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1. 发明申请

WO2011153540A1 ELECTRONIC DEVICE MODULE COMPRISING FILM OF HOMOGENEOUS POLYOLEFIN COPOLYMER AND ADHESIVE PROPERTY ENHANCING GRAFT POLYMER 审中-公开
标题翻译：包含均相聚烯烃共聚物和粘合性能增强聚合物膜的电子器件模块
公开(公告)号：WO2011153540A1
公开(公告)日：2011-12-08
申请号：PCT/US2011/039305
申请日：2011-06-06
申请人： DOW GLOBAL TECHNOLOGIES LLC , NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu , NIEMANN, Debra, H.
发明人： NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu , NIEMANN, Debra, H.
IPC分类号： C08L23/00 , H01L31/00 , C08F210/02
CPC分类号： H05K1/0353 , B32B17/10018 , B32B17/1055 , B32B17/10697 , C08F210/16 , C08L23/08 , H01L31/0481 , Y02E10/50 , C08L2666/24 , C08F210/14 , C08F2500/08 , C08F2500/09 , C08F2500/26
摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm3; total unsaturation of not more than 125 per 100,000 carbons; and; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/Mn), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145°C) and 'H-NMR (125°C), (2) a graft polymer to enhance the adhesion, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt% based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.
摘要翻译：一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合物材料，所述聚合物材料包含（1）乙烯互聚物，其包含总聚合物密度不大于0.905g / cm3; 总不饱和度不超过125 / 100,000个碳; 和; 最多3条长支链/ 1000个碳; 乙烯基-3含量小于5 / 100,000碳; 和总数（1000 / Mn）的乙烯基/ 1000个碳的总数，其中乙烯基-3含量和乙烯基测量通过凝胶渗透色谱法（145℃）和1 H-NMR（125° C），（2）接枝聚合物，以增加粘合力，（3）任选的自由基引发剂或光引发剂，其量为基于共聚物重量的至少约0.05重量％，和（3）任选地，共混剂的量为至少约0.05重量％，基于共聚物的重量。

2. 发明申请

WO2016070087A1 PV MODULE WITH FILM LAYER COMPRISING MICRONIZED SILICA GEL 审中-公开
标题翻译：具有包含微米二氧化硅凝胶的膜片的PV模块
公开(公告)号：WO2016070087A1
公开(公告)日：2016-05-06
申请号：PCT/US2015/058382
申请日：2015-10-30
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： DEPLACE, Fanny , NANJUNDIAH, Kumar , BONEKAMP, Jeffrey, E. , NAUMOVITZ, John, A.
IPC分类号： C08K3/34 , C09D123/08 , C09D123/10 , C09D151/06 , C09D153/02 , C08K9/04 , H01L31/048
CPC分类号： H01L31/049 , C08K3/36 , C08K9/04 , C08L2203/204 , C08L2312/08 , C09D7/62 , C09D123/0815 , C09D123/10 , C09D151/06 , C09D153/00 , H01L31/048 , H01L31/0488 , H02S40/44 , C08L51/06
摘要： The present disclosure provides a photovoltaic module. In an embodiment, the photovoltaic module includes a photovoltaic cell, and a layer composed of a film. The film includes a silane-grafted polyolefin (Si-g-PO) resin composition comprising (i) one or more silane grafted polyolefins and (ii) from greater than 0 wt% to less than 5.0 wt% of a micronized silica gel, based on the total weight of the Si-g-PO resin composition. The film has a glass adhesion greater than or equal to 15 N/mm after aging the film at 40°C and 0% relative humidity for 60 days as measured in accordance with ASTM F88/88M-09.
摘要翻译：本公开提供了一种光伏模块。在一个实施例中，光伏模块包括光伏电池和由薄膜组成的层。该膜包括硅烷接枝聚烯烃（Si-g-PO）树脂组合物，其包含（i）一种或多种硅烷接枝聚烯烃和（ii）大于0重量％至小于5.0重量％的微粉化硅胶，基于关于Si-g-PO树脂组合物的总重量。根据ASTM F88 / 88M-09测量，膜在40℃和0％相对湿度下老化60天后具有大于或等于15N / mm的玻璃粘合力。

