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1. 发明申请

US20110192319A1 Nanotubular Toughening Inclusions 有权
标题翻译：纳米增韧包裹体
公开(公告)号：US20110192319A1
公开(公告)日：2011-08-11
申请号：US13032045
申请日：2011-02-22
申请人： Cheol Park , Dennis C. Working , Emilie J. Siochi , Joycelyn S. Harrison
发明人： Cheol Park , Dennis C. Working , Emilie J. Siochi , Joycelyn S. Harrison
IPC分类号： C08L89/00 , C08L79/08 , C08G73/10 , C08K3/04 , B82Y30/00
CPC分类号： C08K7/24 , B82Y30/00 , C08K2201/011
摘要： Conventional toughening agents are typically rubbery materials or small molecular weight molecules, which mostly sacrifice the intrinsic properties of a matrix such as modulus, strength, and thermal stability as side effects. On the other hand, high modulus inclusions tend to reinforce elastic modulus very efficiently, but not the strength very well. For example, mechanical reinforcement with inorganic inclusions often degrades the composite toughness, encountering a frequent catastrophic brittle failure triggered by minute chips and cracks. Thus, toughening generally conflicts with mechanical reinforcement. Carbon nanotubes have been used as efficient reinforcing agents in various applications due to their combination of extraordinary mechanical, electrical, and thermal properties. Moreover, nanotubes can elongate more than 20% without yielding or breaking, and absorb significant amounts of energy during deformation, which enables them to also be an efficient toughening agent, as well as excellent reinforcing inclusion. Accordingly, an improved toughening method is provided by incorporating nanotubular inclusions into a host matrix, such as thermoset and thermoplastic polymers or ceramics without detrimental effects on the matrix's intrinsic physical properties.
摘要翻译：常规增韧剂通常是橡胶状材料或小分子量分子，其主要牺牲基质的固有性质，例如作为副作用的模量，强度和热稳定性。另一方面，高模量夹杂物倾向于非常有效地增强弹性模量，但是强度非常好。例如，具有无机夹杂物的机械增强剂常常降低复合材料的韧性，遇到由碎片和裂纹引起的频繁的灾难性脆性破坏。因此，增韧通常与机械加强冲突。碳纳米管由于其非凡的机械，电气和热性能的组合，已经在各种应用中用作有效的增强剂。此外，纳米管可以延伸超过20％而不产生或破裂，并且在变形期间吸收大量的能量，这使得它们也可以是有效的增韧剂，以及优异的增强夹杂物。因此，通过将纳米管状夹杂物结合到主体基质如热固性和热塑性聚合物或陶瓷中而不会对基体的固有物理性质产生不利影响，提供了改进的增韧方法。

