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1. 发明授权

US4419222A Hydrocarbon conversion processes using improved transition metal oxide catalysts 失效
标题翻译：使用改进的过渡金属氧化物催化剂的烃转化方法
公开(公告)号：US4419222A
公开(公告)日：1983-12-06
申请号：US332162
申请日：1981-12-18
申请人： Dane C. Grenoble , Chang J. Kim , Lawrence L. Murrell
发明人： Dane C. Grenoble , Chang J. Kim , Lawrence L. Murrell
IPC分类号： B01J23/20 , B01J23/30 , B01J37/10 , C10G11/04 , C10G47/12 , C10G11/16
CPC分类号： C10G47/12 , B01J23/20 , B01J23/30 , B01J37/10 , C10G11/04
摘要： Hydrocarbons are cracked by contacting, in a cracking zone and at elevated temperature, a hydrocarbon feed with an acid catalyst comprising at least a catalytic metal oxide component wherein said metal is selected from the group consisting essentially of (a) tungsten, niobium and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, and wherein said catalytic metal oxide component is supported on a silica-containing inorganic refractory metal oxide support the silica content of which is less than 50 wt. % of the total support, said catalyst being steamed prior to use at a temperature at least 600.degree. C. In a preferred embodiment, the support will comprise a mixture of silica and the .gamma.-alumina wherein the silica content is less than 25 wt. % thereof. Further, one may employ steam in the cracking zone.
摘要翻译：碳氢化合物在裂化区和升高的温度下与含有至少一种催化金属氧化物组分的酸催化剂接触的烃进料裂化，其中所述金属选自（a）钨，铌及其混合物和（b）（a）与钽，铪，铬，钛，锆及其混合物的混合物，其中所述催化金属氧化物组分负载在二氧化硅含量小于 50重量％所述催化剂在使用之前在至少600℃的温度下蒸发。在优选的实施方案中，载体将包含二氧化硅和γ-氧化铝的混合物，其中二氧化硅含量小于25wt。％。此外，可以在裂化区中使用蒸汽。

2. 发明授权

US4440872A Transition metal oxide acid catalysts 失效
标题翻译：过渡金属氧化物酸催化剂
公开(公告)号：US4440872A
公开(公告)日：1984-04-03
申请号：US332214
申请日：1981-12-18
申请人： Dane C. Grenoble , Chang J. Kim , Lawrence L. Murrell
发明人： Dane C. Grenoble , Chang J. Kim , Lawrence L. Murrell
IPC分类号： B01J21/06 , B01J21/12 , B01J23/20 , B01J23/26 , B01J23/30 , B01J37/10
CPC分类号： B01J37/10 , B01J21/06 , B01J21/12 , B01J23/20 , B01J23/26 , B01J23/30
摘要： Acid catalysts comprising a catalytic metal oxide component wherein said metal is selected from the group consisting essentially of (a) tungsten, niobium and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, supported on a silica-containing inorganic refractory metal oxide support support wherein the silica content thereof is less than 50 wt. % of the total support, said catalyst being steamed prior to use at a temperature at least 600.degree. C. In a preferred embodiment, the support will comprise a mixture of silica and the .gamma.-alumina wherein the silica content is less than 25 wt. % thereof.
摘要翻译：包含催化金属氧化物组分的酸催化剂，其中所述金属选自（a）钨，铌及其混合物和（b）（a）与钽，铪，铬，钛，锆及其混合物的混合物负载在含二氧化硅的无机难熔金属氧化物载体载体上，其中二氧化硅含量小于50wt。所述催化剂在使用之前在至少600℃的温度下蒸发。在优选的实施方案中，载体将包含二氧化硅和γ-氧化铝的混合物，其中二氧化硅含量小于25wt。％。