3. 发明申请

WO2014176088A1 ELECTRONIC DEVICES COMPRISING TWO ENCAPSULANT FILMS 审中-公开
标题翻译：包含两个胶囊的电子设备
公开(公告)号：WO2014176088A1
公开(公告)日：2014-10-30
申请号：PCT/US2014/034335
申请日：2014-04-16
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： NANJUNDIAH, Kumar , NAUMOVITZ, John, A. , WHITE, Michael, D.
IPC分类号： H01L31/048
CPC分类号： H01L31/0488 , H01L31/0481 , H01L31/049 , H01L31/18 , Y02E10/50
摘要： An electronic device comprises a first encapsulating film in direct contact with a light- receiving and transmitting film and a second encapsulating film in direct contact with a back sheet. The first encapsulating film has a zero shear viscosity greater than that of the second encapsulating film. The back sheet of the electronic device contains fewer bumps than the back sheet of a comparable electronic device having a first encapsulating film with a zero shear viscosity less than or equal to that of the second encapsulating film.
摘要翻译：电子器件包括与光接收和透射膜直接接触的第一封装膜和与底片直接接触的第二封装膜。第一封装膜的零剪切粘度大于第二封装膜的粘度。电子设备的背板比具有零剪切粘度小于或等于第二封装膜的第一封装膜的类似电子设备的背板具有更少的凸起。

4. 发明申请

WO2012039914A1 ELECTRONIC DEVICE MODULE COMPRISING ETHYLENE-ALPHA OLEFIN TAPERED BLOCK COPOLYMERS AND OPTIONAL VINYL SILANE 审中-公开
标题翻译：包含乙烯 - 丙烯酸酯嵌段嵌段共聚物和可选的乙烯基硅烷的电子器件模块
公开(公告)号：WO2012039914A1
公开(公告)日：2012-03-29
申请号：PCT/US2011/050330
申请日：2011-09-02
申请人： DOW GLOBAL TECHNOLOGIES LLC , NIEMANN, Debra, H. , NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu
发明人： NIEMANN, Debra, H. , NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu
IPC分类号： B32B27/32 , B32B27/20 , B32B17/10 , H01L31/048
CPC分类号： H01L31/0481 , B32B17/10018 , B32B17/10036 , B32B17/1055 , B32B2457/12 , Y02E10/50
摘要： An electronic device module such as a solar cell is described. The electronic device module is made using a polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising a tapered block copolymer comprising an A block, and a B block.
摘要翻译：描述了诸如太阳能电池的电子设备模块。电子器件模块使用与电子器件的至少一个表面紧密接触的聚合物材料制成，聚合物材料包含包含A嵌段和B嵌段的渐缩嵌段共聚物。

5. 发明申请

WO2011163025A1 ELECTRONIC DEVICE MODULE COMPRISING HETEROGENEOUS POLYOLEFIN COPOLYMER AND OPTIONALLY SILANE 审中-公开
标题翻译：包含异质聚烯烃共聚物和可选硅烷的电子器件模块
公开(公告)号：WO2011163025A1
公开(公告)日：2011-12-29
申请号：PCT/US2011/040492
申请日：2011-06-15
申请人： DOW GLOBAL TECHNOLOGIES LLC , NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu , NIEMANN, Debra, H.
发明人： NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu , NIEMANN, Debra, H.
IPC分类号： B32B17/10 , H01L31/048
CPC分类号： H01L31/0203 , B32B17/10018 , B32B17/1055 , B32B17/10697 , B32B17/10788 , C08L23/0815 , C08L2203/204 , H01L31/0481 , H05K1/032 , Y02E10/50
摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) a polyolefin copolymer characterized as having has an average Mv and a valley temperature between the interpolymer and high crystalline fraction, The, such that the average Mv for a fraction above ThC from ATREF divided by average Mv of the whole polymer from ATREF (MhC/Mp) is less than about 1.95 and wherein the copolymer has a CDBI of less than 60%, (2) optionally, a vinyl silane, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt% based on the weight of the copolymer, and (4) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.
摘要翻译：一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料，所述聚合物材料包括（1）聚烯烃共聚物，由于在互聚物和高结晶部分之间具有平均Mv和谷值温度，所以来自ATREF的高于ThC的馏分的平均Mv除以ATREF（MhC / Mp）之外的整个聚合物的平均Mv小于约1.95，并且其中所述共聚物的CDBI小于60％，（2）任选的乙烯基硅烷，（3）任选的自由基引发剂或光引发剂，其量为至少约0.05重量％共聚物，和（4）任选地，基于共聚物的重量，至少约0.05重量％的助剂。