2. 发明授权

US09074066B2 Nanotubular toughening inclusions 有权
标题翻译：纳米管增韧夹杂物
公开(公告)号：US09074066B2
公开(公告)日：2015-07-07
申请号：US13032045
申请日：2011-02-22
申请人： Cheol Park , Dennis C. Working , Emilie J. Siochi , Joycelyn S. Harrison
发明人： Cheol Park , Dennis C. Working , Emilie J. Siochi , Joycelyn S. Harrison
IPC分类号： C08L89/00 , C08L79/08 , C08G73/10 , C08K3/04 , B82Y30/00 , C08K7/24
CPC分类号： C08K7/24 , B82Y30/00 , C08K2201/011
摘要： Conventional toughening agents are typically rubbery materials or small molecular weight molecules, which mostly sacrifice the intrinsic properties of a matrix such as modulus, strength, and thermal stability as side effects. On the other hand, high modulus inclusions tend to reinforce elastic modulus very efficiently, but not the strength very well. For example, mechanical reinforcement with inorganic inclusions often degrades the composite toughness, encountering a frequent catastrophic brittle failure triggered by minute chips and cracks. Thus, toughening generally conflicts with mechanical reinforcement. Carbon nanotubes have been used as efficient reinforcing agents in various applications due to their combination of extraordinary mechanical, electrical, and thermal properties. Moreover, nanotubes can elongate more than 20% without yielding or breaking, and absorb significant amounts of energy during deformation, which enables them to also be an efficient toughening agent, as well as excellent reinforcing inclusion. Accordingly, an improved toughening method is provided by incorporating nanotubular inclusions into a host matrix, such as thermoset and thermoplastic polymers or ceramics without detrimental effects on the matrix's intrinsic physical properties.
摘要翻译：常规增韧剂通常是橡胶状材料或小分子量分子，其主要牺牲基质的固有性质，例如作为副作用的模量，强度和热稳定性。另一方面，高模量夹杂物倾向于非常有效地增强弹性模量，但是强度非常好。例如，具有无机夹杂物的机械增强剂常常降低复合材料的韧性，遇到由碎片和裂纹引起的频繁的灾难性脆性破坏。因此，增韧通常与机械加强冲突。碳纳米管由于其非凡的机械，电气和热性能的组合，已经在各种应用中用作有效的增强剂。此外，纳米管可以延伸超过20％而不产生或破裂，并且在变形期间吸收大量的能量，这使得它们也可以是有效的增韧剂，以及优异的增强夹杂物。因此，通过将纳米管状夹杂物结合到主体基质如热固性和热塑性聚合物或陶瓷中而不会对基体的固有物理性质产生不利影响，提供了改进的增韧方法。

3. 发明授权

US09493635B2 Nanocomposites from stable dispersions of carbon nanotubes in polymeric matrices using dispersion interaction 有权
标题翻译：使用分散相互作用从碳纳米管在聚合物基质中稳定分散的纳米复合材料
公开(公告)号：US09493635B2
公开(公告)日：2016-11-15
申请号：US11644019
申请日：2006-12-22
申请人： Kristopher Eric Wise , Cheol Park , Jin Ho Kang , Emilie J. Siochi , Joycelyn S. Harrison
发明人： Kristopher Eric Wise , Cheol Park , Jin Ho Kang , Emilie J. Siochi , Joycelyn S. Harrison
IPC分类号： B82Y30/00 , C08K7/24
CPC分类号： C08K7/24 , B82Y30/00 , C08K2201/011
摘要： Stable dispersions of carbon nanotubes (CNTs) in polymeric matrices include CNTs dispersed in a host polymer or copolymer whose monomers have delocalized electron orbitals, so that a dispersion interaction results between the host polymer or copolymer and the CNTs dispersed therein. Nanocomposite products, which are presented in bulk, or when fabricated as a film, fiber, foam, coating, adhesive, paste, or molding, are prepared by standard means from the present stable dispersions of CNTs in polymeric matrices, employing dispersion interactions, as presented hereinabove.
摘要翻译：碳纳米管（CNTs）在聚合物基质中的稳定分散体包括分散在其单体具有离域电子轨道的主体聚合物或共聚物中的CNT，使得在主体聚合物或共聚物与分散在其中的CNT之间产生分散相互作用。通过标准方法通过标准方法制备纳米复合材料，其以体积呈现，或当制成膜，纤维，泡沫，涂层，粘合剂，糊剂或模塑时，由CNT在聚合物基质中的稳定分散体采用分散相互作用，如如上所述。

