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    • 1. 发明申请
    • COPOLYAMIDES
    • 共聚酰胺
    • US20120157594A1
    • 2012-06-21
    • US13378980
    • 2010-06-15
    • Christian SchmidtFaissal-Ali El-ToufailiPhilippe DesboisRacquel Fernandez Rodiles
    • Christian SchmidtFaissal-Ali El-ToufailiPhilippe DesboisRacquel Fernandez Rodiles
    • C08K5/05
    • C08G69/265C08G69/14C08G69/36C08L77/02C08L77/06C09D177/02C09D177/06
    • What are described are a solution comprising a terpolymer formed from the monomers of components A, B and C, the total amount of which adds up to 100% by weight,a) 5 to 60% by weight of lactams as component A,b) 5 to 60% by weight of equimolar amounts of adipic acid and one or more aliphatic diamines as component B,c) 10 to 70% by weight of equimolar amounts of adipic acid and 4,4′-diaminodicyclohexylmethane (dicycan) as component C,in an aromatics-free solvent system comprising50 to 100% by weight of C1-4-alkanol,0 to 50% by weight of water andnot more than 10% by weight of further aromatics-free solvents,where the total amount of the solvent system adds up to 100% by weight, and a terpolymer formed from the monomers of components A, B and C, the total amount of which adds up to 100% by weight,a) 15 to 40% by weight of lactams as component A,b) 20 to 45% by weight of equimolar amounts of adipic acid and one or more aliphatic diamines as component B,c) 25 to 60% by weight of equimolar amounts of adipic acid and 4,4′-diaminodicyclohexylmethane (dicycan) as component C,excluding terpolymers formed from 30 to 40% by weight of component A, 30 to 40% by weight of component B and 30 to 40% by weight of component C.
    • 描述的是包含由组分A,B和C的单体形成的三元共聚物的溶液,其总量加至100重量%,a)5至60重量%的作为组分A的内酰胺,b) 5至60重量%的等摩尔量的己二酸和一种或多种脂族二胺作为组分B,c)10至70重量%的等摩尔量的己二酸和作为组分C的4,4'-二氨基二环己基甲烷(二环己烷) 在不含芳族化合物的溶剂体系中,其包含50至100重量%的C 1-4链烷醇,0至50重量%的水和不超过10重量%的其它不含芳族化合物的溶剂,其中 溶剂系统加入到100重量%,和由组分A,B和C的单体形成的三元共聚物,其总量加至100重量%,a)15至40重量%的作为组分的内酰胺 A,b)20〜45重量%的等摩尔量的己二酸和一种或多种作为组分B的脂族二胺,c)25至60重量% 的等摩尔量的己二酸和4,4'-二氨基二环己基甲烷(二环己烷)作为组分C,不包括由30至40重量%的组分A形成的三元共聚物,30至40重量%的组分B和30至40重量% 的组分C.
    • 2. 发明授权
    • Copolyamides
    • 共聚酰胺
    • US08658724B2
    • 2014-02-25
    • US13378980
    • 2010-06-15
    • Christian SchmidtFaissal-Ali El-ToufailiPhilippe DesboisRaquel Fernandez Rodiles
    • Christian SchmidtFaissal-Ali El-ToufailiPhilippe DesboisRaquel Fernandez Rodiles
    • C08K5/05
    • C08G69/265C08G69/14C08G69/36C08L77/02C08L77/06C09D177/02C09D177/06
    • What are described are a solution comprising a terpolymer formed from the monomers of components A, B and C, the total amount of which adds up to 100% by weight, a) 5 to 60% by weight of lactams as component A, b) 5 to 60% by weight of equimolar amounts of adipic acid and one or more aliphatic diamines as component B, c) 10 to 70% by weight of equimolar amounts of adipic acid and 4,4′-diaminodicyclohexylmethane (dicycan) as component C, in an aromatics-free solvent system comprising 50 to 100% by weight of C1-4-alkanol, 0 to 50% by weight of water and not more than 10% by weight of further aromatics-free solvents, where the total amount of the solvent system adds up to 100% by weight, and a terpolymer formed from the monomers of components A, B and C, the total amount of which adds up to 100% by weight, a) 15 to 40% by weight of lactams as component A, b) 20 to 45% by weight of equimolar amounts of adipic acid and one or more aliphatic diamines as component B, c) 25 to 60% by weight of equimolar amounts of adipic acid and 4,4′-diaminodicyclohexylmethane (dicycan) as component C, excluding terpolymers formed from 30 to 40% by weight of component A, 30 to 40% by weight of component B and 30 to 40% by weight of component C.
