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1. 发明申请

WO2005023912A2 IMPROVED RESIN COMPOSITIONS FOR EXTRUSION COATING 审中-公开
标题翻译：改进的用于挤出涂料的树脂组合物
公开(公告)号：WO2005023912A2
公开(公告)日：2005-03-17
申请号：PCT/US2004029124
申请日：2004-09-03
申请人： DOW GLOBAL TECHNOLOGIES INC , OSWALD THOMAS T , COOPER JAMES L , WEINHOLD JEFFREY , GILLESPIE DAVID T
发明人： OSWALD THOMAS T , COOPER JAMES L , WEINHOLD JEFFREY , GILLESPIE DAVID T
IPC分类号： C08J5/18 , C08L23/06 , C08L23/08
CPC分类号： C09D123/08 , C08J5/18 , C08J2300/00 , C08J2323/06 , C08L23/06 , C08L23/08 , C08L23/0815 , C09D123/06 , C08L2666/06
摘要： A composition is disclosed which is particularly suited for use in extrusion coating. The composition comprises a polymeric material having a rheology such that the slope S of a natural log-natural log plot of loss modulus (or G") versus storage modulus (or G') is greater than [0.635 (melt index)+13.2]/[(melt index)+16.6], and wherein the polymeric material has a CDF RI fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater. The compositions exhibit reduced neck-in when used in extrusion coating and the neck-in is independent of melt strength, thereby facilitating improved extrusion processes.
摘要翻译：公开了一种特别适用于挤出涂层的组合物。该组合物包含具有流变性的聚合材料，使得损耗模量（或G“）对储能模量（或G'）的自然对数 - 自然对数图的斜率S大于[0.635×（熔体指数） +13.2] / [（熔体指数）+16.6]，并且其中聚合物材料的CDF RI分数小于GPC色谱图的0.23，其分子量高于85,000g / mol，CDF LS分数大于0.07 在常规GPC分子量为1750,000g / mol或更高时，当用于挤出涂布时，组合物显示出减小的颈缩，并且颈缩不依赖于熔体强度，从而有利于改进的挤出过程。

2. 发明申请

WO2006081116B1 APPARATUS FOR METHOD FOR POLYMER CHARACTERIZATION 审中-公开
标题翻译：聚合物表征方法的设备
公开(公告)号：WO2006081116B1
公开(公告)日：2006-11-09
申请号：PCT/US2006001803
申请日：2006-01-19
申请人： DOW GLOBAL TECHNOLOGIES INC , GILLESPIE DAVID T , LI PI SHAN COLIN , HAZLITT LONNIE G , DEGROOT ALEXANDER W , ARNOUDSE PETER B , WILLIAMS CHARLES A
发明人： GILLESPIE DAVID T , LI PI SHAN COLIN , HAZLITT LONNIE G , DEGROOT ALEXANDER W , ARNOUDSE PETER B , WILLIAMS CHARLES A
IPC分类号： G01N30/46 , B01D15/34 , G01N25/14 , G01N30/30 , G01N30/54 , G01N33/44
CPC分类号： G01N30/468 , G01N25/147 , G01N30/463 , G01N30/54 , G01N33/442 , G01N2030/008 , G01N2030/3007
摘要： Apparatus for GPC/TREF and TREF/GPC characterization of a polymer sample. The apparatus provides for the automated and integrated use of multiple TREF columns and a GPC system employing a multiple flow through detectors. In addition, a method for TREF/GPC characterization of a polymer sample by GPC analysis of TREF fractions at increasing TREF elution temperatures from multiple TREF columns operated in a coordinated and synchronized temperature cycle for increased sample throughput. Also, a method for GPC/TREF characterization of a polymer sample by GPC fractionation followed by TREF fractionation of the GPC fractionations.
摘要翻译：聚合物样品的GPC / TREF和TREF / GPC表征装置。该装置提供了多个TREF柱的自动化和集成使用以及采用多个流过检测器的GPC系统。此外，通过在增加TREF洗脱温度的TREF洗脱温度下，通过GPC分析TREF级分，通过在协同和同步的温度循环中操作以提高样品通量的多个TREF柱来对聚合物样品进行TREF / GPC表征的方法。此外，通过GPC分级随后进行GPC分馏的TREF分馏，GPC / TREF表征聚合物样品的方法。

