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1. 发明授权

US6111356A Method for fabricating pixelated polymer organic light emitting devices 失效
标题翻译：制造像素化聚合物有机发光器件的方法
公开(公告)号：US6111356A
公开(公告)日：2000-08-29
申请号：US59608
申请日：1998-04-13
申请人： Daniel B. Roitman , James R. Sheats , Fereidoun Pourmirzaie
发明人： Daniel B. Roitman , James R. Sheats , Fereidoun Pourmirzaie
IPC分类号： G09F9/30 , H01L27/32 , H01L51/50 , H01L51/52 , H05B33/12 , H05B33/14 , H05B33/22 , H01J1/62
CPC分类号： H01L27/3281 , H01L51/5221 , H01L27/3283 , H01L51/5048
摘要： A display having a plurality of addressable pixels and a method for constructing the same. The display includes a substrate having a first conducting layer thereon. The conducting layer includes a plurality of parallel row electrodes having edges separated by insulating material. A first polymer layer constructed from one or more thin films overlies the parallel row electrodes. An insulating layer overlies the polymer layer, the insulating layer having windows therein defining pixels for the display. The insulating layer overlies the edges of the row electrodes while providing access to the first polymer layer in the area of the pixels. A second conducting layer overlies the insulating layer and includes a plurality of separated column electrodes. Each column electrode crosses a plurality of the row electrodes and is located over the windows in the insulating layer at points defining the pixels. The second conducting layer is preferably constructed by depositing a layer of photoresist over the insulating layer and patterning the layer of photoresist to provide openings extending therethrough. The openings are wider in the portion of the layer nearest to the insulating layer. This layer acts as a shadow mask for depositing a layer of conducting material. In one embodiment of the invention, a second polymer layer is located between the insulating layer and the second conducting layer. The insulating layer is preferably constructed from a layer of photoresist that is baked to cross-link the photoresist. The polymer layers include an electroluminescent material, which is preferably based on a polyfluorene.
摘要翻译：具有多个可寻址像素的显示器及其构造方法。显示器包括其上具有第一导电层的基板。导电层包括多个平行的行电极，其边缘由绝缘材料分开。由一个或多个薄膜构成的第一聚合物层覆盖在平行行电极上。绝缘层覆盖聚合物层，绝缘层上具有窗口，用于显示器的像素。绝缘层覆盖行电极的边缘，同时提供对像素区域中的第一聚合物层的访问。第二导电层覆盖绝缘层并且包括多个分离的列电极。每个列电极与多个行电极交叉，并且在限定像素的点处位于绝缘层中的窗口上方。第二导电层优选通过在绝缘层上沉积光致抗蚀剂层并且图案化该光致抗蚀剂层以提供贯穿其中的开口而构成。开口在最靠近绝缘层的层的部分较宽。该层用作沉积导电材料层的荫罩。在本发明的一个实施例中，第二聚合物层位于绝缘层和第二导电层之间。绝缘层优选由烘烤以交联光致抗蚀剂的光致抗蚀剂层构成。聚合物层包括电致发光材料，其优选基于聚芴。

2. 发明授权

US06713955B1 Organic light emitting device having a current self-limiting structure 有权
标题翻译：具有电流自限制结构的有机发光器件
公开(公告)号：US06713955B1
公开(公告)日：2004-03-30
申请号：US09197012
申请日：1998-11-20
申请人： Daniel B. Roitman , Ronald L. Moon , Homer Antoniadis , James R. Sheats
发明人： Daniel B. Roitman , Ronald L. Moon , Homer Antoniadis , James R. Sheats
IPC分类号： H05B3302
CPC分类号： H01L51/5203 , H01L51/50 , H01L2251/5392 , H01L2251/568
摘要： An organic light emitting device having a process compatible current self-limiting (CSL) structure applied in the vicinity of an electrode of the device prevents the occurrence of high current flow in the vicinity of a short within the device. Should a short occur, the CSL structure becomes resistive, or non-conducting in the vicinity of the short, thus preventing the occurrence of “runaway” current in the vicinity of the short. By limiting the current flow between conductors in the device, the non-emissive areas of the device can be minimized, thus improving the overall reliability of the device.
摘要翻译：具有应用于器件电极附近的工艺兼容电流自限制（CSL）结构的有机发光器件防止在器件内的短路附近发生高电流流动。如果发生短路，则CSL结构在短路附近变成电阻或不导通，从而防止在短路附近发生“失控”电流。通过限制器件中的导体之间的电流流动，器件的非发射区域可以最小化，从而提高器件的整体可靠性。

