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1. 发明授权

US06380342B2 Aqueous coating compositions, their preparation and use in stoving lacquers 有权
标题翻译：水性涂料组合物，它们的制备和用于烘烤漆
公开(公告)号：US06380342B2
公开(公告)日：2002-04-30
申请号：US09371822
申请日：1999-08-11
申请人： Christoph Irle , Harald Blum , Joachim Petzoldt , Heino Müller
发明人： Christoph Irle , Harald Blum , Joachim Petzoldt , Heino Müller
IPC分类号： C08G1862
CPC分类号： C09D175/06 , C08F283/006 , C08F283/01 , C08G18/631 , C08G18/8077 , C09D167/06 , C09D175/04 , Y10T428/31551 , C08F220/10 , C08F4/28 , C08L33/00 , C08L2666/28
摘要： The present invention relates to an aqueous dispersion containing A) a polyol component containing A1) 20 to 60 wt. %, based on the resin solids content of polyol component A), of a polyester resin containing 10 to 60 wt. %, based on the weight of the polyester resin, of one or more aliphatic, saturated or unsaturated monocarboxylic acids having 8 to 30 carbon atoms, and 0.4 to 5 wt. % of one or more radically polymerizable &agr;,&bgr;-unsaturated mono- or di-carboxylic acids having 3 to 8 carbon atoms, or their anhydrides, and A2) 40 to 80 wt. %, based on the resin solids content of polyol component A), of a polyacrylate, which is prepared in the presence of component A1), and B) 1 to 70 wt. %, based on the resin solids content of the aqueous dispersion, of one or more blocked polyisocyanates.
摘要翻译：本发明涉及含有A）多元醇成分的水性分散体，其含有：A1〜20重量％％，基于多元醇组分A）的树脂固体含量，含有10至60wt。基于聚酯树脂的重量，具有8至30个碳原子的一种或多种脂族，饱和或不饱和一元羧酸和0.4至5重量％％的具有3至8个碳原子的一种或多种可自由基聚合的α，β-不饱和单羧酸或其酸酐，和A2）40至80重量％基于在组分A1）存在下制备的聚丙烯酸酯的多元醇组分A）的树脂固体含量％，和B）1-70重量％％，基于水性分散体的树脂固体含量，一种或多种封端的多异氰酸酯。

2. 发明授权

US06903156B2 Strippable coating compositions 失效
标题翻译：可剥离涂料组合物
公开(公告)号：US06903156B2
公开(公告)日：2005-06-07
申请号：US09799238
申请日：2001-03-05
申请人： Hanns-Peter Müller , Horst Gruttmann , Joachim Petzoldt , Heino Müller , Christoph Irle
发明人： Hanns-Peter Müller , Horst Gruttmann , Joachim Petzoldt , Heino Müller , Christoph Irle
IPC分类号： C08F283/00 , C08G18/08 , C08G18/12 , C08G18/66 , C09D5/00 , C09D5/20 , C09D157/00 , C09D175/04 , C08L51/00
CPC分类号： C08G18/12 , C08F283/006 , C08G18/0823 , C08G18/6659 , C09D5/20 , C09D175/04 , C08G18/3234 , C08L33/00
摘要： The present invention relates to light fast, aqueous, strippable coating compositions containing A) 40 to 90 wt. %, based on resin solids of A) and B), of aqueous polyurethane-polyureas and B) 10 to 60 wt. %, based on resin solids of A) and B), of polymers prepared from radically polymerizable monomers,wherein the percentages of A) and B) add up to 100, based on the weight of resin solids of A) and B). The present invention relates also to substrates coated with these strippable coating compositions. In addition, the present invention relates to the use of the stripped coatings as recycled material by mechanically comminuting the stripped coatings, optionally after cleaning, and then either pressing them in heatable presses to form sheets, or extruding them in an extruder to form endless thermoplastic threads, and then processing the resulting threads by known granulating methods to form cylindrical, spherical, lenticular or rhombic granules. Finally, the present invention relates to the use of the resulting thermoplastic granules for the production of articles by known processes such as injection molding, blow molding, deep-drawing, slush molding or flat extrusion.
摘要翻译：本发明涉及一种轻质，含水，可剥离的涂料组合物，其含有A）40-90wt。％，基于A）和B）的树脂固体，水性聚氨酯 - 聚脲和B）10至60wt。基于A）和B）的树脂固体，由可自由基聚合的单体制备的聚合物，其中A）和B）的百分比基于A）和B）的树脂固体的重量加到100上。本发明还涉及涂覆有这些可剥离涂料组合物的基材。此外，本发明涉及剥离的涂层作为再循环材料的用途，通过机械粉碎剥离的涂层，任选地在清洁之后，然后在可加热的压力机中压制以形成片材，或者在挤出机中挤出以形成环形热塑性塑料螺纹，然后通过已知的造粒方法处理所得螺纹以形成圆柱形，球形，透镜状或菱形颗粒。最后，本发明涉及所得到的热塑性颗粒用于通过已知方法如注射成型，吹塑，深冲，搪塑或扁平挤出生产制品的用途。

