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1. 发明申请

WO2007130515A3 HIGH-DENSITY POLYETHYLENE COMPOSITIONS, METHOD OF MAKING THE SAME, ARTICLES MADE THEREFROM, AND METHOD OF MAKING SUCH ARTICLES 审中-公开
标题翻译：高密度聚乙烯组合物，其制备方法，制备方法和制备这些制品的方法
公开(公告)号：WO2007130515A3
公开(公告)日：2008-03-13
申请号：PCT/US2007010735
申请日：2007-05-02
申请人： DOW GLOBAL TECHNOLOGIES INC , MICHIE WILLIAM J , KAY THOMAS W , WHITED STEPHANIE M , ELLEY-BRISTOW DALE M , GILLESPIE DAVID T , HAZLITT LONNIE G
发明人： MICHIE WILLIAM J , KAY THOMAS W , WHITED STEPHANIE M , ELLEY-BRISTOW DALE M , GILLESPIE DAVID T , HAZLITT LONNIE G
IPC分类号： C08L23/04 , B65D41/00 , H01B3/44
CPC分类号： C08L23/08 , C08L23/04 , C08L23/06 , C08L23/0815 , C08L2203/10 , Y10T428/24992 , Y10T428/273 , C08L2666/06
摘要： The instant invention is a high-density polyethylene composition, method of producing the same, articles made therefrom, and method of making such articles. The high- density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm 3 , and a melt index (I 21.6 ) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm 3 , and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of (I2) in the range of 0, 950 to 0,960g/cm 3 , and g' of equal or greater than 1. The method of producing a high-density polyethylene composition includes the following steps: (1) introducing ethylene, and one or more alpha-olefin comonomers into a first reactor; (2) (co)polymerizing the ethylene in the presence of one or more alpha-olefin comonomers in the first reactor thereby producing a first component, wherein the first component being a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm 3 , and a melt index (I 21.6 ) in the range of 0.5 to 10 g/10 minutes; (3) introducing the first component and additional ethylene into a second reactor; (4) polymerizing the additional ethylene in the second reactor thereby producing a second component, wherein the second component being a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm 3 , and a melt index (I 2 ) in the range of 50 to 1500 g/10 minutes; and (5) thereby producing the high-density polyethylene composition, wherein the high-density polyethylene composition having a melt index (I 2 ) of at least 1, a density in the range of 0.950 to 0.960 g/cm 3 , and g' of equal or greater than 1. The articles according to instant invention comprise the above-described inventive high-density polyethylene composition, and such articles may be made via compression molding, injection molding, or injection blow molding.
摘要翻译：本发明是高密度聚乙烯组合物，其制造方法，由其制成的制品及其制造方法。本发明的高密度聚乙烯组合物包括第一组分和第二组分。第一组分是密度在0.915至0.940g / cm 3范围内的高分子量乙烯α-烯烃共聚物，熔体指数（I 21.6）在0.5〜10g / 10分钟的范围内。第二组分是密度在0.965至0.980g / cm 3范围内的低分子量乙烯聚合物，熔体指数（I 2）在50至1500g / 10分钟的范围内。高密度聚乙烯组合物的熔体指数（I 2）至少为1，在（I2）范围内的密度在0,950至0.96g / cm 3的范围内，g 等于或大于1.制备高密度聚乙烯组合物的方法包括以下步骤：（1）将乙烯和一种或多种α-烯烃共聚单体引入第一反应器; （2）（共）在第一反应器中在一种或多种α-烯烃共聚单体存在下聚合乙烯，从而产生第一组分，其中第一组分是密度在该范围内的高分子量乙烯α-烯烃共聚物为0.915〜0.940g / cm 3，熔体指数（I <21.6℃）为0.5〜10g / 10分钟; （3）将第一组分和另外的乙烯引入第二反应器中; （4）在第二反应器中聚合另外的乙烯，从而产生第二组分，其中第二组分是密度在0.965至0.980g / cm 3范围内的低分子量乙烯聚合物，和熔体指数（I 2 H 2）在50至1500g / 10分钟的范围内; 和（5），从而制备高密度聚乙烯组合物，其中熔体指数（I 2/2）至少为1的密度为0.950-0.960g的高密度聚乙烯组合物 / cm 3，g'等于或大于1.本发明的制品包含上述本发明的高密度聚乙烯组合物，并且这些制品可以通过压塑，注射成型或注射吹塑。

