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    • 2. 发明申请
    • FAST DISINTEGRATING NONWOVEN BINDER
    • 快速消毒非金属粘合剂
    • WO2016028832A1
    • 2016-02-25
    • PCT/US2015/045784
    • 2015-08-19
    • DOW GLOBAL TECHNOLOGIES LLCROHM AND HAAS COMPANY
    • NUNN, Maureen B.RICE, Katherine SueKLINE, Debra A.TOMLINSON, Ian A.
    • D04H1/587A47L13/16A61K8/02
    • D04H1/587A61K8/0208A61K8/06A61K8/8164A61K2800/20A61Q19/00A61Q19/10C08F220/18C08F2220/1808C08F220/06C08F212/08C08F222/02
    • A method for forming a dispersible nonwoven substrate in an aqueous medium comprising, consisting of, or consisting essentially of contacting a fibrous substrate with an aqueous nonwoven binder comprising an emulsion polymer having a polydispersity index of at least 10, a weight average molecular weight of less than 1,000,000 and from 8 weight percent to 22 weight percent acid monomer, based on the weight of the emulsion polymer, is disclosed. The aqueous nonwoven binder can be prepared by a method comprising the steps of: a) emulsion polymerizing at least one mono-ethylenically unsaturated monomer and at least one acid monomer in an aqueous solution using an initiator wherein the initiator is present in the aqueous solution in an amount in the range of from 0.5 weight percent to 1.5 weight percent, based on the total weight of the monomers, to form the emulsion polymer; and b) neutralizing the emulsion polymer with a neutralizer selected from the group consisting of an amine having a pKb of 4 to 7, an alkali hydroxide, and combinations thereof to form the aqueous nonwoven binder. The dispersible nonwoven substrates can be used to produce dispersible wipes, such as baby wipes, personal care wipes, cleaning wipes, or any other wet nonwoven containing lotion having a pH of below 5 or 6.
    • 一种在水性介质中形成可分散非织造基材的方法,包括由纤维基材与水性非织造粘合剂组成或基本上使其与多分散指数为至少为10的乳液聚合物接触,重均分子量较少 公开了基于乳液聚合物重量的1,000,000和8重量%至22重量%的酸单体。 水性无纺粘合剂可以通过包括以下步骤的方法制备:a)使用引发剂在水溶液中使至少一种单烯属不饱和单体和至少一种酸单体乳液聚合,其中引发剂存在于水溶液中 基于单体总重量的0.5重量%至1.5重量%范围内的量,以形成乳液聚合物; 和b)用选自pKb为4-7的胺,碱金属氢氧化物及其组合的中和剂中和乳液聚合物,以形成水性非织造粘合剂。 可分散的非织造基材可用于生产可分散的擦拭物,例如婴儿擦拭物,个人护理擦拭物,清洁擦拭物,或任何其它含有PH值低于5或6的洗剂的湿非织造布。
    • 5. 发明公开
    • FAST DISINTEGRATING NONWOVEN BINDER
    • 快速分散无纺布粘合剂
    • EP3183383A1
    • 2017-06-28
    • EP15759988.7
    • 2015-08-19
    • Dow Global Technologies LLCRohm and Haas Company
    • NUNN, Maureen B.RICE, Katherine SueKLINE, Debra A.TOMLINSON, Ian A.
    • D04H1/587A47L13/16A61K8/02
    • D04H1/587A61K8/0208A61K8/06A61K8/8164A61K2800/20A61Q19/00A61Q19/10C08F220/18C08F2220/1808C08F220/06C08F212/08C08F222/02
    • A method for forming a dispersible nonwoven substrate in an aqueous medium comprising, consisting of, or consisting essentially of contacting a fibrous substrate with an aqueous nonwoven binder comprising an emulsion polymer having a polydispersity index of at least 10, a weight average molecular weight of less than 1,000,000 and from 8 weight percent to 22 weight percent acid monomer, based on the weight of the emulsion polymer, is disclosed. The aqueous nonwoven binder can be prepared by a method comprising the steps of: a) emulsion polymerizing at least one mono-ethylenically unsaturated monomer and at least one acid monomer in an aqueous solution using an initiator wherein the initiator is present in the aqueous solution in an amount in the range of from 0.5 weight percent to 1.5 weight percent, based on the total weight of the monomers, to form the emulsion polymer; and b) neutralizing the emulsion polymer with a neutralizer selected from the group consisting of an amine having a pKb of 4 to 7, an alkali hydroxide, and combinations thereof to form the aqueous nonwoven binder. The dispersible nonwoven substrates can be used to produce dispersible wipes, such as baby wipes, personal care wipes, cleaning wipes, or any other wet nonwoven containing lotion having a pH of below 5 or 6.
    • 一种在含水介质中形成可分散的非织造基底的方法,该方法包括,由或基本由以下步骤组成:使纤维基底与含水非织造粘合剂接触,所述含水非织造粘合剂包含多分散指数为至少10,重均分子量小于 公开了基于乳液聚合物的重量为1,000,000和8重量%至22重量%的酸单体。 含水非织造粘合剂可以通过包括以下步骤的方法制备:a)使用引发剂使至少一种单烯属不饱和单体和至少一种酸单体在水溶液中乳液聚合,其中引发剂存在于水溶液中 基于单体总重量的0.5重量%至1.5重量%的量,以形成乳液聚合物; 和b)用选自pKb为4-7的胺,碱金属氢氧化物及其组合的中和剂中和乳液聚合物以形成水性非织造粘合剂。 可分散的非织造基底可用于生产可分散的擦拭物,例如婴儿擦巾,个人护理擦拭物,清洁擦拭物或任何其它pH低于5或6的含湿润非织造物的洗液。
    • 10. 发明申请
    • COMPOSITE POLYAMIDE MEMBRANE POST-TREATED WITH NITROUS ACID
    • 复合聚酰胺膜后处理硝酸
    • WO2015167759A1
    • 2015-11-05
    • PCT/US2015/024617
    • 2015-04-07
    • DOW GLOBAL TECHNOLOGIES LLC
    • PAUL, MouROY, AbhishekTOMLINSON, Ian A.JANSMA, Matthew J.
    • B01D67/00B01D69/12B01D71/56
    • B01D67/0093B01D69/125B01D71/56
    • A method for making a composite polyamide membrane comprising a porous support and a polyamide layer, including the steps of: i) applying a polar solution comprising a polyiunctional amine monomer and a non-polar solution comprising a polyiunctional acyl halide monomer to a surface of a porous support and interfacially polymerizing the monomers to form a polyamide layer; and ii) exposing the thin film polyamide layer to nitrous acid; wherein the method is characterized by at least one of: conducting the interfacial polymerization of step i) in the presence of a subject amine- reactive compound, or applying a subject amine-reactive compound to the interfacially polymerized polyamide layer prior to step ii), wherein the subject amine-reactive compound is different from the polyiunctional acyl halide and polyiunctional amine monomers and is represented by the following formula:
    • 一种制备包括多孔载体和聚酰胺层的复合聚酰胺膜的方法,包括以下步骤:i)将包含多官能胺单体的极性溶液和包含多官能酰卤单体的非极性溶液施加到 多孔载体和界面聚合单体以形成聚酰胺层; 和ii)将薄膜聚酰胺层暴露于亚硝酸; 其特征在于以下至少一个:在主题胺反应性化合物的存在下进行步骤i)的界面聚合,或在步骤ii)之前将主题胺反应性化合物施加到界面聚合的聚酰胺层上, 其中主题胺反应性化合物不同于多官能酰基卤和多官能胺单体,并由下式表示: