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1. 发明申请

WO2018060516A1 DENTAL COMPOSITION 审中-公开
标题翻译：牙科组合物
公开(公告)号：WO2018060516A1
公开(公告)日：2018-04-05
申请号：PCT/EP2017/074959
申请日：2017-10-02
申请人： DENTSPLY DETREY GMBH
发明人： SZILLAT, Florian , RENN, Caroline , ELSNER, Oliver , KLEE, Joachim E. , SCHEUFLER, Christian
IPC分类号： A61K6/083 , A61K6/00
摘要： The present invention relates to a dental composition which is a resin modified dental cement composition, comprising a radically polymerizable compound and a redox initiator system comprising one or more clathrate compounds comprising a host molecule and one or more guest molecules, wherein the guest molecule is an oxidising agent selected from organic peroxides and organic hydroperoxides. Furthermore, the present invention relates to a use of the redox initiator system in a dental composition which is a resin modified dental cement composition.
摘要翻译：牙科用组合物本发明涉及一种牙科用组合物，它是树脂改性的牙科用粘固剂组合物，其包含可自由基聚合的化合物和氧化还原引发剂体系，所述氧化还原引发剂体系包含一种或多种包含主体分子和一种或多种客体分子，其中客体分子是选自有机过氧化物和有机氢过氧化物的氧化剂。此外，本发明涉及氧化还原引发剂体系在牙科组合物中的用途，所述牙科组合物是树脂改性的牙科粘固剂组合物。

2. 发明申请

WO2014040729A1 DENTAL COMPOSITION 审中-公开
标题翻译：牙科成分
公开(公告)号：WO2014040729A1
公开(公告)日：2014-03-20
申请号：PCT/EP2013/002731
申请日：2013-09-11
申请人： DENTSPLY DETREY GMBH
发明人： KLEE, Joachim E. , GANSEL, Julia , FIK, Christoph P. , WAGNER, Caroline , ELSNER, Oliver , MAIER, Maximilian , LAMPE, Ulrich , RITTER, Helmut , KAVALLAR, Lisa-Maria
IPC分类号： A61K6/083
CPC分类号： A61K6/0023 , A61K6/0044 , C08L33/10 , C08L33/26
摘要： Dental composition comprising a polymerizable compound of the following formula (I):A-L(B) wherein A, L, B, and n are as defined in claim 1.
摘要翻译：含有下式（I）的聚合性化合物的组合物：A-L（B）其中A，L，B和n如权利要求1所定义。

