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1. 发明专利

JP2005200226A Environmentally resistant film material, film structure and ceramic structure using the same 有权
标题翻译：环保膜材料，膜结构和使用其的陶瓷结构
公开(公告)号：JP2005200226A
公开(公告)日：2005-07-28
申请号：JP2004005216
申请日：2004-01-13
申请人： Central Res Inst Of Electric Power Ind , National Institute Of Advanced Industrial & Technology , 独立行政法人産業技術総合研究所 , 財団法人電力中央研究所
发明人： HISAMATSU NOBORU , YURI ISAO , UENO SHUNKICHI , OJI TATSUKI , KANZAKI SHUZO
IPC分类号： F01D5/28 , B32B9/00 , C04B35/00 , C04B35/48 , C04B35/486 , C04B41/52 , C04B41/89 , F02C7/00
CPC分类号： C04B35/486 , C04B35/481 , C04B41/009 , C04B41/52 , C04B41/89 , C04B2111/00405 , C04B2235/3224 , C04B2235/3225 , C04B2235/3418 , C04B2235/75 , C04B2235/9684 , F01D5/288 , F05D2230/31 , F05D2300/5021 , C04B41/4539 , C04B41/4556 , C04B41/5024 , C04B41/5035 , C04B41/4826 , C04B35/565 , C04B35/584
摘要： PROBLEM TO BE SOLVED: To manufacture an environmentally resistant film or structure which protects e.g. a gas turbine member from undergoing corrosion and thickness reduction even in an environment in which the member is exposed to a high-speed steam-containing gas stream at a temperature as high as 1,300°C or above. SOLUTION: The environmentally resistant film material comprises at least one member selected from the group consisting of hafnia, hafnia containing zirconia, and hafnia containing hafnia or zirconia stabilized with a rare earth oxide and/or silica. The environmentally resistant film structure is a film structure covering a support having a low coefficient of thermal expansion, wherein hafnon (HfSiO 4 ) is a first layer 2 directly formed on a support 1, and hafnia is formed thereon as a second layer 3. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：制造环境保护膜或结构，其保护例如即使在高达1300℃或更高的温度下将构件暴露于含有高速含蒸汽的气流的环境中，也能够进行腐蚀和厚度减小的燃气涡轮机构件。解决方案：环境保护膜材料包括选自由铪，含铪的氧化锆和含有铪的铪或由稀土氧化物和/或二氧化硅稳定的氧化锆的至少一种。环境保护膜结构是覆盖热膨胀系数低的载体的膜结构，其中，铪（HfSiO 4 SBB）是直接形成在载体1上的第一层2，并且在其上形成有铪作为第二层。3.版权所有（C）2005，JPO＆NCIPI

2. 发明专利

JP2006252982A Fuel cell equipped with heat shielding container 有权
标题翻译：燃料电池装有热屏蔽容器
公开(公告)号：JP2006252982A
公开(公告)日：2006-09-21
申请号：JP2005068586
申请日：2005-03-11
申请人： Central Res Inst Of Electric Power Ind , 財団法人電力中央研究所
发明人： OTAKA MADOKA , ABE TOSHIO , HISAMATSU NOBORU , ETORI YOSHIYUKI
IPC分类号： H01M8/04 , H01M8/02 , H01M8/12
CPC分类号： Y02E60/525
摘要： PROBLEM TO BE SOLVED: To enable to handle safely a power generator by granting a heat exchange function to a container itself housing a power generating stack having an exothermic portion of a fuel cell, and by removing excess heat from the power generator, while maintaining the power generating equipment such as a stack in high temperature without deteriorating power generation efficiency.
SOLUTION: The stack 5 is mainly constructed of a heat shielding container 3 which is formed in lamination of an outer case material 23 made of a metallic wall 22 having ventilation holes 21 communicating between the outside and inside opened at a plurality of places in order to house a ceramic burner 6 and a ceramic heat exchanger 7 or the like and a porous material 24 having ventilation capacity arranged inside the metallic wall 22, and a heat exchange gap 25 at the surrounding of the stack 5. Cooling air is introduced from each ventilation hole 21 of the heat shield container 3 and the cooling air is circulated in the heat exchange gap 25, and the reaction heat generated in the stack 5 is heat exchanged.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了能够通过向容纳本体的容器本身赋予热交换功能来安全地处理发电机，该容器本身容纳具有燃料电池的放热部分的发电堆，并且通过从发电机去除多余的热量，同时在高温下保持诸如堆叠的发电设备，而不会降低发电效率。解决方案：堆叠5主要由隔热容器3构成，该隔热容器3层压由金属壁22制成的外壳材料23，金属壁22具有在多个位置在外部和内部之间连通的通风孔21 为了容纳陶瓷燃烧器6和陶瓷热交换器7等，并且具有布置在金属壁22内部的通气量的多孔材料24和在堆叠5的周围的热交换间隙25.引入冷却空气从隔热容器3的各个通气孔21和冷却空气在热交换间隙25中循环，并且在堆叠5中产生的反应热进行热交换。版权所有（C）2006，JPO＆NCIPI

