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1. 发明授权

US08092671B2 Method for processing hydrocarbon pyrolysis effluent 有权
标题翻译：烃热解流出物的处理方法
公开(公告)号：US08092671B2
公开(公告)日：2012-01-10
申请号：US12643470
申请日：2009-12-21
申请人： Robert David Strack , Richard C. Stell , John R. Messinger , Dane C. Grenoble , John E. Asplin
发明人： Robert David Strack , Richard C. Stell , John R. Messinger , Dane C. Grenoble , John E. Asplin
IPC分类号： C10C3/00 , C10L1/02
CPC分类号： C10G9/00 , C10G9/002 , C10G2300/1033 , C10G2300/1044 , C10G2300/1051 , C10G2300/1059 , C10G2300/107 , C10G2300/1077 , C10G2300/206
摘要： A method is disclosed for treating gaseous effluent from a hydrocarbon pyrolysis unit to provide steam cracked tar of reduced asphaltene and toluene insolubles content. The method is suitable for preparing reduced viscosity tar useful as a fuel blending stock, or feedstock for producing carbon black, while reducing or eliminating the need for externally sourced lighter aromatics additives to meet viscosity specifications. The method comprises drawing steam cracked tar from a separation vessel, e.g., a primary fractionator or tar knock-out drum, cooling the tar, and returning it to the separation vessel to effect lower overall tar temperatures within the separation vessel, in order to reduce viscosity increasing condensation reactions. An apparatus for carrying out the method is also provided.
摘要翻译：公开了一种用于处理来自烃热解单元的气态流出物以提供减少的沥青质和甲苯不溶物含量的蒸汽裂化焦油的方法。该方法适用于制备用作燃料混合原料的还原粘度焦油或用于生产炭黑的原料，同时减少或消除对来自外部的较轻芳烃添加剂以满足粘度规格的需要。该方法包括从分离容器（例如主分馏器或焦油脱除鼓）中抽出蒸汽裂解焦油，冷却焦油，并将其返回到分离容器中以降低分离容器内的总焦油温度，以便减少粘度增加缩合反应。还提供了一种用于执行该方法的装置。

2. 发明申请

US20100096296A1 Method For Processing Hydrocarbon Pyrolysis Effluent 有权
标题翻译：烃热解废水处理方法
公开(公告)号：US20100096296A1
公开(公告)日：2010-04-22
申请号：US12643470
申请日：2009-12-21
申请人： Robert David Strack , Richard C. Stell , John R. Messinger , Dane C. Grenoble , John E. Asplin
发明人： Robert David Strack , Richard C. Stell , John R. Messinger , Dane C. Grenoble , John E. Asplin
IPC分类号： C10L1/04
CPC分类号： C10G9/00 , C10G9/002 , C10G2300/1033 , C10G2300/1044 , C10G2300/1051 , C10G2300/1059 , C10G2300/107 , C10G2300/1077 , C10G2300/206
摘要： A method is disclosed for treating gaseous effluent from a hydrocarbon pyrolysis unit to provide steam cracked tar of reduced asphaltene and toluene insolubles content. The method is suitable for preparing reduced viscosity tar useful as a fuel blending stock, or feedstock for producing carbon black, while reducing or eliminating the need for externally sourced lighter aromatics additives to meet viscosity specifications. The method comprises drawing steam cracked tar from a separation vessel, e.g., a primary fractionator or tar knock-out drum, cooling the tar, and returning it to the separation vessel to effect lower overall tar temperatures within the separation vessel, in order to reduce viscosity increasing condensation reactions. An apparatus for carrying out the method is also provided.
摘要翻译：公开了一种用于处理来自烃热解单元的气态流出物以提供减少的沥青质和甲苯不溶物含量的蒸汽裂化焦油的方法。该方法适用于制备用作燃料混合原料的还原粘度焦油或用于生产炭黑的原料，同时减少或消除对来自外部的较轻芳烃添加剂以满足粘度规格的需要。该方法包括从分离容器（例如主分馏器或焦油脱除鼓）中抽出蒸汽裂解焦油，冷却焦油，并将其返回到分离容器中以降低分离容器内的总焦油温度，以便减少粘度增加缩合反应。还提供了一种用于执行该方法的装置。

