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    • 4. 发明专利
    • DE19849702A1
    • 2000-05-04
    • DE19849702
    • 1998-10-28
    • SUEDDEUTSCHE KALKSTICKSTOFF
    • INGRISCH STEFANMAIER ALOISWINKELMANN HERBERTWOLFERTSTETTER FRANZKERN ALFREDWEICHMANN JOSEF
    • C08F283/00C08G18/08C08G18/12C08G18/66C09D175/06C08G18/10C08G18/67C08L75/04
    • The invention relates to hybrid polyurethane-polymer dispersion with high film hardness, characterized in that it contains the following conversion components: (A) 3 to 25 % by weight of a polyol consisting of (i) 2 to 20 % by weight of a high-molecular weight polyol; (ii) 0.5 to 5 % by weight of a low-molecular weight polyol; (iii) 0.5 to 3 % by weight of a low-molecular weight and anionically modifiable polyol; (B) 2 to 20 % by weight of a polyisocyanate; (C) optionally 0 to 6 % by weight of a solvent consisting of: (i) at least one organic solvent that is inert in relation to a polyisocyanate and/or (ii) a reactive thinner that is inert in relation to polyisocyanates; (D) 0.15 to 1.5 % by weight of a neutralizer; (E) 0.1 to 1 % by weight of a chain extender; (F) 5 to 40 % by weight of a monomer; (G) 0.01 to 1.5 % by weight of an initiator, the remainder consisting of water. The advantages provided by the hybrid polyurethane-polymer dispersion according to the invention such as great hardness and high flexibility of the crackless films, good resistance to chemicals, great stability of the dispersion over a wide pH range, good freeze-thaw stability and the utilization of cost-effective raw materials, are achieved in a simplified synthesis pathway without subsequent chemical cross-linking and with a low content in organic solvent ( /= +10 DEG C.