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1. 发明申请

WO2005116099A1 PERFLUORINATED ESTERS, POLYESTER, ETHERS AND CARBONATES 审中-公开
标题翻译：全脂酸酯，聚酯，乙二醇和碳酸酯
公开(公告)号：WO2005116099A1
公开(公告)日：2005-12-08
申请号：PCT/EP2005/052267
申请日：2005-05-18
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CIBA SPECIALTY CHEMICALS S.P.A. , LAZZARI, Dario , PERI, Francesca , BRUNNER, Martin , ZEDDA, Alessandro
发明人： LAZZARI, Dario , PERI, Francesca , BRUNNER, Martin , ZEDDA, Alessandro
IPC分类号： C08G18/00
CPC分类号： C08G63/6886 , C07C323/12 , C08G63/6826 , C08K5/372 , C09D167/00 , C14C9/00
摘要： The present instant invention relates to new compounds of the formula (I) wherein T is H or R; R is R 1 , -CO-R 2 , -CO-R 3 -COOH, -COO-R 4 or R 5 ; R 1 is independently Formula (II) or Formula (III); and to compositions comprising these novel compounds and natural, synthetic or semisynthetic material. Such compounds are useful as water and/or oil repellents.
摘要翻译：本发明涉及式（I）的新化合物，其中T是H或R; R是R 1，-CO-R 2，-CO-R 3 -COOH，-COO-R 4或R 5; R1独立地为式（II）或式（III）; 以及包含这些新化合物和天然，合成或半合成材料的组合物。这些化合物可用作水和/或拒油剂。

2. 发明申请

WO2005028402A2 ROMP WITH FLUORINATED GROUPS 审中-公开
标题翻译：带有荧光团的ROMP
公开(公告)号：WO2005028402A2
公开(公告)日：2005-03-31
申请号：PCT/EP2004/052190
申请日：2004-09-15
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , CIBA SPECIALTY CHEMICALS S.P.A. , LAZZARI, Dario , PICCINELLI, Piero , ZEDDA, Alessandro , PERI, Francesca , BRUNNER, Martin
发明人： LAZZARI, Dario , PICCINELLI, Piero , ZEDDA, Alessandro , PERI, Francesca , BRUNNER, Martin
IPC分类号： C07C
CPC分类号： C08G61/08
摘要： The instant invention relates to new metathesis oligomers which are substituted with fluorinated groups. Also disclosed is a polymerisable composition comprising a catalytically effective amount of a penta- or hexavalent ruthenium or osmium carbene catalyst, the process for preparing the metathesis oligomers by applying the reaction conditions of Ring Opening Metathesis Polymerisation (ROMP) to the polymerisable composition. These new methathesis oligomers are useful for increasing the oil and water repellency of organic materials.
摘要翻译：本发明涉及被氟化基团取代的新的复分解低聚物。还公开了一种可聚合组合物，其包含催化有效量的五价或六价钌或锇卡因催化剂，通过将开环复分解聚合（ROMP）的反应条件应用于可聚合组合物来制备复分解低聚物的方法。这些新的化合物低聚物可用于增加有机材料的防油和拒水性。

3. 发明公开

EP1749037A1 PERFLUORINATED ESTERS, POLYESTER, ETHERS AND CARBONATES 审中-公开
标题翻译：全氟辛酸酯，聚酯，凯撒
公开(公告)号：EP1749037A1
公开(公告)日：2007-02-07
申请号：EP05747200.3
申请日：2005-05-18
申请人： Ciba Specialty Chemicals Holding Inc. , Ciba Specialty Chemicals S.p.A.
发明人： LAZZARI, Dario , PERI, Francesca , BRUNNER, Martin , ZEDDA, Alessandro
IPC分类号： C08G18/00 , C08L67/00
CPC分类号： C08G63/6886 , C07C323/12 , C08G63/6826 , C08K5/372 , C09D167/00 , C14C9/00
摘要： The present instant invention relates to new compounds of the formula (I) wherein T is H or R; R is R1, -CO-R2, -CO-R3-COOH, -COO-R4 or R5; R1 is independently Formula (II) or Formula (III); and to compositions comprising these novel compounds and natural, synthetic or semisynthetic material. Such compounds are useful as water and/or oil repellents.

