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    • 1. 发明申请
    • Top electrode in a strongly oxidizing environment
    • 顶极电极处于强氧化环境
    • US20070069270A1
    • 2007-03-29
    • US11398498
    • 2006-04-04
    • Cem BasceriHoward RhodesGurtej SandhuF. GealyThomas Graettinger
    • Cem BasceriHoward RhodesGurtej SandhuF. GealyThomas Graettinger
    • H01L29/94
    • H01L28/65H01L21/31637H01L21/31691H01L23/5222H01L27/10852H01L28/56H01L28/60H01L2924/0002H01L2924/00
    • An improved charge storing device and methods for providing the same, the charge storing device comprising a conductor-insulator-conductor (CIC) sandwich. The CIC sandwich comprises a first conducting layer deposited on a semiconductor integrated circuit. The CIC sandwich further comprises a first insulating layer deposited over the first conducting layer in a flush manner. The first insulating layer comprises a structure having a plurality of oxygen cites and a plurality of oxygen atoms that partially fill the oxygen cites, wherein the unfilled oxygen cites define a concentration of oxygen vacancies. The CIC sandwich further comprises a second conducting layer deposited over the first insulating layer in a strongly oxidizing ambient so as to reduce the concentration of oxygen vacancies in the first insulating layer, so as to provide an oxygen-rich interface layer between the first insulating layer and the second conducting layer, and so as to trap a plurality of oxygen atoms within the second conducting layer. The oxygen-rich interface layer and second conducting layer act as oxygen vacancy sinks for absorbing migrating oxygen vacancies that originate from the first insulating layer to thereby reduce the concentration of oxygen vacancies in the first insulating layer and to thereby reduce the buildup of oxygen vacancies at the interface layer. Thus, the first insulating layer provides an increased dielectric constant and an increased resistance to current flowing therethrough so as to increase the capacitance of the CIC sandwich and so as to reduce leakage currents flowing through the CIC sandwich.
    • 一种改进的电荷存储装置及其提供方法,电荷存储装置包括导体 - 绝缘体导体(CIC)三明治。 CIC夹层包括沉积在半导体集成电路上的第一导电层。 CIC夹层还包括以齐平方式沉积在第一导电层上的第一绝缘层。 第一绝缘层包括具有多个氧化物和部分填充氧化物的多个氧原子的结构,其中未填充的氧气定义氧空位的浓度。 CIC夹层还包括在强氧化环境中沉积在第一绝缘层上的第二导电层,以便降低第一绝缘层中氧空位的浓度,从而在第一绝缘层之间提供富氧界面层 和第二导电层,以便在第二导电层内捕获多个氧原子。 富氧界面层和第二导电层用作氧空位吸收器,用于吸收源于第一绝缘层的迁移氧空位,从而降低第一绝缘层中氧空位的浓度,从而减少氧空位的累积 接口层。 因此,第一绝缘层提供增加的介电常数和增加的电流流过其中,从而增加CIC夹层的电容,并且减少流过CIC夹层的漏电流。
    • 3. 发明申请
    • Constructions comprising hafnium oxide
    • 包含氧化铪的构造
    • US20060249778A1
    • 2006-11-09
    • US11485592
    • 2006-07-11
    • Cem BasceriF. GealyGurtej Sandhu
    • Cem BasceriF. GealyGurtej Sandhu
    • H01L29/94H01L29/00
    • H01G4/33H01G4/1209H01G4/1272H01L21/31645H01L27/10852H01L28/60H01L28/65H01L28/90H01L28/91H01L29/7833
    • The invention includes methods of forming hafnium-containing materials, such as, for example, hafnium oxide. In one aspect, a semiconductor substrate is provided, and first reaction conditions are utilized to form hafnium-containing seed material in a desired crystalline phase and orientation over the substrate. Subsequently, second reaction conditions are utilized to grow second hafnium-containing material over the seed material. The second hafnium-containing material is in a crystalline phase and/or orientation different from the crystalline phase and orientation of the hafnium-containing seed material. The second hafnium-containing material can be, for example, in an amorphous phase. The seed material is then utilized to induce a desired crystalline phase and orientation in the second hafnium-containing material. The invention also includes capacitor constructions utilizing hafnium-containing materials, and circuit assemblies comprising the capacitor constructions.
    • 本发明包括形成含铪材料的方法,例如氧化铪。 在一个方面,提供了半导体衬底,并且利用第一反应条件来形成在衬底上所需的结晶相和取向的含铪种子材料。 随后,利用第二反应条件在种子材料上生长第二含铪材料。 第二含铪材料处于与含铪种子材料的结晶相和取向不同的结晶相和/或取向。 第二含铪材料可以是例如非晶相。 然后将种子材料用于在第二含铪材料中诱导所需的结晶相和取向。 本发明还包括使用含铪材料的电容器结构和包括电容器结构的电路组件。