3. 发明授权

US4424114A Separating basic asphaltenes using transition metal oxide acid catalysts 失效
标题翻译：使用过渡金属氧化物酸催化剂分离碱性沥青质
公开(公告)号：US4424114A
公开(公告)日：1984-01-03
申请号：US305268
申请日：1981-09-24
申请人： Lawrence L. Murrell , Dane C. Grenoble , Robert B. Long
发明人： Lawrence L. Murrell , Dane C. Grenoble , Robert B. Long
IPC分类号： C10G25/00 , C10G11/04 , C10G25/12
CPC分类号： C10G25/003
摘要： Basic asphaltenes are selectively removed from asphaltene-containing hydrocarbon feeds by contacting the feed with a transition metal oxide solid acid catalyst which selectively adsorbs the basic asphaltenes. The catalyst will comprise a catalytic metal component selected from the group consisting essentially of oxides of (a) tungsten, niobium, and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, supported on an inorganic refractory oxide support such as alumina. Asphalt-laden catalyst is separated from the feed, the asphaltenes adsorbed thereon are cracked off in the presence of steam and the catalyst is regenerated and recycled back to the adsorption zone.
摘要翻译：通过使进料与选择性吸附碱性沥青质的过渡金属氧化物固体酸催化剂接触，从含沥青烯的烃进料中选择性地除去碱性沥青质。催化剂将包含选自以下的催化金属组分：（a）钨，铌及其混合物的氧化物和（b）（a）与钽，铪，铬，钛，锆及其混合物的混合物，负载在无机耐火氧化物载体如氧化铝上。将含沥青的催化剂与进料分离，吸附在其上的沥青质在蒸汽存在下破裂，催化剂再生并再循环回吸附区。

4. 发明授权

US4421637A Catalytic cracking process with simultaneous production of a low BTU fuel gas and catalyst regeneration 失效
标题翻译：催化裂化过程同时生产低BTU燃料气体和催化剂再生
公开(公告)号：US4421637A
公开(公告)日：1983-12-20
申请号：US332161
申请日：1981-12-18
申请人： Dane C. Grenoble , Walter Weissman
发明人： Dane C. Grenoble , Walter Weissman
IPC分类号： C01B3/36 , C01B3/38 , C10G11/04
CPC分类号： C10G11/04 , C01B3/363 , C01B3/386 , C01B2203/0233 , C01B2203/0261 , C01B2203/0283 , C01B2203/0811 , C01B2203/1041 , C01B2203/1082 , C01B2203/1094 , C01B2203/1247 , C01B2203/1258 , Y02P20/584
摘要： A process for catalytically cracking a hydrocarbon with simultaneous production of a low BTU fuel gas and catalyst regeneration comprising contacting a hydrocarbon feed, at elevated temperature and in a cracking zone, with a solid acid catalyst comprising a catalytic metal oxide component wherein said metal is selected from the group consisting essentially of (a) tungsten, niobium and mixtures thereof (b) mixture of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, said oxide component being supported on a silica-containing inorganic refractory metal oxide support having a silica content less than 50 wt. % of the total support, to produce a cracked product and a deactivated catalyst and regenerating the deactive catalyst to produce a low BTU gas rich in CO, a gas rich in H.sub.2, or both and recirculating the regenerated catalyst back to the cracking zone, said catalyst being steamed prior to use at a temperature at least 600.degree. C. In a preferred embodiment, the catalyst support will comprise a mixture of silica and .gamma.-alumina.
摘要翻译：一种同时生产低BTU燃料气体和催化剂再生的催化裂化烃的方法，包括使烃进料在升高的温度和在裂化区中与包含催化金属氧化物组分的固体酸催化剂接触，其中所述金属被选择由（a）钨，铌及其混合物组成的组（b）（a）与钽，铪，铬，钛，锆及其混合物的混合物，所述氧化物组分负载在含二氧化硅的无机难熔金属氧化物载体，其二氧化硅含量小于50wt。产生裂化产物和失活的催化剂并再生该活性催化剂以产生富含CO，富含H 2的二氧化碳或二者的低BTU气体，并将再生催化剂再循环回裂化区，所述催化剂在使用前在至少600℃的温度下蒸发。在优选的实施方案中，催化剂载体将包含二氧化硅和γ-氧化铝的混合物。