3. 发明申请

WO2014067666A1 DENTAL COMPOSITION 审中-公开
公开(公告)号：WO2014067666A1
公开(公告)日：2014-05-08
申请号：PCT/EP2013/003311
申请日：2013-11-04
申请人： DENTSPLY DETREY GMBH
发明人： KLEE, Joachim , ELSNER, Oliver , FIK, Christoph , GANSEL, Julia , LAMPE, Ulrich , MAIER, Maximilian , RITTER, Helmut , KAVALLAR, Lisa-Maria
IPC分类号： A61K6/083 , C07D307/14
CPC分类号： C07D307/14 , A61K6/0038 , C08L33/10 , A61K6/0023 , A61K6/0835
摘要： A composition comprising a polymerizable compound of the following formula (I) A is a group of the following formula (II) wherein X 1 is CO or CS; X 2 is a single bond, CO, CS, CH 2 , or a group Z[X'Z'] k , wherein X' is an oxygen atom, a sulfur atom or NR, (wherein R is a hydrogen atom, a straight chain or branched C 1-16 alkyl group which may be substituted by a C 3-6 cycloalkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -0-PO 3 M 2 or -SO 3 M, a C 3-6 cycloalkyl group which may be substituted by a C 1-16 alkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -0-PO 3 M 2 or -SO 3 M, a C 6-14 aryl or C 3-14 heteroaryl group which may be substituted by -COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M), Z is a straight chain or branched C 1-4 alkylene group, Z' is a bond, a straight chain or branched C 1-4 alkylene group, and k is an integer of from 1 to 50; is a monocylic, bicyclic or tricyclic cycloalkyl group having 3 to 20 carbon atoms or a monocylic, bicyclic or tricyclic heterocycloalkyi group having 2 to 20 carbon atoms and 1 to 4 heteroatoms selected from oxygen, sulfur and nitrogen atoms, which groups may be substituted with 1 to 3 groups selected from a C 1-16 alkyl group, - COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M; R 1 is a hydrogen atom, -COOM, a straight chain or branched C 1-16 alkyl group which may be substituted by a C 3-6 cycloalkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M, a C 3-6 cycloalkyl group which may be substituted by a C 1-16 alkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M, a C 6-14 aryl or C 3-14 heteroaryl group which may be substituted by -COOM, -PO 3 M, - O-PO 3 M 2 or -SO 3 M, R 2 is a hydrogen atom, -COOM, a straight chain or branched C 1-16 alkyl group which may be substituted by a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O-PO 3 M 2 and -SO 3 M, a C 3-6 cycloalkyl group which may be substituted by a C 1-16 alkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M, or a C 6-14 aryl or C 3-14 heteroaryl group which may be substituted by -COOM, -PO 3 M, - O-PO 3 M 2 and -SO 3 M, L is a single bond or an (n+1 ) -valent linker group; B independently is a group according to the definition of A, a group of the following formula (III) wherein X 1 independently has the same meaning as defined for X 1 in formula (II), CH 2 , or a group [X'Z] k , wherein X' is an oxygen atom, a sulfur atom or NH, Z is a straight chain or branched C 1-4 alkylene group, and k' is an integer of from 1 to 50; R 1 and R 2 are independent from each other and independently have the same meaning as defined for formula (II), a group of the following formula (IV) wherein X 2 independently has the same meaning as defined for X 1 in formula (III) wherein X 1 independently has the same meaning as defined for X 1 in formula (II), CH 2 , or a group [X'Z] k' , wherein X' is an oxygen atom, a sulfur atom or NH, Z is a straight chain or branched C 1-4 alkylene group, and k' is an integer of from 1 to 50; R 1 and R 2 are independent from each other and independently have the same meaning as defined for formula (II), R is a hydrogen atom, a straight chain or branched C 1-16 alkyl group which may be substituted by a C 3-6 cycloalkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M, a C 3-6 cycloalkyl group which may be substituted by a C 1-16 alkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O- PO 3 M 2 or -SO 3 M, a C 6-14 aryl or C 3-14 heteroaryl group which may be substituted by - COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M, a group of the following formula (V) wherein X 3 is CH 2 , CO, -CH 2 CO-, CS, or -CH 2 CS-, R 1 and R 2 which are independent from each other and independently have the same meaning as defined for formula (II), or a group [ Z'X"] m E, wherein Z' is a straight chain or branched C 1-4 alkylene group, X" is an oxygen atom, a sulfur atom or NR, (wherein R is a hydrogen atom, a straight chain or branched C 1-16 alkyl group which may be substituted by a C 3-6 cycloalkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M, a C 3-6 cycloalkyl group which may be substituted by a C 1-16 alkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O-PO 3 M 2 or-SO 3 M, a C 6-14 aryl or C 3-14 heteroaryl group which may be substituted by -COOM, - PO 3 M, -O-PO 3 M 2 or -SO 3 M), E is a hydrogen atom, PO 3 M 2 , a straight chain or branched C 1-16 alkyl group which may be substituted by a C 3-6 cycloalkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M, a C 3-6 cycloalkyl group which may be substituted by a C 1-16 alkyl group, a C 6-14 aryl or C 3-14 heteroaryl group, -COOM, -PO 3 M, -O- PO 3 M 2 or -SO 3 M, a C 6-14 aryl or C 3-14 heteroaryl group which may be substituted by - COOM, -PO 3 M, -O-PO 3 M 2 or -SO 3 M, and m is an integer of from 1 to 10; and n is an integer of from from 1 to 6; wherein M which are independent from each other each represent a hydrogen atom or a metal atom; provided that in case L is a single bond, B cannot be a group according to the definition of A or a group of the formula (III) or (IV).