3. 发明授权

US5629389A Polymer-based electroluminescent device with improved stability 失效
标题翻译：基于聚合物的电致发光器件具有改进的稳定性
公开(公告)号：US5629389A
公开(公告)日：1997-05-13
申请号：US463141
申请日：1995-06-06
申请人： Daniel B. Roitman , James R. Sheats , Mark R. Hueschen
发明人： Daniel B. Roitman , James R. Sheats , Mark R. Hueschen
IPC分类号： H05B33/20 , C09K11/02 , C09K11/06 , H01L51/00 , H01L51/30 , H01L51/50 , H05B33/12 , H05B33/14 , C08F283/00 , H01B1/00 , H01L27/15 , H01L31/12
CPC分类号： H01L51/5012 , C09K11/025 , C09K11/06 , H05B33/14 , H01L51/0038 , Y10S362/80
摘要： An improved electroluminescent device which includes a hole injection electrode, an electron injection electrode, and an electroluminescent layer located between the hole and electron injection electrodes. The electroluminescent layer includes an organic polymer and a hindered phenolic additive in a concentration greater than 4% by weight. The preferred organic polymer is a derivative of PPV. The preferred hindered phenolic additives are and 2,4,6 tri-tert-butyl phenol 2,6 di-tert-butyl-methylphenol. The device has higher efficiency and a slower rate of degradation than devices lacking the hindered phenolic additive.
摘要翻译：一种改进的电致发光器件，其包括位于空穴和电子注入电极之间的空穴注入电极，电子注入电极和电致发光层。电致发光层包括浓度大于4重量％的有机聚合物和受阻酚类添加剂。优选的有机聚合物是PPV的衍生物。优选的受阻酚添加剂是2,4,6-三叔丁基苯酚2,6-二叔丁基 - 甲基苯酚。该装置具有比缺乏受阻酚添加剂的装置更高的效率和更低的降解速率。

4. 发明授权

US6137221A Organic electroluminescent device with full color characteristics 失效
标题翻译：有机电致发光器件具有全彩色特性
公开(公告)号：US6137221A
公开(公告)日：2000-10-24
申请号：US111474
申请日：1998-07-08
申请人： Daniel B. Roitman , James R. Sheats
发明人： Daniel B. Roitman , James R. Sheats
IPC分类号： H01L27/32 , H01L51/50 , H01J1/62
CPC分类号： H01L27/322 , H01L51/5036
摘要： An organic polymer based display and method for making the same. The display is constructed on a flexible sheet having first and second surfaces, the first and second surfaces being parallel to one another. The flexible sheet is transparent to light of a first wavelength. A first electrode, which includes a first electrode layer in contact with the first surface, is deposited on the flexible sheet. The first electrode layer is also transparent to light of the first wavelength. A light-emitting layer that includes an organic polymer is deposited on the electrode layer. A second electrode that includes a second electrode layer in contact with the light emitting layer is deposited on the light-emitting layer. The light emitting layer generates light of the first wavelength when a potential difference is applied across the first and second electrodes. A light conversion layer is deposited in contact with the second surface of the flexible sheet. The light conversion layer absorbs light of the first wavelength and emitting light of a second wavelength. In an addressable pixelated display, the light conversion layer and one of the first or second electrodes are patterned as parallel strips overlying one another.
摘要翻译：一种基于有机聚合物的显示器及其制造方法。显示器构造在具有第一表面和第二表面的柔性片上，第一和第二表面彼此平行。柔性片对于第一波长的光是透明的。包括与第一表面接触的第一电极层的第一电极沉积在柔性片上。第一电极层对于第一波长的光也是透明的。包含有机聚合物的发光层沉积在电极层上。包括与发光层接触的第二电极层的第二电极沉积在发光层上。当跨越第一和第二电极施加电位差时，发光层产生第一波长的光。沉积与柔性片的第二表面接触的光转换层。光转换层吸收第一波长的光并发射第二波长的光。在可寻址的像素化显示器中，光转换层和第一或第二电极之一被图案化成彼此重叠的平行条纹。

