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1. 发明申请

WO2017140508A1 ALKOXYLATED PHENOL DERIVATIVES 审中-公开
标题翻译：烷氧基酚衍生物
公开(公告)号：WO2017140508A1
公开(公告)日：2017-08-24
申请号：PCT/EP2017/052241
申请日：2017-02-02
申请人： CLARIANT INTERNATIONAL LTD
发明人： COHRS, Carsten , DIEDERICHS, Jan , LEINWEBER, Dirk , MUTCH, James Kevin , ROMANSKI, Steffen , BATCHELOR, Stephen Norman , BIRD, Jayne Michelle
IPC分类号： C08G65/26 , C11D3/37 , C08G65/332 , C08G65/334 , C08G65/335 , C08G65/337
CPC分类号： C08G65/2612 , C08G65/3322 , C08G65/3344 , C08G65/3353 , C08G65/337 , C11D1/72
摘要： Alkoxylates are described that are obtainable by (i) in a first step reacting a) one or more compounds selected from the group consisting of phenols that are substituted with one substituent, wherein the one substituent is in the ortho-, meta- or para-position to the OH group of the phenol and is selected from the group consisting of OH, R8, OR8, F, CI, Br, I, CN, NO 2 or COOR9, wherein R8 is a linear or branched alkyl group with 1 to 4 C-atoms and R9 is a linear or branched alkyl group comprising 1 to 22 C-atoms or a linear or branched mono- or polyunsaturated alkenyl group comprising 2 to 22 C-atoms with b) an aryl-substituted linear or branched C 1 -C 3 alkyl alcohol or an aryl-substituted linear or branched C 2 - or C 3 -alkene, and (ii) in a second step alkoxylating the reaction product of the first step and (iii) in an optional third step reacting the reaction product of step (ii) with an alkylating agent providing a C 1 -C 4 alkyl group, with a carboxymethylating agent, with a sulfating agent, with a phosphating agent or with a sulfosuccinating agent. These alkoxylates may advantageously be used as anti-redeposition agents in laundry applications.
摘要翻译：描述了可通过以下方式获得的烷氧基化物：（i）在第一步中使a）一种或多种选自由一个取代基取代的苯酚组成的组的化合物反应，其中一个取代基在与苯酚的OH基团相邻，间位或对位，并且选自OH，R 8，OR 8，F，Cl，Br，I，CN，NO 2或 COOR9，其中R8是具有1至4个碳原子的直链或支链烷基，并且R9是包含1至22个碳原子的直链或支链烷基或包含2至22个碳原子的直链或支链单或多不饱和链烯基 - 原子与b）芳基取代的直链或支链C 1 -C 3烷基醇或芳基取代的直链或支链C 2 - （ii）在第二步中将第一步和（iii）的反应产物在任选的第三步中烷氧基化，使步骤（ii）的反应产物与烷化剂提供C < 用羧甲基化剂，与硫酸化剂，与磷酸化剂或与磺化琥珀酸化剂反应。这些烷氧基化物可以有利地用作洗衣应用中的抗再沉积剂。

2. 发明申请

WO2022228945A1 MIXTURE OF METHYL ESTER ETHOXYLATES 审中-公开
公开(公告)号：WO2022228945A1
公开(公告)日：2022-11-03
申请号：PCT/EP2022/060309
申请日：2022-04-19
申请人： CLARIANT INTERNATIONAL LTD
发明人： DIEDERICHS, Jan , GUO, Xiaoqiang , HALLIER, Peter Josef , HÖVELMANN, Felix , MUTCH, Kevin James , SCHAEFER, Carsten , BATCHELOR, Stephen Norman , BENNETT, Julie
IPC分类号： C11D1/74 , C11D11/00 , C11D3/00
摘要： Specific mixtures of methyl ester ethoxylates are described. The mixtures may be advantageously used as surfactants in laundry detergent compositions and preferably in liquid laundry detergent compositions.