6. 发明申请

WO2011153541A1 ELECTRONIC DEVICE MODULE COMPRISING FILM OF HOMOGENEOUS POLYOLEFIN COPOLYMER AND GRAFTED SILANE 审中-公开
标题翻译：包含均相聚烯烃共聚物和接枝硅烷的膜的电子器件模块
公开(公告)号：WO2011153541A1
公开(公告)日：2011-12-08
申请号：PCT/US2011/039307
申请日：2011-06-06
申请人： DOW GLOBAL TECHNOLOGIES LLC , NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu , NIEMANN, Debra, H.
发明人： NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu , NIEMANN, Debra, H.
IPC分类号： C08F210/02 , C08L23/00 , H01L31/00
CPC分类号： H01L31/0203 , B32B17/10018 , B32B17/1055 , C08F210/16 , C08L23/08 , H01L23/293 , H01L31/0481 , H01L2924/0002 , Y02E10/50 , C08L2666/24 , C08F210/14 , C08F2500/02 , C08F2500/09 , C08F2500/11 , C08F2500/26 , H01L2924/00
摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene interpolymer comprising an overall polymer density of not more than 0.905 g/cm 3 ; total unsaturation of not more than 125 per 100,000 carbons;; up to 3 long chain branches/1000 carbons; vinyl-3 content of less than 5 per 100,000 carbons; and a total number of vinyl groups/1000 carbons of less than the quantity (8000/M n ), wherein the vinyl-3 content and vinyl group measurements are measured by gel permeation chromatography (145°C) and 1 H-NMR (125°C), (2) grafted vinyl silane, (3) optionally, free radical initiator or a photoinitiator in an amount of at least about 0.05 wt% based on the weight of the copolymer, and (3) optionally, a co-agent in an amount of at least about 0.05 wt% based upon the weight of the copolymer.
摘要翻译：一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合物材料，所述聚合物材料包含（1）乙烯互聚物，其包含总聚合物密度不大于0.905g / cm3; 总不饱和度不超过每100,000个碳原子的125个; 最多3条长支链/ 1000个碳; 乙烯基-3含量小于5 / 100,000碳; 以及小于量（8000 / Mn）的乙烯基/ 1000个碳数的总数，其中通过凝胶渗透色谱法（145℃）和1 H-NMR（125℃）测量乙烯基-3含量和乙烯基测量值），（2）接枝的乙烯基硅烷，（3）任选的自由基引发剂或光引发剂，其量基于共聚物的重量为至少约0.05重量％，和（3）任选地，至少约0.05重量％，基于共聚物的重量。

7. 发明申请

WO2014209632A1 BACKSHEETS/FRONTSHEETS HAVING IMPROVED ADHESION TO ENCAPSULANTS AND PHOTOVOLTAIC MODULES MADE THEREFROM 审中-公开
标题翻译：具有改进的粘合剂和光伏组件的背胶/镜片
公开(公告)号：WO2014209632A1
公开(公告)日：2014-12-31
申请号：PCT/US2014/042238
申请日：2014-06-13
申请人： DOW GLOBAL TECHNOLOGIES LLC
发明人： ZHANG, Huiqing , POCHON, Aude , NAUMOVITZ, John, A. , KOOPMANS, Rudolf, J. , DRUMRIGHT, Ray, E.
IPC分类号： B32B7/10 , B32B7/12 , B32B27/16
CPC分类号： H01L31/0481 , B32B7/10 , B32B7/12 , B32B27/08 , B32B27/16 , B32B27/304 , B32B27/322 , B32B27/34 , B32B27/36 , B32B2250/24 , B32B2255/10 , B32B2255/26 , B32B2457/12 , H01L31/049
摘要： A backsheet or frontsheet having an outer layer with a melting temperature greater than or equal to 1 50°C includes at least one surface comprising a surface modification to improve adhesion between the backsheet or frontsheet and an encapsulant. The adhesion of the backsheet or frontsheet and encapsulant, after lamination, is at least 20 N/cm, preferably at least 40 N/cm or no adhesion failure. More preferably, the adhesion is at least 20 N/cm, even more preferably 40 N/cm or no adhesion failure, before and after 1,000 hours, preferably 2,000 hours, of damp heat aging at 85°C and 85% humidity.
摘要翻译：具有大于或等于115℃的熔融温度的外层的底片或前片包括至少一个表面，其包括表面改性以改善底片或前片与密封剂之间的粘附。底片或前片和密封剂在层压之后的粘附力为至少20N / cm，优选至少40N / cm，或无粘附破坏。更优选的是，在85℃和85％的湿度下，1000小时以上，优选2000小时的湿热老化之前和之后，粘合力至少为20N / cm，甚至更优选为40N / cm，或者没有粘附破坏。