3. 发明授权

US4269737A Method for preparing a group IVB, VB or VIB metal oxide on inorganic refractory oxide support catalyst and the product prepared by said method 失效
$Method for preparing a group IVB, VB or VIB metal oxide on inorganic refractory oxide support catalyst and the product prepared by said method$
标题翻译：在无机耐火氧化物载体催化剂上制备IVB族，VB族或VIB族金属氧化物的方法以及通过所述方法制备的产物
公开(公告)号：US4269737A
公开(公告)日：1981-05-26
申请号：US82316
申请日：1979-10-05
申请人： Dane C. Grenoble , Chang J. Kim , Lawrence L. Murrell
发明人： Dane C. Grenoble , Chang J. Kim , Lawrence L. Murrell
IPC分类号： B01J21/06 , B01J21/12 , B01J23/20 , B01J23/26 , B01J23/30 , B01J37/10 , B01J23/24
CPC分类号： B01J21/066 , B01J21/06 , B01J21/063 , B01J21/12 , B01J23/20 , B01J23/26 , B01J23/30 , B01J37/10
摘要： An acid catalyst comprising a catalytic component selected from the group consisting of oxides of tungsten, niobium and mixtures thereof and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide on an inorganic refractory oxide support is prepared by depositing by means known in the art a metal oxide precursor salt on an inorganic refractory metal oxide which is not itself an acid cracking catalyst or by intimately mixing a metal oxide precursor salt with a refractory metal oxide support precursor salt, converting the salt or salts to the respective metal oxides and subjecting the resultant combination to steaming at elevated temperatures prior to use. Catalysts prepared in this manner exhibit enhanced activity and selectivity as compared to conventional acid catalysts. They also exhibit remarkable resistance to coke make.
摘要翻译：一种酸催化剂，其包含选自钨，铌及其混合物的氧化物和钨或铌氧化物的催化组分与一种或多种另外的金属氧化物的组合，所述另外的金属氧化物选自氧化钽，氧化铪，氧化铬，无机耐火氧化物载体上的氧化钛和氧化锆通过本领域已知的方法将金属氧化物前体盐沉积在本身不是酸裂化催化剂的无机难熔金属氧化物上，或者通过将金属氧化物前体盐与难熔金属氧化物载体前体盐，将盐或盐转化成各自的金属氧化物，并使所得组合物在使用前在升高的温度下蒸汽。与常规酸催化剂相比，以这种方式制备的催化剂表现出增强的活性和选择性。它们也表现出显着的抗焦炭性能。

