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1. 发明授权

US5508380A Fluorinated polymers containing perfluoropolyoxyalkylene sequences and having thermoplastic elastomeric properties 失效
标题翻译：含有全氟聚氧化烯序列并具有热塑性弹性体性质的氟化聚合物
公开(公告)号：US5508380A
公开(公告)日：1996-04-16
申请号：US524104
申请日：1995-08-21
申请人： Stefano Turri , Giuseppe Gianotti , Marinella Levi , Claudio Tonelli
发明人： Stefano Turri , Giuseppe Gianotti , Marinella Levi , Claudio Tonelli
IPC分类号： C08G18/50 , C08G63/682 , C08G65/00 , C08G65/22 , C08G65/32 , C08G65/329 , C08G69/42 , C08G73/02 , C08G73/06 , C08G73/10 , C08G73/16 , C08G75/00 , C08G75/14 , C08G75/23 , C08G77/22 , C08G83/00 , C08G73/24
CPC分类号： C08G65/329 , C08G18/5015 , C08G65/007
摘要： Fluorinated polymers having thermoplastic elastomeric properties comprising in the macromolecule perfluoropolyoxyalkylene sequences of formula:--CF.sub.2 O--(CF.sub.2 CF.sub.2 O).sub.m --(CF.sub.2 O).sub.n --CF.sub.2 --(I)where m/n=0.2+5, are obtained through polycondensation with suitable perfluoropolyoxyalkylene condensation monomers corresponding to formula (I), functionalized with suitable reactive groups and having a functionality at least equal to 1.97, preferably at least equal to 1.99.Such polymers are characterized by an average molecular weight at least 50%, preferably at least 100%, higher than that of the corresponding polymers obtained starting from perfluoropolyoxyalkylenes corresponding to formula (I) having a functionality not higher than 1.96.
摘要翻译：通过与适当的全氟聚氧化烯缩合物缩聚得到具有热分解弹性体的氟化聚合物，其中m / n = 0.2 + 5，其中m / n = 0.2 + 5，其中包含大分子式为：-CF 2 O-（CF 2 CF 2 O）m - （CF 2 O）n -CF 2（I）的全氟聚氧化烯序列对应于式（I）的单体，用合适的反应性基团官能化并具有至少等于1.97，优选至少等于1.99的官能度。这种聚合物的特征在于平均分子量比对应于具有不高于1.96的官能度的式（I）的全氟聚氧化烯开始获得的相应聚合物的平均分子量至少50％，优选至少100％。

2. 发明授权

US5246588A Process for separating from on another the non-functional, monofunctional and bifunctional species contained in the perfluoropolyoxyalkylenes 失效
标题翻译：在其他方法中分离含有全氟聚氧乙烯的非功能，单功能和双功能物种
公开(公告)号：US5246588A
公开(公告)日：1993-09-21
申请号：US963658
申请日：1992-10-20
申请人： Claudio Tonelli , Stefano Turri , Marinella Levi , Giuseppe Gianotti
发明人： Claudio Tonelli , Stefano Turri , Marinella Levi , Giuseppe Gianotti
IPC分类号： B01D15/08 , B01J20/285 , C08G65/00 , C08G65/02 , C08G65/30 , G01N30/88
CPC分类号： C08G65/007 , B01D15/08 , C08G65/30 , B01D15/426
摘要： A process for separating, or enriching, non-functional, monofunctional and bifunctional species in a mixture of perfluoropolyoxyalkylenes of the general formula:Z--O--Rf--YwhereRf=a perfluoropolyoxyalkylene chain comprising one or more monomeric units of formula ##STR1## --CFXO-- (X=F, CF.sub.3), and optionally also units (--CF.sub.2 CF.sub.2 O--); andZ, Y, like or different from each other, are non-functional groups or functional groups containing --OH,which consists in subjecting said mixture of perfluoropolyoxyalkylenes to column chromatography using, as eluents, non-polar fluorinated solvents, either alone or in admixture with polar solvents.

