling fluid through the drill string to the bottom hole assembly where the drilling fluid exits from the bottom hole assembly during drilling and returns up the well bore. A suction module is disposed at the sea floor and collects the drilling fluid emerging from the well bore. A pump module is disposed on a return line, which is in fluid communication with the suction module, at a position below the water surface and above the sea floor. The pump module is operable to receive drilling fluid from the suction module and pump the drilling fluid through the return pipe to the same offshore structure or a different offshore structure.
    • 用于从位于水面上的海上结构的海底结构钻井井的系统和方法,所述钻井钻柱从所述结构悬挂并且包括适于形成所述井孔的顶孔部分的底孔组件。 海上结构上的钻井液源将钻井液通过钻柱提供给井底组件,在钻井过程中钻井液在钻井期间从井底组件中排出并返回井眼。 抽吸模块设置在海底,并收集从井筒出来的钻井液。 泵模块设置在与吸水模块流体连通的返回管线上,位于水面下方和海底上方。 泵模块可操作以从抽吸模块接收钻井液,并将钻井液通过返回管泵送到相同的海上结构或不同的海上结构。