4. 发明授权

US4233139A Acid catalyzed hydrocarbon conversion processes utilizing a catalyst comprising a Group IVB, VB or VIB metal oxide on an inorganic refractory oxide support 失效
$Acid catalyzed hydrocarbon conversion processes utilizing a catalyst comprising a Group IVB, VB or VIB metal oxide on an inorganic refractory oxide support$
标题翻译：在无机耐火氧化物载体上使用含有IVB族，VB族或VIB族金属氧化物的催化剂的酸催化烃转化方法
公开(公告)号：US4233139A
公开(公告)日：1980-11-11
申请号：US927828
申请日：1978-07-25
申请人： Lawrence L. Murrell , Chang J. Kim , Dane C. Grenoble
发明人： Lawrence L. Murrell , Chang J. Kim , Dane C. Grenoble
IPC分类号： B01J23/20 , B01J23/30 , B01J37/10 , C10G11/04 , C10G47/12 , C10G49/04 , C10G49/18
CPC分类号： C10G11/04 , B01J23/20 , B01J23/30 , B01J37/10 , C10G47/12
摘要： It has been discovered and forms the basis of the disclosure that various acid catalyzed hydrocarbon conversion processes such as catalytic cracking of gas oil; xylene isomerization; toluene disproportionation; dealkylation of aromatics; ethylene, butylene, isobutylene, propylene polymerization; olefin isomerization; alcohol dehydration; olefin hydration; alkylation; heavy ends cat cracking, etc. are dramatically improved insofar as percent conversion, and selectivity are concerned by the use of a catalyst selected from the group consisting of the oxides of tungsten, niobium and mixtures thereof, and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide, supported on an inorganic refractory oxide support. These catalysts may be prepared by the methods known in the art, i.e., incipient wetness, impregnation, coprecipitation, etc. of the metal oxide precursor onto or with the supports followed by conversion into the oxide form. Before use, the metal oxide/support combination is preferably subjected to steaming at elevated temperatures either before introduction into the reactor or in situ in the process reactor. Conventional catalytic cracking catalysts are unstable at the elevated temperatures where the metal oxide/support combinations of the present invention are uniquely stable.
摘要翻译：已经发现并形成了各种酸催化烃转化过程如瓦斯油催化裂化的公开的基础; 二甲苯异构化; 甲苯歧化; 芳烃脱烷基化; 乙烯，丁烯，异丁烯，丙烯聚合; 烯烃异构化; 酒精脱水; 烯烃水合; 烷基化; 通过使用选自钨，铌及其混合物的氧化物的催化剂和钨或铌氧化物与一种或多种氧化物的组合，可以显着改善重馏分猫裂解等或更多的另外的金属氧化物，其选自负责在无机难熔氧化物载体上的氧化钽，氧化铪，氧化铬，氧化钛和氧化锆。这些催化剂可以通过本领域已知的方法制备，即金属氧化物前体在载体上或与载体上的初始润湿，浸渍，共沉淀等，然后转化为氧化物形式。在使用之前，金属氧化物/载体组合物优选在引入反应器之前或在加工反应器中原位在高温下进行蒸汽蒸发。常规的催化裂化催化剂在本发明的金属氧化物/载体组合是独特稳定的高温下是不稳定的。

5. 发明授权

US4415437A Hydrocarbon cracking using transition metal oxide Bronsted acid catalysts 失效
标题翻译：使用过渡金属氧化物布朗斯台德酸催化剂进行烃裂解
公开(公告)号：US4415437A
公开(公告)日：1983-11-15
申请号：US305264
申请日：1981-09-24
申请人： Dane C. Grenoble , Lawrence L. Murrell
发明人： Dane C. Grenoble , Lawrence L. Murrell
IPC分类号： B01J23/20 , B01J23/24 , B01J23/30 , C10G11/04
CPC分类号： B01J23/24 , B01J23/20 , B01J23/30 , C10G11/04
摘要： Hydrocarbons are cracked by contacting same, at elevated temperature with a solid acid catalyst having primarily Bronsted acidity which comprises at least one catalytic metal oxide component selected from the group consisting essentially of oxides of (a) tungsten, niobium and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, supported on pyrogenic alumina. The exceptional high temperature steam stability of these catalysts permits the use of steam in the reaction zone, if desired.
摘要翻译：碳氢化合物在高温下与主要具有布朗斯台德酸度的固体酸催化剂接触而开裂，该固体酸催化剂包含至少一种选自（a）钨，铌及其混合物的氧化物的催化金属氧化物组分，和（b）负载在致热氧化铝上的（a）与钽，铪，铬，钛，锆及其混合物的混合物。如果需要，这些催化剂的特殊的高温蒸汽稳定性允许在反应区中使用蒸汽。

