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    • 5. 发明授权
    • Radiation patternable functional materials, methods of their use, and structures formed therefrom
    • 可辐射图案化功能材料,其使用方法和由其形成的结构
    • US07294449B1
    • 2007-11-13
    • US10749876
    • 2003-12-31
    • Christopher GudemanJoerg RockenbergerBrian HubertCriswell ChoiAlfred Renaldo
    • Christopher GudemanJoerg RockenbergerBrian HubertCriswell ChoiAlfred Renaldo
    • G03F7/00G03F7/004
    • G03F7/0047C23C18/06C23C18/14H05K3/02H05K2201/0257H05K2203/0514H05K2203/121
    • Materials, compounds and compositions for radiation patternable functional thin films, methods of synthesizing such materials and compounds, and methods for forming an electronically functional thin film and structures including such a film. The compounds and compositions generally include (a) nanoparticles of an electronically functional material or substance and (b) ligands containing a (photo)reactive group. The method generally includes the steps of (1) irradiating the compound and/or composition, and (2) curing the irradiated compound and/or composition, generally to form an electronically functional film. The functional thin film includes a sintered mixture of nanoparticles. The thin film exhibits improved morphology and/or resolution relative to an otherwise identical structure made by an identical process, but without the (photo)functional group on the ligand, and/or relative to an otherwise identical material patterned by a conventional graphics art-based printing process. The present process also exhibits improved throughput relative to conventional photolithographic processing, by eliminating a metal deposition step. The present invention advantageously provides functional thin film structures having qualities suitable for use in electronics applications, such as display devices or RF ID tags, while enabling elimination of a number of conventional photolithographic processing steps (e.g., functional material sputtering, PECVD, etc.).
    • 用于辐射可图形功能薄膜的材料,化合物和组合物,合成这种材料和化合物的方法,以及形成电子功能薄膜的方法和包括这种膜的结构。 化合物和组合物通常包括(a)电子功能材料或物质的纳米颗粒和(b)含有(光)反应性基团的配体。 该方法通常包括以下步骤:(1)照射化合物和/或组合物,和(2)固化照射的化合物和/或组合物,通常形成电子功能膜。 功能性薄膜包括纳米颗粒的烧结混合物。 相对于通过相同方法制备的其它相同的结构,但是没有配体上的(光)官能团,和/或相对于通过常规图形艺术图案化的其它相同材料,薄膜表现出改善的形态和/或分辨率。 基于打印过程。 通过消除金属沉积步骤,本方法还显示相对于常规光刻处理的改善的生产量。 本发明有利地提供具有适合用于电子应用(例如显示装置或RF ID标签)的质量的功能薄膜结构,同时能够消除许多常规光刻处理步骤(例如,功能材料溅射,PECVD等) 。