5. 发明授权

US5965280A Patterned polymer electroluminescent devices based on microlithographic processes 失效
标题翻译：基于微光刻工艺的图案化聚合物电致发光器件
公开(公告)号：US5965280A
公开(公告)日：1999-10-12
申请号：US813962
申请日：1997-03-03
申请人： Daniel B. Roitman , James R. Sheats , Guillermo Bazan , Michelle Lee Renak
发明人： Daniel B. Roitman , James R. Sheats , Guillermo Bazan , Michelle Lee Renak
IPC分类号： H05B33/02 , C08F293/00 , C09K11/06 , G09G3/12 , H01L27/32 , H01L51/00 , H01L51/30 , H01L51/40 , H01L51/50 , H05B33/10 , H05B33/12 , H05B33/22 , B32B9/00
CPC分类号： H01L51/5012 , H01L51/0003 , H01L51/0015 , H01L51/0038 , H01L2251/558 , H01L27/3239 , H01L27/3281 , H01L51/0021 , Y10S428/917
摘要： A PPV based electroluminescent device and method for constructing the same. The electroluminescent device is constructed on a substrate by depositing a layer of material having a PPV precursor and photoacid generator on the substrate. The substrate typically includes the anode for the device. The PPV precursor is converted to PPV in the presence of an acid. The photoacid generator produces an acid when exposed to electromagnetic radiation. Those portions of the layer that are not to contain electroluminescent elements are masked. The unmasked portion is then illuminated with electromagnetic radiation; and any unreacted PPV precursor is removed to provide a plurality of isolated PPV regions on the substrate. An electron transport layer is then deposited over the PPV regions and the cathode is deposited on top of the electron transport layer. By properly choosing the thickness of the electron transport layer, the electron transport layer also provides electrical isolation between the anode and cathode in the regions of the device that do not include PPV elements.
摘要翻译：一种基于PPV的电致发光器件及其构造方法。电致发光器件通过在衬底上沉积具有PPV前体和光致酸发生剂的材料层构造在衬底上。衬底通常包括用于器件的阳极。 PPV前体在酸的存在下转化为PPV。光电发生器在暴露于电磁辐射时产生酸。不含有电致发光元件的层的那些部分被掩蔽。然后用电磁辐射照射未屏蔽的部分; 并且去除任何未反应的PPV前体以在基底上提供多个分离的PPV区域。然后在PPV区域上沉积电子传输层，阴极沉积在电子传输层的顶部。通过适当地选择电子传输层的厚度，电子传输层还在不包括PPV元件的器件的区域中在阳极和阴极之间提供电隔离。

6. 发明授权

US06582756B1 Method and apparatus for fabricating polymer-based electroluminescent displays 有权
标题翻译：用于制造基于聚合物的电致发光显示器的方法和装置
公开(公告)号：US06582756B1
公开(公告)日：2003-06-24
申请号：US09717655
申请日：2000-11-21
申请人： Homer Antoniadis , Hoyle Curtis , Ronald L. Moon , Daniel B. Roitman , James R. Sheats
发明人： Homer Antoniadis , Hoyle Curtis , Ronald L. Moon , Daniel B. Roitman , James R. Sheats
IPC分类号： B05D512
CPC分类号： H01L27/3283 , H01L51/0004 , H01L51/5221 , H01L51/5253 , H01L2251/5315 , Y10S428/917
摘要： A method for fabricating an electroluminescent display and the substrate and apparatus used therein. The display is preferably constructed on a pre-constructed substrate that includes a flexible base layer having a conducting surface on one side thereof. The base layer is impermeable to oxygen and water. The substrate includes a plurality of wells defined by a barrier layer, each well having an electrode layer connected electrically with the conducting surface. A removable protective layer covering the wells protects the electrode layer from attack by oxygen and water prior to being utilized to make the display. In one embodiment, each of the wells also contains an electron transfer layer in contact with the electrode layer.
摘要翻译：一种用于制造电致发光显示器的方法及其中使用的基板和装置。显示器优选地构造在包括在其一侧具有导电表面的柔性基底层的预构造的基底上。基层对氧和水是不透水的。衬底包括由阻挡层限定的多个阱，每个阱具有与导电表面电连接的电极层。覆盖井的可移除的保护层在用于制造显示器之前保护电极层免受氧气和水的侵害。在一个实施例中，每个阱还包含与电极层接触的电子转移层。