4. 发明申请

US20080275172A1 Nanocomposites from stable dispersions of carbon nanotubes in polymeric matrices using dispersion interaction 有权
标题翻译：使用分散相互作用从碳纳米管在聚合物基质中稳定分散的纳米复合材料
公开(公告)号：US20080275172A1
公开(公告)日：2008-11-06
申请号：US11644019
申请日：2006-12-22
申请人： Kristopher Eric Wise , Cheol Park , Jin Ho Kang , Emilie J. Siochi , Joycelyn S. Harrison
发明人： Kristopher Eric Wise , Cheol Park , Jin Ho Kang , Emilie J. Siochi , Joycelyn S. Harrison
IPC分类号： C08K3/00
CPC分类号： C08K7/24 , B82Y30/00 , C08K2201/011
摘要： Stable dispersions of carbon nanotubes (CNTs) in polymeric matrices include CNTs dispersed in a host polymer or copolymer whose monomers have delocalized electron orbitals, so that a dispersion interaction results between the host polymer or copolymer and the CNTs dispersed therein. Nanocomposite products, which are presented in bulk, or when fabricated as a film, fiber, foam, coating, adhesive, paste, or molding, are prepared by standard means from the present stable dispersions of CNTs in polymeric matrices, employing dispersion interactions, as presented hereinabove.
摘要翻译：碳纳米管（CNTs）在聚合物基质中的稳定分散体包括分散在其单体具有离域电子轨道的主体聚合物或共聚物中的CNT，使得在主体聚合物或共聚物与分散在其中的CNT之间产生分散相互作用。通过标准方法通过标准方法制备纳米复合材料，其以体积呈现，或当制成膜，纤维，泡沫，涂层，粘合剂，糊剂或模塑时，由CNT在聚合物基质中的稳定分散体采用分散相互作用，如如上所述。

5. 发明授权

US07666939B2 Dispersions of carbon nanotubes in polymer matrices 有权
标题翻译：碳纳米管在聚合物基质中的分散体
公开(公告)号：US07666939B2
公开(公告)日：2010-02-23
申请号：US11432201
申请日：2006-05-11
申请人： Kristopher Eric Wise , Cheol Park , Emilie J. Siochi , Joycelyn S. Harrison , Peter T. Lillehei , Sharon E. Lowther
发明人： Kristopher Eric Wise , Cheol Park , Emilie J. Siochi , Joycelyn S. Harrison , Peter T. Lillehei , Sharon E. Lowther
IPC分类号： C08K3/04
CPC分类号： C08K7/24
摘要： Dispersions of carbon nanotubes exhibiting long term stability are based on a polymer matrix having moieties therein which are capable of a donor-acceptor complexation with carbon nanotubes. The carbon nanotubes are introduced into the polymer matrix and separated therein by standard means. Nanocomposites produced from these dispersions are useful in the fabrication of structures, e.g., lightweight aerospace structures.
摘要翻译：显示长期稳定性的碳纳米管的分散体基于其中具有其中能够与碳纳米管的供体 - 受体络合的部分的聚合物基质。将碳纳米管引入聚合物基质中并通过标准方法分离。由这些分散体制备的纳米复合材料可用于制造结构，例如轻质的航空航天结构。

6. 发明申请

US20110169187A1 Mechanically Strong, Thermally Stable, And Electrically Conductive Nanocomposite Structure and Method of Fabricating Same 有权
标题翻译：机械强，热稳定和导电纳米复合结构及其制造方法
公开(公告)号：US20110169187A1
公开(公告)日：2011-07-14
申请号：US13053633
申请日：2011-03-22
申请人： Dennis C. Working , Emilie J. Siochi , Cheol Park , Peter T. Lillehei
发明人： Dennis C. Working , Emilie J. Siochi , Cheol Park , Peter T. Lillehei
IPC分类号： B29C47/00 , B82Y30/00
CPC分类号： C08K7/24 , B82Y30/00 , C08K2201/011
摘要： A nanocomposite structure and method of fabricating same are provided. The nanocomposite structure is a polymer in an extruded shape with carbon nanotubes (CNTs) longitudinally disposed and dispersed in the extruded shape along a dimension thereof. The polymer is characteristically defined as having a viscosity of at least approximately 100,000 poise at a temperature of 200° C.
摘要翻译：提供纳米复合结构及其制造方法。纳米复合结构是挤出形状的聚合物，其中碳纳米管（CNT）沿其尺寸纵向设置并分散在挤出形状中。该聚合物特征定义为在200℃的温度下具有至少约100,000泊的粘度。