3. 发明授权

US06831126B2 Emulsion polymers and their use as peelable coatings 有权
标题翻译：乳液聚合物及其作为可剥离涂料的用途
公开(公告)号：US06831126B2
公开(公告)日：2004-12-14
申请号：US10289806
申请日：2002-11-07
申请人： Rolf Gertzmann , Joachim Petzoldt , Heino Müller , Christoph Irle
发明人： Rolf Gertzmann , Joachim Petzoldt , Heino Müller , Christoph Irle
IPC分类号： C08L7506
CPC分类号： C09D5/20 , C08L33/06 , C09D133/06 , C08L2666/02
摘要： The present invention relates to aqueous coating compositions containing A) at least one aqueous emulsion polymer, B) one or more polymer dispersions as a dispersion medium, C) at least one pigment, D) optionally a neutralizing agent and E) optionally a coatings additive. The present invention also relates to a process for preparing these aqueous coating compositions by preparing a dispersion paste by mixing components B), C) and D) with some of component E) and then component A) and the remainder of component E) are homogeneously blended with the dispersion paste. The present invention further relates to peelable coatings prepared from these coating compositions for the temporary protection of surfaces.
摘要翻译：本发明涉及含有A）至少一种水性乳液聚合物的水性涂料组合物，B）作为分散介质的一种或多种聚合物分散体，C）至少一种颜料，D）任选的中和剂，和E）任选的涂料添加剂。本发明还涉及一种制备这些水性涂料组合物的方法，其通过将组分B），C）和D）与组分E）中的一些混合制备分散糊，然后将组分A）和组分E）的其余部分均匀混合本发明还涉及由这些用于临时保护表面的涂料组合物制备的可剥离涂层。

4. 发明授权

US6139918A Process for preparing physically drying coatings from aqueous dispersions 失效
标题翻译：从水分散体制备物理干燥涂层的方法
公开(公告)号：US6139918A
公开(公告)日：2000-10-31
申请号：US368709
申请日：1999-08-05
申请人： Christoph Irle , Harald Blum , Joachim Petzoldt , Heino Muller
发明人： Christoph Irle , Harald Blum , Joachim Petzoldt , Heino Muller
IPC分类号： B05D7/14 , C08F283/00 , C08F283/01 , C08G18/63 , C08G18/68 , C08G18/80 , C08L5/02 , C08L75/14 , C09D161/28 , C09D167/00 , C09D167/06 , C09D175/04 , C09D175/06 , B05D3/02
CPC分类号： C09D175/06 , C08F283/006 , C08F283/01 , C08G18/631 , C08G18/8077 , C09D167/06 , C09D175/04
摘要： The present invention relates to a process for preparing a coated substrate by coating the substrate with an aqueous dispersion, which may be physically cured to form a light stable, elastic coating, containingA) a polyol component containingA1) 20 to 60 wt. %, based on the resin solids content of polyol component A), of a polyester resin containing 10 to 60 wt. %, based on the weight of the polyester resin, of one or more aliphatic, saturated or unsaturated monocarboxylic acids having 8 to 30 carbon atoms, and 0.4 to 5 wt. %, based on the weight of the polyester resin, of one or more radically polymerizable .alpha.,.beta.-unsaturated mono- or di-carboxylic acids having 3 to 8 carbon atoms, or their anhydrides, andA2) 40 to 80 wt. %, based on the resin solids content of polyol component A), of a polyacrylate, which is prepared in the presence of component A1), andB) 1 to 70 wt. %, based on the resin solids content of the aqueous dispersion, of one or more blocked polyisocyanates,and physically curing the dispersion to form a coating.
摘要翻译：本发明涉及一种通过用水分散体涂覆基材来制备涂布的基材的方法，该水性分散体可以物理固化以形成光稳定的弹性涂层，其包含A）含有Al）20至60wt。％，基于多元醇组分A）的树脂固体含量，含有10至60wt。基于聚酯树脂的重量，具有8至30个碳原子的一种或多种脂族，饱和或不饱和一元羧酸和0.4至5重量％基于聚酯树脂的重量，具有3至8个碳原子的一种或多种可自由基聚合的α，β-不饱和一元或二元羧酸或其酸酐，和A2）40至80重量％基于在组分A1）存在下制备的聚丙烯酸酯的多元醇组分A）的树脂固体含量％，和B）1-70重量％％，基于水性分散体的树脂固体含量，一种或多种封端的多异氰酸酯，并物理固化分散体以形成涂层。