3. 发明申请

WO2007130515A3 HIGH-DENSITY POLYETHYLENE COMPOSITIONS, METHOD OF MAKING THE SAME, ARTICLES MADE THEREFROM, AND METHOD OF MAKING SUCH ARTICLES 审中-公开
标题翻译：高密度聚乙烯组合物，其制备方法，制备方法和制备这些制品的方法
公开(公告)号：WO2007130515A3
公开(公告)日：2008-03-13
申请号：PCT/US2007010735
申请日：2007-05-02
申请人： DOW GLOBAL TECHNOLOGIES INC , MICHIE WILLIAM J , KAY THOMAS W , WHITED STEPHANIE M , ELLEY-BRISTOW DALE M , GILLESPIE DAVID T , HAZLITT LONNIE G
发明人： MICHIE WILLIAM J , KAY THOMAS W , WHITED STEPHANIE M , ELLEY-BRISTOW DALE M , GILLESPIE DAVID T , HAZLITT LONNIE G
IPC分类号： C08L23/04 , B65D41/00 , H01B3/44
CPC分类号： C08L23/08 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2203/10 , Y10T428/24992 , Y10T428/273 , C08L2666/06
摘要： The instant invention is a high-density polyethylene composition, method of producing the same, articles made therefrom, and method of making such articles. The high- density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm 3 , and a melt index (I 21.6 ) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm 3 , and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of (I2) in the range of 0, 950 to 0,960g/cm 3 , and g' of equal or greater than 1. The method of producing a high-density polyethylene composition includes the following steps: (1) introducing ethylene, and one or more alpha-olefin comonomers into a first reactor; (2) (co)polymerizing the ethylene in the presence of one or more alpha-olefin comonomers in the first reactor thereby producing a first component, wherein the first component being a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm 3 , and a melt index (I 21.6 ) in the range of 0.5 to 10 g/10 minutes; (3) introducing the first component and additional ethylene into a second reactor; (4) polymerizing the additional ethylene in the second reactor thereby producing a second component, wherein the second component being a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm 3 , and a melt index (I 2 ) in the range of 50 to 1500 g/10 minutes; and (5) thereby producing the high-density polyethylene composition, wherein the high-density polyethylene composition having a melt index (I 2 ) of at least 1, a density in the range of 0.950 to 0.960 g/cm 3 , and g' of equal or greater than 1. The articles according to instant invention comprise the above-described inventive high-density polyethylene composition, and such articles may be made via compression molding, injection molding, or injection blow molding.
摘要翻译：本发明是高密度聚乙烯组合物，其制造方法，由其制成的制品及其制造方法。本发明的高密度聚乙烯组合物包括第一组分和第二组分。第一组分是密度在0.915至0.940g / cm 3范围内的高分子量乙烯α-烯烃共聚物，熔体指数（I 21.6）在0.5〜10g / 10分钟的范围内。第二组分是密度在0.965至0.980g / cm 3范围内的低分子量乙烯聚合物，熔体指数（I 2）在50至1500g / 10分钟的范围内。高密度聚乙烯组合物的熔体指数（I 2）至少为1，在（I2）范围内的密度在0,950至0.96g / cm 3的范围内，g 等于或大于1.制备高密度聚乙烯组合物的方法包括以下步骤：（1）将乙烯和一种或多种α-烯烃共聚单体引入第一反应器; （2）（共）在第一反应器中在一种或多种α-烯烃共聚单体存在下聚合乙烯，从而产生第一组分，其中第一组分是密度在该范围内的高分子量乙烯α-烯烃共聚物为0.915〜0.940g / cm 3，熔体指数（I <21.6℃）为0.5〜10g / 10分钟; （3）将第一组分和另外的乙烯引入第二反应器中; （4）在第二反应器中聚合另外的乙烯，从而产生第二组分，其中第二组分是密度在0.965至0.980g / cm 3范围内的低分子量乙烯聚合物，和熔体指数（I 2 H 2）在50至1500g / 10分钟的范围内; 和（5），从而制备高密度聚乙烯组合物，其中熔体指数（I 2/2）至少为1的密度为0.950-0.960g的高密度聚乙烯组合物 / cm 3，g'等于或大于1.本发明的制品包含上述本发明的高密度聚乙烯组合物，并且这些制品可以通过压塑，注射成型或注射吹塑。