7. 发明授权

US08608993B2 Mechanically strong, thermally stable, and electrically conductive nanocomposite structure and method of fabricating same 有权
标题翻译：机械强，热稳定和导电的纳米复合结构及其制造方法
公开(公告)号：US08608993B2
公开(公告)日：2013-12-17
申请号：US13053633
申请日：2011-03-22
申请人： Dennis C. Working , Emilie J. Siochi , Cheol Park , Peter T. Lillehei
发明人： Dennis C. Working , Emilie J. Siochi , Cheol Park , Peter T. Lillehei
IPC分类号： B29C47/00
CPC分类号： C08K7/24 , B82Y30/00 , C08K2201/011
摘要： A nanocomposite structure and method of fabricating same are provided. The nanocomposite structure is a polymer in an extruded shape with carbon nanotubes (CNTs) longitudinally disposed and dispersed in the extruded shape along a dimension thereof. The polymer is characteristically defined as having a viscosity of at least approximately 100,000 poise at a temperature of 200° C.
摘要翻译：提供纳米复合结构及其制造方法。纳米复合结构是挤出形状的聚合物，其中碳纳米管（CNT）沿其尺寸纵向设置并分散在挤出形状中。该聚合物特征定义为在200℃的温度下具有至少约100,000泊的粘度。

8. 发明授权

US09822088B2 Anisotropic copoly(imide oxetane) coatings and articles of manufacture, copoly(imide oxetane)s containing pendant fluorocarbon moieties, oligomers and processes therefor 有权
公开(公告)号：US09822088B2
公开(公告)日：2017-11-21
申请号：US13286715
申请日：2011-11-01
申请人： Christopher J. Wohl , John W. Connell , Emilie J. Siochi , Joseph G. Smith
发明人： Christopher J. Wohl , John W. Connell , Emilie J. Siochi , Joseph G. Smith
IPC分类号： C08G73/10 , C07D305/08 , C09D179/08 , C08G65/18 , C08G65/322 , C08G65/333
CPC分类号： C07D305/08 , C08G65/18 , C08G65/322 , C08G65/33389 , C08G73/1042 , C08G73/105 , C09D179/08
摘要： Copoly(imide oxetane) materials are disclosed that can exhibit a low surface energy while possessing the mechanical, thermal, chemical and optical properties associated with polyimides. The copoly(imide oxetane)s are prepared using a minor amount of fluorinated oxetane-derived oligomer with sufficient fluorine-containing segments of the copoly(imide oxetane)s that migrate to the exterior surface of the polymeric material to yield low surface energies. Thus the coatings and articles of manufacture made with the copoly(imide oxetane)s of this invention are characterized as having an anisotropic fluorine composition. The low surface energies can be achieved with very low content of fluorinated oxetane-derived oligomer. The copolymers of this invention can enhance the viability of polyimides for many applications and may be acceptable where homopolyimide materials have been unacceptable.

