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1. 发明授权

US06624254B1 Silane functionalized olefin interpolymer derivatives 失效
标题翻译：硅烷官能化烯烃互聚物衍生物
公开(公告)号：US06624254B1
公开(公告)日：2003-09-23
申请号：US09593861
申请日：2000-06-14
申请人： Daniel J. Arriola , Matthew T. Bishop , Richard E. Campbell, Jr. , David D. Devore , Stephen E. Hahn , Thoi H. Ho , Thomas J. McKeand , Francis J. Timmers
发明人： Daniel J. Arriola , Matthew T. Bishop , Richard E. Campbell, Jr. , David D. Devore , Stephen E. Hahn , Thoi H. Ho , Thomas J. McKeand , Francis J. Timmers
IPC分类号： C08F3008
CPC分类号： C08F290/148 , C08F8/12 , C08F230/08 , C08F2810/50 , C08F210/06 , C08F210/02
摘要： Silane functional polymers having uniform silane distribution, long chain branching or tertiary silane functionality and conversion thereof through coupling, hydrolysis, hydrolysis and neutralization, condensation, oxidation or hydrosilation are disclosed.
摘要翻译：公开了具有均匀的硅烷分布，长链支化或叔硅烷官能团以及通过偶联，水解，水解和中和，缩合，氧化或硅氢化的转化的硅烷官能聚合物。

2. 发明授权

US06323294B1 Cyclopentaphenanthrenyl metal complexes and polymerization process 有权
公开(公告)号：US06323294B1
公开(公告)日：2001-11-27
申请号：US09598803
申请日：2000-06-21
申请人： Richard E. Campbell, Jr. , Ravi B. Shankar , Francis J. Timmers , Daniel J. Arriola
发明人： Richard E. Campbell, Jr. , Ravi B. Shankar , Francis J. Timmers , Daniel J. Arriola
IPC分类号： C08F444
CPC分类号： C07F17/00 , C08F4/65908 , C08F10/02 , C08F210/02 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F212/08
摘要： Group 4 metal complexes comprising a cyclopentaphenanthreneyl ligand, catalytic derivatives thereof and their use as olefin polymerization catalysts, especially for the copolymerization of ethylene and a vinylaromatic monomer are disclosed. The resulting copolymers are uniform, pseudo-random copolymers of ethylene and a vinylaromatic monomer having a cluster index, CIES less than 1.0 and a polymerized vinylaromatic monomer content less than 50 mole percent.

3. 发明授权

US6150297A Cyclopentaphenanthrenyl metal complexes and polymerization process 失效
标题翻译：环戊烷基金属络合物和聚合过程
公开(公告)号：US6150297A
公开(公告)日：2000-11-21
申请号：US122958
申请日：1998-07-27
申请人： Richard E. Campbell, Jr. , Francis J. Timmers , Ravi B. Shankar , Daniel J. Arriola
发明人： Richard E. Campbell, Jr. , Francis J. Timmers , Ravi B. Shankar , Daniel J. Arriola
IPC分类号： C07F7/28 , C07F17/00 , C08F4/44 , C08F4/64 , C08F4/659 , C08F4/6592 , C08F10/02 , C08F210/02 , C08F212/08 , B01J31/02 , B01J31/18
CPC分类号： C07F17/00 , C08F10/02 , C08F210/02 , C08F2420/02 , C08F4/65908 , Y10S526/943
摘要： Group 4 metal complexes comprising a cyclopentaphenanthreneyl ligand, catalytic derivatives thereof and their use as olefin polymerization catalysts, especially for the copolymerization of ethylene and a vinylaromatic monomer are disclosed. The resulting copolymers are uniform, pseudo-random copolymers of ethylene and a vinylaromatic monomer having a cluster index, CI.sub.ES less than 1.0 and a polymerized vinylaromatic monomer content less than 50 mole percent.
摘要翻译：公开了包含环戊基蒽基配体，其催化衍生物和它们作为烯烃聚合催化剂的用途的第4族金属络合物，特别是用于乙烯和乙烯基芳族单体的共聚。得到的共聚物是乙烯和具有聚簇指数CIES小于1.0的乙烯基芳族单体和聚合的乙烯基芳族单体含量低于50摩尔％的均匀的假无规共聚物。

