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    • 3. 发明申请
    • Etching solution for removal of oxide film, method for preparing the same, and method of fabricating semiconductor device
    • 用于去除氧化膜的蚀刻溶液,其制备方法以及制造半导体器件的方法
    • US20060183297A1
    • 2006-08-17
    • US11130030
    • 2005-05-16
    • Chang-Sup MunHyung-Ho KoWoo-Gwan ShimChang-Ki HongSang-Jun Choi
    • Chang-Sup MunHyung-Ho KoWoo-Gwan ShimChang-Ki HongSang-Jun Choi
    • H01L21/30H01L21/302H01L21/46
    • H01L21/31111H01L21/76224H01L28/40
    • Provided are an anionic surfactant-containing etching solution for removal of an oxide film, preparation methods thereof, and methods of fabricating a semiconductor device using the etching solution. The etching solution includes a hydrofluoric acid (HF), deionized water, and an anionic surfactant. The anionic surfactant is a compound in which an anime salt is added as a counter ion, as represented by R1—OSO3−HA+, R1—CO2−HA+, R1—PO42−(HA+)2, (R1)2—PO4−HA+, or R1—SO3−HA+ where R1 is a straight or branched hydrocarbon group of C4 to C22 and A is ammonia or amine. The etching solution provides a high etching selectivity ratio of an oxide film to a nitride film or a polysilicon film. Therefore, in a semiconductor device fabrication process such as a STI device isolation process or a capacitor formation process, when an oxide film is exposed together with a nitride film or a polysilicon film, the etching solution can be efficiently used in selectively removing only the oxide film.
    • 提供了一种用于去除氧化膜的含阴离子表面活性剂的蚀刻溶液,其制备方法以及使用该蚀刻溶液制造半导体器件的方法。 蚀刻溶液包括氢氟酸(HF),去离子水和阴离子表面活性剂。 阴离子表面活性剂是其中加入作为抗衡离子的动物盐的化合物,如R 1〜N 3 O 3 - R 1,R 2,R 1,R 1,...,R 1, (R 1)2 - - - - - (4)其中R 1,R 2, / SUB>)2 + 其中R 1是C 4的直链或支链烃基,其中R 1是直链或支链C 1 -C 4烷基, C 22和A是氨或胺。 蚀刻溶液提供氧化膜与氮化物膜或多晶硅膜的高蚀刻选择性比。 因此,在诸如STI器件隔离处理或电容器形成工艺的半导体器件制造工艺中,当氧化物膜与氮化物膜或多晶硅膜一起暴露时,可以有效地使用蚀刻溶液来仅选择性地除去氧化物 电影。
    • 4. 发明申请
    • ETCHING SOLUTION FOR REMOVAL OF OXIDE FILM, METHOD FOR PREPARING THE SAME, AND METHOD OF FABRICATING SEMICONDUCTOR DEVICE
    • 用于除去氧化膜的蚀刻溶液,其制备方法和制备半导体器件的方法
    • US20090023265A1
    • 2009-01-22
    • US12243728
    • 2008-10-01
    • CHANG-SUP MUNHyung-Ho KoWoo-Gwan ShimChang-Ki HongSang-Jun Choi
    • CHANG-SUP MUNHyung-Ho KoWoo-Gwan ShimChang-Ki HongSang-Jun Choi
    • H01L21/762H01L21/306H01L21/02
    • H01L21/31111H01L21/76224H01L28/40
    • Provided are an anionic surfactant-containing etching solution for removal of an oxide film, preparation methods thereof, and methods of fabricating a semiconductor device using the etching solution. The etching solution includes a hydrofluoric acid (HF), deionized water, and an anionic surfactant. The anionic surfactant is a compound in which an anime salt is added as a counter ion, as represented by R1—OSO3−HA+, R1—CO2−HA+,R1—PO42—(HA+)2,(R1)2—PO4—HA+, or R1—SO3—HA+ where R1 is a straight or branched hydrocarbon group of C4 to C22 and A is ammonia or amine. The etching solution provides a high etching selectivity ratio of an oxide film to a nitride film or a polysilicon film. Therefore, in a semiconductor device fabrication process such as a STI device isolation process or a capacitor formation process, when an oxide film is exposed together with a nitride film or a polysilicon film, the etching solution can be efficiently used in selectively removing only the oxide film.