3. 发明专利

JP2006097042A Heat resistant member having thermal barrier coating and gas turbine 有权
标题翻译：具有热障涂层和气体涡轮的耐热构件
公开(公告)号：JP2006097042A
公开(公告)日：2006-04-13
申请号：JP2004281377
申请日：2004-09-28
申请人： Central Res Inst Of Electric Power Ind , Hitachi Ltd , 株式会社日立製作所 , 財団法人電力中央研究所
发明人： ARIKAWA HIDEYUKI , MEHATA TERU , KOJIMA YOSHIYUKI , ICHIKAWA KUNIHIRO , YOSHIOKA TAKAYUKI , OKADA MITSUTOSHI , HISAMATSU NOBORU
IPC分类号： C23C4/06 , C22C19/00 , C23C4/10 , C23C28/00 , F01D5/28 , F02C7/00
CPC分类号： C23C28/321 , C23C28/3215 , C23C28/345 , C23C28/3455 , F01D5/288 , F05D2230/90 , F05D2300/611 , Y02T50/67 , Y02T50/671 , Y10T428/12611 , Y10T428/12618 , Y10T428/12847 , Y10T428/12931 , Y10T428/12937 , Y10T428/12944
摘要： PROBLEM TO BE SOLVED: To provide a heat resistant member provided with a thermal barrier coating which has excellent durability and usable, e.g., for a gas turbine and an aircraft engine having extremely high driving temperature. SOLUTION: In the heat resistant member, the surface of a heat resistant alloy base material 1 essentially consisting of at least one selected from Ni and Co is provided with a thermal barrier layer 3 composed of ceramics via a bonding layer of an alloy substantially consisting of at least one selected from Ni and Co, Cr and Al. The alloy in the bonding layer can comprise at least one kind selected from the group consisting of Ta, Cs, W, Si, Pt, Mn and B in the range of 0 to 20 wt.%. In the heat resistant member, the durability of the thermal barrier ceramic layer is extremely excellent, and its peeling damage is hard to occur. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种耐热构件，该耐热构件具有优异的耐久性和可用的热障涂层，例如用于具有极高驱动温度的燃气轮机和飞机发动机。解决方案：在耐热构件中，基本上由选自Ni和Co中的至少一种的耐热合金基材1的表面设置有由陶瓷经由合金的接合层构成的热障层3 基本上由选自Ni和Co，Cr和Al中的至少一种组成。接合层中的合金可以包含0至20重量％范围内的选自Ta，Cs，W，Si，Pt，Mn和B中的至少一种。在耐热构件中，隔热陶瓷层的耐久性非常优异，并且难以发生剥离损伤。版权所有（C）2006，JPO＆NCIPI

4. 发明专利

JP2004175627A Corrosion-resistant ceramic 有权
公开(公告)号：JP2004175627A
公开(公告)日：2004-06-24
申请号：JP2002344793
申请日：2002-11-28
申请人： Central Res Inst Of Electric Power Ind , Kyocera Corp , 京セラ株式会社 , 財団法人電力中央研究所
发明人： YURI ISAO , HISAMATSU NOBORU , TSURUZONO SUKEZOU , FUKUTOME TAKEO
IPC分类号： C04B35/584 , C04B41/89
摘要： PROBLEM TO BE SOLVED: To provide high corrosion-resistant ceramics that have high anti-steam corrosiveness to high temperature steam at a high temperature range of 1,000°C or higher and that have a long product life. SOLUTION: The corrosion-resistant ceramics are constituted from a ceramic substrate 1, a corrosion-resistant ceramic layer 2 formed on the surface of the ceramic substrate 1 and a surface protective layer 3 formed on the corrosion-resistant ceramic layer 2. The corrosion-resistant ceramic layer 2 is formed from a plurality of die silicate layers 2a, 2b obtained from disilicate crystals of 3a group elements in the periodic table which are different from each other. The surface protective layer 3 is constituted from a zirconium oxide stabilized by the group 3a element in the periodic table. Further, each of the thermal expansion coefficients of the ceramic substrate 1, a plurality of die silicate layer 2a, 2b to form the corrosion-resistant ceramic layer 2 and the surface protective layer is structured so that each is arranged in a gradient state from the ceramic substrate toward the surface protective layer. COPYRIGHT: (C)2004,JPO