4. 发明申请

WO2011069642A1 DENTAL COMPOSITION 审中-公开
标题翻译：牙科成分
公开(公告)号：WO2011069642A1
公开(公告)日：2011-06-16
申请号：PCT/EP2010/007434
申请日：2010-12-07
申请人： DENTSPLY DETREY GMBH , KLEE, Joachim, E. , RITTER, Helmut , POHLE, Sven , ELSNER, Oliver
发明人： KLEE, Joachim, E. , RITTER, Helmut , POHLE, Sven , ELSNER, Oliver
IPC分类号： A61K6/083 , C08F8/14 , C08F8/32 , C08F8/34 , C08F290/12
CPC分类号： C08F8/32 , A61K6/0835 , C08F8/14 , C08F8/34 , C08F263/06 , C08F267/00 , C08F267/02 , C08F290/00 , C08F290/12 , C08L51/003 , C08F220/06 , C08L2666/02 , C08L33/08
摘要： Dental cement composition comprising (a) a polymerizable polyacidic polymer having repeating units in the polymer backbone, which are represented by the following formula (I) wherein X represents O, S, or NR', whereby R' represents a hydrogen atom or a straight or branched C 1 -C 6 alkyl group, C 3 -C 6 cycloalkyl group, or C 4 -C 8 cycloalkylalkyl group, Y is a moiety of the following formula (II) wherein L 2 represents a single bond, a straight or branched C 1 -C 6 alkylene group, or a straight or branched C 1 -C 2O alkylene group which includes 1 to 8 atoms selected from oxygen and sulfur atoms; L 3 represents a straight or branched C 1 -C 3 alkylene group, which may optionally include 1 to 4 atoms selected from oxygen and sulfur atoms; X' represents O, S, or NR", whereby R" represents a hydrogen atom or a straight or branched C 1 -C 6 alkyl group, C 3 -C 6 cycloalkyl group, or C 4 - C 8 cycloalkylalkyl group; m represents an integer of from 0 to 6; Z represents H or -COOH; Z' represents H or (CH 2 ) X COOH, wherein x is 0, 1, or 2, L 1 represents a single bond, a straight or branched C 1 -C 6 alkylene group, a straight or branched C 1 -C 6 alkylenylene group, or a straight or branched C 1 -C 2O alkylene group which includes 1 to 8 atoms selected from oxygen and sulfur atoms; and having repeating units in the polymer backbone, which are represented by the following formula (III) wherein L 4 represents a single bond, a straight or branched C 1 -C 6 alkylene group, a straight or branched C 1 -C 6 alkylenylene group, or a straight or branched C 1 -C 2O alkylene group which includes 1 to 8 atoms selected from oxygen and sulfur atoms; and Z" represents H or -COOH; (b) a polymerizable monomer having at least one polymerizable functional group; (c) a radical polymerization initiator.
摘要翻译：牙科水泥组合物，其包含（a）在聚合物主链中具有重复单元的可聚合的多元酸聚合物，其由下式（I）表示，其中X表示O，S或NR'，其中R'表示氢原子或直链或支链C 1 -C 6烷基，C 3 -C 6环烷基或C 4 -C 8环烷基烷基，Y是下式（II）的部分，其中L 2表示单键，直链或支链C 1 -C 6亚烷基，或包含1至8个选自氧和硫原子的原子的直链或支链C1-C2O亚烷基; L3表示直链或支链C1-C3亚烷基，其可以任选地包括选自氧和硫原子的1至4个原子; X'表示O，S或NR“，其中R”表示氢原子或直链或支链C 1 -C 6烷基，C 3 -C 6环烷基或C 4 -C 8环烷基烷基; m表示0〜6的整数， Z表示H或-COOH; Z'表示H或（CH 2）XCOOH，其中x为0,1或2，L 1表示单键，直链或支链C 1 -C 6亚烷基，直链或支链C 1 -C 6亚烷基，或直链或支链C 1 -C 6亚烷基包含1至8个选自氧和硫原子的原子的支链C1-C2O亚烷基; 并且在聚合物主链中具有由下式（III）表示的重复单元，其中L4表示单键，直链或支链C 1 -C 6亚烷基，直链或支链C 1 -C 6亚烷基，或直链或支链C 1 -C 6亚烷基包含1至8个选自氧和硫原子的原子的支链C1-C2O亚烷基; Z“表示H或-COOH;（b）具有至少一个可聚合官能团的可聚合单体;（c）自由基聚合引发剂。

