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    • 7. 发明授权
    • Method for fluidizing tars
    • 使焦油流化的方法
    • US06245216B1
    • 2001-06-12
    • US08802742
    • 1997-02-20
    • Philip Dean HillThomas Edwin PruittForrest Lee SandersGilles GuerinBruno Langlois
    • Philip Dean HillThomas Edwin PruittForrest Lee SandersGilles GuerinBruno Langlois
    • C10G1700
    • C10L1/326C01B17/92Y10S516/928
    • Process for the preparation of an aqueous tar suspoemulsion by mixing a mixture including (a) a viscous tar composition formed from a tar, from inorganic solids and, optionally, from water, (b) water (W), (c) a surface-active agent (SA) exhibiting an HLB of at least 10 and, optionally, (d) a thickening water-soluble polymer (TWP) with a molecular mass of greater than 10,000, the relative amounts of constituents (W), (SA) and, optionally, (TWP) being such that the viscosity of the (W)+(SA)+optional (TWP) mixture is preferably equal to or greater than the viscosity of the said tar, and then optional dilution of the mixture obtained with water or with an aqueous acidic solution. The process is particularly advantageous when applied to to the residues, containing sulphuric acid, resulting from the synthesis of white oils from petroleum fractions. The present invention further relates to a method for fluidizing acidic tars/sludges including contacting the tar/sludge with sulfuric acid and a surfactant. Optionally, a carrier for the surfactant's incorporation into the tar/sludge can be utilized. This provides an effective process for cleaning sulfuric acid tars/sludges from containers/vessels such as transportation containers, pipes and storage tanks. Preferably, the process includes the additional step of regeneration of sulfuric acid from the fluidized tar/sludge.
    • 通过混合包括(a)由焦油形成的粘稠焦油组合物,来自无机固体和任选地由水,(b)水(W),(c)表面活性剂的混合物制备含水焦油悬乳剂的方法, 表现出至少10的HLB的活性剂(SA),和(d)分子量大于10,000的增稠水溶性聚合物(TWP),组分(W),(SA)和 ,(W)+(SA)+任选(TWP)混合物的粘度优选等于或大于所述焦油的粘度,然后任选地稀释得到的混合物 或用酸性水溶液。 当应用于由石油馏分合成白油产生的含硫酸的残留物时,该方法特别有利。 本发明还涉及一种使酸性焦油/污泥流化的方法,包括使焦油/污泥与硫酸和表面活性剂接触。 任选地,可以使用表面活性剂掺入焦油/污泥中的载体。 这提供了从容器/容器如运输容器,管道和储罐清洗硫酸焦油/污泥的有效方法。 优选地,该方法包括从流化焦油/污泥再生硫酸的附加步骤。