7. 发明授权

US06174613B1 Method and apparatus for fabricating polymer-based electroluminescent displays 有权
标题翻译：用于制造基于聚合物的电致发光显示器的方法和装置
公开(公告)号：US06174613B1
公开(公告)日：2001-01-16
申请号：US09363964
申请日：1999-07-29
申请人： Homer Antoniadis , Hoyle Curtis , Ronald L. Moon , Daniel B. Roitman , James R. Sheats
发明人： Homer Antoniadis , Hoyle Curtis , Ronald L. Moon , Daniel B. Roitman , James R. Sheats
IPC分类号： B32B900
CPC分类号： H01L27/3283 , H01L51/0004 , H01L51/5221 , H01L51/5253 , H01L2251/5315 , Y10S428/917
摘要： A method for fabricating an electroluminescent display and the substrate and apparatus used therein. The display is preferably constructed on a pre-constructed substrate that includes a flexible base layer having a conducting surface on one side thereof. The base layer is impermeable to oxygen and water. The substrate includes a plurality of wells defined by a barrier layer, each well having an electrode layer connected electrically with the conducting surface. A removable protective layer covering the wells protects the electrode layer from attack by oxygen and water prior to being utilized to make the display. In one embodiment, each of the wells also contains an electron transfer layer in contact with the electrode layer. The electron transfer layer includes a material that improves the efficiency of the injection of electrons from the electrode layer into the electroluminescent layer of the display. This display is fabricated by moving a first dispenser relative to the substrate so as to quantitatively deposit a first electroluminescent material on the substrate, different amounts of the first electroluminescent material being deposited at different locations on the substrate in response to signals defining an illumination pattern to be generated by the display. A conducting material is deposited on the first electroluminescent material. In color displays, a second electroluminescent material is also deposited, the second electroluminescent material emitting light at a different wavelength than the first electroluminescent material. A non-luminescent material, which is preferably an electrical insulator, can be deposited in wells at locations on the display that are not to emit light prior to depositing the conductive material.
摘要翻译：一种用于制造电致发光显示器的方法及其中使用的基板和装置。显示器优选地构造在包括在其一侧具有导电表面的柔性基底层的预构造的基底上。基层对氧和水是不透水的。衬底包括由阻挡层限定的多个阱，每个阱具有与导电表面电连接的电极层。覆盖井的可移除的保护层在用于制造显示器之前保护电极层免受氧气和水的侵害。在一个实施例中，每个阱还包含与电极层接触的电子转移层。电子转移层包括提高从电极层向显示器的电致发光层注入电子的效率的材料。通过相对于衬底移动第一分配器来制造该显示器，以便在衬底上定量沉积第一电致发光材料，响应于限定照明图案的信号，不同量的第一电致发光材料沉积在衬底上的不同位置由显示器生成。导电材料沉积在第一电致发光材料上。在彩色显示器中，还沉积第二电致发光材料，第二电致发光材料以与第一电致发光材料不同的波长发射光。优选为电绝缘体的非发光材料可以沉积在显示器上的在沉积导电材料之前不发光的位置的孔中。