4. 发明专利

PL1836254T3 Kompozycje żywic elastomerycznych o zwiększonej odporności na rezonans rozciągania 未知
公开(公告)号：PL1836254T3
公开(公告)日：2010-01-29
申请号：PL05855688
申请日：2005-12-23
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： BUTLER THOMAS I , CHANG ANDY C , VAN DUN JOZEF J , WEEKS RONALD J , WEINHOLD JEFFREY D , PATEL RAJEN M , GILLESPIE DAVID T
IPC分类号： C08L23/00

5. 发明专利

BRPI0518103A 未知
公开(公告)号：BRPI0518103A
公开(公告)日：2008-10-28
申请号：BRPI0518103
申请日：2005-12-23
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： BUTLER THOMAS I , CHANG ANDY C , DUN JOZEF J VAN , WEEKS RONALD J , WEINHOLD JEFFREY D , PATEL RAJEN M , GILLESPIE DAVID T
IPC分类号： C08L23/00
摘要： This invention relates to polyolefin compositions. In particular, the invention pertains to elastic polymer compositions that can be more easily processed on cast film lines, extrusion lamination or coating lines due to improved resistance to draw resonance. The compositions of the present invention comprise an elastomeric polyolefin resin and a high pressure low density type resin. The preferred compositions of the present invention comprise from 88 to 99 percent elastomer or plastomer and from 1 to 12 percent by weight of a high pressure low density type resin.

6. 发明专利

BRPI0413766A 未知
公开(公告)号：BRPI0413766A
公开(公告)日：2006-10-31
申请号：BRPI0413766
申请日：2004-09-03
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： OSWALD THOMAS T , COOPER JAMES L , WEINHOLD JEFFREY , GILLESPIE DAVID T
IPC分类号： C08J5/18 , C08L23/06 , C08L23/08
摘要： A composition is disclosed which is particularly suited for use in extrusion coating. The composition comprises a polymeric material having a rheology such that the slope S of a natural log-natural log plot of loss modulus (or G″) versus storage modulus (or G′) is greater than [0.635*(melt index)+13.2]/[(melt index)+16.6], and wherein the polymeric material has a CDF RI fraction less than 0.23 of a GPC chromatogram which has a molecular weight above 85,000 g/mol, and a CDF LS fraction of more than 0.07 at a conventional GPC molecular weight of 1,750,000 g/mol or greater. The compositions exhibit reduced neck-in when used in extrusion coating and the neck-in is independent of melt strength, thereby facilitating improved extrusion processes.

7. 发明专利

MXPA06002483A COMPOSICIONES DE RESINA MEJORADAS PARA RECUBRIMIENTO POR EXTRUSION. 未知
公开(公告)号：MXPA06002483A
公开(公告)日：2006-06-20
申请号：MXPA06002483
申请日：2004-09-03
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： GILLESPIE DAVID T
IPC分类号： C08L23/06 , C08L23/08 , C08J5/18
摘要： Se describe una composicion la cual es particularmente adecuada para usarse en recubrimiento or extrusion. La composicion comprende un material polimerico que tiene una reologia de manera que la inclinacion s de una grafica de log natural-log natural de modulo de perdida (o G") contra modulo de almacenamiento (o G') es mayor que [0.635*(indice de fusion)+13.2]/[(indice de fusion )+16.6], y en donde el material polimerico tiene una fraccion CDF RI menor que 0.23 de un cromatograma de GPC, el cual tiene un peso molecular por arriba de 85,000 g/mol, y una fraccion CDF LS de mas de 0.07 a un peso molecular de GPC convencional de 1,750,000 g/mol o mayor. Las composiciones exhiben angostura reducida, cuando se usan en recubrimiento por extrusion y la angostura es independiente de fuerza de fusion, facilitando por ello los procesos de extrusion mejorados.