3. 发明申请

WO2019007637A1 ALKOXYLATED POLYCARBOXYLIC ACID AMIDES 审中-公开
公开(公告)号：WO2019007637A1
公开(公告)日：2019-01-10
申请号：PCT/EP2018/065389
申请日：2018-06-11
申请人： CLARIANT INTERNATIONAL LTD
发明人： MUTCH, Kevin , SCHAEFER, Carsten , BREFFA, Catherine , DIEDERICHS, Jan , ROMANSKI, Steffen , BATCHELOR, Stephen Norman
IPC分类号： C08G69/00
摘要： Alkoxylated polycarboxylic acid amides are provided obtainable by first reacting an aromatic polycarboxylic acid containing at least three carboxylic acid units or anhydrides derived therefrom, preferably an aromatic polycarboxylic acid containing three or four carboxylic acid units or anhydrides derived therefrom, more preferably an aromatic polycarboxylic acid containing three carboxylic acid units or anhydrides derived therefrom, even more preferably trimellitic acid or trimellitic acid anhydride, most preferably trimellitic acid anhydride, with an amine alkoxylate and in a second step reacting the resulting product with an alcohol or amine or a mixture of alcohols and/or amines, preferably with an alcohol.

4. 发明申请

WO2017140510A1 ALKOXYLATED HYDROXYBENZOIC ACID ESTERS OR AMIDES 审中-公开
标题翻译：烷氧基羟基苯甲酸酯或酰胺
公开(公告)号：WO2017140510A1
公开(公告)日：2017-08-24
申请号：PCT/EP2017/052255
申请日：2017-02-02
申请人： CLARIANT INTERNATIONAL LTD
发明人： COHRS, Carsten , DIEDERICHS, Jan , LEINWEBER, Dirk , MUTCH, Kevin , ROMANSKI, Steffen , BATCHELOR, Stephen Norman , BIRD, Jayne Michelle
IPC分类号： C07C67/02 , C07C69/78
CPC分类号： C07C67/08 , C07C67/03 , C07C67/31 , C08G65/2612 , C07C69/84 , C07C69/92
摘要： Alkoxylates according to the following formula (I) are described, wherein X is selected from ethoxy and mixtures of ethoxy and propoxy groups, T is selected from the group consisting of H, C 1 -C 4 alkyl, SO 3 -, CH 2 -COO - , sulfosuccinate and PO 3 2- , R1, R2 and R4 are H, CO-NR8R3 or COO-[X 1 ] v -R3, whereby two of the substituents R1, R2 and R4 are H and the third of these substituents is CO-NR8R3 or COO-[X 1 ] v -R3, R8 is H or a linear or branched alkyl group with 1 to 4 C-atoms, R3 is a linear or branched saturated alkyl group with 6 to 30 carbon atoms, a linear or branched mono- or polyunsaturated alkenyl group with 6 to 30 carbon atoms, an aryl group with 6 to 10 carbon atoms, a group (CH 2 CH 2 O) m aryl, wherein the aryl group comprises 6 to 10 carbon atoms and m, on a molar average, is a number from 1 to 100, or an aryl-substituted linear or branched C 1 -C 3 alkyl group wherein the aryl group comprises 6 to 10 carbon atoms, but in the case, that R1 and R4 are H and R2 is COOR3, R3 can only be an alkyl group, an alkenyl group or a group (CH 2 CH 2 O) m aryl as defined above, X 1 is selected from ethoxy and mixtures of ethoxy and propoxy groups, u on a molar average, is a number of from 3 to 100, and v on a molar average, is a number of from 0 to 20. The compounds of formula (I) may advantageously be used as anti-redeposition agents in laundry applications.
摘要翻译：描述了根据下式（I）的烷氧基化物，其中X选自乙氧基和乙氧基和丙氧基的混合物，T选自H，C 1 -C 4烷基， C 4 -C 4 - 烷基，SO 3 - ，CH 2 -COO - ，磺基琥珀酸盐和PO 4 - R 1，R 2和R 4为H，CO-NR 8 R 3或COO- [X 1] n -V 2，其中取代基R 1，R 2和R 4中的两个是H并且这些取代基中的第三个是CO-NR 8 R 3或COO- [X 1] v -R 3， R 8为H或具有1至4个C原子的直链或支链烷基，R 3为具有6至30个碳原子的直链或支链饱和烷基，具有6至30个碳原子的直链或支链单或多不饱和烯基，具有6至10个碳原子的芳基，基团（CH 2 CH 2 O）m芳基，其中所述芳基包含6个至10个碳原子和m，平均摩尔数为1至100的数，或芳基取代的直链或支链C 1 -C 3烷基，其中芳基包含6至10个碳原子，但在这种情况下，R 1和R 4为H且R 2为COOR 3 R 3只能是如上所定义的烷基，烯基或基团（CH 2 CH 2 O）m芳基，X 1选自乙氧基和乙氧基和丙氧基的混合物，u平均摩尔数为3至100的数，且v在摩尔平均值上为0至20的数式（I）化合物可有利地用作洗衣应用中的抗再沉积剂。

