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1. 发明授权

US06890706B2 Process for removing stain in a photographic material 失效
标题翻译：去除摄影材料污点的方法
公开(公告)号：US06890706B2
公开(公告)日：2005-05-10
申请号：US10301226
申请日：2002-11-20
申请人： Christophe Bulliard , Georges Metzger , Sonia Megert
发明人： Christophe Bulliard , Georges Metzger , Sonia Megert
IPC分类号： G03C7/00 , C07D251/68 , G03C1/775 , G03C1/79 , G03C1/815 , G03C5/305 , G03C7/30 , G03C7/407 , G03C7/413 , G03C7/42 , G03C11/00
CPC分类号： G03C7/413 , G03C1/775 , G03C1/815 , G03C1/8155 , G03C5/305 , G03C7/421 , Y10S430/134
摘要： A process for removing stain in a photographic material is described which process comprises incorporation of at least one compound of the formula (I) wherein X is O or NH; n is 1 or 2, p is 0, 1 or 2, M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an aminoacid residue from which a hydrogen atom on the amino group has been removed; each R2, independently, is hydrogen, C1-C8alkyl, C1-C8alkoxy, halogen, cyano, COOR, wherein R is hydrogen or C1-C3alkyl, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, or SO3M, wherein M has its previous significance, or, if n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl, in that photographic material.
摘要翻译：描述了去除照相材料中污点的方法，该方法包括加入至少一种其中X为O或NH的式（I）化合物; n为1或2，p为0,1或2，M为氢，由胺形成的碱金属原子，铵或阳离子; 每个R 1独立地是氨基上的氢原子被除去的氨基酸残基; 每个R 2独立地是氢，C 1 -C 8烷基，C 1 -C 3 烷氧基，卤素，氰基，COOR，其中R是氢或C 1 -C 3烷基，其中R具有其先前含义的CONH-R ，其中R具有其先前含义的SO 2 NH-R，其中R具有其先前含义的NH-COR，或其中M具有其先前的含义，或者如果n是1，R 2也可以是其中R 3是C 1 H 2的CO-R 3，在这种照相材料中，C 1 -C 3烷基或苯基。

2. 发明授权

US06506545B1 Process for the removing stain in a photographic material 失效
标题翻译：去除照相材料污点的方法
公开(公告)号：US06506545B1
公开(公告)日：2003-01-14
申请号：US09936371
申请日：2001-09-13
申请人： Christophe Bulliard , Georges Metzger , Sonia Megert
发明人： Christophe Bulliard , Georges Metzger , Sonia Megert
IPC分类号： G03C556
CPC分类号： G03C7/413 , G03C1/775 , G03C1/815 , G03C1/8155 , G03C5/305 , G03C7/421 , Y10S430/134
摘要： A process for removing stain in a photographic material is described which process comprises incorporation of at least one compound of formula (I) wherein X is O or NH; n is 1 or 2, p is 0, 1 or 2, M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine; each R1, independently, is an amimoacid residue from which a hydrogen atom on the amino group has been removed; each R2, independendy, is hydrogen, C1-C8alkyl, C1-C8alkoxy, halogen, cyano, COOR, wherein R is hydrogen or C1-C3alky1, CONH—R in which R has its previous significance, SO2NH—R in which R has its previous significance, NH—COR in which R has its previous significance, or SO3M, wherein M has its previous significance, or, if n is 1, R2 can also be CO—R3 in which R3 is C1-C3alkyl or phenyl, in that photographic material.
摘要翻译：描述了一种去除照相材料中染色的方法，该方法包括加入至少一种其中X为O或NH的式（I）化合物; n为1或2，p为0,1或2，M为氢，由胺形成的碱金属原子，铵或阳离子; 每个R 1独立地是氨基上的氢原子被除去的氨基酸残基; 每个R 2独立地是氢，C 1 -C 8烷基，C 1 -C 8烷氧基，卤素，氰基，COOR，其中R是氢或C 1 -C 3烷基，其中R具有其先前含义的CONH-R，其中R具有其以前的意义，其中R具有其先前意义的NH-COR或其中M具有其先前含义的SO 3 M，或者如果n是1，则R2也可以是其中R 3是C 1 -C 3烷基或苯基的CO-R 3，其中照相材料。