2. 发明申请

WO2007140114A3 HIGH-DENSITY POLYETHYLENE COMPOSITIONS AND METHOD OF MAKING THE SAME 审中-公开
标题翻译：高密度聚乙烯组合物及其制备方法
公开(公告)号：WO2007140114A3
公开(公告)日：2008-04-10
申请号：PCT/US2007068952
申请日：2007-05-15
申请人： DOW GLOBAL TECHNOLOGIES INC , MICHIE WILLIAM J , WILSON DEBRA R , WHITED STEPHANIE M , KINNAN MICHAEL A
发明人： MICHIE WILLIAM J , WILSON DEBRA R , WHITED STEPHANIE M , KINNAN MICHAEL A
IPC分类号： C08F210/16 , B29C45/00
CPC分类号： C08F210/16 , B29C45/0001 , B29K2023/065 , C08F210/14 , C08F2500/07 , C08F2500/12 , C08F2500/03 , C08F2500/20 , C08F2500/10
摘要： The instant invention is a high-density polyethylene composition, method of making the same, and articles made therefrom. The high-density polyethylene composition of the instant invention includes an ethylene alpha-olefin copolymer having a density in the range of 0.935 to 0.952 g/cm 3 , a melt index (I 2 ) in the range of 30 to 75 g/10 minutes, an I 21 / I 2 ratio in the range of 13-35, a M w /M n ratio in the range of 3.5-8. The high-density polyethylene composition has a brittleness temperature of at least less than -20 °C. The process for producing a high-density polyethylene composition according to instant invention includes the following steps: (1) introducing ethylene, and one or more alpha-olefin comonomers into a reactor; (2) (co)polymerizing the ethylene in the presence of the one or more alpha-olefin comonomers in the reactor; and (3) thereby producing the high-density polyethylene composition, wherein the high- density polyethylene composition having a density in the range of 0.935 to 0.952 g/cm 3 , a melt index (I2) in the range of 30 to 75 g/10 minutes, an I 21 / I 2 ratio in the range of 13-35, a M w /M n ratio in the range of 3.5-8, and a brittleness temperature of at least less than -20 "C. Articles according to the instant invention include the inventive high-density polyethylene composition.
摘要翻译：本发明是高密度聚乙烯组合物，其制造方法和由其制成的制品。本发明的高密度聚乙烯组合物包括密度在0.935至0.952g / cm 3范围内的乙烯α-烯烃共聚物，熔体指数（I 2） SUB>）在30至75g / 10分钟的范围内，在13-35的范围内的I 2/21 / I 2比值，M W / M 比在3.5-8的范围内。高密度聚乙烯组合物的脆性温度至少低于-20℃。根据本发明的高密度聚乙烯组合物的制造方法包括以下步骤：（1）将乙烯和一种或多种α-烯烃共聚单体引入反应器中; （2）在反应器中在一种或多种α-烯烃共聚单体存在下共聚合乙烯; 和（3），由此制备高密度聚乙烯组合物，其中密度在0.935至0.952g / cm 3范围内的高密度聚乙烯组合物，其中熔体指数（I 2）在范围为30至75g / 10分钟，13-35℃范围内的1/2/2/2比值为1 / 在3.5-8范围内的摩尔比，脆性温度至少低于-20℃。根据本发明的制品包括本发明的高密度聚乙烯组合物。

3. 发明专利

AT464352T 未知
公开(公告)号：AT464352T
公开(公告)日：2010-04-15
申请号：AT05853539
申请日：2005-12-09
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： MICHIE WILLIAM J , HOGAN TODD A , MARTINEZ FELIPE F , NEUBAUER ANTHONY C , COSTEUX STEPHANE , CHANG DANE , KAPUR MRIDULA
IPC分类号： C08L23/04 , C08K5/43
摘要： A composition, comprising the reaction product of: (a) a first composition comprising a polyethylene component prepared in the presence of a chromium-based catalyst system, and (b) a second composition comprising a coupling amount of at least one polysulfonyl azide.