    • 描述的是包含由组分A,B和C的单体形成的三元共聚物的溶液,其总量加至100重量%,a)5至60重量%的作为组分A的内酰胺,b) 5至60重量%的等摩尔量的己二酸和一种或多种脂族二胺作为组分B,c)10至70重量%的等摩尔量的己二酸和作为组分C的4,4'-二氨基二环己基甲烷(二环己烷) 在不含芳族化合物的溶剂体系中,其包含50至100重量%的C 1-4链烷醇,0至50重量%的水和不超过10重量%的其它不含芳族化合物的溶剂,其中 溶剂系统加入到100重量%,和由组分A,B和C的单体形成的三元共聚物,其总量加至100重量%,a)15至40重量%的作为组分的内酰胺 A,b)20〜45重量%的等摩尔量的己二酸和一种或多种脂族二胺作为组分B,c)25〜60重量% 等摩尔量的己二酸和作为组分C的4,4'-二氨基二环己基甲烷(二环己烷),不包括由30至40重量%的组分A,30至40重量%的组分B和30至40重量%的组分B形成的三元共聚物, 组分C.
    • 3. 发明申请
    • PROCESS FOR PREPARING POLYAMIDES
    • 制备聚氨酯的方法
    • US20120245308A1
    • 2012-09-27
    • US13514364
    • 2010-12-03
    • Faissal-Ali El-ToufailiPhilippe DesboisAndreas WollnySven LawrenzChristian Schmidt
    • Faissal-Ali El-ToufailiPhilippe DesboisAndreas WollnySven LawrenzChristian Schmidt
    • C08G69/28C08G69/26
    • C08G69/265C08G69/28
    • The present invention relates to a process for preparing a polyamide based on dicarboxylic acids and diamines, comprising the following stages: A) providing an aqueous monomer mixture composed of dicarboxylic acids and diamines, where the molar ratio of dicarboxylic acids to diamines is adjusted such that, at the outlet of stage C), there is a molar deficiency of dicarboxylic acids or diamines of 1 to 10 mol%, based on the respective other component, B) transferring the aqueous mixture from stage A) into a continuous evaporator reactor in which diamines and dicarboxylic acids are converted at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar, C) transferring the mixture from stage B) into a separator which is operated at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar with removal of gaseous components, D) transferring the mixture from stage C) together with diamine or dicarboxylic acid in an amount suitable for compensation for the molar deficiency into a tubular reactor which is operated at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar, for a residence time in the range from 10 seconds to 30 minutes, E) transferring the mixture from stage D) into an extruder which is operated at a temperature in the range from 150 to 400° C. for a residence time in the range from 10 seconds to 30 minutes with removal of gaseous components through venting orifices.
    • 本发明涉及一种制备基于二羧酸和二胺的聚酰胺的方法,包括以下步骤:A)提供由二羧酸和二胺组成的含水单体混合物,其中二羧酸与二胺的摩尔比被调整为使得 ,在阶段C)的出口处,基于各自的其它组分,存在摩尔不足的二羧酸或二胺的1至10摩尔%,B)将水性混合物从阶段A)转移到连续的蒸发器反应器中,其中 二胺和二羧酸在100至370℃的温度和1至50巴的压力范围内转化,C)将混合物从阶段B)转移到分离器中,该分离器在 范围为100至370℃,压力为1至50巴,除去气态组分,D)将混合物与阶段C)一起转移至二胺或二羧酸的量 适合于将摩尔不足补偿到在100至370℃的温度和1至50巴的压力范围内操作的管式反应器中,停留时间在10秒至 30分钟,E)将混合物从阶段D)转移到挤出机中,该挤出机在150-400℃的温度下操作,停留时间在10秒至30分钟之间,同时除去气体成分 通风孔。
    • 4. 发明授权
    • Process for preparing polyamides
    • 制备聚酰胺的方法
    • US09315626B2
    • 2016-04-19
    • US13514364
    • 2010-12-03
    • Faissal-Ali El-ToufailiPhilippe DesboisAndreas WollnySven LawrenzChristian Schmidt
    • Faissal-Ali El-ToufailiPhilippe DesboisAndreas WollnySven LawrenzChristian Schmidt
    • C08G69/24C08G69/26C08G69/28
    • C08G69/265C08G69/28
    • The present invention relates to a process for preparing a polyamide based on dicarboxylic acids and diamines, comprising the following stages: A) providing an aqueous monomer mixture composed of dicarboxylic acids and diamines, where the molar ratio of dicarboxylic acids to diamines is adjusted such that, at the outlet of stage C), there is a molar deficiency of dicarboxylic acids or diamines of 1 to 10 mol %, based on the respective other component, B) transferring the aqueous mixture from stage A) into a continuous evaporator reactor in which diamines and dicarboxylic acids are converted at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar, C) transferring the mixture from stage B) into a separator which is operated at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar with removal of gaseous components, D) transferring the mixture from stage C) together with diamine or dicarboxylic acid in an amount suitable for compensation for the molar deficiency into a tubular reactor which is operated at a temperature in the range from 100 to 370° C. and a pressure in the range from 1 to 50 bar, for a residence time in the range from 10 seconds to 30 minutes, E) transferring the mixture from stage D) into an extruder which is operated at a temperature in the range from 150 to 400° C. for a residence time in the range from 10 seconds to 30 minutes with removal of gaseous components through venting orifices.