6. 发明授权

US4424114A Separating basic asphaltenes using transition metal oxide acid catalysts 失效
标题翻译：使用过渡金属氧化物酸催化剂分离碱性沥青质
公开(公告)号：US4424114A
公开(公告)日：1984-01-03
申请号：US305268
申请日：1981-09-24
申请人： Lawrence L. Murrell , Dane C. Grenoble , Robert B. Long
发明人： Lawrence L. Murrell , Dane C. Grenoble , Robert B. Long
IPC分类号： C10G25/00 , C10G11/04 , C10G25/12
CPC分类号： C10G25/003
摘要： Basic asphaltenes are selectively removed from asphaltene-containing hydrocarbon feeds by contacting the feed with a transition metal oxide solid acid catalyst which selectively adsorbs the basic asphaltenes. The catalyst will comprise a catalytic metal component selected from the group consisting essentially of oxides of (a) tungsten, niobium, and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, supported on an inorganic refractory oxide support such as alumina. Asphalt-laden catalyst is separated from the feed, the asphaltenes adsorbed thereon are cracked off in the presence of steam and the catalyst is regenerated and recycled back to the adsorption zone.
摘要翻译：通过使进料与选择性吸附碱性沥青质的过渡金属氧化物固体酸催化剂接触，从含沥青烯的烃进料中选择性地除去碱性沥青质。催化剂将包含选自以下的催化金属组分：（a）钨，铌及其混合物的氧化物和（b）（a）与钽，铪，铬，钛，锆及其混合物的混合物，负载在无机耐火氧化物载体如氧化铝上。将含沥青的催化剂与进料分离，吸附在其上的沥青质在蒸汽存在下破裂，催化剂再生并再循环回吸附区。

7. 发明授权

US4169883A Process for preparing ultra-stable, high surface area alpha-alumina 失效
标题翻译：制备超稳定，高表面积ALPHA-ALUMINA的方法
公开(公告)号：US4169883A
公开(公告)日：1979-10-02
申请号：US927827
申请日：1978-07-25
申请人： Lawrence L. Murrell , Dane C. Grenoble , John P. DeLuca
发明人： Lawrence L. Murrell , Dane C. Grenoble , John P. DeLuca
IPC分类号： B01J21/04 , B01J37/00 , C01F7/02
CPC分类号： C01F7/021 , B01J21/04 , B01J37/0018 , C01P2006/12 , C01P2006/13
摘要： The preparation of an ultra-stable, high surface area alpha-alumina catalyst and catalyst support suitable for use in high temperature processes such as petroleum refining processes, e.g., resid cat cracking and steam reforming, is disclosed. The process comprises impregnating high surface area gamma-alumina having narrow pores with a carbonaceous material that readily chars to form carbon. The impregnated alumina is then heated to a temperature sufficient to induce charring, following which the gamma-alumina is converted to alpha-alumina by further heating. The carbon is subsequently removed by oxidation. The alpha-alumina thus produced can withstand temperatures up to at least about 1000.degree. C. in the presence of steam without substantial loss of surface area.
摘要翻译：在从γ-氧化铝制备稳定的高表面α-氧化铝的方法中，用可碳化碳质材料如糖浸渍具有平均尺寸在20至100范围内的孔的γ-氧化铝。将浸渍的γ-氧化铝在非氧化条件下加热以将碳质材料转化为碳。然后将所得含碳γ-氧化铝在非氧化条件下进一步加热以将γ-氧化铝转化为α-氧化铝，最后将含碳的α-氧化铝在氧化气氛中加热以通过氧化除去碳。该产品是具有相对较高表面积的α-氧化铝，并且在蒸汽存在下可承受至少1000℃的温度，而不会显着损失面积。 α-氧化铝产品可用作例如催化剂或催化剂载体。石油炼制工艺。

8. 发明授权

US4415480A Transition metal oxide Bronsted acid catalysts 失效
标题翻译：过渡金属氧化物布朗斯台德酸催化剂
公开(公告)号：US4415480A
公开(公告)日：1983-11-15
申请号：US305266
申请日：1981-09-24
申请人： Lawrence L. Murrell , Dane C. Grenoble
发明人： Lawrence L. Murrell , Dane C. Grenoble
IPC分类号： B01J23/20 , B01J23/26 , B01J23/30 , C10G11/04 , B01J21/04
CPC分类号： B01J23/26 , B01J23/20 , B01J23/30 , C10G11/04
摘要： Solid acid catalysts having primarily Bronsted acidity which comprise at least one catalytic metal oxide component selected from the group consisting essentially of oxides of (a) tungsten, niobium and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, supported on pyrogenic alumina. These catalysts are useful cracking catalysts and have exceptional high temperature steam stability.
摘要翻译：主要具有布朗斯台德酸度的固体酸催化剂包含至少一种选自（a）钨，铌及其混合物的氧化物的催化剂金属氧化物组分和（b）（a）与钽，铪，铬，钛，锆及其混合物，负载在热解氧化铝上。这些催化剂是有用的裂解催化剂，具有卓越的高温蒸汽稳定性。