4. 发明专利

ES2338936T3 COMPOSICIONES DE POLIETILENO DE ALTA DENSIDAD, METODO PARA FABRICAR LAS MISMAS, ARTICULOS FABRICADOS A PARTIR DE ELLAS, Y METODO PARA FABRICAR TALES ARTICULOS. 未知
公开(公告)号：ES2338936T3
公开(公告)日：2010-05-13
申请号：ES07756194
申请日：2007-05-02
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： MICHIE WILLIAM J , KAY THOMAS W , WHITED STEPHANIE M , ELLEY-BRISTOW DALE M , GILLESPIE DAVID T , HAZLITT LONNIE G
IPC分类号： C08L23/04 , B65D41/00 , H01B3/44
摘要： Una composición de polietileno de alta densidad, que comprende: un primer componente, siendo dicho primer componente un copolímero de etileno y una alfa-olefina de alto peso molecular que tiene una densidad en el intervalo de 0,915 a 0,940 g/cm3, y un índice de fluidez de la masa fundida (I21,6) en el intervalo de 0,5 a 10 g/10 minutos; y un segundo componente, siendo dicho segundo componente un polímero de etileno de bajo peso molecular que tiene una densidad en el intervalo de 0,965 a 0,980 g/cm3, y un índice de fluidez de la masa fundida (I2) en el intervalo de 50 a 1500 g/10 minutos; en la que dicha composición de polietileno de alta densidad tiene un índice de fluidez de la masa fundida (I2) de al menos 1 g/10 minutos, una densidad en el intervalo de 0,950 a 0,960 g/cm3, y una g'' de igual o mayor que 1.

5. 发明专利

BRPI0711215A2 未知
公开(公告)号：BRPI0711215A2
公开(公告)日：2011-08-23
申请号：BRPI0711215
申请日：2007-05-15
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： MICHIE WILLIAM J , WILSON DEBRA R , WHITED STEPHANIE M , KINNAN MICHAEL
IPC分类号： C08F210/16 , B29C45/00
摘要： The instant invention is a high-density polyethylene composition, and method of making the same. The high-density polyethylene composition of the instant invention includes an ethylene alpha-olefin copolymer having a density in the range of 0.935 to 0.952 g/cm3, a melt index (I2) in the range of 30 to 75 g/10 minutes, an I21/I2 ratio in the range of 13-35, a Mw/Mn ratio in the range of 3.5-8. The high-density polyethylene composition has a brittleness temperature of at least less than -20° C. The process for producing a high-density polyethylene composition according to instant invention includes the following steps: (1) introducing ethylene, and an alpha-olefin comonomer into a reactor; (2) copolymerizing the ethylene with the alpha-olefin comonomer in the reactor; and (3) thereby producing the high-density polyethylene composition, wherein the high-density polyethylene composition having a density in the range of 0.935 to 0.952 g/cm3, a melt index (I2) in the range of 30 to 75 g/10 minutes, an I21/I2 ratio in the range of 13-35, a Mw/Mn ratio in the range of 3.5-8, and a brittleness temperature of at least less than -20° C.

6. 发明专利

PL1831303T3 Kompozycje polietylenowe o zmodyfikowanej reologii 未知
公开(公告)号：PL1831303T3
公开(公告)日：2010-09-30
申请号：PL05853539
申请日：2005-12-09
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： MICHIE WILLIAM J , HOGAN TODD A , MARTINEZ FELIPE F , NEUBAUER ANTHONY C , COSTEUX STÉPHANE , CHANG DANE , KAPUR MRIDULA
IPC分类号： C08L23/04 , C08K5/43