5. 发明申请

WO2019007636A1 ALKOXYLATED POLYCARBOXYLIC ACID ESTERS 审中-公开
公开(公告)号：WO2019007636A1
公开(公告)日：2019-01-10
申请号：PCT/EP2018/065373
申请日：2018-06-11
申请人： CLARIANT INTERNATIONAL LTD
发明人： MUTCH, Kevin , ROMANSKI, Steffen , SCHAEFER, Carsten , BREFFA, Catherine , DIEDERICHS, Jan , BATCHELOR, Stephen Norman
IPC分类号： C08G63/00
摘要： Alkoxylated polycarboxylic acid esters are provided obtainable by first reacting an aromatic polycarboxylic acid containing at least three carboxylic acid units or anhydrides derived therefrom, preferably an aromatic polycarboxylic acid containing three or four carboxylic acid units or anhydrides derived therefrom, more preferably an aromatic polycarboxylic acid containing three carboxylic acid units or anhydrides derived therefrom, even more preferably trimellitic acid or trimellitic acid anhydride, most preferably trimellitic acid anhydride, with an alcohol alkoxylate and in a second step reacting the resulting product with an alcohol or a mixture of alcohols, preferably with an alcohol.

6. 发明公开

EP4015497A1 ALKOXYLATES PREPARED BY CALCIUM CATALYST 审中-公开
公开(公告)号：EP4015497A1
公开(公告)日：2022-06-22
申请号：EP20215421.7
申请日：2020-12-18
申请人： Clariant International Ltd
发明人： GUO, Xiaoqiang , LEINWEBER, Dirk , DIEDERICHS, Jan , HÖVELMANN, Felix , BATCHELOR, Stephen Norman , BENNETT, Julie
IPC分类号： C07C41/03 , C07C43/11 , C07C43/13 , C07C43/23 , C11D1/06 , C11D1/72
摘要： The present invention relates to a fatty alcohol alkoxylate surfactant, obtainable by reacting at least one fatty alcohol with ethylene oxide or a mixture of ethylene oxide and propylene oxide, wherein the reaction is conducted in the presence of a calcium catalyst. Furthermore, the present invention refers to a fatty alcohol alkoxylate surfactant comprising at least one fatty alcohol alkoxylate and at least one calcium salt. The present invention further refers to a method for preparing a fatty alcohol alkoxylate surfactant according to the invention and the use of a calcium catalyst for preparing such a fatty alcohol alkoxylate surfactant.

7. 发明公开

EP4330364A1 MIXTURE OF METHYL ESTER ETHOXYLATES 审中-实审
公开(公告)号：EP4330364A1
公开(公告)日：2024-03-06
申请号：EP22723431.7
申请日：2022-04-19
申请人： Clariant International Ltd
发明人： DIEDERICHS, Jan , GUO, Xiaoqiang , HALLIER, Peter Josef , HÖVELMANN, Felix , MUTCH, Kevin James , SCHAEFER, Carsten , BATCHELOR, Stephen Norman , BENNETT, Julie
IPC分类号： C11D1/74 , C11D11/00 , C11D3/00

8. 发明授权

EP3416938B1 ALKOXYLATED HYDROXYBENZOIC ACID ESTERS OR AMIDES 有权
公开(公告)号：EP3416938B1
公开(公告)日：2019-10-16
申请号：EP17702135.9
申请日：2017-02-02
申请人： Clariant International Ltd
发明人： COHRS, Carsten , DIEDERICHS, Jan , LEINWEBER, Dirk , MUTCH, Kevin , ROMANSKI, Steffen , BATCHELOR, Stephen Norman , BIRD, Jayne Michelle
IPC分类号： C07C67/03 , C07C67/08 , C07C67/31 , C08G65/26