3. 发明授权

US5476910A Thermoplastic polyesters containing perfluoropolyoxyalkylene sequence 失效
标题翻译：含全氟聚氧化烯序列的热塑性聚酯
公开(公告)号：US5476910A
公开(公告)日：1995-12-19
申请号：US228564
申请日：1994-04-15
申请人： Stefano Turri , Giuseppe Gianotti , Marinella Levi , Claudio Tonelli
发明人： Stefano Turri , Giuseppe Gianotti , Marinella Levi , Claudio Tonelli
IPC分类号： C08G63/66 , C08G63/672 , C08G63/682 , C08G65/32
CPC分类号： C08G63/6826 , C08G63/672
摘要： Fluorinated thermoplastic elastomers having a block structure:--[--R.sub.f --H.sub.1 --H.sub.2 --H.sub.1 --]--where --R.sub.f -- is a perfluoropolyoxyalkylene sequence of formula:--CF.sub.2 O--(CF.sub.2 CF.sub.2 O).sub.m --(CF.sub.2 O).sub.n --CF.sub.2 --with m/n=0.2.div.5, H.sub.1 and H.sub.2, equal or different from each other, are bivalent radicals having arylene, alkylarylene, alkylene or cycloalkylene structure, optionally containing fluorine and/or other heteroatoms selected among oxygen, sulphur, nitrogen. Such products are obtainable by utilizing a perfluoropolyoxyalkylene diol having a functionality at least equal to 1.97, preferably at least equal to 1.99, and are characterized by a tensile strength at 23.degree. C. at least 50% higher than that of the corresponding polyesters obtained starting from perfluoropolyoxyalkylene diols having a functionality not higher than 1.96.
摘要翻译：具有嵌段结构的氟化热塑性弹性体：其中-Rf-是式-CF 2 O-（CF 2 CF 2 O）m - （CF 2 O）n -CF 2的全氟聚氧化烯序列，其中m- n = 0.2分解5，彼此相同或不同的H1和H2是具有亚芳基，烷基亚芳基，亚烷基或亚环烷基结构的二价基团，任选地含有选自氧，硫，氮中的氟和/或其它杂原子。这样的产物可通过使用具有至少等于1.97，优选至少等于1.99的官能度的全氟聚氧亚烷基二醇获得，其特征在于在23℃下的拉伸强度比起始地获得的相应聚酯的拉伸强度高至少50％来自具有不高于1.96的官能度的全氟聚氧亚烷基二醇。

4. 发明授权

US5262057A Process for separating from one another the non-functional, monofunctional and bifunctional species contained in the perfluoropolyoxyalkylenes 失效
标题翻译：在全氟聚亚烷基中包含的非功能性单功能和双功能物质彼此分离的方法
公开(公告)号：US5262057A
公开(公告)日：1993-11-16
申请号：US962936
申请日：1992-10-19
申请人： Claudio Tonelli , Stefano Turri , Giuseppe Gianotti , Marinella Levi
发明人： Claudio Tonelli , Stefano Turri , Giuseppe Gianotti , Marinella Levi
IPC分类号： C08G65/30 , B01D15/08 , B01J20/283 , C08G65/00 , C08G65/02 , G01N30/02 , G01N30/26 , G01N30/88
CPC分类号： B01D15/08 , C08G65/007 , C08G65/30
摘要： A process for separating from one another non-functional, monofunctional and bifunctional species in a mixture of perfluoropolyoxyalkylenes of general formulaX--O--Rf--Ywhere:Rf=a perfluoropolyoxyalkylene chain comprising monomeric units of formulas (CF.sub.2 O), (CF.sub.2 CF.sub.2 O), (CF.sub.2 CF.sub.2 CF.sub.2 O),X, Y, like or different from each other, are non-functional end groups or end groups containing functions OH and/or NH.sub.2,which consists in subjecting said mixture of perfluoropolyoxyalkylenes to column chromatography using, as eluents, non-polar fluorinated solvents, either alone or in admixture with polar solvents.