5. 发明授权

US06610779B1 Aqueous barrier layer based on polyurethane dispersions 失效
标题翻译：基于聚氨酯分散体的水性阻隔层
公开(公告)号：US06610779B1
公开(公告)日：2003-08-26
申请号：US09914169
申请日：2001-08-24
申请人： Harald Blum , Jürgen Meixner , Heino Müller , Joachim Petzoldt
发明人： Harald Blum , Jürgen Meixner , Heino Müller , Joachim Petzoldt
IPC分类号： C08J300
CPC分类号： C08G18/12 , C08G18/0823 , C08G18/44 , C08G18/6659 , C09D175/06 , C08G18/302 , C08L2666/16
摘要： The present invention relates to aqueous polyurethane dispersions wherein the polyurethanes are reaction products of A) at least difunctional polyols having a molecular weight of 500 to 6000, B) at least difunctional low molecular weight alcohols, C) di- and/or trifunctional isocyanates and D) compounds with an acid group and one or two hydroxy- and/or primary or secondary amino groups in an amount sufficient to provide an acid number, based on resin solids, of
摘要翻译：本发明涉及水性聚氨酯分散体，其中聚氨酯是A）至少分子量为500至6000的双官能多元醇的反应产物，B）至少二官能的低分子量醇，C）二官能和/或三官能异氰酸酯和D）具有酸基和一个或两个羟基和/或伯或仲氨基的化合物，其量足以提供基于树脂固体的<25mg KOH / g物质的酸值，其中中和剂为加入足以中和40至105％酸基团的量，并且在扩链反应之前加入足以中和至少60％酸基团的量，ii）至少1wt。基于组分A）至D）的总重量的组分A）和B）的百分比是三或更高官能化合物，和ii）聚氨酯含有1至4重量％通过水和异氰酸酯基团的反应形成的尿素基团的％。本发明还涉及制备这些聚氨酯分散体的方法和含有这些聚氨酯分散体的涂料组合物。

6. 发明授权

US06187860B1 Aqueous polyisocyanate crosslinking agents modified with hydroxycarboxylic acids and pyrazole-based blocking agents 有权
标题翻译：用羟基羧酸和基于吡唑的封闭剂改性的多异氰酸酯交联剂
公开(公告)号：US06187860B1
公开(公告)日：2001-02-13
申请号：US09262858
申请日：1999-03-05
申请人： Eberhard König , Heino Müller , Harald Blum , Joachim Petzoldt
发明人： Eberhard König , Heino Müller , Harald Blum , Joachim Petzoldt
IPC分类号： C08J300
CPC分类号： C08G18/807 , C08G18/348 , C08G18/706 , C09D175/04
摘要： The present invention relates to aqueous or water dilutable blocked polyisocyanates containing a) a polyisocyanate component and, based on the equivalents of isocyanate groups, b) 60 to 85 equivalent % of a pyrazole blocking agent, c) 15 to 40 equivalent % of a monohydroxycarboxylic acid to impart hydrophilic properties and d) 0 to 15 equivalent % of a difunctional chain extender containing OH and/or NH2 groups, wherein the amounts of a) to d) are selected so that the equivalent ratio of NCO groups of component a) to isocyanate-reactive groups of components b), c) and d) is 1:0.8 to 1:1.2. The present invention also relates to a process for preparing these polyisocyanate crosslinking agents and to their use in combination with polyhydroxyl compounds which are soluble and/or dispersible in water as binders for aqueous stoving lacquers.
摘要翻译：本发明涉及包含a）多异氰酸酯组分的水性或水可稀释的封端多异氰酸酯，并且基于异氰酸酯基团的当量，b）60至85当量的吡唑封闭剂，c）15至40当量％的单羟基羧酸以赋予亲水性，并且d）0至15当量％的包含OH和/或NH 2基团的双官能扩链剂，其中选择a）至d）的量使得组分a）的NCO基团与异氰酸酯 - 组分b），c）和d）的反应性基团为1：0.8至1：1.2。本发明还涉及一种制备这些多异氰酸酯交联剂的方法，以及它们与多羟基化合物的组合使用，所述多羟基化合物是可溶的和/或分散在水中作为水性烘烤漆的粘合剂。

7. 发明授权

US07049367B2 Self-crosslinking PU dispersions 失效
公开(公告)号：US07049367B2
公开(公告)日：2006-05-23
申请号：US10411902
申请日：2003-04-11
申请人： Jan Mazanek , Dieter Mager , Joachim Petzoldt , Heino Müller
发明人： Jan Mazanek , Dieter Mager , Joachim Petzoldt , Heino Müller
IPC分类号： C08J3/00 , C08K3/20 , C08L75/00 , C08G18/00 , C06G18/81
CPC分类号： C08G18/8048 , C08G18/0823 , C08G18/283 , C08G18/6644 , C08G18/8077 , C09D175/04
摘要： The present invention relates to aqueous self-crosslinking PU dispersions and to coatings prepared from them.

