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    • 7. 发明授权
    • Alpha-Olefin based branched polymer
    • 基于α-烯烃的支化聚合物
    • US07193024B2
    • 2007-03-20
    • US10481064
    • 2002-06-13
    • Daniel J ArriolaFrancis J. TimmersDavid D. DevoreOscar D. Redwine
    • Daniel J ArriolaFrancis J. TimmersDavid D. DevoreOscar D. Redwine
    • C08F112/08C08F112/36C08F112/10
    • C08F210/18C08F4/65908C08F4/65912C08F4/65916C08F4/65927C08F210/06C08F210/16C08F4/6592C08F212/36C08F2500/03C08F2500/15C08F2500/09C08F236/20C08F2500/25
    • A polymer comprising units (1) derived from an alpha-olefin having at least 3 carbon atoms (1′), units (2) derived from divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′), and units (3) derived from ethylene (3′), the polymer comprising at least 75 mole % of units (1), from 0.01 to 5 mole % of units (2), and up to 20 mole % of units (3), the polymer having a branching factor BF 0.75. A process for preparing a polymer comprising units (1) derived from an alpha-olefin having at least 3 carbon atoms (1′), units (2) derived from divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′), and units (3) derived from ethylene (3′), by contacting the alpha-olefin (1′), the divinylbenzene compound (2′), and ethylene (3′) in the presence of a polymerisation catalyst under polymerisation conditions wherein the mole ratio of alpha-olefin (1′) to divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′) is at least 10:1, the mole ratio of divinylbenzene or C1-10hydrocarbyl substituted derivatives thereof (2′) to ethylene (3′) is in the range of from 1:0.1 to 1:2000, and the mole ratio of (1′) to (3′) is at least 4:1.
    • 包含衍生自具有至少3个碳原子的α-烯烃(1')的单元(1)的聚合物,衍生自二乙烯基苯的单元(2)或其衍生自C 1〜10-20烃基取代的衍生物(2' )和衍生自乙烯(3')的单元(3),所述聚合物包含至少75摩尔%的单元(1),0.01至5摩尔%的单元(2)和至多20摩尔%的单元 3),聚合物具有分支因子BF 0.75。 一种制备聚合物的方法,所述聚合物包含衍生自具有至少3个碳原子(1')的α-烯烃的单元(1),衍生自二乙烯基苯或C 1-10烃基取代衍生物的单元(2) (2')和由乙烯(3')衍生的单元(3),通过在聚合反应的存在下使α-烯烃(1'),二乙烯基苯化合物(2')和乙烯(3')接触 催化剂在聚合条件下,其中α-烯烃(1')与二乙烯基苯或其C 1-10烃基取代的衍生物(2')的摩尔比为至少10:1,二乙烯基苯 或其C 1〜10-20烃基取代的衍生物(2')与乙烯(3')的摩尔比为1:0.1至1:2000,并且(1')与 (3')至少为4:1。