8. 发明专利

CA2585856A1 PROCESS FOR PRODUCING LOW DENSITY POLYETHYLENE COMPOSITIONS AND POLYMERS PRODUCED THEREFROM 未知
公开(公告)号：CA2585856A1
公开(公告)日：2006-05-11
申请号：CA2585856
申请日：2005-10-04
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： GILLESPIE DAVID T , CONRAD CHRISTOPHER W , EDDY CHRISTOPHER R
IPC分类号： C08F10/00 , C08F10/02
摘要： The present invention relates to an ethylene homo or copolymer characterized as having long chain branching, and having a molecular weight distribution, Mw/Mn, and a GPC-LALLS CDF, which satisfies the following relationship: y≧0.0663x−0.015, wherein y=GPC-LALLS CDF and x=Mw/Mn measured by conventional GPC, a line drawn from where the LS chromatogram intersects with molecular weight 350,000 and molecular weight 1,150,000 has a positive slope, preferably with a melt index between 0.15 and 2000 g/10 minutes and having long chain branching. In addition, the invention relates to a free radical initiation polymerization process for the preparation of ethylene polymers or copolymers, comprising reacting ethylene and optionally one or more comonomers at a high pressure, conveniently between 13,000 psig and 100,000 psig, and at reactor temperatures of 115° C. to 400° C., preferably 125-400° C., more preferably 140-350° C., especially 165-320° C., in a reactor system comprising at least one tubular, and at least one autoclave reactor, wherein the monomer(s) feed into the reactors is divided into multiple monomer feed streams, and wherein at least one feed stream into the tubular reactor consists essentially of unreacted monomer.

9. 发明专利

BRPI0516921B1 homopolímero ou copolímero de etileno e processo de polimerização com iniciação via radical livre 未知
公开(公告)号：BRPI0516921B1
公开(公告)日：2016-04-12
申请号：BRPI0516921
申请日：2005-10-04
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： EDDY CHRISTOPHER R , CONRAD CHRISTOPHER W , GILLESPIE DAVID T
IPC分类号： C08F10/00 , C08F10/02
摘要： homopolímero ou copolímero de etileno e processo de polimerização com iniciação via radicais livres. a presente invenção refere-se a um homopolímero ou copolímero de etileno caracterizado por ter ramificação de cadeia longa, e ter uma distribuição de peso molecular, mw/mn, e uma gpc-lalls cdf, que satisfaz a seguinte relação: y 0,0663x - 0,015, na qual y= gpc- lalls cdf e x= mw/mn medido por gpc convencional, uma linha traçada de onde o cromatograma de ls cruza com peso molecular 350.000 e peso molecular 1.150.000 ter uma inclinação positiva, preferivelmente com um índice de fusão entre 0,15 e 2000 g/10 minutos. além disso, a invenção refere-se a um processo de polimerização com iniciação via radicais livres para a preparação de polímeros ou copolímeros de etileno compreendendo reagir etileno e opcionalmente um ou mais comonômeros numa pressão elevada, convenientemente entre 13.000 psig e 100.000 psig, e em temperaturas de reator de 115 °c a 400 °c, preferivelmente 125-400 °c, mais preferivelmente 140-350 °c, especialmente 165-320 °c, num sistema de reatores compreendendo pelo menos um reator tubular, e pelo menos um reator autoclave, sendo que a alimentação de monômeros nos reatores é dividida em múltiplas correntes de alimentação de monômeros, e sendo que pelo menos uma corrente de alimentação de monômeros no reator tubular consiste essencialmente de monâmero não reagido.

10. 发明专利

BRPI0508197B1 película e composição de homopolímero ou interpolímero de etileno 未知
公开(公告)号：BRPI0508197B1
公开(公告)日：2016-04-12
申请号：BRPI0508197
申请日：2005-03-18
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： EVERSDYK DAVID A , GILLESPIE DAVID T , LAVERDURE KENNETH S , KAPUR MRIDULA , LIANG WENBIN
IPC分类号： C08L23/06 , C08L23/08
摘要： película e composição de homopolímero ou interpolímero de etileno divulga-se camadas de película feitas de composições poliméricas formuladas. às camadas de película feitas de tais composições formuladas tem, surpreendentemente boas taxas de transmissão de vapor d'água (por exemplo, baixas) e são particularmente úteis para embalar mercadorias secas tais como cereais. as composições poliméricas têm, preferivelmente, pelo menos um homopolímero de etileno homogêneo e pelo menos um polímero de etileno ramificado heterogeneamente. o homopolímero de etileno tem um peso molecular muito maior que o do polímero de etileno ramificado heterogeneamente, embora a densidade de cada um deles seja, preferivelmente, maior que cerca de 0,95 g/cm^ 3^.

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