4. 发明公开

EP1680458A2 ROMP WITH FLUORINATED GROUPS 审中-公开
标题翻译： ROMP用氟化组
公开(公告)号：EP1680458A2
公开(公告)日：2006-07-19
申请号：EP04787146.2
申请日：2004-09-15
申请人： Ciba Specialty Chemicals Holding Inc. , Ciba Specialty Chemicals S.p.A.
发明人： LAZZARI, Dario , PICCINELLI, Piero , ZEDDA, Alessandro , PERI, Francesca , BRUNNER, Martin
IPC分类号： C08G61/08
CPC分类号： C08G61/08
摘要： The instant invention relates to new metathesis oligomers which are substituted with fluorinated groups. Also disclosed is a polymerisable composition comprising a catalytically effective amount of a penta- or hexavalent ruthenium or osmium carbene catalyst, the process for preparing the metathesis oligomers by applying the reaction conditions of Ring Opening Metathesis Polymerisation (ROMP) to the polymerisable composition. These new methathesis oligomers are useful for increasing the oil and water repellency of organic materials.

5. 发明申请

WO2005059006A1 FLUOROCARBON TERMINATED OLIGO- AND POLY-CARBONATES AS SURFACE MODIFIERS 审中-公开
标题翻译：作为表面改性剂的氟化硼封端的寡糖和多碳酸酯
公开(公告)号：WO2005059006A1
公开(公告)日：2005-06-30
申请号：PCT/EP2004/053331
申请日：2004-12-08
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BRUNNER, Martin , DESAI, Archana, Kishore , HINDALEKAR, Shrirang, Bhikaji , SAHASRABUDHE, Suhas, Dattatraya , SCHNEIDER, Armin , THANKI, Paragkumar, Nathalal , TINKL, Michael , ZEDDA, Alessandro , GERSTER, Michèle , BRAND, Fabien, Jean
发明人： BRUNNER, Martin , DESAI, Archana, Kishore , HINDALEKAR, Shrirang, Bhikaji , SAHASRABUDHE, Suhas, Dattatraya , SCHNEIDER, Armin , THANKI, Paragkumar, Nathalal , TINKL, Michael , ZEDDA, Alessandro , GERSTER, Michèle , BRAND, Fabien, Jean
IPC分类号： C08G64/14
CPC分类号： C08L23/12 , C08G64/10 , C08G64/14 , C08K5/005 , C08L67/00 , C08L69/00 , C08L2666/18
摘要： The instant invention relates to new compounds of the formula (I), wherein R o is (formula II), R 1 and R 2 are each independently of the other a fluorine containing group, R 3 and R 4 are each independently of the other hydrogen, a fluorine containing group, C 1 -C 12 alkyl, phenyl or (formula III), or R 3 and R 4, together with the carbon atom to which they are bonded, form a C 5 -C 8 -cycloalkylidene ring that is unsubstituted or substituted by from 1 to 3 C 1 -C 4 alkyl groups; R 5 , R 6 , R 7 and R 8 are each independently of the other hydrogen, C 1 -C 12 alkyl or C 3 -C 12 alkenyl, X 1 and X 2 are each independently of the other a direct bond or C 1 -C 12 alkylene, m is 1 to 10'000, and n is 0 to 10'000. These new compounds of the formula (I) are useful as reducers of surface energy for organic materials such as polycarbonates, polyesters or polyketones or their mixtures, blends or alloys. Polymers with such a reduced surface energy possess an "easy to clean", "self-cleaning" "antisoiling", "soil-release" "antigraffiti", "oil resistance", "solvent resistance", "chemical resistance", "self lubricating", "scratch resistance", "low moisture absorption" and "hydrophobic" surface.
摘要翻译：本发明涉及新的式（I）化合物，其中Ro为（式II），R 1和R 2各自独立地为含氟基团，R 3和R 4各自独立地为氢，含氟基团，C 1 -C 12烷基，苯基或（式III）或R 3和R 4与它们所键合的碳原子一起形成未被取代或被1至3个C 1 -C 4烷基取代的C 5 -C 8亚烷基环组; R 5，R 6，R 7和R 8各自独立地为另一个氢，C 1 -C 12烷基或C 3 -C 12链烯基，X 1和X 2各自独立地为直接键或C 1 -C 12亚烷基，m为1至10,000，并且n 是0到10'000。这些新的式（I）化合物可用作有机材料如聚碳酸酯，聚酯或聚酮或其混合物，共混物或合金的表面能的还原剂。具有这种表面能降低的聚合物具有“易清洁”，“自清洁”，“防污”，“释放”“防泼溅”，“耐油性”，“耐溶剂性”，“耐化学性” 润滑性“，”耐刮擦性“，”低吸湿性“和”疏水性“表面。