8. 发明申请

WO2013003543A1 MULTILAYERED POLYOLEFIN-BASED FILMS HAVING INTEGRATED BACKSHEET AND ENCAPSULATION PERFORMANCE COMPRISING A LAYER COMPRISING CRYSTALLINE BLOCK COPOLYMER COMPOSITE OR BLOCK COPOLYMER COMPOSITE 审中-公开
标题翻译：具有一体化背衬的多层聚烯烃基膜和包含结晶嵌段共聚物复合材料或嵌段共聚物复合材料层的包封性能
公开(公告)号：WO2013003543A1
公开(公告)日：2013-01-03
申请号：PCT/US2012/044561
申请日：2012-06-28
申请人： DOW GLOBAL TECHNOLOGIES LLC , BONEKAMP, Jeffrey, E. , HU, Yushan , NICKEL, Nichole, E. , CHU, Lih-long , NAUMOVITZ, John, A. , HOFIUS, Mark, G.
发明人： BONEKAMP, Jeffrey, E. , HU, Yushan , NICKEL, Nichole, E. , CHU, Lih-long , NAUMOVITZ, John, A. , HOFIUS, Mark, G.
IPC分类号： H01L31/048 , B32B27/32 , C08L53/00
CPC分类号： H01L31/18 , B32B27/08 , B32B27/32 , B32B27/327 , B32B2457/12 , C08L53/00 , H01L31/0481 , H01L31/049 , Y02E10/50
摘要： A multilayer film structure comprising a top encapsulation layer A, a tie Layer B between top Layer A and bottom Layer C and a bottom layer C, the multilayer film structure characterized in that tie Layer B comprises a crystalline block composite resin or a block composite resin and bottom Layer C comprises a polyolefin having at least one melting point greater than 125°C.
摘要翻译：一种多层膜结构，其包括顶部封装层A，顶层A和底层C之间的连接层B和底层C，多层膜结构的特征在于连接层B包含结晶嵌段复合树脂或嵌段复合树脂并且底层C包含具有至少一个熔点大于125℃的聚烯烃。

9. 发明申请

WO2013003541A1 MULTILAYERED POLYOLEFIN-BASED FILMS HAVING A LAYER COMPRISING A CRYSTALLINE BLOCK COPOLYMER COMPOSITE OR A BLOCK COPOLYMER COMPOSITE RESIN 审中-公开
标题翻译：具有包含结晶嵌段共聚物复合物或嵌段共聚物复合树脂的层的多层基于聚烯烃的膜
公开(公告)号：WO2013003541A1
公开(公告)日：2013-01-03
申请号：PCT/US2012/044558
申请日：2012-06-28
申请人： DOW GLOBAL TECHNOLOGIES LLC , BONEKAMP, Jeffrey, E. , HU, Yushan , NICKEL, Nichole, E. , CHU, Lih-long , NAUMOVITZ, John, A. , HOFIUS, Mark, G.
发明人： BONEKAMP, Jeffrey, E. , HU, Yushan , NICKEL, Nichole, E. , CHU, Lih-long , NAUMOVITZ, John, A. , HOFIUS, Mark, G.
IPC分类号： B32B27/32 , H01L31/048
CPC分类号： H01L31/0487 , B32B27/08 , B32B27/32 , B32B2270/00 , B32B2457/12 , H01L31/049 , H01L31/18 , Y02E10/50
摘要： Disclosed are multilayer film structures comprising a layer (B) that comprises a crystalline block copolymer composite (CBC) or a specified block copolymer composite (BC), comprising i) an ethylene polymer (EP) comprising at least 80 mol % polymerized ethylene; ii) an alpha-olefin- based crystalline polymer (CAOP) and iii) a block copolymer comprising (a) an ethylene polymer block comprising at least 80 mol % polymerized ethylene and (b) a crystalline alpha-olefin block (CAOB); and a layer C that comprises a polyolefin having at least one melting peak greater than 1255C, the top facial surface of layer C in adhering contact with the bottom facial surface of layer B. Such multilayer film structure preferably comprises (A) a seal layer A having a bottom facial surface in adhering contact with the top facial surface of layer B. Such films are suited for use in electronic device (ED) modules comprising an electronic device such as a PV cell. Also disclosed is a lamination process to construct a laminated PV module comprising such multilayer film structures.
摘要翻译：公开了包括包含结晶嵌段共聚物复合物（CBC）或特定嵌段共聚物复合物（BC）的层（B）的多层膜结构，其包含i）包含至少80mol％聚合的乙烯的乙烯聚合物（EP） ii）基于α-烯烃的结晶聚合物（CAOP）和iii）包含（a）包含至少80mol％聚合的乙烯和（b）结晶α-烯烃嵌段（CAOB））的乙烯聚合物嵌段的嵌段共聚物; 以及包含聚烯烃的层C，该聚烯烃具有大于1255℃的至少一个熔融峰，层C的顶部表面与层B的底部表面粘合接触。这种多层膜结构优选包含（A）密封层A 具有与层B的顶部面部表面粘合接触的底部面部表面。这种膜适用于包括诸如PV电池的电子设备的电子设备（ED）模块。还公开了构成包括这种多层膜结构的叠层PV模块的叠层工艺。