5. 发明专利

JP2006028002A Corrosion-resistant silicon nitride ceramic 有权
标题翻译：耐腐蚀氮化硅陶瓷
公开(公告)号：JP2006028002A
公开(公告)日：2006-02-02
申请号：JP2004275135
申请日：2004-09-22
申请人： Central Res Inst Of Electric Power Ind , Kyocera Corp , 京セラ株式会社 , 財団法人電力中央研究所
发明人： FUKUTOME TAKEO , TSURUZONO SUKEZOU , YURI ISAO , HISAMATSU NOBORU
IPC分类号： C04B41/89
CPC分类号： C04B35/584 , C04B35/16 , C04B35/486 , C04B35/6303 , C04B41/009 , C04B41/52 , C04B41/89 , C04B2235/3206 , C04B2235/3224 , C04B2235/3225 , C04B2235/3244 , C04B2235/3289 , C04B2235/3418 , C04B2235/3463 , C04B2235/3481 , C04B2235/72 , C04B2235/77 , C04B2235/9607 , F01D5/288 , F05D2300/21 , F05D2300/2283 , C04B41/4539 , C04B41/5024 , C04B41/5037 , C04B41/5042 , C04B41/524
摘要： PROBLEM TO BE SOLVED: To provide corrosion resistant silicon nitride ceramic which prevents a coating layer mounted on a substrate from exfoliating even under an environment in which a heat cycle occurs like with a thermal engine.
SOLUTION: The corrosion resistant silicon nitride ceramic is constituted by laminating an adhesion acceleration layer 3, a stress relaxation layer 4 and a crack progression prevention layer 5 in this order a ceramic substrate 2 composed of a silicon nitride as a principal component, and laminating a surface corrosion resistance layer 6 composed of zirconium oxide stabilized by a periodic table group 3a element thereon, wherein the coefficient of thermal expansion α
0 of the ceramic substrate 2, the coefficient of thermal expansion α
1 of the adhesion acceleration layer 3, the coefficient of thermal expansion α
2 of the stress relaxation layer 4, the coefficient of thermal expansion α
3 of the crack progression prevention layer 5, and the coefficient of thermal expansion α
4 of the surface corrosion resistance layer 6 satisfy relational expressions (I) to (III).
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供耐腐蚀性氮化硅陶瓷，即使在与热发动机相似的热循环的环境中也能防止安装在基板上的涂层脱落。＆lt; P＆gt;解决方案：耐蚀氮化硅陶瓷通过依次层叠粘附加速层3，应力松弛层4和裂纹进展防止层5构成，该陶瓷基板2由以氮化硅为主要成分构成，将由周期表第3a族元素稳定的氧化锆构成的表面耐腐蚀层6层叠在陶瓷基板2的热膨胀系数α 0 ，热膨胀系数α< 粘合加速层3的SB> 1 ，应力松弛层4的热膨胀系数α 2 ，热膨胀系数α 3 表面耐腐蚀层6的裂纹进展防止层5和热膨胀系数α 4 满足关系式（I）〜（III）。版权所有（C）2006，JPO＆NCIPI

6. 发明专利

JP2004045342A Temperature inferring method, metal element content prediction method, and metal element content decline time prediction method of corrosion resistance coating 有权
公开(公告)号：JP2004045342A
公开(公告)日：2004-02-12
申请号：JP2002206196
申请日：2002-07-15
申请人： Central Res Inst Of Electric Power Ind , 財団法人電力中央研究所
发明人： OKADA MITSUTOSHI , ETORI YOSHIYUKI , HISAMATSU NOBORU , TAKAHASHI TAKESHI
IPC分类号： G01N23/225 , C22C19/07 , G01N17/00
摘要： PROBLEM TO BE SOLVED: To provide a temperature inferring method of a corrosion resistance coating of a high-temperature member capable of grasping the surface temperature without actual measurement, and a metal element content prediction method and a metal element content decline time prediction method of the corrosion resistance coating. SOLUTION: In this method, the diffusion layer thickness from the surface of the corrosion resistance coating where diffusion processing of a metal element applied to the base material surface is applied to the interface between the corrosion resistance coating and the base material is determined by analyzing a plurality of portions of an actual machine, and the correlation between the interference diffusion layer thickness and the metal element content in the corrosion resistance coating is determined, and the metal element content is predicted based on the correlation. The time until the metal element content in the corrosion resistance coating declines up to the same level of the metal element content in the base material is predicted by using the correlation. A growth behavior of the interference diffusion layer is grasped by performing a heating test, and the correlation between the diffusion layer thickness and the temperature is determined, thereby inferring the temperature at the using time. COPYRIGHT: (C)2004,JPO