5. 发明授权

US4169883A Process for preparing ultra-stable, high surface area alpha-alumina 失效
标题翻译：制备超稳定，高表面积ALPHA-ALUMINA的方法
公开(公告)号：US4169883A
公开(公告)日：1979-10-02
申请号：US927827
申请日：1978-07-25
申请人： Lawrence L. Murrell , Dane C. Grenoble , John P. DeLuca
发明人： Lawrence L. Murrell , Dane C. Grenoble , John P. DeLuca
IPC分类号： B01J21/04 , B01J37/00 , C01F7/02
CPC分类号： C01F7/021 , B01J21/04 , B01J37/0018 , C01P2006/12 , C01P2006/13
摘要： The preparation of an ultra-stable, high surface area alpha-alumina catalyst and catalyst support suitable for use in high temperature processes such as petroleum refining processes, e.g., resid cat cracking and steam reforming, is disclosed. The process comprises impregnating high surface area gamma-alumina having narrow pores with a carbonaceous material that readily chars to form carbon. The impregnated alumina is then heated to a temperature sufficient to induce charring, following which the gamma-alumina is converted to alpha-alumina by further heating. The carbon is subsequently removed by oxidation. The alpha-alumina thus produced can withstand temperatures up to at least about 1000.degree. C. in the presence of steam without substantial loss of surface area.
摘要翻译：在从γ-氧化铝制备稳定的高表面α-氧化铝的方法中，用可碳化碳质材料如糖浸渍具有平均尺寸在20至100范围内的孔的γ-氧化铝。将浸渍的γ-氧化铝在非氧化条件下加热以将碳质材料转化为碳。然后将所得含碳γ-氧化铝在非氧化条件下进一步加热以将γ-氧化铝转化为α-氧化铝，最后将含碳的α-氧化铝在氧化气氛中加热以通过氧化除去碳。该产品是具有相对较高表面积的α-氧化铝，并且在蒸汽存在下可承受至少1000℃的温度，而不会显着损失面积。 α-氧化铝产品可用作例如催化剂或催化剂载体。石油炼制工艺。

