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    • 1. 发明授权
    • Method of etching platinum using a silicon carbide mask
    • 使用碳化硅掩模蚀刻铂的方法
    • US06579796B2
    • 2003-06-17
    • US10013605
    • 2001-12-10
    • Chentsau YingJeng H. HwangLuc Van Autryve
    • Chentsau YingJeng H. HwangLuc Van Autryve
    • H01L21302
    • H01J37/32862H01L21/32136H01L21/32139Y10S438/905
    • Disclosed herein is a method of etching platinum using a silicon carbide mask. The method comprises providing an etch stack including a patterned silicon carbide layer overlying a layer of platinum, then pattern etching the platinum layer using a plasma generated from a source gas comprising Cl2, BCl3, and a nonreactive, diluent gas. The silicon carbide mask can be deposited and patterned using standard industry techniques, and can be easily removed without damaging either the platinum or an underlying doped substrate material. The method provides a smooth platinum etch profile and an etch profile angle of about 75° to about 90°. Also disclosed herein are methods of forming semiconductor structures useful in the preparation of DRAM and FeRAM cells.
    • 本文公开了使用碳化硅掩模蚀刻铂的方法。 该方法包括提供包括覆盖铂层的图案化碳化硅层的蚀刻堆叠,然后使用由包含Cl 2,BCl 3和非反应性稀释气体的源气体产生的等离子体来刻蚀铂层。 可以使用标准工业技术沉积和图案化碳化硅掩模,并且可以容易地去除碳化硅掩模,而不会损坏铂或下掺杂的衬底材料。 该方法提供平滑的铂蚀刻轮廓和约75°至约90°的蚀刻轮廓角。 本文还公开了形成用于制备DRAM和FeRAM单元的半导体结构的方法。
    • 3. 发明授权
    • Method of etching an anisotropic profile in platinum
    • 在铂中蚀刻各向异性轮廓的方法
    • US06749770B2
    • 2004-06-15
    • US09948028
    • 2001-09-05
    • Jeng H. HwangChentsau YingKang-Lie ChiangSteve S. Y. Mak
    • Jeng H. HwangChentsau YingKang-Lie ChiangSteve S. Y. Mak
    • C09K1300
    • H01L28/60C23F4/00H01L21/32136H01L21/32139
    • A method of etching a platinum electrode layer disposed on a substrate to produce a semiconductor device including a plurality of platinum electrodes. The method comprises heating the substrate to a temperature greater than about 150° C., and etching the platinum electrode layer by employing a plasma of an etchant gas comprising nitrogen and a halogen (e.g. chlorine), and a gas selected from the group consisting of a noble gas (e.g. argon), BCl3, HBr, SiCl4 and mixtures thereof. The substrate may be heated in a reactor chamber having a dielectric window including a deposit-receiving surface having a surface finish comprising a peak-to-valley roughness height with an average height value of greater than about 1000 Å.
    • 一种蚀刻设置在基板上的铂电极层的方法,以制造包括多个铂电极的半导体器件。 该方法包括将衬底加热到​​大于约150℃的温度,并且通过使用包含氮和卤素(例如氯)的蚀刻剂气体的等离子体和选自以下的气体来蚀刻铂电极层: 惰性气体(例如氩气),BCl 3,HBr,SiCl 4及其混合物。 衬底可以在具有介电窗口的反应器室中加热,所述电介质窗口包括具有表面光洁度的沉积物接收表面,所述沉积物接收表面包括具有大于约的平均高度值的峰 - 谷粗糙度高度。
    • 4. 发明授权
    • Iridium etchant methods for anisotropic profile
    • 各向异性铱刻蚀方法
    • US06265318B1
    • 2001-07-24
    • US09251633
    • 1999-02-17
    • Jeng H. HwangChentsau YingGuang Xiang JinSteve S. Y. Mak
    • Jeng H. HwangChentsau YingGuang Xiang JinSteve S. Y. Mak
    • H01L2100
    • H01L28/60C23F4/00H01L21/32136H01L21/32139
    • A method of etching an electrode layer (e.g., a platinum electrode layer or an iridium electrode layer) disposed on a substrate to produce a semiconductor device including a plurality of electrodes separated by a distance equal to or less than about 0.3 &mgr;m and having a profile equal to or greater than about 85°. The method comprises heating the substrate to a temperature greater than about 150° C., and etching the electrode layer by employing a high density inductively coupled plasma of an etchant gas comprising oxygen and/or chlorine, argon and a gas selected from the group consisting of BCl3, HBr, HCl and mixtures thereof. A semiconductor device having a substrate and a plurality of electrodes supported by the substrate. The electrodes have a dimension (e.g., a width) which include a value equal to or less than about 0.3 &mgr;m and a profile equal to or greater than about 85°.