3. 发明授权

US07087753B2 Naphthyltriazines as stabilizers for organic material 有权
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US07087753B2
公开(公告)日：2006-08-08
申请号：US11098640
申请日：2005-04-04
申请人： Vien Van Toan , Georges Metzger , Thomas Schäfer , Stéphane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Van Toan , Georges Metzger , Thomas Schäfer , Stéphane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： C07D251/24 , A61K7/42 , G03C1/005
CPC分类号： C07D251/24
摘要： Novel compounds of formula I are described wherein E corresponds to the formula or to the formula and the radicals R1, R2, R11, R22, R′22, R′33 and R′33 are as defined in claim 1. Compounds of formula I are suitable for stabilizing organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式I化合物，其中E对应于式或式，基团R 1，R 2，R 11， R 22，R 22，R 33和R 33如权利要求1中所定义。式I化合物适用于稳定有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，以防止光，氧和/或热的损害。

4. 发明授权

US06723846B1 Triazinylaminostilbene derivative as fluorescent whitening agents 失效
标题翻译：三嗪基氨基芪衍生物作为荧光增白剂
公开(公告)号：US06723846B1
公开(公告)日：2004-04-20
申请号：US10070525
申请日：2002-03-06
申请人： Georges Metzger , Serge Hauger , Fabienne Cuesta , Christophe Bulliard , Peter Rohringer , Marc Roger Grienenberger
发明人： Georges Metzger , Serge Hauger , Fabienne Cuesta , Christophe Bulliard , Peter Rohringer , Marc Roger Grienenberger
IPC分类号： C07D25168
CPC分类号： C07D251/68 , Y10S8/919
摘要： The present invention relates to compounds having formula (1): wherein each R1 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, —OCOM, —OCOC1-C4-alkyl, or an amino acid residue from which a hydrogen atom on the amino group has been removed; each R2 represents, independently, a linear C1-C4-alkylene residue which is unsubstituted or substituted by hydroxy, C1-C4-alkyl, C1-C4-alkoxy, C1-C4-hydroxy- or alkoxy-alkoxy, —OCOM, —OCOC1-C4-alkyl, —CO2M, CO2C1-C4-alkyl SO3M or phenoxy which is unsubstituted or substituted by halogen, C1-C4-alkyl or C1-C4-alkoxy, —CO2M or CO2C1-C4-alkyl, NH3 or mono- or disubstituted amino; or phenyl which is unsubstituted or substituted by 1 to 3 SO3M, SO2NHC1-C4-alkyl, —SO2NH2, —CO2M, —CO2M, —CO2C1-C4-alkyl, —CONH2, —CONHC1-C4-alkyl, —NHCOC1-C4-alkyl or mono- or disubstituted amino groups; each R3 represents independently, hydrogen, C1-C4-alkyl, halogen, cyano, SO3M, —SO2NH2, SO2NHC1-C4-alkyl, —CO2M, —CO2C1-C4-alkyl, —CONH2, —CONHC1-C4-alkyl, or —NHCOC1-C4-alkyl; M is hydrogen, an alkali metal atom, ammonium or a cation formed from an amine and m is an integer of 1 to 3, a process for their preparation and use of the compounds as optical brightening agents for synthetic or natural organic materials or for removing stain in photographic materials.
摘要翻译：本发明涉及具有式（1）的化合物：其中每个R 1独立地表示未被取代或被羟基，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4烷基取代的直链C 1 -C 4亚烷基 - 羟基 - 或烷氧基 - 烷氧基，-OCOM，-OCOC1-C4-烷基或氨基上氨基的氢原子被除去的氨基酸残基; 每个R 2独立地表示未被取代或被羟基，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 羟基 - 或烷氧基 - 烷氧基取代的直链C 1 -C 4 - 亚烷基残基，-OCOM，-OCOC 1 -C 1-4烷基，-CO 2 M，CO 2 C 1 -C 4 - 烷基SO 3 M或苯氧基，其未被取代或被卤素，C 1 -C 4 - 烷基或C 1 -C 4 - 烷氧基，-CO 2 M或CO 2 C 1 -C 4烷基，NH 3或单 - 或二取代氨基; 或未被取代或被1至3个SO 3 M，SO 2 NHC 1 -C 4烷基，-SO 2 NH 2，-CO 2 M，-CO 2 M，-CO 2 C 1 -C 4 - 烷基，-CONH 2，-CONHC 1 -C 4烷基，-NHCOC 1 -C 4 - 烷基或单或二取代的氨基; 每个R 3独立地表示氢，C 1 -C 4 - 烷基，卤素，氰基，SO 3 M，-SO 2 NH 2，SO 2 NHC 1 -C 4烷基，-CO 2 M，