4. 发明授权

US06329486B1 Cyclopentaphenanthrenyl metal complexes and polymerization process 有权
标题翻译：环戊烷基金属络合物和聚合过程
公开(公告)号：US06329486B1
公开(公告)日：2001-12-11
申请号：US09598802
申请日：2000-06-21
申请人： Ravi B. Shankar , Francis J. Timmers , Daniel J. Arriola , Richard E. Campbell, Jr.
发明人： Ravi B. Shankar , Francis J. Timmers , Daniel J. Arriola , Richard E. Campbell, Jr.
IPC分类号： C08F1208
CPC分类号： C07F17/00 , C08F4/65908 , C08F10/02 , C08F210/02 , C08F2420/02 , Y10S526/943 , C08F4/6592 , C08F212/08
摘要： Group 4 metal complexes comprising a cyclopentaphenanthreneyl ligand, catalytic derivatives thereof and their use as olefin polymerization catalysts, especially for the copolymerization of ethylene and a vinylaromatic monomer are disclosed. The resulting copolymers are uniform, pseudo-random copolymers of ethylene and a vinylaromatic monomer having a cluster index, CIES less than 1.0 and a polymerized vinylaromatic monomer content less than 50 mole percent.
摘要翻译：公开了包含环戊基蒽基配体，其催化衍生物和它们作为烯烃聚合催化剂的用途的第4族金属络合物，特别是用于乙烯和乙烯基芳族单体的共聚。得到的共聚物是乙烯和具有聚簇指数CIES小于1.0的乙烯基芳族单体和聚合的乙烯基芳族单体含量低于50摩尔％的均匀的假无规共聚物。

5. 发明授权

US07858707B2 Catalytic olefin block copolymers via polymerizable shuttling agent 有权
标题翻译：通过可聚合穿梭剂催化烯烃嵌段共聚物
公开(公告)号：US07858707B2
公开(公告)日：2010-12-28
申请号：US12065867
申请日：2006-09-14
申请人： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC分类号： C08F297/08 , C08F297/00
CPC分类号： C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
摘要： A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
摘要翻译：聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂，支链聚合物，优选包括伪嵌段分子结构。

6. 发明申请

US20090163667A1 CATALYTIC OLEFIN BLOCK COPOLYMERS VIA POLYMERIZABLE SHUTTLING AGENT 有权
标题翻译：催化烯烃嵌段共聚物通过聚合物开关剂
公开(公告)号：US20090163667A1
公开(公告)日：2009-06-25
申请号：US12065867
申请日：2006-09-14
申请人： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC分类号： C08L23/16 , C08F4/44 , C08F2/00 , C08F210/00
CPC分类号： C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
摘要： A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
摘要翻译：聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂，支链聚合物，优选包括伪嵌段分子结构。

7. 发明授权

US08415434B2 Catalytic olefin block copolymers via polymerizable shuttling agent 有权
标题翻译：通过可聚合穿梭剂催化烯烃嵌段共聚物
公开(公告)号：US08415434B2
公开(公告)日：2013-04-09
申请号：US12978006
申请日：2010-12-23
申请人： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC分类号： C08F255/00 , C08F255/02
CPC分类号： C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
摘要： A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
摘要翻译：聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂，支链聚合物，优选包括伪嵌段分子结构。

8. 发明申请

US20110092651A1 Catalytic Olefin Block Copolymers Via Polymerizable Shuttling Agent 有权
标题翻译：催化烯烃嵌段共聚物通过可聚合的穿梭剂
公开(公告)号：US20110092651A1
公开(公告)日：2011-04-21
申请号：US12978006
申请日：2010-12-23
申请人： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
发明人： Daniel J. Arriola , Edmund M. Carnahan , David D. Devore , Phillip D. Hustad , Brian A. Jazdzewski , Roger L. Kuhlman , Francis J. Timmers , Timothy T. Wenzel
IPC分类号： C08F297/02
CPC分类号： C08F297/08 , C08F4/659 , C08F4/65908 , C08F4/6592 , C08F4/65927 , C08F10/00 , C08F210/16 , C08F4/6492 , C08F4/65912 , C08F2/38 , C08F210/14 , C08F2/001 , C08F4/64048 , C08F4/64144 , C08F4/64148 , C08F4/64193
摘要： A polymerization process and the resulting polymer composition, said process comprising polymerizing one or more addition polymerizable monomers and a polymerizable shuttling agent in the presence of at least one addition polymerization catalyst comprising a metal compound or complex and a cocatalyst under conditions characterized by the formation of a branched polymer, preferably comprising pseudo-block molecular architecture.
摘要翻译：聚合方法和所得聚合物组合物，所述方法包括在至少一种包含金属化合物或络合物和助催化剂的加成聚合催化剂的存在下，聚合一种或多种可加聚单体和可聚合穿梭剂，支链聚合物，优选包括伪嵌段分子结构。