7. 发明专利

JP2011027602A Creation method of temperature estimation expression of coating component 有权
标题翻译：涂料组分温度估计表征的创建方法
公开(公告)号：JP2011027602A
公开(公告)日：2011-02-10
申请号：JP2009174829
申请日：2009-07-27
申请人： Central Res Inst Of Electric Power Ind , 財団法人電力中央研究所
发明人： OKADA MITSUTOSHI , HISAMATSU NOBORU , FUJIOKA TERUTAKA
IPC分类号： G01N17/00
摘要： PROBLEM TO BE SOLVED: To provide a creation method of a temperature estimation expression for estimating a temperature of a coating component inexpensively, easily and highly accurately, based on a state of a structure change of a coating on a high temperature component to which a corrosion resistance coating or a thermal barrier coating is applied.
SOLUTION: A test portion which is a portion wherein a structure change is not recognized in a coating on a used component in an actual machine is predetermined, and a test piece is prepared from the test portion, and the test piece is heated at a prescribed temperature for a prescribed time by a heating means. Then, a thickness of a portion wherein a structure of the coating on the test piece is changed is detected, and the temperature estimation expression for estimating the temperature of the coating member is generated, based on the thickness, in which a thickness of the portion wherein the structure of the coating on the coating component whose temperature is to be estimated is changed, and an operation time of the actual machine having the coating component are treated as unknowns.
COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：解决的问题：提供一种用于基于高温部件上的涂层的结构变化的状态容易且高精度地估计涂料组分的温度的温度估计表达式的创建方法，其中施加耐腐蚀涂层或热障涂层。＆lt; P＆gt;解决方案：预先确定在实际机器中使用的部件上的涂层中不发现结构变化的部分的试验部，从试验部准备试验片，将试验片加热在规定温度下通过加热机构规定时间。然后，检测其中测试片上的涂层的结构发生变化的部分的厚度，并且基于厚度来产生用于估计涂层部件的温度的温度估计表达式，其中厚度部分其特征在于，涂布部件上涂布温度要被估计的涂层结构发生变化，具有涂层成分的实际机器的操作时间被视为未知数。版权所有（C）2011，JPO＆INPIT

8. 发明专利

JP2009299192A Heat resistant member having thermal barrier coating and gas turbine 有权
标题翻译：具有热障涂层和气体涡轮的耐热构件
公开(公告)号：JP2009299192A
公开(公告)日：2009-12-24
申请号：JP2009218458
申请日：2009-09-24
申请人： Central Res Inst Of Electric Power Ind , Hitachi Ltd , 株式会社日立製作所 , 財団法人電力中央研究所
发明人： ARIKAWA HIDEYUKI , MEHATA TERU , KOJIMA YOSHIYUKI , ICHIKAWA KUNIHIRO , YOSHIOKA TAKAYUKI , OKADA MITSUTOSHI , HISAMATSU NOBORU
IPC分类号： C23C4/06 , C23C4/10 , C23C28/00 , F01D5/28 , F01D25/00 , F02C7/00
CPC分类号： Y02T50/67
摘要： PROBLEM TO BE SOLVED: To provide a heat resistant member provided with a thermal barrier coating which has excellent durability and usable, e.g. for a gas turbine and an aircraft engine having extremely high driving temperature. SOLUTION: In the heat resistant member, a thermal barrier layer 3 composed of ceramics via a bonding layer 2 of an alloy substantially consisting of at least one selected from Ni and Co, Cr and Al is provided on the surface of a heat resistant alloy base material 1 essentially consisting of at least one selected from Ni and Co. The alloy in the bonding layer can comprise at least one selected from the group consisting Ta, W, Si, Pt, Mn and B in the range of 0 to 20 wt.%. In the heat resistant member, the durability of the thermal barrier ceramic layer is extremely excellent, and its peeling damage is hard to occur. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种耐热构件，其设置有耐热性优异的耐热性涂层，例如耐热性。对于具有极高驱动温度的燃气轮机和飞机发动机。解决方案：在耐热构件中，通过基本上由选自Ni和Co，Cr和Al中的至少一种的合金的接合层2的陶瓷构成的热障层3设置在热表面上基本上由选自Ni和Co中的至少一种的耐碱合金基材1组成。接合层中的合金可以包括选自Ta，W，Si，Pt，Mn和B中的至少一种，其范围为0至 20重量％。在耐热构件中，热障陶瓷层的耐久性极好，难以发生剥离损伤。版权所有（C）2010，JPO＆INPIT