    • 提供了一种用于去除氧化膜的含阴离子表面活性剂的蚀刻溶液,其制备方法以及使用该蚀刻溶液制造半导体器件的方法。 蚀刻溶液包括氢氟酸(HF),去离子水和阴离子表面活性剂。 阴离子表面活性剂是其中以R1-OSO3-HA +,R1-CO2-HA +,R1-PO42-(HA +)2,(R1)2-PO4-HA + 或R1-SO3-HA +,其中R1是C4至C22的直链或支链烃基,A是氨或胺。 蚀刻溶液提供氧化膜与氮化物膜或多晶硅膜的高蚀刻选择性比。 因此,在诸如STI器件隔离处理或电容器形成工艺的半导体器件制造工艺中,当氧化物膜与氮化物膜或多晶硅膜一起暴露时,可以有效地使用蚀刻溶液来仅选择性地除去氧化物 电影。
    • 6. 发明申请
    • Method for cleaning substrate having exposed silicon and silicon germanium layers and related method for fabricating semiconductor device
    • 用于清洁具有暴露的硅和锗锗层的衬底的方法和用于制造半导体器件的相关方法
    • US20070072431A1
    • 2007-03-29
    • US11527473
    • 2006-09-27
    • Chang-Sup MunWoo-Gwan ShimHan-Ku ChoChang-Ki HongDoo-Won Kwon
    • Chang-Sup MunWoo-Gwan ShimHan-Ku ChoChang-Ki HongDoo-Won Kwon
    • H01L21/302H01L21/461
    • H01L21/02057H01L21/02082
    • A method for cleaning a substrate on which a silicon layer and a silicon germanium layer are formed and exposed, and method for fabricating a semiconductor device using the cleaning method are disclosed. The cleaning method comprises preparing a semiconductor substrate on which a silicon layer and a silicon germanium layer are formed and exposed; and performing a first cleaning sub-process that uses a first cleaning solution to remove a native oxide layer from the semiconductor substrate. The cleaning method further comprises performing a second cleaning sub-process on the semiconductor substrate after performing the first cleaning sub-process, wherein the second cleaning sub-process comprises using a second cleaning solution. In addition, the second cleaning solution comprises ammonium hydroxide (NH4OH), hydrogen peroxide (H2O2), and deionized water (H2O), and the second cleaning solution comprises at least 200 times more deionized water (H2O) than ammonium hydroxide (NH4OH) by volume.
    • 公开了一种用于清洁其上形成和暴露硅层和硅锗层的衬底的方法,以及使用该清洁方法制造半导体器件的方法。 该清洗方法包括:制备半导体衬底,在其上形成和暴露硅层和硅锗层; 以及执行使用第一清洁溶液从半导体衬底去除自然氧化物层的第一清洁子过程。 清洁方法还包括在执行第一清洁子过程之后在半导体衬底上执行第二清洁子处理,其中第二清洁子处理包括使用第二清洁溶液。 此外,第二清洗溶液包括氢氧化铵(NH 4 OH),过氧化氢(H 2 O 2 O 2)和去离子水( H 2 O),并且第二清洁溶液包含比氢氧化铵(NH 4 O 2)少至少200倍的去离子水(H 2 O 2 O) OH)。
    • 7. 发明授权
    • Method for cleaning substrate having exposed silicon and silicon germanium layers and related method for fabricating semiconductor device
    • 用于清洁具有暴露的硅和锗锗层的衬底的方法和用于制造半导体器件的相关方法
    • US07344999B2
    • 2008-03-18
    • US11527473
    • 2006-09-27
    • Chang-Sup MunWoo-Gwan ShimHan-Ku ChoChang-Ki HongDoo-Won Kwon
    • Chang-Sup MunWoo-Gwan ShimHan-Ku ChoChang-Ki HongDoo-Won Kwon
    • H01L21/302
    • H01L21/02057H01L21/02082
    • A method for cleaning a substrate on which a silicon layer and a silicon germanium layer are formed and exposed, and method for fabricating a semiconductor device using the cleaning method are disclosed. The cleaning method comprises preparing a semiconductor substrate on which a silicon layer and a silicon germanium layer are formed and exposed; and performing a first cleaning sub-process that uses a first cleaning solution to remove a native oxide layer from the semiconductor substrate. The cleaning method further comprises performing a second cleaning sub-process on the semiconductor substrate after performing the first cleaning sub-process, wherein the second cleaning sub-process comprises using a second cleaning solution. In addition, the second cleaning solution comprises ammonium hydroxide (NH4OH), hydrogen peroxide (H2O2), and deionized water (H2O), and the second cleaning solution comprises at least 200 times more deionized water (H2O) than ammonium hydroxide (NH4OH) by volume.
    • 公开了一种用于清洁其上形成和暴露硅层和硅锗层的衬底的方法,以及使用该清洁方法制造半导体器件的方法。 该清洗方法包括:制备半导体衬底,在其上形成和暴露硅层和硅锗层; 以及执行使用第一清洁溶液以从半导体衬底去除自然氧化物层的第一清洁子过程。 清洁方法还包括在执行第一清洁子过程之后在半导体衬底上执行第二清洁子处理,其中第二清洁子处理包括使用第二清洁溶液。 此外,第二清洗溶液包括氢氧化铵(NH 4 OH),过氧化氢(H 2 O 2 O 2)和去离子水( H 2 O),并且第二清洁溶液包含比氢氧化铵(NH 4 O 2)少至少200倍的去离子水(H 2 O 2 O) OH)。