5. 发明申请

WO2020099518A1 BIFUNCTIONAL AND POLYFUNCTIONAL COINITIATORS IN DENTAL COMPOSITIONS 审中-公开
公开(公告)号：WO2020099518A1
公开(公告)日：2020-05-22
申请号：PCT/EP2019/081241
申请日：2019-11-13
申请人： DENTSPLY DETREY GMBH
发明人： KLEE, Joachim , ELSNER, Oliver , SZILLAT, Florian , RENN, Caroline
IPC分类号： A61K6/00 , A61K6/79
摘要： A dental composition comprising (a) a polymerizable monomer; and (b) an initiator system comprising (b-1) a sensitizer or an oxidizing agent of a redox initiator system; and (b-2) a coinitiator of the following formula (I): Q-X (I) wherein Q and X are as defined in claim 1.

6. 发明申请

WO2017042333A1 POLYMERIZABLE POLYACIDIC POLYMER 审中-公开
标题翻译：聚合聚合物聚合物
公开(公告)号：WO2017042333A1
公开(公告)日：2017-03-16
申请号：PCT/EP2016/071304
申请日：2016-09-09
申请人： DENTSPLY DETREY GMBH
发明人： KLEE, Joachim, E. , RENN, Caroline , SZILLAT, Florian , ELSNER, Oliver , SCHEUFLER, Christian , LAMPE, Ulrich , RITTER, Helmut
IPC分类号： C08F220/06 , A61K6/083 , C08F222/38 , C08F8/30
CPC分类号： C08F220/06 , C07C233/20 , C08F8/30 , C08F290/126 , C08F2800/10 , C08F2800/20 , C08F2810/30 , C08F2810/50 , C08F220/58 , A61K6/0835 , C08L33/10 , A61K6/0023 , C08L33/26
摘要： The present invention relates to a polymerizable polyacidic polymer and to a process for preparing the polymerizable polyacidic polymer. Furthermore, the present invention relates to an aqueous dental composition comprising the polymerizable polyacidic polymer, to a use of the polymerizable polyacidic polymer for the preparation of a dental composition and to an acrylic acid derivative copolymer.
摘要翻译：本发明涉及可聚合的聚酸聚合物和一种制备可聚合的聚酸聚合物的方法。此外，本发明涉及包含可聚合的多元酸聚合物的水性牙科用组合物，其用于制备牙科用组合物和丙烯酸衍生物共聚物的可聚合多元酸聚合物。

