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    • 3. 发明申请
    • PREPARATION OF 157NM TRANSMITTING BARIUM FLUORIDE CRYSTALS WITH PERMEABLE GRAPHITE
    • 用透明石墨制备157纳米发射的氟化镁晶体
    • WO2002079549A2
    • 2002-10-10
    • PCT/US2002/009803
    • 2002-03-28
    • CORNING INCORPORATED
    • MEYER-FREDHOLM, Michèle, M., L.PELL, Michael, A.
    • C30B
    • C30B11/002C30B11/00C30B29/12
    • The object of the present invention is a process of preparing an optical fluoride crystal containing barium fluoride , which comprises : loading a crucible with a barium fluoride starting material crystal feedstock which contains at least one oxide as impurity, and an effective and non-excess amount of at least one fluorinating agent which is solid at ambient temperature, melting said mixture within said crucible, growing the crystal, by controlled cooling of the molten mixture, controlled cooling of said crystal to ambient temperature, recovering said crystal; and which is characterised in that the oxide(s) resulting from the reaction between said fluorinating agent(s) and said oxide(s), the impurity or impurities, can be discharged from said crucible, in view of the intrinsic permeability of the material constituting it. Said process is particularly adapted for preparing 157nm transmitting lithography excimer laser optical fluoride crystals in graphite crucibles.
    • 本发明的目的是制备含有氟化钡的氟化物晶体的方法,该方法包括将含有至少一种氧化物杂质的钡氟原料晶体原料装载在坩埚中,并且将有效和不过量的 至少一种氟化剂,其在环境温度下为固体,熔化所述坩埚内的所述混合物,通过熔融混合物的受控冷却使晶体生长,将所述晶体控制冷却至环境温度,回收所述晶体; 其特征在于,考虑到材料的固有渗透性,从所述氟化剂和所述氧化物之间的反应产生的氧化物,杂质或杂质可以从所述坩埚中排出 构成它。 所述方法特别适用于在石墨坩埚中制备157nm透射光刻准分子激光氟化物晶体。