    • 一种蚀刻设置在基板上的电极层(例如,铂电极层或铱电极层)的方法,以制造半导体器件,该半导体器件包括间隔等于或小于约0.3μm的多个电极,并具有轮廓 等于或大于约85°。 该方法包括将衬底加热到​​大于约150℃的温度,并且通过采用包含氧和/或氯,氩和选自以下的气体的气体的高密度电感耦合等离子体来蚀刻电极层: 的BCl 3,HBr,HCl及其混合物。 一种半导体器件,具有基板和由基板支撑的多个电极。 电极具有包括等于或小于约0.3μm的值和等于或大于约85°的轮廓的尺寸(例如,宽度)。
    • 5. 发明授权
    • Etching methods for anisotropic platinum profile
    • 各向异性铂型材蚀刻方法
    • US06323132B1
    • 2001-11-27
    • US09251826
    • 1999-02-17
    • Jeng H. HwangChentsau YingKang-Lie ChiangSteve S. Y. Mak
    • Jeng H. HwangChentsau YingKang-Lie ChiangSteve S. Y. Mak
    • H01L21302
    • H01L28/60C23F4/00H01L21/32136H01L21/32139
    • A method of etching a platinum electrode layer disposed on a substrate to produce a semiconductor device including a plurality of platinum electrodes. The method comprises heating the substrate to a temperature greater than about 150° C., and etching the platinum electrode layer by employing a plasma of an etchant gas comprising nitrogen and a halogen (e.g. chlorine), and a gas selected from the group consisting of a noble gas (e.g. argon), BCl3, HBr, SiCl4 and mixtures thereof. The substrate may be heated in a reactor chamber having a dielectric window including a deposit-receiving surface having a surface finish comprising a peak-to-valley roughness height with an average height value of greater than about 1000 Å.
    • 一种蚀刻设置在基板上的铂电极层的方法,以制造包括多个铂电极的半导体器件。 该方法包括将衬底加热到​​大于约150℃的温度,并且通过使用包含氮和卤素(例如氯)的蚀刻剂气体的等离子体和选自以下的气体来蚀刻铂电极层: 惰性气体(例如氩气),BCl 3,HBr,SiCl 4及其混合物。 衬底可以在具有介电窗口的反应器室中加热,所述电介质窗口包括具有表面光洁度的沉积物接收表面,所述沉积物接收表面包括具有大于约的平均高度值的峰 - 谷粗糙度高度。
    • 6. 发明授权
    • Plasma etching process for metals and metal oxides, including metals and metal oxides inert to oxidation
    • 金属和金属氧化物的等离子体蚀刻工艺,包括对氧化物惰性的金属和金属氧化物
    • US06541380B2
    • 2003-04-01
    • US09912579
    • 2001-07-24
    • Chentsau YingJeng H. Hwang
    • Chentsau YingJeng H. Hwang
    • H01L21302
    • H01L21/32139C23F4/00H01L21/32136H01L28/60
    • A method of etching a metal or metal oxide, including a platinum family metal or a platinum family metal oxide. A wafer is first provided which comprises: (a) a semiconductor substrate, (b) a metal or metal oxide layer over the semiconductor substrate, and (c) a titanium containing patterned mask layer having one or more apertures formed therein positioned over the metal or metal oxide layer. The metal or metal oxide is then etched through the apertures in the mask layer by a plasma etching step that uses plasma source gases comprising the following: (a) a gas that comprises one or more carbon-oxygen bonds (for example, CO gas or CO2 gas) and (b) a gas that comprises one or more chlorine atoms (for example, Cl2 gas, carbon tetrachloride gas, silicon tetrachloride gas or boron trichloride gas).
    • 一种蚀刻包括铂族金属或铂族金属氧化物的金属或金属氧化物的方法。 首先提供晶片,其包括:(a)半导体衬底,(b)半导体衬底上的金属或金属氧化物层,以及(c)在其上形成有一个或多个孔的含钛图案化掩模层,位于金属 或金属氧化物层。 然后通过使用等离子体源气体的等离子体蚀刻步骤,通过掩模层中的孔蚀刻金属或金属氧化物,所述等离子体源气体包括:(a)包含一个或多个碳 - 氧键的气体(例如,CO气体或 CO 2气体)和(b)包含一个或多个氯原子的气体(例如,Cl 2气体,四氯化碳气体,四氯化硅气体或三氯化硼气体)。