7. 发明申请

WO2016202744A1 AQUEOUS DENTAL GLASS IONOMER COMPOSITION 审中-公开
标题翻译：水性透明玻璃离子组合物（AQUEOUS DENTAL GLASS IONOMER COMPOSITION）
公开(公告)号：WO2016202744A1
公开(公告)日：2016-12-22
申请号：PCT/EP2016/063515
申请日：2016-06-13
申请人： DENTSPLY DETREY GMBH
发明人： RENN, Caroline , ELSNER, Oliver , GANSEL, Julia , SCHEUFLER, Christian , WALZ, Uwe
IPC分类号： A61K6/083
CPC分类号： A61K6/0835
摘要： The present invention relates to an aqueous dental glass ionomer composition comprising (A) a reactive particulate glass, (B) a water-soluble, polymerizable polymer comprising acidic groups, which is reactive with the particulate glass in a cement reaction, whereby the polymerizable polymer has a polymer backbone and hydrolysis-stable pendant groups having one or more polymerizable carbon-carbon double bonds, wherein the polymerizable polymer is obtainable by a process comprising a) a step of copolymerizing a mixture comprising (i) a first copolymerizable monomer comprising at least one optionally protected carboxylic acid group and a first polymerizable organic moiety, and (ii) a second copolymerizable monomer comprising one or more optionally protected primary and/or secondary amino groups and a second polymerizable organic moiety, for obtaining an amino group containing copolymer; b) a step of coupling to the amino group containing copolymer a compound having a polymerizable moiety and a functional group reactive with an amino group of repeating units derived from the second copolymerizable monomer in the amino group containing copolymer obtained in the first step, wherein the optionally protected amino group is deprotected, so that polymerizable pendant groups are linked to the backbone by hydrolysis-stable linking groups, and, optionally, a step of deprotecting the protected carboxylic acid group after step a) or step b), for obtaining a polymerizable polymer; (C) a hydrolysis-stable, water-soluble monomer having one polymerizable double bond and optionally a carboxylic acid group, said monomer having a molecular weight of at most 200 Da; (D) a polymerization initiator system; and (E) a polymerizable hydrolysis-stable crosslinker having at least two polymerizable carbon-carbon double bonds.
摘要翻译：本发明涉及一种水性牙科玻璃离聚物组合物，其包含（A）反应性颗粒玻璃，（B）包含酸性基团的水溶性可聚合聚合物，其在水泥反应中与颗粒状玻璃反应，由此可聚合聚合物具有聚合物主链和具有一个或多个可聚合碳 - 碳双键的水解稳定侧基，其中可聚合聚合物可通过以下方法获得：a）使混合物共聚的步骤，该混合物包含（i）至少包含第一可共聚单体一种任选保护的羧酸基团和第一可聚合有机部分，和（ii）包含一个或多个任选保护的伯和/或仲氨基和第二可聚合有机部分的第二可共聚单体，用于获得含氨基的共聚物; b）在第一步骤中获得的含氨基共聚物中与含氨基的共聚物偶联具有可聚合部分的化合物和与源自第二可共聚单体的重复单元的氨基反应的官能团的步骤，其中，任选地保护的氨基被去保护，使得可聚合侧基通过水解稳定的连接基团连接到主链上，并且任选地在步骤a）或步骤b）之后使被保护的羧酸基脱保护的步骤，以获得可聚合的聚合物; （C）具有一个可聚合双键和任选的羧酸基团的水解稳定的水溶性单体，所述单体的分子量至多为200Da; （D）聚合引发剂体系; 和（E）具有至少两个可聚合碳 - 碳双键的可聚合水解稳定的交联剂。