9. 发明授权

US09048759B2 Multistage force amplification of piezoelectric stacks 有权
标题翻译：压电堆的多级力放大
公开(公告)号：US09048759B2
公开(公告)日：2015-06-02
申请号：US13293846
申请日：2011-11-10
申请人： Tian-Bing Xu , Emilie J. Siochi , Lei Zuo , Xiaoning Jiang , Jin Ho Kang
发明人： Tian-Bing Xu , Emilie J. Siochi , Lei Zuo , Xiaoning Jiang , Jin Ho Kang
IPC分类号： H01L41/00 , H02N2/04 , H02N2/18
CPC分类号： H02N2/043 , H02N2/186
摘要： Embodiments of the disclosure include an apparatus and methods for using a piezoelectric device, that includes an outer flextensional casing, a first cell and a last cell serially coupled to each other and coupled to the outer flextensional casing such that each cell having a flextensional cell structure and each cell receives an input force and provides an output force that is amplified based on the input force. The apparatus further includes a piezoelectric stack coupled to each cell such that the piezoelectric stack of each cell provides piezoelectric energy based on the output force for each cell. Further, the last cell receives an input force that is the output force from the first cell and the last cell provides an output apparatus force In addition, the piezoelectric energy harvested is based on the output apparatus force. Moreover, the apparatus provides displacement based on the output apparatus force.
摘要翻译：本公开的实施例包括一种用于使用压电装置的装置和方法，该装置和方法包括外张力壳体，第一单元和最后一个单元，它们彼此串联连接并耦合到外部弯曲壳体，使得每个单元具有弯曲单元结构并且每个单元接收输入力并提供基于输入力而被放大的输出力。该装置还包括耦合到每个单元的压电堆叠，使得每个单元的压电叠层基于每个单元的输出力提供压电能量。此外，最后一个单元接收作为来自第一单元的输出力的输入力，并且最后一个单元提供输出设备的力。此外，所收集的压电能量基于输出设备的力。此外，该装置基于输出装置的力提供位移。

10. 发明授权

US09005604B2 Aligned and electrospun piezoelectric polymer fiber assembly and scaffold 有权
标题翻译：对称和静电压电聚合物纤维组装和支架
公开(公告)号：US09005604B2
公开(公告)日：2015-04-14
申请号：US12969076
申请日：2010-12-15
申请人： Lisa A. Scott-Carnell , Emilie J. Siochi , Nancy M. Holloway , Kam W. Leong , Karina Kulangara
发明人： Lisa A. Scott-Carnell , Emilie J. Siochi , Nancy M. Holloway , Kam W. Leong , Karina Kulangara
IPC分类号： C12N11/08 , C12N13/00 , A61L27/16 , A61L27/38 , C12N5/00 , A61K35/12
CPC分类号： C12N5/0068 , A61K35/12 , A61K35/28 , A61L27/16 , A61L27/3834 , C12N11/08 , C12N13/00 , C12N2529/00 , C12N2533/30 , C08L27/16
摘要： A scaffold assembly and related methods of manufacturing and/or using the scaffold for stem cell culture and tissue engineering applications are disclosed which at least partially mimic a native biological environment by providing biochemical, topographical, mechanical and electrical cues by using an electroactive material. The assembly includes at least one layer of substantially aligned, electrospun polymer fiber having an operative connection for individual voltage application. A method of cell tissue engineering and/or stem cell differentiation uses the assembly seeded with a sample of cells suspended in cell culture media, incubates and applies voltage to one or more layers, and thus produces cells and/or a tissue construct. In another aspect, the invention provides a method of manufacturing the assembly including the steps of providing a first pre-electroded substrate surface; electrospinning a first substantially aligned polymer fiber layer onto the first surface; providing a second pre-electroded substrate surface; electrospinning a second substantially aligned polymer fiber layer onto the second surface; and, retaining together the layered surfaces with a clamp and/or an adhesive compound.
摘要翻译：公开了制造和/或使用用于干细胞培养和组织工程应用的支架的支架组件和相关方法，其通过使用电活性材料提供生物化学，地形学，机械和电学提示，至少部分地模拟天然生物环境。该组件包括至少一层基本对准的电纺聚合物纤维，其具有用于单独电压施加的操作连接。细胞组织工程和/或干细胞分化的方法利用悬浮在细胞培养基中的细胞样品接种组合物，孵育并施加电压至一层或多层，从而产生细胞和/或组织构建体。另一方面，本发明提供一种制造组件的方法，其包括以下步骤：提供第一预电镀基底表面; 将第一基本上排列的聚合物纤维层静电纺丝到第一表面上; 提供第二预电镀衬底表面; 将第二基本上排列的聚合物纤维层静电纺丝到第二表面上; 并且用夹具和/或粘合剂化合物将层压表面保持在一起。

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