5. 发明授权

US4230583A Supported anisotropic reverse osmosis membranes based on synthetic polyamides and processes for their preparation 失效
标题翻译：基于合成聚酰胺的支撑各向异性反渗透膜及其制备方法
公开(公告)号：US4230583A
公开(公告)日：1980-10-28
申请号：US951365
申请日：1978-10-16
申请人： Antonio Chiolle , Giuseppe Gianotti , Gianfranco Parrini
发明人： Antonio Chiolle , Giuseppe Gianotti , Gianfranco Parrini
IPC分类号： B01D71/38 , B01D69/10 , B01D71/40 , B01D71/44 , B01D71/56 , C08G69/26 , C08J3/16 , C08J5/18
CPC分类号： C08G69/26 , B01D69/10 , B01D71/56
摘要： Supported anisotropic reverse osmosis membrane based on synthetic polyamides are prepared by first preparing a support therefor for treating a material suited for serving as a support for a polyamide membrane, with a heat resistant water soluble polymer which is insoluble in the polar solvents to be used for preparing the polyamide solution described below; preparing a solution of the polyamide in an organic polar solvent, in the presence of a saline compound; spreading the thus prepared polyamide solution onto the prepared support; partially evaporating the solvent by heating; coagulating the membrane in an aqueous medium; and optionally, thermally treating the membrane.
摘要翻译：基于合成聚酰胺的支撑的各向异性反渗透膜通过首先制备用于处理适合用作聚酰胺膜的载体的材料的载体与通过极性溶剂不溶的耐热水溶性聚合物制备下述聚酰胺溶液; 在有机极性溶剂中，在盐水化合物的存在下制备聚酰胺的溶液; 将如此制备的聚酰胺溶液铺展到制备的载体上; 通过加热部分蒸发溶剂; 在水介质中凝结膜; 并任选地热处理膜。

6. 发明授权

US4713416A Thermoplastic compositions including polyphenylenether, having improved impact strength and processability characteristics 失效
标题翻译：热塑性组合物包括聚苯乙烯，具有改进的冲击强度和加工特性
公开(公告)号：US4713416A
公开(公告)日：1987-12-15
申请号：US671314
申请日：1984-11-14
申请人： Luciano Del Giudice , Roberto Nocci , Umberto Giannini , Giuseppe Gianotti
发明人： Luciano Del Giudice , Roberto Nocci , Umberto Giannini , Giuseppe Gianotti
IPC分类号： C08L23/02 , C08L7/00 , C08L21/00 , C08L23/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L51/06 , C08L53/00 , C08L67/00 , C08L69/00 , C08L71/00 , C08L71/12 , C08L77/00 , C08L101/00 , C08L61/04 , C08L71/04
CPC分类号： C08L71/123 , C08L67/00 , C08L69/00 , C08L71/00 , C08L77/00 , Y10S525/905
摘要： Thermoplastic compositions based on polyphenylenether resins, endowed with improved mechanical, thermal and solvent-resistance characteristics, comprising, for 100 parts by weight of polyphenylenether resin:(a) from 0 to 90 parts by weight of a thermoplastic polymer other than polystyrene and incompatible with the polyphenylenether resin, and(b) from 1 to 90 parts by weight of a polymeric compatibility-promoting agent comprising one or more blocks of vinylacromatic monomeric units compatible with the polyphenylenether resin, and one or more blocks of monomeric units of the same nature as the thermoplastic polymer (a), or compatible with that polymer.
摘要翻译：基于多苯基树脂的热塑性组合物具有改进的机械，耐热和耐溶剂性特征，包括：对于100重量份的聚苯基树脂：（a）0至90重量份的除聚苯乙烯以外的热塑性聚合物，所述多苯基树脂和（b）1至90重量份的包含与所述多苯基树脂相容的一个或多个乙烯基芳族单体单元的嵌段的聚合物相容性促进剂，以及一种或多种与热塑性聚合物（a），或与该聚合物相容。

7. 发明授权

US4560522A Process for preparing poly-piperazinamide anisotropic shaped articles 失效
标题翻译：制备聚哌嗪酰胺各向异性成型制品的方法
公开(公告)号：US4560522A
公开(公告)日：1985-12-24
申请号：US509655
申请日：1983-06-30
申请人： Catia Bastioli , Giuseppe Gianotti , Adriano Mattera , Paolo Parrini
发明人： Catia Bastioli , Giuseppe Gianotti , Adriano Mattera , Paolo Parrini
IPC分类号： B29D99/00 , B01D71/56 , B29B7/00 , B29C47/00 , B29C47/88 , B29C59/00 , B29C69/00 , C08J5/02 , C08J5/18 , C08J9/28 , D01D5/24 , D01F6/60 , D01F6/00
CPC分类号： B01D71/56 , D01D5/24
摘要： Process for preparing poly-piperazinamide, anisotropic shaped articles comprising the preparation of the polymer solution in a polar organic solvent, the transformation of the solution into shaped bodies by spreading or spinning, the gelation of the shaped articles by phase inversion, and, optionally, the heat treatment of the gellified shaped articles.
摘要翻译：制备聚哌嗪酰胺的方法，包括在极性有机溶剂中制备聚合物溶液的各向异性成型制品，通过铺展或纺丝将溶液转化成成形体，通过相转化将成型制品凝胶化，胶凝成型制品的热处理。

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