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    • 3. 发明专利
    • Method for curing photocurable resin composition, and method of manufacturing relief pattern
    • 光固化树脂组合物的固化方法及其制备方法
    • JP2012130906A
    • 2012-07-12
    • JP2011259241
    • 2011-11-28
    • Dainippon Printing Co Ltd大日本印刷株式会社
    • KATAYAMA ASAMIFUKUDA TOSHIHARUKAWAGUCHI KOJISAKAYORI KATSUYA
    • B05D3/06C09D5/00C09D7/12C09D163/00C09D171/00C09D175/04C09D181/02C09D201/02C09K3/00
    • PROBLEM TO BE SOLVED: To provide a method for curing a photocurable resin composition, capable of controlling stepwisely and stably a cured condition in a desired condition and easily taking process margin; and to provide a method for making a relief pattern.SOLUTION: In the method for curing the photocurable resin composition, a base generating agent for generating a polyamine through photoisomerization reaction and intramolecular cyclization reaction by heating and a photocurable resin composition containing a specific polymer precursor are used, and storage elasticity of the resin composition at predetermined temperature is stepwisely changed by the steps 1 to 4. The method for manufacturing the relief pattern is also disclosed. A step 1 is for coating the photocurable resin composition on a base material and forming a coated film, a step 2 is for irradiating the coated film with light from the base material side or the coated film surface side, a step 3 is for heating the coated film and curing at least a part of the coated film, and a step 4 is for repeating the steps 2 and 3 to cure the coated film.
    • 要解决的问题:提供一种固化光固化性树脂组合物的方法,其能够在期望的条件下分步稳定地固化固化条件,并且容易获得加工余量; 并提供制作浮雕图案的方法。 解决方案:在固化光固化性树脂组合物的方法中,使用通过光异构化反应产生多胺的基础发生剂和通过加热进行分子内环化反应和含有特定聚合物前体的光固化性树脂组合物, 预定温度下的树脂组合物通过步骤1至步骤4逐步改变。还公开了浮雕图案的制造方法。 步骤1是将光固化树脂组合物涂布在基材上并形成涂膜,步骤2用于从基材侧或涂膜表面侧的光照射涂布膜,步骤3用于加热 涂覆膜并固化至少一部分涂膜,步骤4用于重复步骤2和3以固化涂膜。 版权所有(C)2012,JPO&INPIT
    • 9. 发明专利
    • Method of producing base generating agent
    • 生产基质发生剂的方法
    • JP2012171953A
    • 2012-09-10
    • JP2011038681
    • 2011-02-24
    • Dainippon Printing Co Ltd大日本印刷株式会社
    • TAKADA YOSHIHIROTSUBOI JUNICHIMONMA YOSHINARIKATAYAMA ASAMIAMANO HIROKOSAKAYORI KATSUYA
    • C07D295/16
    • PROBLEM TO BE SOLVED: To provide a method of producing a base generating agent capable of producing inexpensively the highly sensitive base generating agent at a high yield in a low environmental load.SOLUTION: The method of producing the base generating agent expressed by General Formula (1) includes a process for reacting a benzaldehyde derivative expressed by General Formula (A), with an acetoamide derivative expressed by General Formula (B), in the presence of a base, in an organic solvent. In the General Formula (A), General Formula (B) and the General Formula (1), Ris hydrogen atom, or a protection group deprotected by heating and/or application of an electromagnetic wave, R, R, Rand Rare respectively independently hydrogen atoms, halogen atoms, hydroxide groups, mercapto groups, sulfide groups, silyl groups, silanol groups, nitro groups, nitroso groups, sulfino groups, sulfo groups, sulfonate groups, phosphino groups, phosphinyl groups, phosphono groups, phosphonate groups, amino groups, ammonio groups, azide groups, or organic groups, and may be same or different, R, R, Rand Rmay be coupled with two or more thereof, to form cyclic structure and may contain a coupling of hetero atom, Rand Rare respectively independently hydrogen atoms or organic groups, and may be same or different, and Rand Rmay be coupled each other to form cyclic structure and may contain a coupling of hetero atom (on condition that at least one of Rand Ris the organic group).
    • 待解决的问题:提供一种能够在低环境负荷下以高产率生产廉价地生产高敏感性碱性发生剂的碱产生剂的方法。 解决方案:由通式(1)表示的碱产生剂的制造方法包括使由通式(A)表示的苯甲醛衍生物与通式(B)表示的乙酰胺衍生物反应的方法 在有机溶剂中存在碱。 在通式(A),通式(B)和通式(1)中,R 1是氢原子,或通过加热和/或应用脱保护的保护基团 的电磁波,R 2 ,R 3 ,R 4 和 卤素原子,氢氧基,巯基,硫醚基,甲硅烷基,硅烷醇基,硝基,亚硝基,亚磺酰基,磺基, 磺酸酯基,膦基,氧膦基,膦酰基,膦酸酯基,氨基,氨基,叠氮基或有机基团,并且可以相同或不同,R 2 R 3 ,R 4 和R 5 可以与两个或 以形成环状结构,并且可以含有杂原子的偶合,R 6分别独立地表示氢原子 或orga nic组,并且可以相同或不同,并且R 6 和R 7 可以彼此耦合以形成循环结构, 可以包含杂原子的偶合(条件是R 6 和R 7 中的至少一个是有机基团)。 版权所有(C)2012,JPO&INPIT