8. 发明申请

WO2016156461A1 UNIT DOSE PACKAGE 审中-公开
标题翻译：单位剂量包装
公开(公告)号：WO2016156461A1
公开(公告)日：2016-10-06
申请号：PCT/EP2016/057013
申请日：2016-03-31
申请人： DENTSPLY DETREY GMBH
发明人： EVERS, Markus , EBERHARDT, Alexandra , GRÜTZNER, Ernst Andreas , MATT, Nicole , WEBER, Tillmann , POHLE, Sven , ELSNER, Oliver , FIK, Christoph P.
IPC分类号： A61C5/06 , B65D83/00
CPC分类号： A61C5/64 , A61C5/62 , A61C17/005 , A61C19/063
摘要： A unit dose package for a dental composition, comprising: (a) a rigid support member having a proximal end and a distal end, the rigid support member supporting one or more storage compartments for the dental composition and providing fluid flow communication between the one or more storage compartments and one or more discharge orifices, wherein the one or more storage compartments each have a volume of 10 pi to 1000 pi, and (b) a discharge conduit having a longitudinal axis extending from a proximal end to a distal end, the discharge conduit being rotatably attached to the distal end of the rigid support member for rotation around its longitudinal axis, wherein the attachment of the discharge conduit (b) and the rigid support member (a) is provided by two-component injection molding; whereby fluid flow communication between the discharge conduit and the one or more storage compartments may be established by rotating the discharge conduit around its longitudinal axis relative to the rigid support member from a first position to a second position and whereby the fluid flow communication between the discharge conduit and the one or more storage compartments may be interrupted by rotating the discharge conduit around its longitudinal axis relative to the rigid support member from the second position to the first position, wherein the one or more storage compartments are provided by flexible films made of composite material films, which are attached to the rigid support member.
摘要翻译：一种用于牙科用组合物的单位剂量包，其包括：（a）具有近端和远端的刚性支撑构件，所述刚性支撑构件支撑牙科用组合物的一个或多个储存室，并提供所述牙科组合物之间的流体流动连通更多的储存室和一个或多个排放孔，其中所述一个或多个储存室各自具有10pi至1000pI的体积，和（b）具有从近端延伸到远端的纵向轴线的排出导管，排出管道可旋转地附接到刚性支撑构件的远端以围绕其纵向轴线旋转，其中排出管道（b）和刚性支撑构件（a）的附接通过双组分注射成型提供; 从而可以通过使排放导管围绕其纵向轴线相对于刚性支撑构件从第一位置旋转到第二位置而建立排放管道和一个或多个储存室之间的流体流动连通，并且由此排出管道导管，并且一个或多个存储隔间可以通过相对于刚性支撑构件围绕其纵向轴线从第二位置旋转到第一位置而中断，其中一个或多个存储隔室由复合材料制成的柔性膜提供材料膜，其附接到刚性支撑构件。

9. 发明申请

WO2020127380A1 DENTAL COMPOSITION 审中-公开
公开(公告)号：WO2020127380A1
公开(公告)日：2020-06-25
申请号：PCT/EP2019/085794
申请日：2019-12-17
申请人： DENTSPLY DETREY GMBH , DENTSPLY SIRONA INC.
发明人： KLEE, Joachim E. , WORM, Matthias , SCHEUFLER, Christian , ELSNER, Oliver , TIGGES, Thomas
IPC分类号： C08G71/04 , C07C269/04 , A61K6/30 , A61K6/889 , A61K6/893 , C09J175/04
摘要： Described herein is a dental composition containing a polymerizable compound having at least one optionally derivatized β-hydroxy urethane unit. The polymerizable compound having at least one optionally derivatized β-hydroxy urethane unit is obtained without use of organo-metal catalysts and isocyanates and by a reaction between an at least one component A having at least one cyclic carbonate group with an at least one component B having at least one of primary amine functional group and secondary amine functional group. The present disclosure relates to use of the polymerizable compound having at least one optionally derivatized β-hydroxy urethane unit for the preparation of a dental composition, in particular a dental composite, a glass ionomer, a dental cement, a dental sealant, and a dental adhesive.

10. 发明申请

WO2019072787A1 PHOTOCURABLE DENTAL COMPOSITION 审中-公开
公开(公告)号：WO2019072787A1
公开(公告)日：2019-04-18
申请号：PCT/EP2018/077383
申请日：2018-10-09
申请人： DENTSPLY DETREY GMBH
发明人： SZILLAT, Florian , MAIER, Maximilian , RENN, Caroline , KLEE, Joachim E. , ELSNER, Oliver , KEMPTER, Jörg , LALEVÉE, Jacques , BOUZRATI-ZERELLI, Mariem , KIRSCHNER, Julie
IPC分类号： A61K6/083 , A61K6/00 , A61K6/10
摘要： The present invention relates to a photocurable dental composition comprising a specific polymerization initiator system containing the combination of a photoinitiator compound and a coinitiator compound being a sulfinate compound or a sulfonate compound. The present invention also relates to the use of this polymerization initiator system in a photocurable dental composition.

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