    • 本发明涉及一种制备基于二羧酸和二胺的聚酰胺的方法,其包括以下步骤:A)提供由二羧酸和二胺组成的含水单体混合物,其中二羧酸与二胺的摩尔比被调整为使得 ,在阶段C)的出口处,基于各自的其它组分,存在摩尔不足的二羧酸或二胺的1至10摩尔%,B)将水性混合物从阶段A)转移到连续的蒸发器反应器中,其中 二胺和二羧酸在100至370℃的温度和1至50巴的压力范围内转化,C)将混合物从阶段B)转移到分离器中,该分离器在 范围为100至370℃,压力范围为1至50巴,除去气态组分,D)将混合物从阶段C)与二胺或二羧酸一起转移 t适用于将摩尔不足补偿为在100至370℃的温度和1至50巴的压力范围内操作的管式反应器中,停留时间为10秒 至30分钟,E)将混合物从阶段D)转移到挤出机中,该挤出机在150-400℃的温度下操作,停留时间为10秒至30分钟,同时除去气体组分 通过通风口。
    • 7. 发明授权
    • Skin protectant, particularly against hydrophobic (lipophilic) and against hydrophilic (lipophobic) harmful substances
    • 皮肤保护剂,特别是防止疏水(亲脂)和抗亲水(疏油)有害物质
    • US08673879B2
    • 2014-03-18
    • US13379489
    • 2010-06-30
    • Brigitte ThoernerPetra AllefChristian SchmidtMarcel VeegerStefani SchmidtTanja KloerenAnne Claassen
    • Brigitte ThoernerPetra AllefChristian SchmidtMarcel VeegerStefani SchmidtTanja KloerenAnne Claassen
    • A61K31/715
    • A61K8/73A61K8/733A61K8/737A61K8/87A61Q17/00
    • The invention relates to a skin protectant, particularly against hydrophobic (lipophilic) and hydrophilic (lipophobic) harmful substances, obtainable by means of an amount of at least one barrier-forming component, particularly against hydrophobic (lipophilic) harmful substances, wherein the nephelometric turbidity unit of the barrier-forming component is determined by means of turbidimetry and at least one barrier-forming component, a 1% solution in water thereof having a nephelometric turbidity unit of greater than 40 (NTU), is used to produce the protectant and a method for producing skin protectants, particularly against hydrophobic (lipophilic) and hydrophilic (lipophobic) harmful substances, where in the barrier-forming component is selected for production of the protectant such that the nephelometric turbidity unit of the barrier-forming component of the skin protectant is determined by means of turbidimetry and at least one barrier-forming component, a 1% solution in water thereof having a nephelometric turbidity unit of greater than 40 (NTU), is used to produce the skin protectant.
    • 本发明涉及一种皮肤保护剂,特别是针对疏水性(亲脂性)和亲水性(疏油性)有害物质,其通过一定量的阻挡形成组分,特别是抗疏水性(亲脂性)有害物质可获得,其中浊光浊度 屏障形成部件的单位通过比浊法和至少一个形成阻挡层的组分,其中具有大于40(NTU)的比浊浊度单位的1%的水溶液用于制备保护剂和 用于生产皮肤保护剂的方法,特别是针对疏水性(亲脂性)和亲水性(疏油性)的有害物质,其中在形成屏障的组分中选择用于制备保护剂,使得皮肤保护剂的屏障形成成分的比浊浊度单位 通过比浊法和至少一种形成阻挡层的成分,1%的水溶液来确定 使用具有大于40(NTU)的比浊浊度单位的eof来生产皮肤保护剂。
    • 9. 发明申请
    • PRODUCT DATA MANAGEMENT AND WORKFLOW SYSTEMS AND METHODS
    • 产品数据管理和工作流系统和方法
    • US20100281426A1
    • 2010-11-04
    • US12433722
    • 2009-04-30
    • Christian Schmidt
    • Christian Schmidt
    • G06F17/30G06F3/048
    • G06F17/30551
    • An exemplary method comprises maintaining product data in a computer-readable data store, the product data including a data entry comprising a question and an answer about a product, setting a lifetime date for the data entry, publishing the question and the answer about the product for access by at least one user, and, in response to the lifetime date being reached, automatically hiding the question and the answer about the product from access by the at least one user and designating the data entry for a lifetime review. In certain embodiments, the method further comprises providing, for display, data representative of a graphical user interface configured to facilitate the lifetime review of the data entry by a user, receiving data representative of a renewal of the data entry, and updating the lifetime date for the data entry based on the data representative of the renewal of the data entry.
    • 示例性方法包括将计算机可读数据存储器中的产品数据维护,产品数据包括包括关于产品的问题和答案的数据条目,设置数据输入的生命期,发布问题和关于产品的答案 用于由至少一个用户访问,并且响应于到达的生命期,自动隐藏关于该产品的问题和答案,以供至少一个用户访问并指定用于终身审查的数据条目。 在某些实施例中,该方法还包括提供用于显示代表图形用户界面的数据,该图形用户界面被配置为便于用户对数据输入进行终身审查,接收表示数据输入的更新的数据,以及更新生命周期 用于基于表示数据条目更新的数据的数据输入。