9. 发明授权

US07193024B2 Alpha-Olefin based branched polymer 有权
标题翻译：基于α-烯烃的支化聚合物
公开(公告)号：US07193024B2
公开(公告)日：2007-03-20
申请号：US10481064
申请日：2002-06-13
申请人： Daniel J Arriola , Francis J. Timmers , David D. Devore , Oscar D. Redwine
发明人： Daniel J Arriola , Francis J. Timmers , David D. Devore , Oscar D. Redwine
IPC分类号： C08F112/08 , C08F112/36 , C08F112/10
CPC分类号： C08F210/18 , C08F4/65908 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F210/06 , C08F210/16 , C08F4/6592 , C08F212/36 , C08F2500/03 , C08F2500/15 , C08F2500/09 , C08F236/20 , C08F2500/25
摘要： A polymer comprising units (1) derived from an alpha-olefin having at least 3 carbon atoms (1′), units (2) derived from divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′), and units (3) derived from ethylene (3′), the polymer comprising at least 75 mole % of units (1), from 0.01 to 5 mole % of units (2), and up to 20 mole % of units (3), the polymer having a branching factor BF 0.75. A process for preparing a polymer comprising units (1) derived from an alpha-olefin having at least 3 carbon atoms (1′), units (2) derived from divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′), and units (3) derived from ethylene (3′), by contacting the alpha-olefin (1′), the divinylbenzene compound (2′), and ethylene (3′) in the presence of a polymerisation catalyst under polymerisation conditions wherein the mole ratio of alpha-olefin (1′) to divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′) is at least 10:1, the mole ratio of divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′) to ethylene (3′) is in the range of from 1:0.1 to 1:2000, and the mole ratio of (1′) to (3′) is at least 4:1.
摘要翻译：包含衍生自具有至少3个碳原子的α-烯烃（1'）的单元（1）的聚合物，衍生自二乙烯基苯的单元（2）或其衍生自C 1〜10-20烃基取代的衍生物（2' ）和衍生自乙烯（3'）的单元（3），所述聚合物包含至少75摩尔％的单元（1），0.01至5摩尔％的单元（2）和至多20摩尔％的单元 3），聚合物具有分支因子BF 0.75。一种制备聚合物的方法，所述聚合物包含衍生自具有至少3个碳原子（1'）的α-烯烃的单元（1），衍生自二乙烯基苯或C 1-10烃基取代衍生物的单元（2）（2'）和由乙烯（3'）衍生的单元（3），通过在聚合反应的存在下使α-烯烃（1'），二乙烯基苯化合物（2'）和乙烯（3'）接触催化剂在聚合条件下，其中α-烯烃（1'）与二乙烯基苯或其C 1-10烃基取代的衍生物（2'）的摩尔比为至少10:1，二乙烯基苯或其C 1〜10-20烃基取代的衍生物（2'）与乙烯（3'）的摩尔比为1：0.1至1：2000，并且（1'）与（3'）至少为4：1。

10. 发明授权

US07943546B2 Polymerization modifiers 有权
标题翻译：聚合改性剂
公开(公告)号：US07943546B2
公开(公告)日：2011-05-17
申请号：US12434436
申请日：2009-05-01
申请人： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
发明人： Daryoosh Beigzadeh , Richard E. Campbell, Jr. , David D. Devore , Duane R. Romer , James C. Stevens , Francis J. Timmers , Hendrik E. Tuinstra , Paul C. Vosejpka
IPC分类号： B01J31/14 , B01J31/22 , C08F4/64 , C08F4/642
CPC分类号： C08F10/02 , B01J2219/00585 , B01J2219/0059 , B01J2219/00702 , B01J2219/00736 , B01J2219/00738 , C08F4/659 , C08F4/65908 , C08F10/00 , C08F2410/01 , Y10S526/943 , C08F4/65912 , C08F4/6592 , C08F210/02 , C08F212/08 , C08F210/16 , C08F210/14 , C08F210/06
摘要： A combinatorial method for identifying a catalyst composition for use in the homogeneous addition polymerization of an olefin monomers, said catalyst composition comprising a transition metal compound, a cocatalyst and a polymerization modifier, as well as catalyst compositions and improved olefin polymerization processes resulting therefrom.
摘要翻译：用于鉴定用于烯烃单体的均相加成聚合的催化剂组合物的组合方法，所述催化剂组合物包含过渡金属化合物，助催化剂和聚合改性剂，以及由此产生的催化剂组合物和改进的烯烃聚合方法。

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