6. 发明申请

WO2007147847A2 REVERSIBLY THERMOCHROMIC COMPOSITIONS 审中-公开
标题翻译：可逆热敏成分
公开(公告)号：WO2007147847A2
公开(公告)日：2007-12-27
申请号：PCT/EP2007/056132
申请日：2007-06-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FISCHER, Walter , BASBAS, Abdel-Ilah , BRUNNER, Martin , BENZ, Rolf
发明人： FISCHER, Walter , BASBAS, Abdel-Ilah , BRUNNER, Martin , BENZ, Rolf
CPC分类号： C09B1/06 , C09B1/12
摘要： A reversible thermochromic system comprising a) a compound of the formula (IA) or a tautomer thereof or a compound of the formula (IB) or a tautomer thereof (IA) (IB) wherein R 1 is C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; phenyl, phenyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; or C 7 -C 12 phenylalkyl; R 2 is hydrogen or a group -SO 2 -R; R 3 and R 4 independently of one another are hydrogen, C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; phenyl, phenyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; or C 7 -C 12 phenylalkyl; and R is C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; phenyl, phenyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; or C 7 -C 12 phenylalkyl; and b) a compound containing a group of the formula (III).
摘要翻译：一种可逆热变色系统，其包含a）式（IA）化合物或其互变异构体或式（IB）的化合物或其互变异构体（IA）（IB），其中R 1为C C 1 -C 18烷基，C 2 -C 18链烯基，C 3 -C 18烷基，C 1 -C 12烷基， -C 12 - 环烷基，被1,2或3个C 1 -C 3烷基取代的C 3 -C 12环烷基 _{4 烷基; 苯基，被1,2或3个C 1 -C 4烷基取代的苯基; 或C 7 -C 12苯基烷基; R 2是氢或基团-SO 2 R; R 3和R 4彼此独立地是氢，C 1 -C 18烷基，C _{-C _{4 烷基; 苯基，被1,2或3个C 1 -C 4烷基取代的苯基; 或C 7 -C 12苯基烷基; 和b）含有式（III）的基团的化合物。}}}

7. 发明申请

WO2007147843A2 REVERSIBLY THERMOCHROMIC COMPOSITIONS 审中-公开
标题翻译：可逆的热变性组合物
公开(公告)号：WO2007147843A2
公开(公告)日：2007-12-27
申请号：PCT/EP2007/056127
申请日：2007-06-20
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , FISCHER, Walter , BASBAS, Abdel-Ilah , BRUNNER, Martin , BENZ, Rolf , VITALI, Manuele
发明人： FISCHER, Walter , BASBAS, Abdel-Ilah , BRUNNER, Martin , BENZ, Rolf , VITALI, Manuele
CPC分类号： C09B29/12 , B41M5/284 , C09B29/0003 , C09B29/103 , C09B31/062 , C09B31/068 , C09D11/50 , C09K9/02 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1059 , C09K2211/1425 , C09K2211/1433 , G01K11/16
摘要： A reversible thermochromic system comprising a) a compound of the formula (I) or a tautomer thereof (I) wherein R 1 is C 1 -C 18 alkyl, C 2 -C 18 alkenyl, C 3 -C 12 cycloalkyl, C 3 -C 12 cycloalkyl substituted by 1, 2 or 3 C 1 -C 4 alkyl; or C 7 -C 12 phenylalkyl; R 2 and R 3 are hydrogen or R 2 and R 3 together form a group -CH=CH-CH=CH-; and R 4 is hydrogen, -NO 2 , -SO 2 -R 1 or (4-nitrophenyl)azo; and b) a compound containing a group of the formula (II).
摘要翻译：一种可逆热变色系统，其包含a）式（I）化合物或其互变异构体（I），其中R 1是C 1 -C 18 - C 1 -C 6烷基，C 2 -C 18链烯基，C 3 -C 12环烷基，C 1 -C 12烷基，被1,2或3个C 1 -C 4烷基取代的3个-C 12环烷基; 或C 7 -C 12 - 苯基烷基; R 2和R 3是氢或R 2和R 3一起形成基团-CH = CH- CH = CH-; 和R 4是氢，-NO 2，-SO 2 -R 1或（4-硝基苯基）偶氮; 和b）含有式（II）的基团的化合物。