5. 发明申请

US20050169859A1 Naphthyltriazines as stabilizers for organic material 有权
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US20050169859A1
公开(公告)日：2005-08-04
申请号：US11098640
申请日：2005-04-04
申请人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/00 , A61Q19/00 , C07D251/24 , C09K15/30 , A61K7/42 , C07D251/48 , G03C1/005 , G03C1/494
CPC分类号： C07D251/24
摘要： Novel compounds of formula I are described wherein E corresponds to the formula or to the formula and the radicals R1, R2, R11, R22, R′22, R′33 and R′33 are as defined in claim 1. Compounds of formula I are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式I化合物，其中E对应于式或式，基团R 1，R 2，R 11， R 22，R 22，R 33a和R 33如权利要求1中所定义。式I化合物适用于稳定化有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，防止光，氧和/或热的损害。

6. 发明申请

US20050038245A1 Naphthyltriazines as stabilizers for organic material 审中-公开
标题翻译：萘基三嗪作为有机材料的稳定剂
公开(公告)号：US20050038245A1
公开(公告)日：2005-02-17
申请号：US10492721
申请日：2002-10-10
申请人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
发明人： Vien Toan , Georges Metzger , Thomas Schafer , Stephane Biry , Christophe Bulliard , Dieter Reinehr , Peter Michaelis
IPC分类号： A61K8/00 , A61K8/49 , A61Q5/00 , A61Q19/00 , C07D251/24 , C09K15/30 , A61K7/42 , C07D251/48
CPC分类号： C07D251/24
摘要： Novel compounds of formula (I) are described, wherein E corresponds to the formula (a) or to the formula (b) and the radicals R1, R2, R11, R22, R′22, R33, and R′33 are as defined in claim 1. Compounds of formula (I) are suitable for stabilising organic material, especially plastics materials, surface-coatings, cosmetic preparations, sun protection agents or photographic material, against damage by light, oxygen and/or heat.
摘要翻译：描述了新的式（I）化合物，其中E对应于式（a）或式（b），基团R 1，R 2，R 11，R 22，R 22，R 33和R 33如上定义式（I）化合物适于稳定有机材料，特别是塑料材料，表面涂层，化妆品制剂，防晒剂或照相材料，以防止光，氧和/或热的损害。

7. 发明申请

US20070274933A1 Amino- and hydroxysubstituted triphenyl-S-triazines as stabilizers 失效
公开(公告)号：US20070274933A1
公开(公告)日：2007-11-29
申请号：US11891554
申请日：2007-08-10
申请人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
发明人： Dieter Reinehr , Georges Metzger , Peter Michaelis , Helmut Luther
IPC分类号： A61K31/785 , A61K47/22 , A61K8/00 , A61Q17/04
CPC分类号： A61K8/4966 , A61K31/785 , A61K2800/52 , A61Q17/04 , C07D251/24 , C07D265/22 , Y10S514/972
摘要： The present invention provides compounds having the formula: in which R is hydrogen, hydroxy, halogen, C1-C20-alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy or C7-C13aralkyl; R1 and R2, independently, are hydrogen, C1-C20alkyl, C4-C12cycloalkyl, C7-C13 aralkyl, —C(═O)—R4 (in which R4 is C1-C20alkyl, C2-C20alkyl interrupted by 1 to 6 oxygen atoms, hetero-substituted C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, C6-C12 aryl, C6-C12 aryloxy or C7-C13 aralkyl), or —C(═O)—NH—R1 in which R1 has its previous significance; and R3 is hydrogen, halogen, hydroxy, C1-C20alkyl, C4-C12cycloalkyl, C2-C20alkenyl, C2-C20alkynyl, C1-C20-alkoxy, C4-C12cycloalkoxy, C2-C20alkenoxy, C2-C20alkynoxy, phenyl, C7-C13 aralkyl or —N(R1)(R2) in which R1 and R2 have their previous significance, or R1 and R2 together form a C4-C12 membered ring. The new triphenyltriazine compounds have improved absorption spectrum characteristics and superior resistance to exposure to UV light, relative to known triphenyltriazine compounds.