9. 发明专利

JP2008014748A Life control method of heat barrier coating 有权
标题翻译：热障涂层的寿命控制方法
公开(公告)号：JP2008014748A
公开(公告)日：2008-01-24
申请号：JP2006185240
申请日：2006-07-05
申请人： Central Res Inst Of Electric Power Ind , 財団法人電力中央研究所
发明人： OKADA MITSUTOSHI , HISAMATSU NOBORU
IPC分类号： G01N17/00 , F01D5/28 , F01D25/00 , F02C7/00
摘要： PROBLEM TO BE SOLVED: To provide a life control method of heat barrier coating capable of efficiently controlling the life of a high-temperature part by precisely estimating a deterioration state with respect to the high-temperature part equipped with TBC. SOLUTION: In the life control method of the heat barrier coating formed by applying a bond coating layer, which comprises an interfacial oxide forming metal-containing alloy, and a topcoating layer comprising ceramics to the surface of the base material of the high-temperature part, the correlation of the heating time and heating temperature of the high-temperature part with a change in the content of the interfacial oxide forming metal in the bond coating layer of the high-temperature part is calculated to measure the average content of an interfacial oxide forming metal in the bond coating layer of the heat barrier coating at a predetermined region of the high-temperature part used in an actual machine. The life of the heat barrier coating is estimated from this measured value and the correlation. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：解决的问题：提供一种能够通过精确地估计相对于配备有TBC的高温部件的劣化状态来有效地控制高温部件的寿命的隔热涂层的寿命控制方法。解决方案：在通过将包含界面氧化物形成含金属的合金的粘合涂层和包含陶瓷的表面涂层形成在所述耐高温涂层的基材的表面上形成的隔热涂层的寿命控制方法中，温度部分，计算出高温部分的加热时间和加热温度与高温部分的接合涂层中界面氧化物形成金属含量变化的相关性，以测量高温部分的接合涂层中的平均含量在实际机器中使用的高温部件的预定区域处的隔热涂层的接合涂层中的界面氧化物形成金属。从该测量值和相关性估计隔热涂层的寿命。版权所有（C）2008，JPO＆INPIT

10. 发明专利

JP2006124226A Ceramic part for corrosion-resistant gas turbine 有权
标题翻译：陶瓷部件耐腐蚀气体涡轮机
公开(公告)号：JP2006124226A
公开(公告)日：2006-05-18
申请号：JP2004313756
申请日：2004-10-28
申请人： Central Res Inst Of Electric Power Ind , Kyocera Corp , 京セラ株式会社 , 財団法人電力中央研究所
发明人： FUKUTOME TAKEO , TSURUZONO SUKEZOU , YURI ISAO , HISAMATSU NOBORU
IPC分类号： C04B41/89 , C04B35/48 , C04B35/584 , C04B41/87 , F01D5/28 , F02C7/00 , F23R3/42
摘要： PROBLEM TO BE SOLVED: To provide a ceramic part for a corrosion-resistant gas turbine capable of restraining the consumption by corrosion even if used at a part where the combustion gas of a gas turbine directly comes in contact, and capable of preventing the release of coating layer located on a substrate even if exposed to the heat cycle environment in the gas turbine. SOLUTION: This is a ceramic part for corrosion-resistant gas turbine used at a part where the combustion gas of the gas turbine directly comes in contact, and it is a laminate of a ceramic substrate 2 mainly composed of silicon nitride, a close adhesion promoting layer 3, a stress relaxation layer 4, a crack development preventive layer 5, and a surface corrosion-resistant layer 6 mainly composed of zirconia stabilized with a group 3a element of the periodical table in this order from the bottom, and the coefficients of thermal expansion of each layers have a certain relation. COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：为了提供一种用于耐腐蚀燃气轮机的陶瓷部件，其能够在燃气轮机的燃烧气体直接接触的部分使用时能够抑制腐蚀消耗，并且能够防止即使暴露于燃气轮机中的热循环环境，也释放位于基板上的涂层。解决方案：这是在燃气轮机的燃烧气体直接接触的部分使用的耐腐蚀燃气轮机的陶瓷部件，是主要由氮化硅构成的陶瓷基板2的层叠体，紧密附着促进层3，应力缓和层4，裂纹展开防止层5和主要由周期表的第3a族元素稳定的氧化锆构成的表面耐腐蚀层6从底部开始，每层的热膨胀系数有一定关系。版权所有（C）2006，JPO＆NCIPI

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