8. 发明授权

US06146225A Transparent, flexible permeability barrier for organic electroluminescent devices 失效
标题翻译：透明，柔性的有机电致发光器件的导电屏障
公开(公告)号：US06146225A
公开(公告)日：2000-11-14
申请号：US126689
申请日：1998-07-30
申请人： James R. Sheats , Mark R. Hueschen , Karen L. Seaward , Daniel B. Roitman , George Andrew Davidson Briggs
发明人： James R. Sheats , Mark R. Hueschen , Karen L. Seaward , Daniel B. Roitman , George Andrew Davidson Briggs
IPC分类号： H01L51/50 , H01L51/52 , H05B33/04 , H05B33/10 , H05B33/12 , H05B33/14
CPC分类号： H01L51/5256 , H01L51/5259 , H05B33/04
摘要： A barrier for preventing water or oxygen from a source thereof from reaching a device that is sensitive to water or oxygen. The barrier is constructed by depositing a first polymer layer between the device and the source. An inorganic layer is deposited on the first polymer layer of the device by plasma enhanced chemical vapor deposition utilizing an electron cyclotron resonance source ECR-PECVD. A second polymer layer is then deposited on the inorganic layer. The inorganic layer is preferably an oxide or nitride. A second barrier layer having a compound that absorbs oxygen or water can be placed between the inorganic layer and the device to further retard the passage of oxygen or water. The present invention is particularly useful in encapsulating electroluminescent displays.
摘要翻译：用于防止来自其源的水或氧气到达对水或氧气敏感的装置的屏障。通过在装置和源之间沉积第一聚合物层来构造阻挡层。通过使用电子回旋共振源ECR-PECVD的等离子体增强化学气相沉积在器件的第一聚合物层上沉积无机层。然后将第二聚合物层沉积在无机层上。无机层优选为氧化物或氮化物。具有吸收氧气或水的化合物的第二阻隔层可以放置在无机层和装置之间，以进一步延缓氧气或水的通过。本发明特别可用于封装电致发光显示器。

9. 发明申请

US20120090661A1 INDIVIDUALLY ENCAPSULATED SOLAR CELLS AND SOLAR CELL STRINGS 审中-公开
标题翻译：个体化的太阳能电池和太阳能电池
公开(公告)号：US20120090661A1
公开(公告)日：2012-04-19
申请号：US13274567
申请日：2011-10-17
申请人： Philip Capps , Paul Adriani , James R. Sheats
发明人： Philip Capps , Paul Adriani , James R. Sheats
IPC分类号： H01L31/048 , H01L31/052
CPC分类号： H01L31/048 , Y02E10/50
摘要： Methods and devices are provided for improved environmental protection for photovoltaic devices and assemblies. In one embodiment, the device comprises of an individually encapsulated solar cell, wherein the encapsulated solar cell includes at least one protective layer coupled to at least one surface of the solar cell. The protective layer has a chemical composition that prevents moisture from entering the solar cell and wherein light passes through the protective layer to reach an absorber layer in the solar cell.
摘要翻译：提供了用于光伏器件和组件的改进的环境保护的方法和装置。在一个实施例中，该装置包括单独封装的太阳能电池，其中封装的太阳能电池包括耦合到太阳能电池的至少一个表面的至少一个保护层。保护层具有防止水分进入太阳能电池的化学成分，并且其中光通过保护层以到达太阳能电池中的吸收层。

10. 发明申请

US20110019277A1 ANTI-REFLECTIVE COATING 审中-公开
标题翻译：防反射涂层
公开(公告)号：US20110019277A1
公开(公告)日：2011-01-27
申请号：US12741919
申请日：2008-11-10
申请人： Brian M. Sager , James R. Sheats
发明人： Brian M. Sager , James R. Sheats
IPC分类号： G02B1/11 , B05D5/00
CPC分类号： B29D11/00865 , G02B1/113 , G02B2207/107
摘要： Methods and devices are provided for improved anti-reflective coatings. Non-vacuum deposition of transparent conductive electrodes in a roll-to-roll manufacturing environment is disclosed. In one embodiment of the present invention, a device is provided comprising a multi-layer anti-reflective coating formed over a substantially transparent substrate; wherein the multi-layer anti-reflective coating comprises of a plurality of nanostructured layers, wherein each of the layers has a tuned porosity and at least some of the nanostructured layers have different porosities to create a different index of refraction for those layers. In some embodiments, the absorber layer for use with this anti-reflective layer is a group IB-IIIA-VIA absorber layer.
摘要翻译：提供了改进的抗反射涂层的方法和装置。透明导电电极在卷对卷制造环境中的非真空沉积被公开。在本发明的一个实施例中，提供一种装置，其包括在基本上透明的基底上形成的多层抗反射涂层; 其中所述多层抗反射涂层由多个纳米结构层组成，其中每个层具有调谐的孔隙度，并且所述纳米结构层中的至少一些具有不同的孔隙率以产生对于那些层的不同折射率。在一些实施例中，与该抗反射层一起使用的吸收层是IB-IIIA-VIA族吸收层。

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