8. 发明授权

US06919454B2 Biphenyl-substituted triazines 失效
标题翻译：联苯取代三嗪
公开(公告)号：US06919454B2
公开(公告)日：2005-07-19
申请号：US10921282
申请日：2004-08-18
申请人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
发明人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
IPC分类号： C07D251/10 , C07D251/24 , C07D405/04 , C08K5/3435 , C08K5/3475 , C08K5/3492 , C08K5/34
CPC分类号： C07D405/04 , A61K8/4966 , A61Q17/04 , C07D251/10 , C07D251/24 , C08K5/3435 , C08K5/3475 , C08K5/3492
摘要： Biphenyl-substituted triazines of the formula which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
摘要翻译：用于高热稳定性的联苯取代三嗪作为有机聚合物的稳定剂用作抗光，氧和热引起的损伤，作为纺织纤维材料的光稳定剂和用作人体皮肤的防晒剂。

9. 发明申请

US20050019281A1 Biphenyl-substituted triazines 失效
标题翻译：联苯取代三嗪
公开(公告)号：US20050019281A1
公开(公告)日：2005-01-27
申请号：US10921282
申请日：2004-08-18
申请人： Ian Fletcher , Jurgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
发明人： Ian Fletcher , Jurgen Kaschig , Georges Metzger , Dieter Reinehr , Pascal Hayoz
IPC分类号： C07D251/10 , C07D251/24 , C07D405/04 , C08K5/3435 , C08K5/3475 , C08K5/3492 , A61K7/42 , C07D413/14
CPC分类号： C07D405/04 , A61K8/4966 , A61Q17/04 , C07D251/10 , C07D251/24 , C08K5/3435 , C08K5/3475 , C08K5/3492
摘要： Biphenyl-substituted triazines of the formulae which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
摘要翻译：用于高热稳定性的配方的联苯取代三嗪作为有机聚合物的稳定剂用作抗光，氧和热引起的损伤，作为纺织纤维材料的光稳定剂和用于人体皮肤的防晒剂。

10. 发明授权

US06841670B2 Biphenyl-substituted triazines 失效
标题翻译：联苯取代三嗪
公开(公告)号：US06841670B2
公开(公告)日：2005-01-11
申请号：US10209440
申请日：2002-07-31
申请人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr
发明人： Ian John Fletcher , Jürgen Kaschig , Georges Metzger , Dieter Reinehr
IPC分类号： C07D251/10 , C07D251/24 , C07D405/04 , C08K5/3435 , C08K5/3475 , C08K5/3492
CPC分类号： C07D405/04 , A61K8/4966 , A61Q17/04 , C07D251/10 , C07D251/24 , C08K5/3435 , C08K5/3475 , C08K5/3492
摘要： Biphenyl-substituted triazines of the formulae which are notable for high thermal stability, are used as stabilizers for organic polymers to counter damage thereto caused by light, oxygen and heat, as light stabilizers for textile fiber materials and as sunscreens for the human skin.
摘要翻译：用于高热稳定性的配方的联苯取代三嗪作为有机聚合物的稳定剂用作抗光，氧和热引起的损伤，作为纺织纤维材料的光稳定剂和用作人体皮肤的防晒剂。

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