8. 发明专利

CA2711048A1 ETHYLENE-BASED POLYMER COMPOSITIONS, METHODS OF MAKING THE SAME, AND ARTICLES PREPARED FROM THE SAME 未知
公开(公告)号：CA2711048A1
公开(公告)日：2009-07-09
申请号：CA2711048
申请日：2008-12-18
申请人： DOW GLOBAL TECHNOLOGIES INC 20
发明人： KAPUR MRIDULA , JORGENSEN ROBERT JAMES , WAGNER BURKHARD ERIC , MICHIE WILLIAM J
IPC分类号： C08F4/00 , C08F4/52 , C08F4/642
摘要： The invention provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer, and a low molecular weight ethylene- based polymer, and wherein the high molecular weight ethylene-based polymer has a density less than, or equal to, 0.955 g/cm3, and wherein the blend has a high load melt index (I2i) greater than, or equal to, 15 g/10 min, and wherein the blend has a molecular weight distribution (Mw/Mn) greater than, or equal to, 15. The invention also provides a composition comprising a blend, which comprises a high molecular weight ethylene-based polymer and a low molecular weight ethylene-based polymer, and wherein the high molecular weight ethylene-based polymer component has a density less than, or equal to, 0.945 g/cm3, and a melt index (I2) less than, or equal to, 0.1 g/10 min, and wherein the blend has a high load melt index (I2i) less than, or equal to, 15 g/10 min, and a melt index (I5) less than, or equal to 1 g/10 min, and a molecular weight distribution (Mw/Mn) greater than, or equal to, 15. Additional compositions are disclosed.

9. 发明专利

MX2008014834A COMPOSICIONES DE POLIETILENO DE ALTA DENSIDAD Y METODO PARA ELABORARLAS. 未知
公开(公告)号：MX2008014834A
公开(公告)日：2009-01-30
申请号：MX2008014834
申请日：2007-05-15
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： MICHIE WILLIAM J , WILSON DEBRA R , KINNAN MICHAEL A , WHITED STEPHANIE M
IPC分类号： C08F210/16 , B29C45/00
摘要： La presente invención es una composición de polietileno de alta densidad, un método para elaborarla, y artículos elaborados a partir de ella. La composición de polietileno de alta densidad de la presente invención incluye un copolímero de etileno y alfa-olefina que tiene una densidad en el rango desde 0.935 hasta 0.952 g/cm3, un índice de fusión (12) en el rango desde 20 hasta 75 g/10 minutos, y una proporción de I21/I2 en el rango de 13-35, una proporción de PM/PN en el rango de 3.5-8. La composición de polietileno de alta densidad tiene una temperatura de fragilidad al menos menor que -20 ºC. El proceso para producir una composición de polietileno de alta densidad de acuerdo con la presente invención incluye los siguientes pasos: (1) introducir etileno, y uno o más comonómeros de alfa-olefina en un reactor; (2) (co)polimerizar el etileno en la presencia del uno o más comonómeros de alfa-olefina en el reactor; y (3) producir de esta forma la composición de polietileno de alta densidad, en donde la composición polietileno de alta densidad tiene una densidad en el rango desde 0.935 hasta 0.952 g/cm3, un índice de fusión (12) en el rango de 30 a 75 g/10 minutos, una proporción I21/I2 en el rango de 13-35, una proporción de PM/PN en el rango de 3.5-8 y una temperatura de fragilidad al menos menor que -20 ºC. Los artículos de acuerdo con la presente invención incluyen la composición de polietileno de alta densidad de la invención.

10. 发明专利

AU2007248554A1 High-density polyethylene compositions, method of making the same, articles made therefrom, and method of making such articles 未知
公开(公告)号：AU2007248554A1
公开(公告)日：2007-11-15
申请号：AU2007248554
申请日：2007-05-02
申请人： DOW GLOBAL TECHNOLOGIES INC
发明人： GILLESPIE DAVID T , KAY THOMAS W , ELLEY-BRISTOW DALE M , MICHIE WILLIAM J , WHITED STEPHANIE M , HAZLITT LONNIE G
IPC分类号： C08L23/04
摘要： The instant invention is a high-density polyethylene composition, method of producing the same, articles made therefrom, and method of making such articles. The high-density polyethylene composition of the instant invention includes a first component, and a second component. The first component is a high molecular weight ethylene alpha-olefin copolymer having a density in the range of 0.915 to 0.940 g/cm3, and a melt index (I21.6) in the range of 0.5 to 10 g/10 minutes. The second component is a low molecular weight ethylene polymer having a density in the range of 0.965 to 0.980 g/cm3, and a melt index (I2) in the range of 50 to 1500 g/10 minutes. The high-density polyethylene composition has a melt index (I2) of at least 1, a density in the range of 0.950 to 0.960 g/cm3, and g′ of 1.

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