8. 发明授权

US06827983B2 Low temperature-drying waterborne coatings 失效
标题翻译：低温干燥水性涂料
公开(公告)号：US06827983B2
公开(公告)日：2004-12-07
申请号：US09960034
申请日：2001-09-20
申请人： Joachim Petzoldt , Heino Müller
发明人： Joachim Petzoldt , Heino Müller
IPC分类号： C09D17504
CPC分类号： C08G18/6659 , C08G18/0823 , C09D175/04 , Y10T428/31551 , Y10T428/31605 , C08L2666/16
摘要： The present invention relates to a storage-stable, waterborne, one-component, coating composition, which can be cured at temperatures below 100° C. to provide a stone chip resistant and sandable coating, containing as the binder a polyurethane dispersion A, which after physical drying results in a coating having a pendulum hardness according to DIN 53 157 of >90 s; a polyurethane dispersion B, which after physical drying results in a coating having a pendulum hardness (DIN 53 157) of
摘要翻译：本发明涉及一种储存稳定的水性单组分涂料组合物，其可以在低于100℃的温度下固化，以提供耐石棉片和可打磨的涂层，其包含作为粘合剂的聚氨酯分散体A，其中在物理干燥后，导致具有根据DIN 53 157> 90s的摆锤硬度的涂层; 在物理干燥后导致摆锤硬度（DIN 53 157）<90秒的涂层的聚氨酯分散体B; 和三聚氰胺树脂C，其优选是高反应性的。本发明还涉及用这些涂料组合物和所得基材涂布基材的方法。

9. 发明授权

US06482885B1 Coating composition comprising diverse anionic polyurethane-polyurea dispersions 失效
标题翻译：包含各种阴离子聚氨酯 - 聚脲分散体的涂料组合物
公开(公告)号：US06482885B1
公开(公告)日：2002-11-19
申请号：US09628875
申请日：2000-07-24
申请人： Hanns-Peter Müller , Horst Gruttmann , Joachim Petzoldt , Heino Müller , Jürgen Meixner , Gerald Kurek
发明人： Hanns-Peter Müller , Horst Gruttmann , Joachim Petzoldt , Heino Müller , Jürgen Meixner , Gerald Kurek
IPC分类号： C09D500
CPC分类号： C09D175/02 , C08G18/0823 , C08G18/12 , C08G18/6625 , C09D5/20 , C08G18/3225
摘要： The present invention relates to coating compositions comprising a mixture of at least two aqueous, anionic polyurethane polyurea dispersions A and B, wherein dispersion A as a dry film has a TG in the range from −30° C., to −45° and dispersion B as a dry film has a first TG in the range from −30° C. to −45° C. and a second TG in the range from +45° C. to +60° C., and the mixture of A and B as a dry film has only one TG in the range from −30° C. to −45° C.
摘要翻译：本发明涉及包含至少两种水性阴离子聚氨酯聚脲分散体A和B的混合物的涂料组合物，其中作为干膜的分散体A具有在-30℃至-45℃范围内的TG和分散体 B作为干膜具有在-30℃至-45℃范围内的第一TG和在+ 45℃至+ 60℃范围内的第二TG，并且A和 B作为干膜只有一个TG在-30°C至-45°C的范围内。

10. 发明申请

US20120059118A1 TWO-PACK POLYURETHANE PAINT FOR BACKING FILMS 审中-公开
标题翻译：用于背衬薄膜的两包聚氨酯涂料
公开(公告)号：US20120059118A1
公开(公告)日：2012-03-08
申请号：US13147477
申请日：2010-02-05
申请人： Andreas Klein , Joachim Petzoldt , Nusret Yuva , Christoph Irle
发明人： Andreas Klein , Joachim Petzoldt , Nusret Yuva , Christoph Irle
IPC分类号： C09D175/06
CPC分类号： C08G18/0823 , C08G18/12 , C08G18/4216 , C08G18/44 , C08G18/664 , C08G18/6659 , C08G18/73 , C08J7/047 , C08J2475/04 , C09D175/06 , C08G18/706 , C08G18/2875
摘要： The invention relates to a two-pack polyurethane paint for a backing film, a method for the production thereof and use thereof for application to moulded plastic parts.
摘要翻译：本发明涉及用于背衬薄膜的双组分聚氨酯涂料，其制备方法及其应用于模塑塑料部件的用途。

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