6. 发明授权

US5444176A Process for recovering olefins from cat-cracked gas without accumulating undesirable oxides of nitrogen 失效
标题翻译：从催化裂化气体回收烯烃的方法，而不会积聚不需要的氮氧化物
公开(公告)号：US5444176A
公开(公告)日：1995-08-22
申请号：US967835
申请日：1992-10-28
申请人： Dane C. Grenoble , Roy T. Halle , William D. Thomson
发明人： Dane C. Grenoble , Roy T. Halle , William D. Thomson
IPC分类号： C07C7/11 , B01D53/14 , B01D53/54 , C07C11/02 , C10G55/06 , C10G70/04 , C10G70/06 , F25J3/02 , C07C7/00 , F25J3/00
CPC分类号： C10G70/041 , C10G70/06 , F25J3/0209 , F25J3/0219 , F25J3/0233 , F25J3/0238 , F25J3/0242 , F25J3/0247 , F25J3/0252 , F25J2205/50 , F25J2210/12 , F25J2215/62 , F25J2215/64 , F25J2220/02
摘要： A safe, effective, and economical method is provided for recovering olefins from cat-cracked gases without accumulating dangerous amounts of nitrogen oxides. A stream of cat-cracked gas first is scrubbed to remove acid gases, including nitrogen dioxide (NO.sub.2), and then is passed through a depropanizer fractionation tower. Hydrocarbons having four or more carbon atoms are recovered in the bottoms of the depropanizer, and the overhead from the depropanizer--which is composed of hydrocarbons having three or fewer carbon atoms--is sent to an absorber demethanizer tower. Hydrocarbons having two or more carbon atoms are recovered in the bottoms from the absorber demethanizer tower, where temperatures are no lower than about -45.56.degree. C. (-50.degree. F.). The overhead from the absorber demethanizer tower--which is composed of methane, hydrogen, and trace amounts of nitrogen oxide, C.sub.2, and absorbent (C.sub.3)--then is chilled to condense and recover trace amounts of C.sub.2 and heavier gases, including trace amounts of the C.sub.3 absorbent, at temperatures of about -101.11.degree. C. (-150.degree. F.) or higher. Thus, recovery of desired hydrocarbons from the cat-cracked gas is conducted at temperatures that are high enough to prevent the oxidation of nitric oxide (NO) to form nitrogen dioxide (NO.sub.2) and high enough to prevent the accumulation of unwanted nitrogen oxides.
摘要翻译：提供了一种安全，有效和经济的方法来回收来自猫裂纹气体的烯烃，而不会累积危险的氮氧化物。首先将一批猫裂纹气体洗涤以除去包括二氧化氮（NO2）在内的酸性气体，然后通过脱丙烷塔分馏塔。具有四个或更多碳原子的碳氢化合物被回收到脱丙烷塔的底部，并且由脱丙烷化器（其由具有三个或更少碳原子的烃组成）的塔顶馏出物被送到吸收器脱甲烷塔。具有两个或多个碳原子的烃在来自吸收器脱甲烷塔的塔底中回收，其中温度不低于约-45.56℃（-50°F）。由甲烷，氢气和痕量的氮氧化物C2和吸收剂（C3）组成的吸收剂脱甲烷塔的塔顶馏出物冷凝并回收痕量的C2和较重的气体，包括痕量的 C3吸收剂，在约-101.11℃（-150°F）或更高的温度下。因此，从破裂气体回收所需的烃是在足够高的温度下进行的，以防止一氧化氮（NO）氧化形成二氧化氮（NO 2），并且足够高以防止不想要的氮氧化物的积聚。

7. 发明授权

US4415480A Transition metal oxide Bronsted acid catalysts 失效
标题翻译：过渡金属氧化物布朗斯台德酸催化剂
公开(公告)号：US4415480A
公开(公告)日：1983-11-15
申请号：US305266
申请日：1981-09-24
申请人： Lawrence L. Murrell , Dane C. Grenoble
发明人： Lawrence L. Murrell , Dane C. Grenoble
IPC分类号： B01J23/20 , B01J23/26 , B01J23/30 , C10G11/04 , B01J21/04
CPC分类号： B01J23/26 , B01J23/20 , B01J23/30 , C10G11/04
摘要： Solid acid catalysts having primarily Bronsted acidity which comprise at least one catalytic metal oxide component selected from the group consisting essentially of oxides of (a) tungsten, niobium and mixtures thereof and (b) mixtures of (a) with tantalum, hafnium, chromium, titanium, zirconium and mixtures thereof, supported on pyrogenic alumina. These catalysts are useful cracking catalysts and have exceptional high temperature steam stability.
摘要翻译：主要具有布朗斯台德酸度的固体酸催化剂包含至少一种选自（a）钨，铌及其混合物的氧化物的催化剂金属氧化物组分和（b）（a）与钽，铪，铬，钛，锆及其混合物，负载在热解氧化铝上。这些催化剂是有用的裂解催化剂，具有卓越的高温蒸汽稳定性。