8. 发明申请

WO2006089851A1 FLUORINATED COMPOUNDS 审中-公开
标题翻译：氟化合物
公开(公告)号：WO2006089851A1
公开(公告)日：2006-08-31
申请号：PCT/EP2006/050935
申请日：2006-02-15
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , BRAND, Fabien Jean , BRUNNER, Martin , GERSTER, Michèle , LEGGIO, Andrew Joseph , TINKL, Michael
发明人： BRAND, Fabien Jean , BRUNNER, Martin , GERSTER, Michèle , LEGGIO, Andrew Joseph , TINKL, Michael
IPC分类号： C08K5/00
CPC分类号： C08K5/02
摘要： The invention describes a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least a compound of the formula (I) wherein Q is a direct bond (II), R 1 is C 1 -C 100 alkyl, C 2 -C 100 alkenyl, C 3 -C 12 cycloalkyl or C 3 -C 12 cycloalkyl substituted by 1 to 5 C 1 -C 4 alkyl; R 2 is a fluorine containing group, and R 3 and R 4 independently of each other are hydrogen or C 1 -C 4 alkyl. The compounds of the formula (I) are useful as reducers of surface energy for organic materials, for example, for increasing the oil and water repellency of organic materials.
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热或光诱导降解敏感的有机材料，和b）至少一种式（I）化合物，其中Q是直接键（II），R _{1是C 1 -C 12烷基，C 2 -C 20链烯基，C 由1至5个C 1取代的C 3 -C 12环烷基或C 3 -C 12 -C 12环烷基 -C _{4 烷基; R 2是含氟基团，R 3和R 4彼此独立地是氢或C 1 H 2 > -C _{4 烷基。式（I）的化合物可用作有机材料的表面能的还原剂，例如用于增加有机材料的防油和拒水性。}}}

9. 发明申请

WO2006021529A1 SURFACE MODIFIERS 审中-公开
标题翻译：表面改性剂
公开(公告)号：WO2006021529A1
公开(公告)日：2006-03-02
申请号：PCT/EP2005/053995
申请日：2005-08-15
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. , SCHNEIDER, Armin , ZEDDA, Alessandro , BRUNNER, Martin , GERSTER, Michèle
发明人： SCHNEIDER, Armin , ZEDDA, Alessandro , BRUNNER, Martin , GERSTER, Michèle
IPC分类号： C08K5/00 , C08K5/02 , C08K5/12 , C08K5/101
CPC分类号： C08K5/12 , C08K5/02 , C08L21/00
摘要： The invention describes a composition comprising a) an organic material which is susceptible to oxidative, thermal or light-induced degradation, and b) at least one melt additive of a compound of the formula (I) wherein the general symbols are as defined in claim 1. The compounds of the formula (I) are useful as reducers of surface energy for organic materials, for example, for increasing the oil and water repellency of organic materials.
摘要翻译：本发明描述了一种组合物，其包含a）对氧化，热或光诱导降解敏感的有机材料，和b）至少一种式（I）化合物的熔融添加剂，其中通式如权利要求中所定义式（I）的化合物可用作有机材料的表面能的还原剂，例如用于增加有机材料的防油和拒水性。

10. 发明公开

EP1697440A1 FLUOROCARBON TERMINATED OLIGO- AND POLY-CARBONATES AS SURFACE MODIFIERS 有权
标题翻译： FLUOR烃TERMINATED低聚糖和聚碳酸酯AS表面改性剂
公开(公告)号：EP1697440A1
公开(公告)日：2006-09-06
申请号：EP04817567.3
申请日：2004-12-08
申请人： CIBA SPECIALTY CHEMICALS HOLDING INC. Patent Departement
发明人： BRUNNER, Martin , DESAI, Archana K., Plot 63, B-6, Premier Society , HINDALEKAR, Shrirang, Bhikaji, 9/55, B.D.D. Colony , SAHASRABUDHE, Suhas, D., 8, Om Abhiram Society , SCHNEIDER, Armin , THANKI, P., N., A-302, Shri Panchamrut HC Society , TINKL, Michael , ZEDDA, Alessandro , GERSTER, Michèle , BRAND, Fabien, Jean
IPC分类号： C08G64/14 , C08G64/10
CPC分类号： C08L23/12 , C08G64/10 , C08G64/14 , C08K5/005 , C08L67/00 , C08L69/00 , C08L2666/18
摘要： The instant invention relates to new compounds of the formula (I), wherein Ro is (formula II), R1 and R2 are each independently of the other a fluorine containing group, R3 and R4 are each independently of the other hydrogen, a fluorine containing group, C1-C12alkyl, phenyl or (formula III), or R3 and R4, together with the carbon atom to which they are bonded, form a C5-C8-cycloalkylidene ring that is unsubstituted or substituted by from 1 to 3 C1-C4alkyl groups; R5, R6, R7 and R8 are each independently of the other hydrogen, C1-C12alkyl or C3-C12alkenyl, X1 and X2 are each independently of the other a direct bond or C1-C12alkylene, m is 1 to 10'000, and n is 0 to 10'000. These new compounds of the formula (I) are useful as reducers of surface energy for organic materials such as polycarbonates, polyesters or polyketones or their mixtures, blends or alloys. Polymers with such a reduced surface energy possess an 'easy to clean', 'self-cleaning' 'antisoiling', 'soil-release' 'antigraffiti', 'oil resistance', 'solvent resistance', 'chemical resistance', 'self lubricating', 'scratch resistance', 'low moisture absorption' and 'hydrophobic' surface.

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