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    • 9. 发明申请
    • ALKOXYLATED PHENOL DERIVATIVES
    • 烷氧基酚衍生物
    • WO2017140508A1
    • 2017-08-24
    • PCT/EP2017/052241
    • 2017-02-02
    • CLARIANT INTERNATIONAL LTD
    • COHRS, CarstenDIEDERICHS, JanLEINWEBER, DirkMUTCH, James KevinROMANSKI, SteffenBATCHELOR, Stephen NormanBIRD, Jayne Michelle
    • C08G65/26C11D3/37C08G65/332C08G65/334C08G65/335C08G65/337
    • C08G65/2612C08G65/3322C08G65/3344C08G65/3353C08G65/337C11D1/72
    • Alkoxylates are described that are obtainable by (i) in a first step reacting a) one or more compounds selected from the group consisting of phenols that are substituted with one substituent, wherein the one substituent is in the ortho-, meta- or para-position to the OH group of the phenol and is selected from the group consisting of OH, R8, OR8, F, CI, Br, I, CN, NO 2 or COOR9, wherein R8 is a linear or branched alkyl group with 1 to 4 C-atoms and R9 is a linear or branched alkyl group comprising 1 to 22 C-atoms or a linear or branched mono- or polyunsaturated alkenyl group comprising 2 to 22 C-atoms with b) an aryl-substituted linear or branched C 1 -C 3 alkyl alcohol or an aryl-substituted linear or branched C 2 - or C 3 -alkene, and (ii) in a second step alkoxylating the reaction product of the first step and (iii) in an optional third step reacting the reaction product of step (ii) with an alkylating agent providing a C 1 -C 4 alkyl group, with a carboxymethylating agent, with a sulfating agent, with a phosphating agent or with a sulfosuccinating agent. These alkoxylates may advantageously be used as anti-redeposition agents in laundry applications.
    • 描述了可通过以下方式获得的烷氧基化物:(i)在第一步中使a)一种或多种选自由一个取代基取代的苯酚组成的组的化合物反应,其中一个取代基在 与苯酚的OH基团相邻,间位或对位,并且选自OH,R 8,OR 8,F,Cl,Br,I,CN,NO 2或 COOR9,其中R8是具有1至4个碳原子的直链或支链烷基,并且R9是包含1至22个碳原子的直链或支链烷基或包含2至22个碳原子的直链或支链单或多不饱和链烯基 - 原子与b)芳基取代的直链或支链C 1 -C 3烷基醇或芳基取代的直链或支链C 2 - (ii)在第二步中将第一步和(iii)的反应产物在任选的第三步中烷氧基化,使步骤(ii)的反应产物与 烷化剂提供C < 用羧甲基化剂,与硫酸化剂,与磷酸化剂或与磺化琥珀酸化剂反应。 这些烷氧基化物可以有利地用作洗衣应用中的抗再沉积剂。