8. 发明授权

US4269737A Method for preparing a group IVB, VB or VIB metal oxide on inorganic refractory oxide support catalyst and the product prepared by said method 失效
$Method for preparing a group IVB, VB or VIB metal oxide on inorganic refractory oxide support catalyst and the product prepared by said method$
标题翻译：在无机耐火氧化物载体催化剂上制备IVB族，VB族或VIB族金属氧化物的方法以及通过所述方法制备的产物
公开(公告)号：US4269737A
公开(公告)日：1981-05-26
申请号：US82316
申请日：1979-10-05
申请人： Dane C. Grenoble , Chang J. Kim , Lawrence L. Murrell
发明人： Dane C. Grenoble , Chang J. Kim , Lawrence L. Murrell
IPC分类号： B01J21/06 , B01J21/12 , B01J23/20 , B01J23/26 , B01J23/30 , B01J37/10 , B01J23/24
CPC分类号： B01J21/066 , B01J21/06 , B01J21/063 , B01J21/12 , B01J23/20 , B01J23/26 , B01J23/30 , B01J37/10
摘要： An acid catalyst comprising a catalytic component selected from the group consisting of oxides of tungsten, niobium and mixtures thereof and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide on an inorganic refractory oxide support is prepared by depositing by means known in the art a metal oxide precursor salt on an inorganic refractory metal oxide which is not itself an acid cracking catalyst or by intimately mixing a metal oxide precursor salt with a refractory metal oxide support precursor salt, converting the salt or salts to the respective metal oxides and subjecting the resultant combination to steaming at elevated temperatures prior to use. Catalysts prepared in this manner exhibit enhanced activity and selectivity as compared to conventional acid catalysts. They also exhibit remarkable resistance to coke make.
摘要翻译：一种酸催化剂，其包含选自钨，铌及其混合物的氧化物和钨或铌氧化物的催化组分与一种或多种另外的金属氧化物的组合，所述另外的金属氧化物选自氧化钽，氧化铪，氧化铬，无机耐火氧化物载体上的氧化钛和氧化锆通过本领域已知的方法将金属氧化物前体盐沉积在本身不是酸裂化催化剂的无机难熔金属氧化物上，或者通过将金属氧化物前体盐与难熔金属氧化物载体前体盐，将盐或盐转化成各自的金属氧化物，并使所得组合物在使用前在升高的温度下蒸汽。与常规酸催化剂相比，以这种方式制备的催化剂表现出增强的活性和选择性。它们也表现出显着的抗焦炭性能。