9. 发明授权

US4422926A Separating basic asphaltenes using Bronsted acid transition metal oxide acid catalysts 失效
标题翻译：使用布朗斯台德酸过渡金属氧化物酸催化剂分离碱性沥青质
公开(公告)号：US4422926A
公开(公告)日：1983-12-27
申请号：US305265
申请日：1981-09-24
申请人： Kenneth A. Gould , Dane C. Grenoble , Lawrence L. Murrell , Wim J. M. Pieters
发明人： Kenneth A. Gould , Dane C. Grenoble , Lawrence L. Murrell , Wim J. M. Pieters
IPC分类号： B01J23/00 , C10G25/00 , C10G11/04 , C10G25/12
CPC分类号： C10G25/003
摘要： Basic asphaltenes are selectively removed from asphaltene-containing hydrocarbon feeds by contacting the feed with a transition metal oxide solid acid catalyst exhibiting Bronsted acidity. The catalyst selectively adsorbs the basic asphaltenes. The catalysts will comprise a catalytic metal component selected from the group consisting essentially of oxides of (a) tungsten, niobium and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, supported on pyrogenic alumina. Asphalt-laden catalyst is separated from the feed, the asphaltenes adsorbed thereon are cracked off in the presence of steam and the catalyst is regenerated and recycled back to the adsorption zone.
摘要翻译：通过使进料与显示布朗斯台德酸度的过渡金属氧化物固体酸催化剂接触，基本沥青质从含沥青烯的烃进料中选择性地除去。催化剂选择性吸附碱性沥青质。催化剂将包括选自以下的催化金属组分：（a）钨，铌及其混合物的氧化物和（b）（a）与钽，铪，铬，钛，锆及其混合物的混合物，其被负载在致热氧化铝上。将含沥青的催化剂与进料分离，吸附在其上的沥青质在蒸汽存在下破裂，催化剂再生并再循环回吸附区。

10. 发明授权

US06231792B1 Production of composite structures 有权
标题翻译：复合结构的生产
公开(公告)号：US06231792B1
公开(公告)日：2001-05-15
申请号：US09131151
申请日：1998-08-07
申请人： Rudolf A. Overbeek , Ali M. Khonsari , Yung-Feng Chang , Lawrence L. Murrell , Bruce J. Tatarchuk , Michael W. Meffert
发明人： Rudolf A. Overbeek , Ali M. Khonsari , Yung-Feng Chang , Lawrence L. Murrell , Bruce J. Tatarchuk , Michael W. Meffert
IPC分类号： B29C6500
CPC分类号： C04B30/02 , B01J35/06 , B01J2208/00884 , B22F3/002 , B22F3/1121 , C04B2111/0081 , C04B14/46 , C04B24/383 , C04B40/0268 , C04B14/386 , C04B14/48 , C04B38/0675 , C04B40/0263
摘要： A porous composite product comprised of a network of fibers is produced by forming an unsintered preformed network of fibers and a gasifiable structure forming agent, followed by gasification of the structure forming agent prior to sintering of the fibers at appropriate junction points. The preferred structure forming agent is a cellulosic material.
摘要翻译：由纤维网构成的多孔复合产品通过形成未烧结的预成型纤维网络和可气化结构形成剂来制备，然后在适当的连接点将纤维烧结之前气化结构形成剂。优选的结构形成剂是纤维素材料。

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