9. 发明公开

EP3416938A1 ALKOXYLATED HYDROXYBENZOIC ACID ESTERS OR AMIDES 有权
公开(公告)号：EP3416938A1
公开(公告)日：2018-12-26
申请号：EP17702135.9
申请日：2017-02-02
申请人： Clariant International Ltd
发明人： COHRS, Carsten , DIEDERICHS, Jan , LEINWEBER, Dirk , MUTCH, Kevin , ROMANSKI, Steffen , BATCHELOR, Stephen Norman , BIRD, Jayne Michelle
IPC分类号： C07C67/02 , C07C69/78
摘要： Alkoxylates according to the following formula (I) are described, wherein X is selected from ethoxy and mixtures of ethoxy and propoxy groups, T is selected from the group consisting of H, C 1 -C 4 alkyl, SO 3 -, CH 2 -COO - , sulfosuccinate and PO 3 2- , R1, R2 and R4 are H, CO-NR8R3 or COO-[X 1 ] v -R3, whereby two of the substituents R1, R2 and R4 are H and the third of these substituents is CO-NR8R3 or COO-[X 1 ] v -R3, R8 is H or a linear or branched alkyl group with 1 to 4 C-atoms, R3 is a linear or branched saturated alkyl group with 6 to 30 carbon atoms, a linear or branched mono- or polyunsaturated alkenyl group with 6 to 30 carbon atoms, an aryl group with 6 to 10 carbon atoms, a group (CH 2 CH 2 O) m aryl, wherein the aryl group comprises 6 to 10 carbon atoms and m, on a molar average, is a number from 1 to 100, or an aryl-substituted linear or branched C 1 -C 3 alkyl group wherein the aryl group comprises 6 to 10 carbon atoms, but in the case, that R1 and R4 are H and R2 is COOR3, R3 can only be an alkyl group, an alkenyl group or a group (CH 2 CH 2 O) m aryl as defined above, X 1 is selected from ethoxy and mixtures of ethoxy and propoxy groups, u on a molar average, is a number of from 3 to 100, and v on a molar average, is a number of from 0 to 20. The compounds of formula (I) may advantageously be used as anti-redeposition agents in laundry applications.

10. 发明公开

EP3416999A1 ALKOXYLATED PHENOL DERIVATIVES 审中-公开
公开(公告)号：EP3416999A1
公开(公告)日：2018-12-26
申请号：EP17702132.6
申请日：2017-02-02
申请人： Clariant International Ltd
发明人： COHRS, Carsten , DIEDERICHS, Jan , LEINWEBER, Dirk , MUTCH, Kevin , ROMANSKI, Steffen , BATCHELOR, Stephen Norman , BIRD, Jayne Michelle
IPC分类号： C08G65/26 , C11D3/37 , C08G65/332 , C08G65/334 , C08G65/335 , C08G65/337
CPC分类号： C08G65/2612 , C08G65/3322 , C08G65/3344 , C08G65/3353 , C08G65/337 , C11D1/72
摘要： Alkoxylates are described that are obtainable by (i) in a first step reacting a) one or more compounds selected from the group consisting of phenols that are substituted with one substituent, wherein the one substituent is in the ortho-, meta- or para-position to the OH group of the phenol and is selected from the group consisting of OH, R8, OR8, F, Cl, Br, I, CN, NO 2 or COOR9, wherein R8 is a linear or branched alkyl group with 1 to 4 C-atoms and R9 is a linear or branched alkyl group comprising 1 to 22 C-atoms or a linear or branched mono- or polyunsaturated alkenyl group comprising 2 to 22 C-atoms with b) an aryl-substituted linear or branched C 1 -C 3 alkyl alcohol or an aryl-substituted linear or branched C 2 - or C 3 -alkene, and (ii) in a second step alkoxylating the reaction product of the first step and (iii) in an optional third step reacting the reaction product of step (ii) with an alkylating agent providing a C 1 -C 4 alkyl group, with a carboxymethylating agent, with a sulfating agent, with a phosphating agent or with a sulfosuccinating agent. These alkoxylates may advantageously be used as anti-redeposition agents in laundry applications.

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