9. 发明授权

US4233139A Acid catalyzed hydrocarbon conversion processes utilizing a catalyst comprising a Group IVB, VB or VIB metal oxide on an inorganic refractory oxide support 失效
$Acid catalyzed hydrocarbon conversion processes utilizing a catalyst comprising a Group IVB, VB or VIB metal oxide on an inorganic refractory oxide support$
标题翻译：在无机耐火氧化物载体上使用含有IVB族，VB族或VIB族金属氧化物的催化剂的酸催化烃转化方法
公开(公告)号：US4233139A
公开(公告)日：1980-11-11
申请号：US927828
申请日：1978-07-25
申请人： Lawrence L. Murrell , Chang J. Kim , Dane C. Grenoble
发明人： Lawrence L. Murrell , Chang J. Kim , Dane C. Grenoble
IPC分类号： B01J23/20 , B01J23/30 , B01J37/10 , C10G11/04 , C10G47/12 , C10G49/04 , C10G49/18
CPC分类号： C10G11/04 , B01J23/20 , B01J23/30 , B01J37/10 , C10G47/12
摘要： It has been discovered and forms the basis of the disclosure that various acid catalyzed hydrocarbon conversion processes such as catalytic cracking of gas oil; xylene isomerization; toluene disproportionation; dealkylation of aromatics; ethylene, butylene, isobutylene, propylene polymerization; olefin isomerization; alcohol dehydration; olefin hydration; alkylation; heavy ends cat cracking, etc. are dramatically improved insofar as percent conversion, and selectivity are concerned by the use of a catalyst selected from the group consisting of the oxides of tungsten, niobium and mixtures thereof, and tungsten or niobium oxides in combination with one or more additional metal oxides selected from the group consisting of tantalum oxide, hafnium oxide, chromium oxide, titanium oxide and zirconium oxide, supported on an inorganic refractory oxide support. These catalysts may be prepared by the methods known in the art, i.e., incipient wetness, impregnation, coprecipitation, etc. of the metal oxide precursor onto or with the supports followed by conversion into the oxide form. Before use, the metal oxide/support combination is preferably subjected to steaming at elevated temperatures either before introduction into the reactor or in situ in the process reactor. Conventional catalytic cracking catalysts are unstable at the elevated temperatures where the metal oxide/support combinations of the present invention are uniquely stable.
摘要翻译：已经发现并形成了各种酸催化烃转化过程如瓦斯油催化裂化的公开的基础; 二甲苯异构化; 甲苯歧化; 芳烃脱烷基化; 乙烯，丁烯，异丁烯，丙烯聚合; 烯烃异构化; 酒精脱水; 烯烃水合; 烷基化; 通过使用选自钨，铌及其混合物的氧化物的催化剂和钨或铌氧化物与一种或多种氧化物的组合，可以显着改善重馏分猫裂解等或更多的另外的金属氧化物，其选自负责在无机难熔氧化物载体上的氧化钽，氧化铪，氧化铬，氧化钛和氧化锆。这些催化剂可以通过本领域已知的方法制备，即金属氧化物前体在载体上或与载体上的初始润湿，浸渍，共沉淀等，然后转化为氧化物形式。在使用之前，金属氧化物/载体组合物优选在引入反应器之前或在加工反应器中原位在高温下进行蒸汽蒸发。常规的催化裂化催化剂在本发明的金属氧化物/载体组合是独特稳定的高温下是不稳定的。

10. 发明授权

US06210561B1 Steam cracking of hydrotreated and hydrogenated hydrocarbon feeds 失效
标题翻译：加氢处理和氢化烃进料的蒸汽裂化
公开(公告)号：US06210561B1
公开(公告)日：2001-04-03
申请号：US08854017
申请日：1997-05-08
申请人： Carl W. Bradow , Dane C. Grenoble , Richard M. Foley , Brendan D. Murray , Bruce H. C. Winquist , Stanley N. Milam
发明人： Carl W. Bradow , Dane C. Grenoble , Richard M. Foley , Brendan D. Murray , Bruce H. C. Winquist , Stanley N. Milam
IPC分类号： C10G6902
CPC分类号： C10G65/04 , C10G45/08 , C10G65/08 , C10G69/06
摘要： An integrated process for converting a hydrocarbon feedstock having components boiling above about 100° C. into steam cracked products is described. The process first involves passing the feedstock to a hydrotreating zone to effect substantially complete decomposition of organic sulfur and/or nitrogen compounds. The product from the hydrotreating zone is passed to an aromatics saturation zone. The product is then passed to a steam cracking zone. Hydrogen and C1-C4 hydrocarbons, steam cracked naphtha, steam cracked gas oils and steam cracked tar are recovered. The amount of steam cracked tar produced is reduced by at least about 30 percent, and the amount of steam cracked tar produced is reduced by at least about 40 percent, basis the starting hydrocarbon feedstock which has not been subject to hydrotreating and aromatics saturation.
摘要翻译：描述了将沸点高于约100℃的组分的烃原料转化成蒸汽裂化产物的整合方法。该方法首先涉及将原料转移到加氢处理区以实现有机硫和/或氮化合物的基本完全分解。来自加氢处理区的产物通入芳烃饱和区。然后将产物通入蒸汽裂解区。氢和C1-C4烃，蒸汽裂解石脑油，蒸汽裂化瓦斯油和蒸汽裂解焦油回收。产生的蒸汽裂解焦油的量减少至少约30％，并且基于未进行加氢处理和芳族化合物饱和的原料烃原料，产生的蒸汽裂解焦油的量减少至少约40％。

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