10. 发明申请

WO2011150193A1 ELECTRONIC DEVICE MODULE COMPRISING POLYOLEFIN COPOLYMER WITH LOW UNSATURATION AND OPTIONAL VINYL SILANE 审中-公开
标题翻译：具有低不饱和度和可选的乙烯基硅烷的聚烯烃共聚物的电子器件模块
公开(公告)号：WO2011150193A1
公开(公告)日：2011-12-01
申请号：PCT/US2011/038116
申请日：2011-05-26
申请人： DOW GLOBAL TECHNOLOGIES LLC , NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu , NIEMANN, Debra, H.
发明人： NAUMOVITZ, John, A. , PATEL, Rajen, M. , WU, Shaofu , NIEMANN, Debra, H.
IPC分类号： C08L23/00 , H01L31/00 , C08F210/02
CPC分类号： C08L23/08 , B32B17/10018 , B32B17/1055 , C08L2205/02 , H01L31/0481 , Y02E10/50 , C08L2666/06
摘要： An electronic device module comprising: A. At least one electronic device, e.g., a solar cell, and B. A polymeric material in intimate contact with at least one surface of the electronic device, the polymeric material comprising (1) an ethylene-based polymer composition characterized by a Comonomer Distribution Constant greater than about 45, more preferably greater than 50, most preferably greater than 95, and as high as 400, preferably as high as 200, wherein the composition has less than 120 total unsaturation unit/1,000,000C, preferably the ethylene-based polymer compositions comprise up to about 3 long chain branches/1000 carbons, more preferably from about 0.01 to about 3 long chain branches/1000 carbons; the ethylene-based polymer composition can have a ZSVR of at least 2; the ethylene-based polymer compositions can be further characterized by comprising less than 20 vinylidene unsaturation unit/1, 000,000C; the ethylene-based polymer compositions can have a bimodal molecular weight distribution (MWD) or a multi-modal MWD; the ethylene-based polymer compositions can have a comonomer distribution profile comprising a mono or bimodal distribution from 35°C to 120°C, excluding purge; the ethylene-based polymer compositions can comprise a single DSC melting peak; the ethylene-based polymer compositions can comprise a weight average molecular weight (Mw) from about 17,000 to about 220,000, (2) optionally, a vinyl silane, (3) optionally, a free radical initiator, e.g., a peroxide or azo compound, or a photoinitiator, e.g., benzophenone, and (4) optionally, a co-agent.
摘要翻译：一种电子设备模块，包括：A.至少一个电子设备，例如太阳能电池和B.与所述电子设备的至少一个表面紧密接触的聚合材料，所述聚合物材料包括（1）基于乙烯的聚合物组合物的特征在于共聚单体分布常数大于约45，更优选大于50，最优选大于95，高达400，优选高达200，其中组合物具有小于120总不饱和单元/ 1,000,000C 优选地，基于乙烯的聚合物组合物包含最多约3个长链分支/ 1000个碳，更优选约0.01至约3个长支链/ 1000个碳; 基于乙烯的聚合物组合物可以具有至少2的ZSVR; 基于乙烯的聚合物组合物可以进一步表征为包含少于20个亚乙烯基不饱和单元/ 1,000,000C; 乙烯基聚合物组合物可以具有双峰分子量分布（MWD）或多模态MWD; 基于乙烯的聚合物组合物可以具有包含35℃至120℃的单峰或双峰分布的共聚单体分布分布，不包括吹扫; 基于乙烯的聚合物组合物可以包含单个DSC熔融峰; 基于乙烯的聚合物组合物可包含约17,000至约220,000的重均分子量（Mw），（2）任选的乙烯基硅烷，（3）任选的自由基引发剂，例如过氧化物或偶氮化合物，或光引发剂，例如二苯甲酮，和（4）任选的助剂。

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